UN No. Proper shipping name (PSN) Class or division Subsidiary hazard(s) Packing group Special provisions Limited and excepted quantity provisions Packing IBC Portable tanks and bulk containers EmS Stowage and handling Segregation Properties and observations UN No.
Limited quantities Excepted quantities Instructions Provisions Instructions Provisions Tank instructions Provisions
(1) (2) 3.1.2 (3) 2.0 (4) 2.0 (5) 2.0.1.3 (6) 3.3 (7a) 3.4 (7b) 3.5 (8) 4.1.4 (9) 4.1.4 (10) 4.1.4 (11) 4.1.4 (12) (13) 4.2.5 4.3 (14) 4.2.5 (15) 5.4.3.4 7.8 (16a) 7.1 7.37.7 (16b) 7.27.7 (17) (18)
0004 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) PP26 F-B, S-Y Category 04 SW1 SGG2 SG27 SG31 Substance. 0004
0005 CARTRIDGES FOR WEAPONS with bursting charge 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0005
0006 CARTRIDGES FOR WEAPONS with bursting charge 1.1E 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0006
0007 CARTRIDGES FOR WEAPONS with bursting charge 1.2 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0007
0009 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 1.2G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0009
0010 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 1.3G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0010
0012 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 1.4S 364 5 kg E0 P130 LP101 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0012
0014 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK or CARTRIDGES FOR TOOLS, BLANK 1.4S 364 5 kg E0 P130 LP101 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0014
0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 1.2G See SP204 204 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0015
0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 1.3G See SP204 204 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0016
0018 AMMUNITION, TEAR- PRODUCING with burster, expelling charge or propelling charge 1.2G 6.1/8 0 E0 P130 LP101 PP67 L1 F-B, S-Z Category 03 SW1 SG2 See glossary of terms in appendix B. 0018
0019 AMMUNITION, TEAR-PRODUCING with burster, expelling charge or propelling charge 1.3G 6.1/8 0 E0 P130 LP101 PP67 L1 F-B, S-Z Category 03 SW1 SG3 See glossary of terms in appendix B. 0019
0020 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 1.2 K 6.1 274 0 E0 P101 F-B, S-Z Category 05 SW1 See glossary of terms in appendix B. 0020
0021 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 1.3 K 6.1 274 0 E0 P101 F-B, S-Z Category 05 SW1 See glossary of terms in appendix B. 0021
0027 BLACK POWDER (GUNPOWDER) granular, or as a meal 1.1D 0 E0 P113 PP50 F-B, S-Y Category 04 SW1 See glossary of terms in appendix B. 0027
0028 BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS 1.1D 0 E0 P113 PP51 F-B, S-Y Category 04 SW1 See glossary of terms in appendix B. 0028
0029 DETONATORS, NON-ELECTRIC for blasting 1.1B 0 E0 P131 PP68 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0029
0030 DETONATORS, ELECTRIC for blasting 1.1B 399 0 E0 P131 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0030
0033 BOMBS with bursting charge 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0033
0034 BOMBS with bursting charge 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0034
0035 BOMBS with bursting charge 1.2D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0035
0037 BOMBS, PHOTO-FLASH 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0037
0038 BOMBS, PHOTO-FLASH 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0038
0039 BOMBS, PHOTO-FLASH 1.2G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0039
0042 BOOSTERS without detonator 1.1D 0 E0 P132 (a) or (b) F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0042
0043 BURSTERS explosive 1.1D 0 E0 P133 PP69 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0043
0044 PRIMERS, CAP TYPE 1.4S 0 E0 P133 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0044
0048 CHARGES, DEMOLITION 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0048
0049 CARTRIDGES, FLASH 1.1G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0049
0050 CARTRIDGES, FLASH 1.3G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0050
0054 CARTRIDGES, SIGNAL 1.3G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0054
0055 CASES, CARTRIDGE, EMPTY, WITH PRIMER 1.4S 364 5 kg E0 P136 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0055
0056 CHARGES, DEPTH 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0056
0059 CHARGES, SHAPED, without detonator 1.1D 0 E0 P137 PP70 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0059
0060 CHARGES, SUPPLEMENTARY, EXPLOSIVE 1.1D 0 E0 P132 (a) or (b) F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0060
0065 CORD, DETONATING, flexible 1.1D 0 E0 P139 PP71 PP72 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0065
0066 CORD, IGNITER 1.4G 0 E0 P140 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0066
0070 CUTTERS, CABLE, EXPLOSIVE 1.4S 0 E0 P134 LP102 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0070
0072 CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass 1.1D 266 0 E0 P112 (a) PP45 F-B, S-Y Category 04 SW1 Mass detonating explosive which becomes more sensitive if the wetting agent is lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0072
0073 DETONATORS FOR AMMUNITION 1.1B 0 E0 P133 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0073
0074 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass 1.1A 266 0 E0 P110 (a) or (b) PP42 F-B, S-Y Category 05 SW1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0074
0075 DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer, by mass 1.1D 266 0 E0 P115 PP53 PP54 PP57 PP58 F-B, S-Y Category 04 SW1 This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0075
0076 DINITROPHENOL, dry or wetted with less than 15% water, by mass 1.1D 6.1 0 E0 P112 (a), (b) or (c) PP26 F-B, S-Z Category 04 SW1 SG31 Substance. 0076
0077 DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass 1.3 C 6.1 0 E0 P114 (a) or (b) PP26 F-B, S-Z Category 04 SW1 SG31 Substance. 0077
0078 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0078
0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0079
0081 EXPLOSIVE, BLASTING, TYPE A 1.1D 0 E0 P116 PP63 PP66 F-B, S-Y Category 04 SW1 SG34 Substance. See glossary of terms in appendix B. 0081
0082 EXPLOSIVE, BLASTING, TYPE B 1.1D 0 E0 P116 PP61 PP62 IBC100 B9 F-B, S-Y Category 04 SW1 SG34 Substance. See glossary of terms in appendix B. 0082
0083 EXPLOSIVE, BLASTING, TYPE C 1.1D 267 0 E0 P116 F-B, S-Y Category 04 SW1 SG28 Substance. See glossary of terms in appendix B. 0083
0084 EXPLOSIVE, BLASTING, TYPE D 1.1D 0 E0 P116 F-B, S-Y Category 04 SW1 Substance. See glossary of terms in appendix B. 0084
0092 FLARES, SURFACE 1.3G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0092
0093 FLARES, AERIAL 1.3G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0093
0094 FLASH POWDER 1.1G 0 E0 P113 PP49 F-B, S-Y Category 03 SW1 See glossary of terms in appendix B. 0094
0099 FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells 1.1D 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0099
0101 FUSE, NON-DETONATING 1.3G 0 E0 P140 PP74 PP75 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0101
0102 CORD (FUSE), DETONATING, metal-clad 1.2D 0 E0 P139 PP71 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0102
0103 FUSE, IGNITER tubular, metal-clad 1.4G 0 E0 P140 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0103
0104 CORD (FUSE), DETONATING, MILD EFFECT, metal-clad 1.4D 0 E0 P139 PP71 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0104
0105 FUSE, SAFETY 1.4S 0 E0 P140 PP73 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0105
0106 FUZES, DETONATING 1.1B 0 E0 P141 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0106
0107 FUZES, DETONATING 1.2B 0 E0 P141 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0107
0110 GRENADES, PRACTICE, hand or rifle 1.4S 0 E0 P141 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0110
0113 GUANYL NITROSAMINO-GUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass 1.1A 266 0 E0 P110 (a) or (b) PP42 F-B, S-Y Category 05 SW1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0113
0114 GUANYL NITROSAMINO-GUANYLTETRAZENE (TETRAZENE), WETTED with not less than 30% water, or mixture of alcohol and water, by mass 1.1A 266 0 E0 P110 (a) or (b) PP42 F-B, S-Y Category 05 SW1 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0114
0118 HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mixtures of mass detonating explosives. 0118
0121 IGNITERS 1.1G 0 E0 P142 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0121
0124 JET PERFORATING GUNS, CHARGED, oil well, without detonator 1.1D 0 E0 P101 F-B, S-X Category 03 SW1 SW30 See glossary of terms in appendix B. 0124
0129 LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1.1A 266 0 E0 P110 (a) or (b) PP42 F-B, S-Y Category 05 SW1 SGG7 SGG9 SGG17 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0129
0130 LEAD STYPHNATE (LEAD TRINITRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1.1A 266 0 E0 P110 (a) or (b) PP42 F-B, S-Y Category 05 SW1 SGG7 SGG9 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0130
0131 LIGHTERS, FUSE 1.4S 0 E0 P142 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0131
0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRO-DERIVATIVES, N.O.S. 1.3 C 0 E0 P114 (b) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0132
0133 MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass 1.1D 266 0 E0 P112 (a) F-B, S-Y Category 04 SW1 This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0133
0135 MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1.1A 266 0 E0 P110 (a) or (b) PP42 F-B, S-Y Category 05 SW1 SGG7 SGG11 Sensitive substance used in detonators which will become extremely sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0135
0136 MINES with bursting charge 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0136
0137 MINES with bursting charge 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0137
0138 MINES with bursting charge 1.2D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0138
0143 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer, by mass 1.1D See SP271 266 271 272 0 E0 P115 PP53 PP54 PP57 PP58 F-B, S-Z Category 04 SW1 Substance. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0143
0144 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin 1.1D 358 0 E0 P115 PP45 PP55 PP56 PP59 PP60 F-B, S-Y Category 04 SW1 Substance. 0144
0146 NITROSTARCH, dry or wetted, with less than 20% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0146
0147 NITRO UREA 1.1D 0 E0 P112 (b) F-B, S-Y Category 04 SW1 Substance. 0147
0150 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), WETTED with not less than 25% water, by mass or PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), DESENSITIZED with not less than 15% phlegmatizer, by mass 1.1D 266 0 E0 P112 (a) or (b) F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive which will become more sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0150
0151 PENTOLITE, dry or wetted with less than 15% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mixtures of mass detonating explosive substances. 0151
0153 TRINITROANILINE (PICRAMIDE) 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0153
0154 TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0154
0155 TRINITROCHLOROBENZENE (PICRYL CHLORIDE) 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0155
0159 POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass 1.3 C 266 0 E0 P111 PP43 F-B, S-Y Category 04 SW1 Substance consisting of nitrocellulose impregnated with not more than 60% of nitroglycerin or other liquid organic nitrates or a mixture of these. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0159
0160 POWDER, SMOKELESS 1.1 C 0 E0 P114 (b) PP50 PP52 F-B, S-Y Category 04 SW1 Substances based on nitrocellulose used as propellant. Sensitive to sparks, friction, pressure and electrostatic discharge. 0160
0161 POWDER, SMOKELESS 1.3 C 0 E0 P114 (b) PP50 PP52 F-B, S-Y Category 04 SW1 Substances based on nitrocellulose used as propellant. Sensitive to sparks, friction, pressure and electrostatic discharge. 0161
0167 PROJECTILES with bursting charge 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0167
0168 PROJECTILES with bursting charge 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0168
0169 PROJECTILES with bursting charge 1.2D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0169
0171 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 1.2G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0171
0173 RELEASE DEVICES, EXPLOSIVE 1.4S 0 E0 P134 LP102 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0173
0174 RIVETS, EXPLOSIVE 1.4S 0 E0 P134 LP102 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0174
0180 ROCKETS with bursting charge 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0180
0181 ROCKETS with bursting charge 1.1E 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0181
0182 ROCKETS with bursting charge 1.2E 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0182
0183 ROCKETS with inert head 1.3 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0183
0186 ROCKET MOTORS 1.3 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0186
0190 SAMPLES, EXPLOSIVE, other than initiating explosive 1 16 274 0 E0 P101 F-B, S-X Category 05 SW1 Substance or article. Division and compatibility group as classified by the competent authority. 0190
0191 SIGNAL DEVICES, HAND 1.4G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0191
0192 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.1G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0192
0193 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0193
0194 SIGNALS, DISTRESS, ship 1.1G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0194
0195 SIGNALS, DISTRESS, ship 1.3G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0195
0196 SIGNALS, SMOKE 1.1G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0196
0197 SIGNALS, SMOKE 1.4G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0197
0204 SOUNDING DEVICES, EXPLOSIVE 1.2 F 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0204
0207 TETRANITROANILINE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0207
0208 TRINITROPHENYLMETHYL-NITRAMINE (TETRYL) 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive. 0208
0209 TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) PP46 F-B, S-Y Category 04 SW1 Substance. Tritonal is a substance consisting of trinitrotoluene (TNT) mixed with aluminium. 0209
0212 TRACERS FOR AMMUNITION 1.3 G 0 E0 P133 PP69 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0212
0213 TRINITROANISOLE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0213
0214 TRINITROBENZENE, dry or wetted with less than 30% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0214
0215 TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0215
0216 TRINITRO--CRESOL 1.1D 0 E0 P112 (b) or (c) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0216
0217 TRINITRONAPHTHALENE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0217
0218 TRINITROPHENETOLE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0218
0219 TRINITRORESORCINOL (STYPHNIC ACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by mass 1.1D 0 E0 P112 (a), (b) or (c) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0219
0220 UREA NITRATE, dry or wetted with less than 20% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0220
0221 WARHEADS, TORPEDO with bursting charge 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0221
0222 AMMONIUM NITRATE 1.1D 370 0 E0 P112 (b) or (c) PP47 IBC100 B2 B3 B17 F-B, S-Y Category 04 SW1 SGG2 SG27 Substance. 0222
0224 BARIUM AZIDE, dry or wetted with less than 50% water, by mass 1.1A 6.1 0 E0 P110 (a) or (b) PP42 F-B, S-Z Category 05 SW1 SGG17 Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0224
0225 BOOSTERS WITH DETONATOR 1.1B 0 E0 P133 PP69 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0225
0226 CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15% water, by mass 1.1D 266 0 E0 P112 (a) PP45 F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agent is lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0226
0234 SODIUM DINITRO--CRESOLATE, dry or wetted with less than 15% water, by mass 1.3 C 6.1 0 E0 P114 (a) or (b) PP26 F-B, S-Z Category 04 SW1 SG31 Substance. 0234
0235 SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass 1.3 C 0 E0 P114 (a) or (b) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0235
0236 ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass 1.3 C 0 E0 P114 (a) or (b) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0236
0237 CHARGES, SHAPED, FLEXIBLE, LINEAR 1.4D 0 E0 P138 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0237
0238 ROCKETS, LINE-THROWING 1.2 G 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0238
0240 ROCKETS, LINE-THROWING 1.3 G 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0240
0241 EXPLOSIVE, BLASTING, TYPE E 1.1D 0 E0 P116 PP61 PP62 IBC100 B10 F-B, S-X Category 04 SW1 SG34 See glossary of terms in appendix B. 0241
0242 CHARGES, PROPELLING, FOR CANNON 1.3 C 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0242
0243 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1.2 H 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0243
0244 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1.3 H 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0244
0245 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1.2 H 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0245
0246 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1.3 H 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0246
0247 AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge 1.3 J 0 E0 P101 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0247
0248 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge 1.2 L 4.3 274 0 E0 P144 PP77 F-B, S-Y Category 05 SW1 See glossary of terms in appendix B. 0248
0249 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge 1.3 L 4.3 274 0 E0 P144 PP77 F-B, S-Y Category 05 SW1 See glossary of terms in appendix B. 0249
0250 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 1.3 L 0 E0 P101 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0250
0254 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 1.3 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0254
0255 DETONATORS, ELECTRIC for blasting 1.4B 399 0 E0 P131 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0255
0257 FUZES, DETONATING 1.4B 0 E0 P141 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0257
0266 OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mixtures of mass detonating explosives. 0266
0267 DETONATORS, NON-ELECTRIC for blasting 1.4B 0 E0 P131 PP68 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0267
0268 BOOSTERS WITH DETONATOR 1.2B 0 E0 P133 PP69 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0268
0271 CHARGES, PROPELLING 1.1 C 0 E0 P143 PP76 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0271
0272 CHARGES, PROPELLING 1.3 C 0 E0 P143 PP76 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0272
0275 CARTRIDGES, POWER DEVICE 1.3 C 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0275
0276 CARTRIDGES, POWER DEVICE 1.4 C 0 E0 P134 LP102 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0276
0277 CARTRIDGES, OIL WELL 1.3 C 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0277
0278 CARTRIDGES, OIL WELL 1.4 C 0 E0 P134 LP102 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0278
0279 CHARGES, PROPELLING, FOR CANNON 1.1 C 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0279
0280 ROCKET MOTORS 1.1 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0280
0281 ROCKET MOTORS 1.2 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 04 SW1 See glossary of terms in appendix B. 0281
0282 NITROGUANIDINE (PICRITE), dry or wetted with less than 20% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0282
0283 BOOSTERS without detonator 1.2D 0 E0 P132 (a) or (b) F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0283
0284 GRENADES, hand or rifle, with bursting charge 1.1D 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0284
0285 GRENADES, hand or rifle, with bursting charge 1.2D 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0285
0286 WARHEADS, ROCKET with bursting charge 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0286
0287 WARHEADS, ROCKET with bursting charge 1.2D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0287
0288 CHARGES, SHAPED, FLEXIBLE, LINEAR 1.1D 0 E0 P138 F-B, S-X Category 04 SW1 See glossary of terms in appendix B. 0288
0289 CORD, DETONATING, flexible 1.4D 0 E0 P139 PP71 PP72 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0289
0290 CORD (FUSE), DETONATING, metal-clad 1.1D 0 E0 P139 PP71 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0290
0291 BOMBS with bursting charge 1.2 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0291
0292 GRENADES, hand or rifle, with bursting charge 1.1 F 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0292
0293 GRENADES, hand or rifle, with bursting charge 1.2 F 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0293
0294 MINES with bursting charge 1.2 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0294
0295 ROCKETS with bursting charge 1.2 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0295
0296 SOUNDING DEVICES, EXPLOSIVE 1.1 F 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0296
0297 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 1.4 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0297
0299 BOMBS, PHOTO-FLASH 1.3 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0299
0300 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 1.4 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0300
0301 AMMUNITION, TEAR- PRODUCING with burster, expelling charge or propelling charge 1.4 G 6.1/8 0 E0 P130 LP101 PP67 L1 F-B, S-Z Category 02 SW1 SG74 See glossary of terms in appendix B. 0301
0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 1.4G See SP204 204 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0303
0305 FLASH POWDER 1.3 G 0 E0 P113 PP49 F-B, S-Y Category 03 SW1 See glossary of terms in appendix B. 0305
0306 TRACERS FOR AMMUNITION 1.4 G 0 E0 P133 PP69 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0306
0312 CARTRIDGES, SIGNAL 1.4 G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0312
0313 SIGNALS, SMOKE 1.2 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0313
0314 IGNITERS 1.2 G 0 E0 P142 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0314
0315 IGNITERS 1.3 G 0 E0 P142 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0315
0316 FUZES, IGNITING 1.3 G 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0316
0317 FUZES, IGNITING 1.4 G 0 E0 P141 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0317
0318 GRENADES, PRACTICE, hand or rifle 1.3 G 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0318
0319 PRIMERS, TUBULAR 1.3 G 0 E0 P133 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0319
0320 PRIMERS, TUBULAR 1.4 G 0 E0 P133 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0320
0321 CARTRIDGES FOR WEAPONS with bursting charge 1.2E 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0321
0322 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 1.2 L 0 E0 P101 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0322
0323 CARTRIDGES, POWER DEVICE 1.4S 347 0 E0 P134 LP102 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0323
0324 PROJECTILES with bursting charge 1.2 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0324
0325 IGNITERS 1.4 G 0 E0 P142 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0325
0326 CARTRIDGES FOR WEAPONS, BLANK 1.1 C 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0326
0327 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 1.3 C 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0327
0328 CARTRIDGES FOR WEAPONS, INERT PROJECTILE 1.2 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0328
0329 TORPEDOES with bursting charge 1.1E 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0329
0330 TORPEDOES with bursting charge 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0330
0331 EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B) 1.5D 0 E0 P116 PP61 PP62 PP64 IBC100 T1 TP17 TP32 F-B, S-Y Category 03 SW1 SG34 See glossary of terms in appendix B. 0331
0332 EXPLOSIVE, BLASTING, TYPE E (AGENT, BLASTING, TYPE E) 1.5D 0 E0 P116 PP61 PP62 IBC100 T1 TP1 TP17 TP32 F-B, S-Y Category 03 SW1 SG34 See glossary of terms in appendix B. 0332
0333 FIREWORKS 1.1 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0333
0334 FIREWORKS 1.2 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0334
0335 FIREWORKS 1.3 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0335
0336 FIREWORKS 1.4 G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0336
0337 FIREWORKS 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0337
0338 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 1.4 C 0 E0 P130 LP101 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0338
0339 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 1.4 C 0 E0 P130 LP101 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0339
0340 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass 1.1D 393 0 E0 P112 (c) or (b) F-B, S-Y Category 04 SW1 Substance. 0340
0341 NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass 1.1D 393 0 E0 P112 (b) F-B, S-Y Category 04 SW1 Substance. 0341
0342 NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass 1.3 C 105 393 0 E0 P114 (a) PP43 F-B, S-Y Category 04 SW1 Substance. 0342
0343 NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass 1.3 C 105 393 0 E0 P111 F-B, S-Y Category 04 SW1 Substance. 0343
0344 PROJECTILES with bursting charge 1.4D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0344
0345 PROJECTILES, inert with tracer 1.4S 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0345
0346 PROJECTILES with burster or expelling charge 1.2D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0346
0347 PROJECTILES with burster or expelling charge 1.4D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0347
0348 CARTRIDGES FOR WEAPONS with bursting charge 1.4 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0348
0349 ARTICLES, EXPLOSIVE, N.O.S. 1.4S 178 274 347 0 E0 P101 F-B, S-X Category 01 SW1 0349
0350 ARTICLES, EXPLOSIVE, N.O.S. 1.4B 178 274 0 E0 P101 F-B, S-X Category 05 SW1 0350
0351 ARTICLES, EXPLOSIVE, N.O.S. 1.4 C 178 274 0 E0 P101 F-B, S-X Category 02 SW1 0351
0352 ARTICLES, EXPLOSIVE, N.O.S. 1.4D 178 274 0 E0 P101 F-B, S-X Category 02 SW1 0352
0353 ARTICLES, EXPLOSIVE, N.O.S. 1.4 G 178 274 0 E0 P101 F-B, S-X Category 02 SW1 0353
0354 ARTICLES, EXPLOSIVE, N.O.S. 1.1 L See SP943 178 274 0 E0 P101 F-B, S-X Category 05 SW1 0354
0355 ARTICLES, EXPLOSIVE, N.O.S. 1.2 L See SP943 178 274 0 E0 P101 F-B, S-X Category 05 SW1 0355
0356 ARTICLES, EXPLOSIVE, N.O.S. 1.3 L See SP943 178 274 0 E0 P101 F-B, S-X Category 05 SW1 0356
0357 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1 L 178 274 0 E0 P101 F-B, S-Y Category 05 SW1 0357
0358 SUBSTANCES, EXPLOSIVE, N.O.S. 1.2 L 178 274 0 E0 P101 F-B, S-Y Category 05 SW1 0358
0359 SUBSTANCES, EXPLOSIVE, N.O.S. 1.3 L 178 274 0 E0 P101 F-B, S-Y Category 05 SW1 0359
0360 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 1.1B 0 E0 P131 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0360
0361 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 1.4B 0 E0 P131 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0361
0362 AMMUNITION, PRACTICE 1.4 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0362
0363 AMMUNITION, PROOF 1.4 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0363
0364 DETONATORS FOR AMMUNITION 1.2B 0 E0 P133 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0364
0365 DETONATORS FOR AMMUNITION 1.4B 0 E0 P133 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0365
0366 DETONATORS FOR AMMUNITION 1.4S 347 0 E0 P133 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0366
0367 FUZES, DETONATING 1.4S 347 0 E0 P141 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0367
0368 FUZES, IGNITING 1.4S 0 E0 P141 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0368
0369 WARHEADS, ROCKET with bursting charge 1.1 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0369
0370 WARHEADS, ROCKET with burster or expelling charge 1.4D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0370
0371 WARHEADS, ROCKET with burster or expelling charge 1.4 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0371
0372 GRENADES, PRACTICE, hand or rifle 1.2 G 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0372
0373 SIGNAL DEVICES, HAND 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0373
0374 SOUNDING DEVICES, EXPLOSIVE 1.1D 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0374
0375 SOUNDING DEVICES, EXPLOSIVE 1.2D 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0375
0376 PRIMERS, TUBULAR 1.4S 0 E0 P133 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0376
0377 PRIMERS, CAP TYPE 1.1B 0 E0 P133 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0377
0378 PRIMERS, CAP TYPE 1.4B 0 E0 P133 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0378
0379 CASES, CARTRIDGE, EMPTY, WITH PRIMER 1.4 C 0 E0 P136 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0379
0380 ARTICLES, PYROPHORIC 1.2 L 0 E0 P101 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0380
0381 CARTRIDGES, POWER DEVICE 1.2 C 0 E0 P134 LP102 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0381
0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.2B 178 274 0 E0 P101 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0382
0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.4B 178 274 0 E0 P101 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0383
0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.4S 178 274 347 0 E0 P101 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0384
0385 5-NITROBENZOTRIAZOL 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0385
0386 TRINITROBENZENESULPHONIC ACID 1.1D 0 E0 P112 (b) or (c) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. 0386
0387 TRINITROFLUORENONE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0387
0388 TRINITROTOLUENE (TNT) AND TRINITROBENZENE MIXTURE or TRINITROTOLUENE (TNT) AND HEXANITROSTILBENE MIXTURE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0388
0389 TRINITROTOLUENE (TNT) MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0389
0390 TRITONAL 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Tritonal is a substance consisting of trinitrotoluene (TNT) mixed with aluminium. 0390
0391 CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN) MIXTURE, WETTED with not less than 15% water, by mass or CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN) MIXTURE, DESENSITIZED with not less than 10% phlegmatizer, by mass 1.1D 266 0 E0 P112 (c) or (b) F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. 0391
0392 HEXANITROSTILBENE 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive. 0392
0393 HEXOTONAL 1.1D 0 E0 P112 (b) F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive. 0393
0394 TRINITRORESORCINOL (STYPHNIC ACID), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1.1D 0 E0 P112 (a) PP26 F-B, S-Y Category 04 SW1 SG31 Substance. Mass detonating explosive. 0394
0395 ROCKET MOTORS, LIQUID FUELLED 1.2 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0395
0396 ROCKET MOTORS, LIQUID FUELLED 1.3 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0396
0397 ROCKETS, LIQUID FUELLED with bursting charge 1.1 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0397
0398 ROCKETS, LIQUID FUELLED with bursting charge 1.2 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0398
0399 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1.1 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0399
0400 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1.2 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0400
0401 DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass 1.1D 0 E0 P112 (a), (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0401
0402 AMMONIUM PERCHLORATE 1.1D 152 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 SGG2 SG27 Substance. 0402
0403 FLARES, AERIAL 1.4 G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0403
0404 FLARES, AERIAL 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0404
0405 CARTRIDGES, SIGNAL 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0405
0406 DINITROSOBENZENE 1.3 C 0 E0 P114 (b) F-B, S-Y Category 04 SW1 Substance. 0406
0407 TETRAZOL−1-ACETIC ACID 1.4 C 0 E0 P114 (b) F-B, S-Y Category 02 SW1 Substance. 0407
0408 FUZES, DETONATING with protective features 1.1D 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0408
0409 FUZES, DETONATING with protective features 1.2D 0 E0 P141 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0409
0410 FUZES, DETONATING with protective features 1.4D 0 E0 P141 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0410
0411 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with not less than 7% wax, by mass 1.1D 131 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0411
0412 CARTRIDGES FOR WEAPONS with bursting charge 1.4E 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0412
0413 CARTRIDGES FOR WEAPONS, BLANK 1.2 C 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0413
0414 CHARGES, PROPELLING, FOR CANNON 1.2 C 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0414
0415 CHARGES, PROPELLING 1.2 C 0 E0 P143 PP76 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0415
0417 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 1.3 C 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0417
0418 FLARES, SURFACE 1.1 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0418
0419 FLARES, SURFACE 1.2 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0419
0420 FLARES, AERIAL 1.1 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0420
0421 FLARES, AERIAL 1.2 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0421
0424 PROJECTILES, inert with tracer 1.3 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0424
0425 PROJECTILES, inert with tracer 1.4 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0425
0426 PROJECTILES with burster or expelling charge 1.2 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0426
0427 PROJECTILES with burster or expelling charge 1.4 F 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0427
0428 ARTICLES, PYROTECHNIC for technical purposes 1.1 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0428
0429 ARTICLES, PYROTECHNIC for technical purposes 1.2 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0429
0430 ARTICLES, PYROTECHNIC for technical purposes 1.3 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0430
0431 ARTICLES, PYROTECHNIC for technical purposes 1.4 G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0431
0432 ARTICLES, PYROTECHNIC for technical purposes 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0432
0433 POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass 1.1 C 266 0 E0 P111 F-B, S-Y Category 04 SW1 See glossary of terms in appendix B. 0433
0434 PROJECTILES with burster or expelling charge 1.2 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0434
0435 PROJECTILES with burster or expelling charge 1.4 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0435
0436 ROCKETS with expelling charge 1.2 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0436
0437 ROCKETS with expelling charge 1.3 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0437
0438 ROCKETS with expelling charge 1.4 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0438
0439 CHARGES, SHAPED, without detonator 1.2D 0 E0 P137 PP70 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0439
0440 CHARGES, SHAPED, without detonator 1.4D 0 E0 P137 PP70 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0440
0441 CHARGES, SHAPED, without detonator 1.4S 347 0 E0 P137 PP70 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0441
0442 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 1.1D 0 E0 P137 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0442
0443 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 1.2D 0 E0 P137 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0443
0444 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 1.4D 0 E0 P137 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0444
0445 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 1.4S 347 0 E0 P137 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0445
0446 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 1.4 C 0 E0 P136 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0446
0447 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 1.3 C 0 E0 P136 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0447
0448 5-MERCAPTOTETRAZOL−1-ACETIC ACID 1.4 C 0 E0 P114 (b) F-B, S-Y Category 02 SW1 Substance. 0448
0449 TORPEDOES, LIQUID FUELLED with or without bursting charge 1.1 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0449
0450 TORPEDOES, LIQUID FUELLED with inert head 1.3 J 0 E0 P101 F-B, S-X Category 05 SW1 SG67 See glossary of terms in appendix B. 0450
0451 TORPEDOES with bursting charge 1.1D 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0451
0452 GRENADES, PRACTICE, hand or rifle 1.4 G 0 E0 P141 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0452
0453 ROCKETS, LINE-THROWING 1.4 G 0 E0 P130 LP101 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0453
0454 IGNITERS 1.4S 0 E0 P142 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0454
0455 DETONATORS, NON-ELECTRIC for blasting 1.4S 347 0 E0 P131 PP68 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0455
0456 DETONATORS, ELECTRIC for blasting 1.4S 347 399 0 E0 P131 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0456
0457 CHARGES, BURSTING, PLASTICS BONDED 1.1D 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0457
0458 CHARGES, BURSTING, PLASTICS BONDED 1.2D 0 E0 P130 LP101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0458
0459 CHARGES, BURSTING, PLASTICS BONDED 1.4D 0 E0 P130 LP101 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0459
0460 CHARGES, BURSTING, PLASTICS BONDED 1.4S 347 0 E0 P130 LP101 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0460
0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.1B 178 274 0 E0 P101 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0461
0462 ARTICLES, EXPLOSIVE, N.O.S. 1.1 C 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0462
0463 ARTICLES, EXPLOSIVE, N.O.S. 1.1D 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0463
0464 ARTICLES, EXPLOSIVE, N.O.S. 1.1E 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0464
0465 ARTICLES, EXPLOSIVE, N.O.S. 1.1 F 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0465
0466 ARTICLES, EXPLOSIVE, N.O.S. 1.2 C 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0466
0467 ARTICLES, EXPLOSIVE, N.O.S. 1.2D 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0467
0468 ARTICLES, EXPLOSIVE, N.O.S. 1.2E 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0468
0469 ARTICLES, EXPLOSIVE, N.O.S. 1.2 F 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0469
0470 ARTICLES, EXPLOSIVE, N.O.S. 1.3 C 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0470
0471 ARTICLES, EXPLOSIVE, N.O.S. 1.4E 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0471
0472 ARTICLES, EXPLOSIVE, N.O.S. 1.4 F 178 274 0 E0 P101 F-B, S-X Category 03 SW1 0472
0473 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1A 178 274 0 E0 P101 F-B, S-Y Category 05 SW1 0473
0474 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1 C 178 274 0 E0 P101 F-B, S-Y Category 04 SW1 0474
0475 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1D 178 274 0 E0 P101 F-B, S-Y Category 04 SW1 0475
0476 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1 G 178 274 0 E0 P101 F-B, S-Y Category 03 SW1 0476
0477 SUBSTANCES, EXPLOSIVE, N.O.S. 1.3 C 178 274 0 E0 P101 F-B, S-Y Category 04 SW1 0477
0478 SUBSTANCES, EXPLOSIVE, N.O.S. 1.3 G 178 274 0 E0 P101 F-B, S-Y Category 03 SW1 0478
0479 SUBSTANCES, EXPLOSIVE, N.O.S. 1.4 C 178 274 0 E0 P101 F-B, S-Y Category 02 SW1 0479
0480 SUBSTANCES, EXPLOSIVE, N.O.S. 1.4D 178 274 0 E0 P101 F-B, S-Y Category 02 SW1 0480
0481 SUBSTANCES, EXPLOSIVE, N.O.S. 1.4S 178 274 347 0 E0 P101 F-B, S-Y Category 01 SW1 0481
0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S. 1.5D 178 274 0 E0 P101 F-B, S-Y Category 03 SW1 0482
0483 CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX), DESENSITIZED 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. 0483
0484 CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN), DESENSITIZED 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. 0484
0485 SUBSTANCES, EXPLOSIVE, N.O.S. 1.4 G 178 274 0 E0 P101 F-B, S-Y Category 02 SW1 0485
0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) 1.6 N 0 E0 P101 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0486
0487 SIGNALS, SMOKE 1.3 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0487
0488 AMMUNITION, PRACTICE 1.3 G 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0488
0489 DINITROGLYCOLURIL (DINGU) 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0489
0490 NITROTRIAZOLONE (NTO) 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. 0490
0491 CHARGES, PROPELLING 1.4 C 0 E0 P143 PP76 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0491
0492 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.3 G 0 E0 P135 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0492
0493 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1.4 G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0493
0494 JET PERFORATING GUNS, CHARGED, oil well, without detonator 1.4D 0 E0 P101 F-B, S-X Category 02 SW1 SW30 See glossary of terms in appendix B. 0494
0495 PROPELLANT, LIQUID 1.3 C 224 0 E0 P115 PP53 PP54 PP57 PP58 F-B, S-Y Category 04 SW1 See glossary of terms in appendix B. 0495
0496 OCTONAL 1.1D 0 E0 P112 (b) or (c) F-B, S-Y Category 04 SW1 Substance. Mixtures of mass detonating explosives. 0496
0497 PROPELLANT, LIQUID 1.1 C 224 0 E0 P115 PP53 PP54 PP57 PP58 F-B, S-Y Category 04 SW1 See glossary of terms in appendix B. 0497
0498 PROPELLANT, SOLID 1.1 C 0 E0 P114 (b) F-B, S-Y Category 04 SW1 See glossary of terms in appendix B. 0498
0499 PROPELLANT, SOLID 1.3 C 0 E0 P114 (b) F-B, S-Y Category 04 SW1 See glossary of terms in appendix B. 0499
0500 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 1.4S 347 0 E0 P131 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0500
0501 PROPELLANT, SOLID 1.4 C 0 E0 P114 (b) F-B, S-Y Category 02 SW1 See glossary of terms in appendix B. 0501
0502 ROCKETS with inert head 1.2 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 03 SW1 See glossary of terms in appendix B. 0502
0503 SAFETY DEVICES, PYROTECHNIC 1.4 G 235 289 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0503
0504 1 -TETRAZOLE 1.1D 0 E0 P112 (c) PP48 F-B, S-Y Category 04 SW1 Substance. 0504
0505 SIGNALS, DISTRESS, ship 1.4 G 0 E0 P135 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0505
0506 SIGNALS, DISTRESS, ship 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0506
0507 SIGNALS, SMOKE 1.4S 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0507
0508 1-HYDROXYBENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass 1.3 C 0 E0 P114 (b) PP48 PP50 F-B, S-Y Category 04 SW1 Substance. 0508
0509 POWDER, SMOKELESS 1.4 C 0 E0 P114(b) PP48 F-B, S-Y Category 02 SW1 See glossary of terms in appendix B. 0509
0510 ROCKET MOTORS 1.4 C 0 E0 P130 LP101 PP67 L1 F-B, S-X Category 02 SW1 See glossary of terms in appendix B. 0510
0511 DETONATORS, ELECTRONIC programmable for blasting 1.1B 399 0 E0 P131 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0511
0512 DETONATORS, ELECTRONIC programmable for blasting 1.4B 399 0 E0 P131 F-B, S-X Category 05 SW1 See glossary of terms in appendix B. 0512
0513 DETONATORS, ELECTRONIC programmable for blasting 1.4S 347 399 0 E0 P131 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0513
0514 FIRE SUPPRESSANT DISPERSING DEVICES 1.4S 407 0 E0 P135 F-B, S-X Category 01 SW1 See glossary of terms in appendix B. 0514
1001 ACETYLENE, DISSOLVED 2.1 0 E0 P200 F-D, S-U Category D SW1 SW2 SG46 Flammable gas with slight odour. Explosive limits: 2.1% to 80%. Lighter than air (0.907). Rough handling and exposure to local heating should be avoided, since these conditions may result in delayed explosion. Empty cylinders should be carried with the same precautions as filled cylinders. 1001
1002 AIR, COMPRESSED 2.2 392 397 120 mL E1 P200 F-C, S-V Category A Non-flammable gas. 1002
1003 AIR, REFRIGERATED LIQUID 2.2 5.1 0 E0 P203 T75 TP5 TP22 F-C, S-W Category D Liquefied, non-flammable gas. Strong oxidizing agent. Mixtures of liquid air with combustible materials or oils may explode. May ignite organic materials. 1003
1005 AMMONIA, ANHYDROUS 2.3 8 23 379 0 E0 P200 T50 F-C, S-U Category D SW2 SGG18 SG35 SG46 Liquefied, non-flammable, toxic and corrosive gas with a pungent odour. Lighter than air (0.6). Suffocating in low concentrations. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. Reacts violently with acids. Highly irritating to skin, eyes and mucous membranes. 1005
1006 ARGON, COMPRESSED 2.2 378 392 406 120 mL E1 P200 F-C, S-V Category A Inert gas. Heavier than air (1.4). 1006
1008 BORON TRIFLUORIDE 2.3 8 373 0 E0 P200 F-C, S-U Category D SW2 Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass and most metals. Much heavier than air (2.35). Highly irritating to skin, eyes and mucous membranes. 1008
1009 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas with a slight odour. Much heavier than air (5.2). 1009
1010 BUTADIENES, STABILIZED or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, containing more than 20% butadienes 2.1 386 402 0 E0 P200 T50 F-D, S-U Category B SW1 SW2 Liquefied, flammable gas with an unpleasant odour. Explosive limits: 2% to 12%. Heavier than air (1.84). 1010
1011 BUTANE 2.1 392 0 E0 P200 T50 F-D, S-U Category E SW2 Flammable hydrocarbon gas. Explosive limits: 1.8% to 8.4%. Heavier than air (2.11). 1011
1012 BUTYLENE 2.1 398 0 E0 P200 T50 F-D, S-U Category E SW2 Flammable hydrocarbon gas. Explosive limits: 1.6% to 10%. Heavier than air (2.0). 1012
1013 CARBON DIOXIDE 2.2 378 392 406 120 mL E1 P200 F-C, S-V Category A Liquefied, non-flammable gas. Heavier than air (1.5). Cannot remain in the liquid state above 31°C. 1013
1016 CARBON MONOXIDE, COMPRESSED 2.3 2.1 974 0 E0 P200 F-D, S-U Category D SW2 Flammable, toxic, odourless gas. Explosive limits: 12% to 75%. Slightly lighter than air (0.97). 1016
1017 CHLORINE 2.3 5.1/8 0 E0 P200 T50 TP19 F-C, S-U Category D SW2 SG6 SG19 Non-flammable, toxic and corrosive yellow gas with a pungent odour. Corrosive to glass and to most metals. Much heavier than air (2.4). Highly irritating to skin, eyes and mucous membranes. Powerful oxidant which may cause fire. 1017
1018 CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (3.0). 1018
1020 CHLOROPENTAFLUORO-ETHANE (REFRIGERANT GAS R 115) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas. Much heavier than air (5.4). 1020
1021 1-CHLORO−1,2,2,2-TETRA-FLUOROETHANE (REFRIGERANT GAS R 124) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas. Much heavier than air (4.7). 1021
1022 CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) 2.2 120 mL E1 P200 F-C, S-V Category A Liquefied, non-flammable gas. Much heavier than air (3.6). Cannot remain in the liquid state above 29°C. 1022
1023 COAL GAS, COMPRESSED 2.3 2.1 0 E0 P200 F-D, S-U Category D SW2 Flammable, toxic gas. Explosive limits: 4.5% to 40%. Much lighter than air (0.4 to 0.6). 1023
1026 CYANOGEN 2.3 2.1 0 E0 P200 F-D, S-U Category D SW2 Liquefied, flammable, toxic gas with a pungent odour. Explosive limits: 6.6% to 43%. Heavier than air (1.9). 1026
1027 CYCLOPROPANE 2.1 0 E0 P200 T50 F-D, S-U Category E SW2 Flammable hydrocarbon gas. Heavier than air. 1027
1028 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas. Much heavier than air (4.2). 1028
1029 DICHLOROFLUOROMETHANE (REFRIGERANT GAS R 21) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (3.6). Boiling point: 9°C. 1029
1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) 2.1 0 E0 P200 T50 F-D, S-U Category B SW2 Flammable gas. Explosive limits: 5% to 17%. Much heavier than air (2.3). 1030
1032 DIMETHYLAMINE, ANHYDROUS 2.1 0 E0 P200 T50 F-D, S-U Category D SW2 SG35 Liquefied, flammable gas with an ammonia-like odour. Heavier than air (1.6). Boiling point: 7°C. Suffocating in low concentrations. 1032
1033 DIMETHYL ETHER 2.1 0 E0 P200 T50 F-D, S-U Category B SW2 Flammable gas with a chloroform-like odour. Heavier than air (1.6). 1033
1035 ETHANE 2.1 0 E0 P200 F-D, S-U Category E SW2 Flammable gas. Explosive limits: 3% to 16%. Slightly heavier than air (1.05). 1035
1036 ETHYLAMINE 2.1 912 0 E0 P200 T50 F-D, S-U Category D SW2 SG35 Liquefied, flammable gas with an ammonia-like odour. Explosive limits: 3.5% to 14%. Heavier than air (1.6). Boiling point: 17°C. 1036
1037 ETHYL CHLORIDE 2.1 0 E0 P200 T50 F-D, S-U Category B SW2 Liquefied, flammable gas. Explosive limits: 3.5% to 15%. Much heavier than air (2.2). Boiling point: 13°C. 1037
1038 ETHYLENE, REFRIGERATED LIQUID 2.1 0 E0 P203 T75 TP5 F-D, S-U Category D SW2 Liquefied, flammable gas. Explosive limits: 3% to 34%. Lighter than air (0.98). 1038
1039 ETHYL METHYL ETHER 2.1 0 E0 P200 F-D, S-U Category B SW2 Liquefied, flammable gas. Explosive limits: 2% to 10%. Much heavier than air (2.1). Boiling point: 11°C. 1039
1040 ETHYLENE OXIDE or ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50°C 2.3 2.1 342 0 E0 P200 T50 TP20 TP90 F-D, S-U Category D SW2 Liquefied, flammable, toxic gases with an ether-like odour. Heavier than air (1.5). Boiling point: 11°C. 1040
1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide 2.1 0 E0 P200 T50 F-D, S-U Category B SW2 Liquefied, flammable gas with an ether-like odour. Heavier than air (1.5). 1041
1043 FERTILIZER AMMONIATING SOLUTION with free ammonia 2.2 120 mL E0 P200 F-C, S-V Category E SW2 Non-flammable aqueous solution of ammonium nitrate, calcium nitrate, urea and their mixtures containing ammonia gas. Emits toxic vapours of ammonia. 1043
1044 FIRE EXTINGUISHERS with compressed or liquefied gas 2.2 225 120 mL E0 P003 PP91 F-C, S-V Category A Fire extinguishers, containing compressed or liquefied gases under pressure above 175 kPa for expelling fire-extinguishing contents. 1044
1045 FLUORINE, COMPRESSED 2.3 5.1/8 0 E0 P200 F-C, S-W Category D SW2 SG6 SG19 Non-flammable, toxic and corrosive pale yellowish gas with a pungent odour. Powerful oxidant which may cause fire. Reacts with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Will explode when mixed with hydrogen. Heavier than air (1.3). Highly irritating to skin, eyes and mucous membranes. 1045
1046 HELIUM, COMPRESSED 2.2 378 392 406 974 120 mL E1 P200 F-C, S-V Category A Inert gas. Much lighter than air (0.14). 1046
1048 HYDROGEN BROMIDE, ANHYDROUS 2.3 8 0 E0 P200 F-C, S-U Category D SW2 Non-flammable, toxic and corrosive gas with a pungent odour. Highly corrosive in the presence of water. Much heavier than air (3.6). Highly irritating to the skin, eyes and mucous membranes. 1048
1049 HYDROGEN, COMPRESSED 2.1 392 974 0 E0 P200 F-D, S-U Category E SW2 SG46 Flammable, odourless gas. Explosive limits: 4% to 75%. Much lighter than air (0.07). 1049
1050 HYDROGEN CHLORIDE, ANHYDROUS 2.3 8 0 E0 P200 F-C, S-U Category D SW2 Non-flammable, toxic and corrosive colourless gas with a pungent odour. Highly corrosive in the presence of water. Heavier than air (1.3). Highly irritating to skin, eyes and mucous membranes. 1050
1051 HYDROGEN CYANIDE, STABILIZED containing less than 3% water 6.1 3 I 386 0 E0 P200 F-E, S-D Category D SW1 SW2 Very volatile, colourless flammable liquid, evolving extremely toxic flammable vapours. Boiling point: 26°C. Flashpoint: −18°C c.c. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1051
1052 HYDROGEN FLUORIDE, ANHYDROUS 8 6.1 I 0 E0 P200 T10 TP2 F-C, S-U Category D SW2 SGG1 SG36 SG49 Colourless, fuming and highly volatile liquid with an irritating and pungent odour. Highly corrosive to metals and glass in the presence of moisture. Boiling point: 20°C. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. 1052
1053 HYDROGEN SULPHIDE 2.3 2.1 0 E0 P200 F-D, S-U Category D SW2 Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.2). 1053
1055 ISOBUTYLENE 2.1 0 E0 P200 T50 F-D, S-U Category E SW2 Flammable hydrocarbon gas. Explosive limits: 1.8% to 8.8%. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air (1.94). 1055
1056 KRYPTON, COMPRESSED 2.2 378 392 120 mL E1 P200 F-C, S-V Category A Inert gas. Much heavier than air (2.9). 1056
1057 LIGHTERS or LIGHTER REFILLS containing flammable gas 2.1 201 0 E0 P002 PP84 F-D, S-U Category B SW2 Lighters or lighter refills containing butane or other flammable gas. 1057
1058 LIQUEFIED GASES non-flammable, charged with nitrogen, carbon dioxide or air 2.2 392 120 mL E1 P200 F-C, S-V Category A Non-flammable gases or mixtures of such gases which are used for filling receptacles from which the contents are to be dispersed under pressure. Vapour may be heavier than air. 1058
1060 METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED 2.1 386 0 E0 P200 T50 F-D, S-U Category B SW1 SW2 Flammable gas. Explosive limits: 3% to 11%. Heavier than air (1.4). 1060
1061 METHYLAMINE, ANHYDROUS 2.1 0 E0 P200 T50 F-D, S-U Category B SW2 SG35 Liquefied, flammable gas with an ammonia-like odour. Heavier than air (1.09). 1061
1062 METHYL BROMIDE with not more than 2.0% chloropicrin 2.3 23 0 E0 P200 T50 F-C, S-U Category D SW2 Liquefied, toxic gas with a chloroform-like odour. Much heavier than air (3.3). Boiling point: 4.5°C. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. 1062
1063 METHYL CHLORIDE (REFRIGERANT GAS R 40) 2.1 0 E0 P200 T50 F-D, S-U Category D SW2 Liquefied, flammable gas. Explosive limits: 8% to 20%. Heavier than air (1.8). 1063
1064 METHYL MERCAPTAN 2.3 2.1 0 E0 P200 T50 F-D, S-U Category D SW2 Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.7). Boiling point: 6°C. 1064
1065 NEON, COMPRESSED 2.2 378 392 120 mL E1 P200 F-C, S-V Category A Inert gas. Lighter than air (0.7). 1065
1066 NITROGEN, COMPRESSED 2.2 378 392 406 120 mL E1 P200 F-C, S-V Category A Non-flammable, odourless gas. Lighter than air (0.97). 1066
1067 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 2.3 5.1/8 0 E0 P200 T50 TP21 F-C, S-W Category D SW2 SG6 SG19 Liquefied, non-flammable, toxic and corrosive gas which gives off brown vapour with a pungent odour. Strong oxidizing agent. Boiling point: 21°C. Highly irritating to skin, eyes and mucous membranes. Toxic by inhalation, with delayed effect, similar to phosgene. 1067
1069 NITROSYL CHLORIDE 2.3 8 0 E0 P200 F-C, S-U Category D SW2 Non-flammable, toxic yellow gas with an irritating odour. Corrosive to steel. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. 1069
1070 NITROUS OXIDE 2.2 5.1 0 E0 P200 F-C, S-W Category A SW2 Non-flammable gas. Strong oxidizing agent. Heavier than air (1.5). 1070
1071 OIL GAS, COMPRESSED 2.3 2.1 0 E0 P200 F-D, S-U Category D SW2 Flammable, toxic gas. A mixture of hydrocarbons and carbon monoxide. 1071
1072 OXYGEN, COMPRESSED 2.2 5.1 355 0 E0 P200 F-C, S-W Category A Non-flammable, odourless gas. Strong oxidizing agent. Heavier than air (1.1). 1072
1073 OXYGEN, REFRIGERATED LIQUID 2.2 5.1 0 E0 P203 T75 TP5 TP22 F-C, S-W Category D Liquefied, non-flammable gas. Strong oxidizing agent. Mixtures of liquid oxygen with acetylene or oils may explode. 1073
1075 PETROLEUM GASES, LIQUEFIED 2.1 392 0 E0 P200 T50 F-D, S-U Category E SW2 Flammable hydrocarbon gases or mixtures obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air. 1075
1076 PHOSGENE 2.3 8 0 E0 P200 F-C, S-U Category D SW2 Liquefied, non-flammable, toxic and corrosive gas with a foul odour. Corrosive in the presence of water. Much heavier than air (3.5). Boiling point: 8°C. Highly irritating to skin, eyes and mucous membranes. This gas is particularly dangerous in that it may be inhaled without immediate effect but can cause severe damage and death after a few hours’ delay. 1076
1077 PROPYLENE 2.1 0 E0 P200 T50 F-D, S-U Category E SW2 Flammable hydrocarbon gas. Explosive limits: 2% to 11.1%. Heavier than air (1.5). 1077
1078 REFRIGERANT GAS, N.O.S. 2.2 274 120 mL E1 P200 T50 F-C, S-V Category A Different chlorofluorohydrocarbons or other non-flammable, non-toxic gases considered as refrigerant agents. 1078
1079 SULPHUR DIOXIDE 2.3 8 0 E0 P200 T50 TP19 F-C, S-U Category D SW2 Non-flammable, toxic and corrosive gas with a pungent odour. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. 1079
1080 SULPHUR HEXAFLUORIDE 2.2 392 120 mL E1 P200 F-C, S-V Category A Liquefied, non-flammable, odourless gas. Much heavier than air (5.1). 1080
1081 TETRAFLUOROETHYLENE, STABILIZED 2.1 386 0 E0 P200 F-D, S-U Category E SW1 SW2 Liquefied, flammable gas. Explosive limits: 11% to 60%. Much heavier than air (3.5). Irritating to skin, eyes and mucous membranes. 1081
1082 TRIFLUOROCHLORO-ETHYLENE, STABILIZED (REFRIGERANT GAS R 1113) 2.3 2.1 386 0 E0 P200 T50 F-D, S-U Category D SW1 SW2 Flammable, toxic, odourless gas. Explosive limits: 8.4% to 38.7%. Much heavier than air (4.0). 1082
1083 TRIMETHYLAMINE, ANHYDROUS 2.1 0 E0 P200 T50 F-D, S-U Category B SW2 SG35 Liquefied, flammable gas with a fishy odour. Explosive limits: 2% to 12%. Much heavier than air (2.1). Boiling point: 3°C. 1083
1085 VINYL BROMIDE, STABILIZED 2.1 386 0 E0 P200 T50 F-D, S-U Category B SW1 SW2 Liquefied, flammable gas. Much heavier than air (3.7). Boiling point: 16°C. 1085
1086 VINYL CHLORIDE, STABILIZED 2.1 386 0 E0 P200 T50 F-D, S-U Category B SW1 SW2 Liquefied, flammable gas. Explosive limits: 4% to 31%. Much heavier than air (2.2). 1086
1087 VINYL METHYL ETHER, STABILIZED 2.1 386 0 E0 P200 T50 F-D, S-U Category B SW1 SW2 Liquefied, flammable gas. Explosive limits: 2.6% to 39%. Heavier than air (2.0). Boiling point: 6°C. 1087
1088 ACETAL 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category E Colourless, volatile liquid with an agreeable odour. Flashpoint: below −18°C c.c. Explosive limits: 1.6% to 10.4%. Miscible with water. 1088
1089 ACETALDEHYDE 3 I 0 E0 P001 T11 TP2 TP7 F-E, S-D Category E Colourless liquid with a pungent, fruity odour. Flashpoint: −27°C c.c. Explosive limits: 4% to 57%. Boiling point: 21°C. Miscible with water. Harmful if swallowed or by inhalation. 1089
1090 ACETONE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category E Colourless, clear liquid, with a characteristic mint-like odour. Flashpoint: −20°C to −18°C c.c. Explosive limits: 2.5% to 13%. Miscible with water. 1090
1091 ACETONE OILS 3 II 1 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-D Category B Light yellow to brownish, oily liquids. Flashpoint: −4°C to 8°C c.c. Immiscible with water. 1091
1092 ACROLEIN, STABILIZED 6.1 3 I 354 386 0 E0 P601 T22 TP2 TP7 TP13 F-E, S-D Category D SW1 SW2 Colourless or yellow liquid with a most irritating odour. Flashpoint: −26°C c.c. Explosive limits: 2.8% to 31%. Boiling point: 52°C. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1092
1093 ACRYLONITRILE, STABILIZED 3 6.1 I 386 0 E0 P001 T14 TP2 TP13 F-E, S-D Category D SW1 SW2 Colourless, mobile liquid with a mild pungent odour. Flashpoint: −5°C c.c. Explosive limits: 3% to 17%. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Practice has shown that this substance may leak from packagings that ordinarily are leakproof to other chemicals. 1093
1098 ALLYL ALCOHOL 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW2 Colourless liquid with a pungent mustard-like odour. Flashpoint: 21°C c.c. Explosive limits: 2.5% to 18%. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1098
1099 ALLYL BROMIDE 3 6.1 I 0 E0 P001 T14 TP2 TP13 F-E, S-D Category B SW2 SGG10 Colourless to light yellow liquid with an irritating odour. Flashpoint: −1°C c.c. Explosive limits: 4.4% to 7.3%. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1099
1100 ALLYL CHLORIDE 3 6.1 I 0 E0 P001 T14 TP2 TP13 F-E, S-D Category E SW2 SGG10 Colourless liquid with an unpleasant pungent odour. Flashpoint: −29°C c.c. Explosive limits: 3.3% to 11.1%. Boiling point: 44°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1100
1104 AMYL ACETATES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquids with a pear- or banana-like odour. -AMYL ACETATE: flashpoint 25°C c.c. -AMYL ACETATE: flashpoint 32°C c.c. Immiscible with water. 1104
1105 PENTANOLS 3 II 1 L E2 P001 IBC02 T4 TP1 TP29 F-E, S-D Category B Colourless liquids with a strong odour. Immiscible with water. -AMYL ALCOHOL: flashpoint 19°C to 21°C c.c. 1105
1105 PENTANOLS 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. Explosive limits: 1.2% to 10.5%. 1105
1106 AMYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SG35 Colourless, clear liquids. Explosive limits: 2.2% to 22%. -AMYLAMINE (1-PENTYLAMINE): flashpoint 4°C c.c. -AMYLAMINE (3-PENTYLAMINE): flashpoint 2°C c.c. Miscible with water. Harmful by inhalation. Cause burns to skin, eyes and mucous membranes. 1106
1106 AMYLAMINE 3 8 III 223 5 L E1 P001 IBC03 T4 TP1 F-E, S-C Category A SG35 See entry above. However, irritating to skin, eyes and mucous membranes. 1106
1107 AMYL CHLORIDE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B SGG10 Colourless or light brown liquids with an aromatic odour. -AMYL CHLORIDE: flashpoint 11°C. Explosive limits: -AMYL CHLORIDE 1.4% to 8.6%. Immiscible with water. 1107
1108 1-PENTENE (-AMYLENE) 3 I 0 E3 P001 T11 TP2 F-E, S-D Category E Colourless, volatile liquid with a disagreeable odour. Flashpoint: −20°C c.c. Explosive limits: 1.4% to 8.7%. Boiling point: 30°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. 1108
1109 AMYL FORMATES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquids with a pleasant odour. -AMYL FORMATE: flashpoint 27°C c.c. ISOAMYL FORMATE: flashpoint 26°C c.c. Explosive limits: 1.7% to 10%. Immiscible with water. 1109
1110 -AMYL METHYL KETONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. 1110
1111 AMYL MERCAPTAN 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B SG50 SG57 Colourless to yellow liquids with an extremely disagreeable garlic-like odour. -AMYL MERCAPTAN: flashpoint −7°C c.c. -AMYL MERCAPTAN: flashpoint 19°C c.c. ISOAMYL MERCAPTAN: flashpoint 18°C c.c. Immiscible with water. These substances may leak from packagings that ordinarily are leakproof to other chemicals. 1111
1112 AMYL NITRATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A SW2 Colourless liquids with an ether-like odour. -AMYL NITRATE: flashpoint 48°C c.c. ISOAMYL NITRATE: flashpoint 52°C c.c. Immiscible with water. Harmful by inhalation. 1112
1113 AMYL NITRITE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category E SW2 Yellowish, transparent, volatile liquid with a fragrant fruity odour. Flashpoint of the pure ISOAMYL NITRITE: −20°C c.c. Flashpoint of pure -AMYL NITRITE: 10°C c.c. Decomposes on exposure to air, light or water, evolving toxic nitrous fumes which are orange in colour. Immiscible with water. Harmful by inhalation. 1113
1114 BENZENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B SW2 Colourless liquid with a characteristic odour. Flashpoint: −11°C c.c. Explosive limits: 1.4% to 8%. Freezing point 5°C; flashes below its freezing point. Immiscible with water. Narcotic. Exposure to this substance may produce serious chronic effects of a toxic nature. 1114
1120 BUTANOLS 3 II 1 L E2 P001 IBC02 T4 TP1 TP29 F-E, S-D Category B Colourless liquids with a disagreeable odour. Explosive limits: -BUTANOL 1.4% to 11.2%. -BUTANOL 1.7% to 9.8%. -BUTANOL 2.4% to 8%. -BUTANOL solidifies at about 25°C. -BUTANOL is immiscible with water. -BUTANOL is immiscible with water. -BUTANOL is miscible with water. Irritating to skin, eyes and mucous membranes. 1120
1120 BUTANOLS 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1120
1123 BUTYL ACETATES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquids with a pineapple-like odour. Immiscible with water. -BUTYL ACETATE: flashpoint 27°C c.c. Explosive limits: 1.5% to 15%. 1123
1123 BUTYL ACETATES 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1123
1125 -BUTYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SW2 SG35 Flashpoint: −9°C c.c. Explosive limits: 1.7% to 10%. Colourless, volatile liquid with an ammonia-like odour. Miscible with water. Causes burns to skin, eyes and mucous membranes. 1125
1126 1-BROMOBUTANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B SW2 SGG10 Colourless to pale straw-coloured, clear liquid. Flashpoint: 13°C c.c. Explosive limits: 2.6% to 6.6%. Immiscible with water. Narcotic. 1126
1127 CHLOROBUTANES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B SGG10 Colourless liquids. -BUTYL CHLORIDE: flashpoint −30°C c.c., boiling point 51°C. Immiscible with water. 1127
1128 -BUTYL FORMATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: 18°C c.c. Explosive limits: 1.6% to 8.3%. Immiscible with water. 1128
1129 BUTYRALDEHYDE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with a characteristic pungent odour. Flashpoint: −7°C c.c. Explosive limits: 1.4% to 12.5%. Immiscible with water. 1129
1130 CAMPHOR OIL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E Category A Colourless oil with a characteristic odour. Flashpoint: 47°C c.c. Immiscible with water. 1130
1131 CARBON DISULPHIDE 3 6.1 I 0 E0 P001 PP31 T14 TP2 TP7 TP13 F-E, S-D Category D SW2 SG63 Colourless or faintly yellow, clear liquid, almost odourless when pure; the commercial substance has a strong disagreeable odour. Flashpoint: −30°C c.c. Explosive limits: 1% to 60%. Boiling point: 46°C. Ignition temperature: 100°C. Immiscible with water. Vapours are heavier than air, will travel a considerable distance to a source of ignition and will flash back. Vapours may be ignited by contact with an ordinary light bulb or a warm steam pipe. Toxic if swallowed, by skin contact or by inhalation. 1131
1133 ADHESIVES containing flammable liquid 3 I 500 mL E3 P001 T11 TP1 TP8 TP27 F-E, S-D Category E Adhesives are solutions of gums, resins, etc., usually volatile due to the solvents. Miscibility with water depends upon their composition. 1133
1133 ADHESIVES containing flammable liquid 3 II 5 L E2 P001 PP1 IBC02 T4 TP1 TP8 F-E, S-D Category B See entry above. 1133
1133 ADHESIVES containing flammable liquid 3 III 223 955 5 L E1 P001 LP01 PP1 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1133
1134 CHLOROBENZENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A SGG10 Colourless liquid with an almond-like odour. Flashpoint: 29°C c.c. Explosive limits: 1.3% to 11%. Immiscible with water. 1134
1135 ETHYLENE CHLOROHYDRIN 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW2 Colourless flammable liquid with a faint, ethereal odour. Flashpoint: 60°C o.c. Explosive limits: 4.9% to 15.9%. Miscible with water. When involved in a fire, evolves extremely toxic (phosgene) and corrosive (hydrogen chloride) fumes. Highly toxic if swallowed, by skin contact or by inhalation. 1135
1136 COAL TAR DISTILLATES, FLAMMABLE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-E Category B Immiscible with water. May form extremely sensitive compounds with heavy metals or their salts. 1136
1136 COAL TAR DISTILLATES, FLAMMABLE 3 III 223 955 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-E Category A See entry above. 1136
1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under-coating, drum or barrel lining) 3 I 500 mL E3 P001 T11 TP1 TP8 TP27 F-E, S-E Category E Miscibility with water depends upon the composition. 1139
1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under-coating, drum or barrel lining) 3 II 5 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-E Category B See entry above. 1139
1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under-coating, drum or barrel lining) 3 III 955 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E Category A See entry above. 1139
1143 CROTONALDEHYDE or CROTONALDEHYDE, STABILIZED 6.1 3 I 324 354 386 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW1 SW2 Colourless, mobile liquid with a pungent odour. Turns to pale yellow in contact with light and air. Miscible with water. Flashpoint: 13°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. May cause lung damage. 1143
1144 CROTONYLENE 3 I 0 E3 P001 T11 TP2 F-E, S-D Category E Colourless liquid. Flashpoint: −53°C c.c. Lower explosive limit: 1.4%. Boiling point: 27°C. Immiscible with water. 1144
1145 CYCLOHEXANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category E Colourless, mobile liquid with a sweet aromatic odour. Flashpoint: −18°C c.c. Explosive limits: 1.2% to 8.4%. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. 1145
1146 CYCLOPENTANE 3 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D Category E Colourless liquid with a pungent odour. Flashpoint: below −18°C c.c. Explosive limits: 1.4% to 8%. Boiling point: 49°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. 1146
1147 DECAHYDRONAPHTHALENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquids with an aromatic odour. Flashpoint: 52°C to 57°C c.c. Explosive limits: 0.7% to 4.9%. Immiscible with water. Harmful by inhalation. 1147
1148 DIACETONE ALCOHOL 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Explosive limits: 1.4% to 8%. Miscible with water. 1148
1148 DIACETONE ALCOHOL 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1148
1149 DIBUTYL ETHERS 3 III 5 L E1 P001 IBC03 T2 TP1 F-E, S-D Category A Colourless liquids with a mild ether-like odour. Explosive limits: 0.9% to 8.5%. Immiscible with water. -DIBUTYL ETHER: flashpoint 25°C c.c. 1149
1150 1,2-DICHLOROETHYLENE 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-D Category B SGG10 Colourless liquid with a chloroform-like odour. Flashpoint: 6°C c.c. Explosive limits: 5.6% to 16%. Immiscible with water. Boiling range: 48°C to 61°C. 1150
1152 DICHLOROPENTANES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A SGG10 Light yellow liquids. 1,5-DICHLOROPENTANE: flashpoint 26°C c.c. Immiscible with water. 1152
1153 ETHYLENE GLYCOL DIETHYL ETHER 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category A Colourless liquid with an ether-like odour. Flashpoint: 35°C c.c. Immiscible with water. 1153
1153 ETHYLENE GLYCOL DIETHYL ETHER 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1153
1154 DIETHYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category E SW2 SG35 Colourless liquid with an ammonia-like odour. Flashpoint: −39°C c.c. Explosive limits: 1.7% to 10.1%. Boiling point: 55°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. Higher concentrations cause dangerous lung irritation. 1154
1155 DIETHYL ETHER (ETHYL ETHER) 3 I 0 E3 P001 T11 TP2 F-E, S-D Category E SW2 Colourless, volatile and mobile liquid with a pleasant aromatic odour. Flashpoint: −40°C c.c. Explosive limits: 1.7% to 48%. Boiling point: 34°C. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Strongly narcotic. Readily ignited by static electricity. 1155
1156 DIETHYL KETONE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless, mobile liquid. Flashpoint: 13°C c.c. Lower explosive limit: 1.6%. Immiscible with water. 1156
1157 DIISOBUTYL KETONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 49°C c.c. Explosive limits: 0.8% to 7.1%. Immiscible with water. 1157
1158 DIISOPROPYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SG35 Colourless, volatile liquid with a fishy odour. Flashpoint: −7°C c.c. Explosive limits: 1.1% to 7.1%. Partially miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. 1158
1159 DIISOPROPYL ETHER 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category E SW2 Colourless liquid with an ether-like odour. Flashpoint: −29°C c.c. Explosive limits: 1.1% to 21%. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Strongly narcotic. Readily ignited by static electricity. 1159
1160 DIMETHYLAMINE, AQUEOUS SOLUTION 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SGG18 SG35 Aqueous solution of a flammable gas with an ammonia-like odour. Flashpoint for 60% solution in water: −32°C c.c. Explosive limits: 2.8% to 14.4%. Boiling point for 60% solution in water: 36°C. Flashpoint for 25% solution in water: 0°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1160
1161 DIMETHYL CARBONATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Immiscible with water. Flashpoint: 18°C c.c. 1161
1162 DIMETHYLDICHLOROSILANE 3 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C Category B SW2 Colourless liquid with a pungent odour. Flashpoint: −9°C c.c. Explosive limits: 1.4% to 9.5%. Immiscible with water. Reacts with water to form a complex mixture of dimethylsiloxanes and evolves hydrogen chloride, a toxic and corrosive gas. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. 1162
1163 DIMETHYLHYDRAZINE, UNSYMMETRICAL 6.1 3/8 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-C Category D SW2 SGG18 SG5 SG8 SG13 SG35 Colourless liquid with an ammonia-like odour. Flashpoint: −18°C c.c. Explosive limits: 2% to 95%. Miscible with water, generating heat. Reacts violently with acids. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. May react dangerously with oxidizing substances. 1163
1164 DIMETHYL SULPHIDE 3 II 1 L E2 P001 IBC02 B8 T7 TP2 F-E, S-D Category E SW2 Colourless liquid with a disagreeable odour. Flashpoint: −37°C c.c. Explosive limits: 2.2% to 19.7%. Boiling point: 37°C. Immiscible with water. When involved in a fire, evolves toxic gases. Narcotic in high concentrations. 1164
1165 DIOXANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with an ether-like odour. Flashpoint: 12°C c.c. Explosive limits: 2% to 22%. Miscible with water. Harmful by inhalation. 1165
1166 DIOXOLANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B SW2 Colourless liquid. Flashpoint: 2°C c.c. Miscible with water. Harmful by inhalation. 1166
1167 DIVINYL ETHER, STABILIZED 3 I 386 0 E3 P001 T11 TP2 F-E, S-D Category E SW1 SW2 Colourless, clear liquid with a characteristic odour. Flashpoint: −30°C c.c. Explosive limits: 1.7% to 27%. Boiling point: 30°C. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Strongly narcotic. Readily ignited by static electricity. 1167
1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 3 II 144 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category A Colourless, volatile liquids. Pure ETHANOL: flashpoint 13°C c.c. Explosive limits: 3.3% to 19%. Miscible with water. 1170
1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 3 III 144 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1170
1171 ETHYLENE GLYCOL MONOETHYL ETHER 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 40°C c.c. Explosive limits: 1.7% to 15.6%. Miscible with water. 1171
1172 ETHYLENE GLYCOL MONOETHYL ETHER ACETATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 51°C c.c. Explosive limits: 1.7% to 10.1%. Partially miscible with water. 1172
1173 ETHYL ACETATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with a fragrant odour. Flashpoint: −4°C c.c. Explosive limits: 2.18% to 11.5%. Immiscible with water. 1173
1175 ETHYLBENZENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with an aromatic odour. Flashpoint: 22°C c.c. Explosive limits: 1% to 6.7%. Immiscible with water. 1175
1176 ETHYL BORATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: 11°C c.c. Immiscible with water. 1176
1177 2-ETHYLBUTYL ACETATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 54°C o.c. Immiscible with water. 1177
1178 2-ETHYLBUTYRALDEHYDE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: 11°C c.c. Explosive limits: 1.2% to 7.7%. Immiscible with water. 1178
1179 ETHYL BUTYL ETHER 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: −1°C c.c. Immiscible with water. 1179
1180 ETHYL BUTYRATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless, volatile liquid with a pineapple-like odour. Flashpoint: 26°C c.c. Immiscible with water. 1180
1181 ETHYL CHLOROACETATE 6.1 3 II 100 mL E4 P001 IBC02 T7 TP2 F-E, S-D Category A Colourless, flammable liquid with a pungent and fruity odour. Flashpoint: 54°C c.c. Immiscible with water. When heated, evolves toxic and corrosive fumes. Toxic if swallowed, by skin contact or by inhalation. 1181
1182 ETHYL CHLOROFORMATE 6.1 3/8 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-C Category D SW2 SGG1 SG5 SG8 SG36 SG49 Colourless liquid. Flashpoint: 16°C c.c. Reacts and decomposes with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1182
1183 ETHYLDICHLOROSILANE 4.3 3/8 I 0 E0 P401 PP31 T14 TP2 TP7 TP13 F-G, S-O Category D SW2 H1 SGG1 SG5 SG8 SG13 SG25 SG26 SG36 SG49 Colourless, very volatile liquid with a pungent odour. Flashpoint: −1°C c.c. Immiscible with water. Reacts violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Causes burns to skin, eyes and mucous membranes. 1183
1184 ETHYLENE DICHLORIDE 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D Category B SW2 SGG10 Colourless liquid with a chloroform-like odour. Flashpoint: 13°C c.c. Explosive limits: 6.2% to 15.9%. Immiscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. 1184
1185 ETHYLENEIMINE, STABILIZED 6.1 3 I 354 386 0 E0 P601 T22 TP2 TP13 F-E, S-D Category D SW1 SW2 Colourless oily flammable liquid with a pungent ammonia-like odour. Flashpoint: −13°C c.c. Boiling point: 55°C. Explosive limits: 3.6% to 6.0%. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1185
1188 ETHYLENE GLYCOL MONOMETHYL ETHER 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 38°C c.c. Explosive limits: 1.8% to 20%. Miscible with water. 1188
1189 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid with a characteristic odour. Flashpoint: 44°C c.c. Explosive limits: 1.7% to 8.2%. Miscible with water. 1189
1190 ETHYL FORMATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category E Colourless liquid with a pleasant aromatic odour. Flashpoint: −20°C c.c. Explosive limits: 3.5% to 16.5%. Boiling point: 54°C. Immiscible with water. 1190
1191 OCTYL ALDEHYDES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquids with a characteristic odour. Flashpoint: 44°C to 52°C c.c. Explosive limits: 0.9% to 7.2%. Immiscible with water. 1191
1192 ETHYL LACTATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 46°C c.c. Explosive limits: 1.5% to 11.4%. Miscible with water. 1192
1193 ETHYL METHYL KETONE (METHYL ETHYL KETONE) 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: −1°C c.c. Explosive limits: 1.8% to 11.5%. Miscible with water. 1193
1194 ETHYL NITRITE SOLUTION 3 6.1 I 900 0 E0 P001 F-E, S-D Category D SW2 Alcoholic solution of ethyl nitrite. Extremely volatile, with an aromatic, ethereal odour. Explosive limits of the pure product: 3% to 50%. Boiling point of pure product: 17°C. Miscible or partially miscible with water. Decomposes under exposure to air, light, water or heat to evolve toxic nitrous fumes. Toxic if swallowed, by skin contact or by inhalation. Inhalation of ethyl nitrite vapours, even in small quantities, rapidly affects the heart and can be dangerous. Transport of ETHYL NITRITE pure is prohibited. 1194
1195 ETHYL PROPIONATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with a pineapple-like odour. Flashpoint: 12°C c.c. Explosive limits: 1.8% to 11%. Immiscible with water. 1195
1196 ETHYLTRICHLOROSILANE 3 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C Category B SW2 Colourless liquid with a pungent odour. Flashpoint: 14°C c.c. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Causes burns to skin and eyes. Irritating to mucous membranes. 1196
1197 EXTRACTS, LIQUID, for flavour or aroma 3 II 5 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-D Category B Usually consist of alcoholic solutions. Miscibility with water depends upon the composition. 1197
1197 EXTRACTS, LIQUID, for flavour or aroma 3 III 223 955 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1197
1198 FORMALDEHYDE SOLUTION, FLAMMABLE 3 8 III 5 L E0 P001 IBC03 T4 TP1 F-E, S-C Category A SW2 Colourless liquids with a pungent odour. Flashpoint: 32−60°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. 1198
1199 FURALDEHYDES 6.1 3 II 100 mL E4 P001 IBC02 T7 TP2 F-E, S-D Category A Colourless or reddish-brown, mobile liquids with a pungent odour. Miscible with water. Explosive limits for 2-FURALDEHYDE: 2.1% to 19.3%. Flashpoints: 2-FURALDEHYDE 60°C c.c., 3-FURALDEHYDE 48°C c.c. Toxic if swallowed, by skin contact or by inhalation. 1199
1201 FUSEL OIL 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless, oily liquid with a disagreeable odour. A mixture consisting of amyl alcohols. Immiscible with water. 1201
1201 FUSEL OIL 3 III 223 955 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1201
1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E Category A Immiscible with water. 1202
1203 MOTOR SPIRIT or GASOLINE or PETROL 3 II 243 1 L E2 P001 IBC02 T4 TP1 F-E, S-E Category E Immiscible with water. 1203
1204 NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin 3 II 28 1 L E0 P001 PP5 IBC02 F-E, S-D Category B Immiscible with water. Ignites readily. When involved in a fire, evolves toxic nitrous fumes. Not explosive in this state but damage to, or leakage from, a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. 1204
1206 HEPTANES 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-D Category B Colourless, volatile liquids. Explosive limits: 1.1% to 6.7%. -HEPTANE: flashpoint −4°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1206
1207 HEXALDEHYDE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid with a pungent odour. Flashpoint: 32°C c.c. Immiscible with water. 1207
1208 HEXANES 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-D Category E Colourless, volatile liquids with a faint odour. Explosive limits: 1.1% to 7.5%. -HEXANE: flashpoint −22°C c.c., boiling point 69°C. NEOHEXANE: flashpoint −48°C c.c., boiling point 50°C. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. 1208
1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 3 I 163 367 500 mL E3 P001 T11 TP1 TP8 F-E, S-D Category E Fluid or viscous liquid containing colouring matter in solution or suspension. Miscibility with water depends upon the solvent. 1210
1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 3 II 163 367 5 L E2 P001 PP1 IBC02 T4 TP1 TP8 F-E, S-D Category B See entry above. 1210
1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 3 III 163 223 367 955 5 L E1 P001 LP01 PP1 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1210
1212 ISOBUTANOL (ISOBUTYL ALCOHOL) 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid with a sweet odour. Flashpoint: 28°C c.c. Explosive limits: 1.2% to 10.9%. Partially miscible with water. 1212
1213 ISOBUTYL ACETATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with a pineapple-like odour. Flashpoint: 18°C c.c. Explosive limits: 1.3% to 10.5%. Immiscible with water. 1213
1214 ISOBUTYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SW2 SG35 Colourless liquid. Flashpoint: −9°C c.c. Explosive limits: 3.4% to 9%. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 1214
1216 ISOOCTENES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquids. Immiscible with water. 1216
1218 ISOPRENE, STABILIZED 3 I 386 0 E3 P001 T11 TP2 F-E, S-D Category D SW1 Colourless, volatile liquid. Flashpoint: −48°C c.c. Explosive limits: 1.5% to 9.7%. Boiling point: 34°C. Immiscible with water. 1218
1219 ISOPROPANOL (ISOPROPYL ALCOHOL) 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless, mobile liquid. Flashpoint: 12°C c.c. Explosive limits: 2% to 12%. Miscible with water. 1219
1220 ISOPROPYL ACETATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with an aromatic odour. Flashpoint: 11°C c.c. Explosive limits: 1.8% to 7.8%. Immiscible with water. 1220
1221 ISOPROPYLAMINE 3 8 I 0 E0 P001 T11 TP2 F-E, S-C Category E SW2 SG35 Colourless, volatile liquid with an ammonia-like odour. Flashpoint: −37°C c.c. Explosive limits: 2.3% to 10.4%. Boiling point: 32°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. 1221
1222 ISOPROPYL NITRATE 3 II 26 1 L E2 P001 F-E, S-D Category D Colourless liquid. Flashpoint: 12°C c.c. Explosive limits: up to 100%. Immiscible with water. May explode on heating. Harmful by inhalation. 1222
1223 KEROSENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-E Category A Immiscible with water. 1223
1224 KETONES, LIQUID, N.O.S. 3 II 274 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-D Category B 1224
1224 KETONES, LIQUID, N.O.S. 3 III 223 274 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D Category A 1224
1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 6.1 II 274 1 L E0 P001 IBC02 T11 TP2 TP27 F-E, S-D Category B SW2 SG50 SG57 Colourless to yellow liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1228
1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 6.1 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-E, S-D Category B SW2 SG50 SG57 Colourless to yellow liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1228
1229 MESITYL OXIDE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless, oily liquid with a sweet odour. Flashpoint: 32°C c.c. Miscible with water. 1229
1230 METHANOL 3 6.1 II 279 1 L E2 P001 IBC02 T7 TP2 F-E, S-D Category B SW2 Colourless, volatile liquid. Flashpoint: 12°C c.c. Explosive limits: 6% to 36.5%. Miscible with water. Toxic if swallowed; may cause blindness. Avoid skin contact. 1230
1231 METHYL ACETATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless, volatile liquid with a fragrant odour. Flashpoint: −10°C c.c. Explosive limits: 3% to 16%. Miscible with water. 1231
1233 METHYLAMYL ACETATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 43°C o.c. Immiscible with water. 1233
1234 METHYLAL 3 II 1 L E2 P001 IBC02 B8 T7 TP2 F-E, S-D Category E Colourless, volatile liquid with a chloroform-like odour. Flashpoint: −28°C c.c. Explosive limits: 3.6% to 12.6%. Boiling point: 42°C. Miscible with water. Irritating to skin, eyes and mucous membranes. 1234
1235 METHYLAMINE, AQUEOUS SOLUTION 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category E SGG18 SG35 SG54 Aqueous solution of a flammable gas having an ammonia-like odour. Explosive limits: 5% to 20.7% (pure product). Boiling point: −7°C (pure product). Commercial product is a 40% solution with: boiling point 48°C, flashpoint −13°C c.c. Miscible with water. May react explosively with mercury. Causes burns to skin, eyes and mucous membranes. 1235
1237 METHYL BUTYRATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: 14°C c.c. Immiscible with water. 1237
1238 METHYL CHLOROFORMATE 6.1 3/8 I 354 0 E0 P602 T22 TP2 TP13 F-E, S-C Category D SW2 SGG1 SG5 SG8 SG36 SG49 Colourless liquid. Flashpoint: 5°C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1238
1239 METHYL CHLOROMETHYL ETHER 6.1 3 I 354 0 E0 P602 T22 TP2 TP13 F-E, S-D Category D SW2 Colourless liquid. Flashpoint: below −18°C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1239
1242 METHYLDICHLOROSILANE 4.3 3/8 I 0 E0 P401 PP31 T14 TP2 TP7 TP13 F-G, S-O Category D SW2 H1 SGG1 SG5 SG8 SG13 SG25 SG26 SG36 SG49 Colourless, very volatile liquid with a pungent odour. Flashpoint: −26°C c.c. Explosive limits: 4.5% to 70%. Boiling point: 41°C. Immiscible with water. Reacts violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Causes burns to skin, eyes and mucous membranes. 1242
1243 METHYL FORMATE 3 I 0 E3 P001 T11 TP2 F-E, S-D Category E Colourless liquid with an agreeable odour. Flashpoint: −32°C c.c. Explosive limits: 5% to 22.7%. Boiling point: 32°C. Miscible with water. 1243
1244 METHYLHYDRAZINE 6.1 3/8 I 354 0 E0 P602 T22 TP2 TP13 F-E, S-C Category D SW2 SGG18 SG5 SG8 SG13 SG35 Colourless liquid with an ammonia-like odour. Flashpoint: 20°C c.c. Explosive limits: 2.5% to 98%. Miscible with water. Reacts violently with acids. May react dangerously with oxidizing substances. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1244
1245 METHYL ISOBUTYL KETONE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with a pleasant odour. Flashpoint: 14°C c.c. Explosive limits: 1.4% to 7.5%. Immiscible with water. 1245
1246 METHYL ISOPROPENYL KETONE, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category C SW1 Colourless liquid with a pleasant odour. Explosive limits: 1.8% to 9%. Immiscible with water. 1246
1247 METHYL METHACRYLATE MONOMER, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category C SW1 SW2 Colourless, volatile liquid. Flashpoint: 8°C c.c. Explosive limits: 1.5% to 11.6%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1247
1248 METHYL PROPIONATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: −2°C c.c. Explosive limits: 2.4% to 13%. Immiscible with water. 1248
1249 METHYL PROPYL KETONE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: 7°C c.c. Explosive limits: 1.5% to 8.2%. Immiscible with water. 1249
1250 METHYLTRICHLOROSILANE 3 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C Category B SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Flashpoint: 8°C o.c. Explosive limits: 5.1% to 20%. Immiscible with water. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin and eyes. Irritating to mucous membranes. 1250
1251 METHYL VINYL KETONE, STABILIZED 6.1 3/8 I 354 386 0 E0 P601 T22 TP2 TP13 F-E, S-C Category D SW1 SW2 SG5 SG8 Colourless liquid with a pungent odour. Miscible with water. Explosive limits: 2.1% to 15.6%. Flashpoint: −7°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1251
1259 NICKEL CARBONYL 6.1 3 I 0 E0 P601 F-E, S-D Category D SW2 SG63 Colourless or yellow, volatile, flammable liquid. Flashpoint: below −20°C c.c. Oxidizes in air and explodes at a temperature of 60°C. Lower explosive limit: 2.0%. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1259
1261 NITROMETHANE 3 II 26 1 L E0 P001 F-E, S-D Category A Colourless liquid. Flashpoint: 35°C c.c. Explosive limits: 7.1% to 63%. Miscible with water. Fire and explosion hazard if package is ruptured. 1261
1262 OCTANES 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-E Category B Colourless liquids. Explosive limits: 1% to 6.5%. ISOOCTANE: flashpoint −12°C c.c. -OCTANE: flashpoint 13°C c.c. Immiscible with water. 1262
1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) 3 I 163 367 500 mL E3 P001 T11 TP1 TP8 TP27 F-E, S-E Category E Miscibility with water depends upon the composition. 1263
1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) 3 II 163 367 5 L E2 P001 PP1 IBC02 T4 TP1 TP8 TP28 F-E, S-E Category B See entry above. 1263
1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) 3 III 163 223 367 955 5 L E1 P001 LP01 PP1 IBC03 T2 TP1 TP29 F-E, S-E Category A See entry above. 1263
1264 PARALDEHYDE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 27°C c.c. Lower explosive limit: 1.3%. Miscible with water. 1264
1265 PENTANES, liquid 3 I 0 E3 P001 T11 TP2 F-E, S-D Category E Colourless liquids with a paraffin-like odour. Explosive limits: 1.4% to 8%. ISOPENTANE (2-METHYLBUTANE): boiling point 28°C. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. 1265
1265 PENTANES, liquid 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category E See entry above. -PENTANE: boiling point 36°C. 1265
1266 PERFUMERY PRODUCTS with flammable solvents 3 II 163 5 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-D Category B Miscibility with water depends upon the composition. 1266
1266 PERFUMERY PRODUCTS with flammable solvents 3 III 163 223 904 955 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1266
1267 PETROLEUM CRUDE OIL 3 I 357 500 mL E3 P001 T11 TP1 TP8 F-E, S-E Category E Immiscible with water. 1267
1267 PETROLEUM CRUDE OIL 3 II 357 1 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-E Category B See entry above. 1267
1267 PETROLEUM CRUDE OIL 3 III 223 357 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E Category A See entry above. 1267
1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 3 I 500 mL E3 P001 T11 TP1 TP8 F-E, S-E Category E Immiscible with water. 1268
1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 3 II 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-E Category B See entry above. 1268
1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 3 III 223 955 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-E Category A See entry above. 1268
1272 PINE OIL 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-E Category A Volatile oils with characteristic odours. Flashpoint: 57°C to 60°C c.c. Immiscible with water. 1272
1274 -PROPANOL (PROPYL ALCOHOL, NORMAL) 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Explosive limits: 2% to 12%. Flashpoint: 15°C to 23°C c.c. Miscible with water. 1274
1274 -PROPANOL (PROPYL ALCOHOL, NORMAL) 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. Flashpoint: 23°C to 26°C c.c. 1274
1275 PROPIONALDEHYDE 3 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D Category E Colourless liquid with a pungent odour. Flashpoint: below −18°C c.c. Explosive limits: 2.3% to 21%. Boiling point: 49°C. Miscible with water. Irritating to skin, eyes and mucous membranes. 1275
1276 -PROPYL ACETATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless, clear liquid with a pleasant odour. Flashpoint: 10°C c.c. Explosive limits: 1.8% to 8%. Immiscible with water. 1276
1277 PROPYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category E SW2 SG35 Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 2% to 10.4%. Boiling point: 48°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. 1277
1278 1-CHLOROPROPANE 3 II 1 L E0 P001 IBC02 B8 T7 TP2 F-E, S-D Category E SGG10 Colourless liquid with a chloroform-like odour. Flashpoint: −18°C c.c. Explosive limits: 2.6% to 10.5%. Boiling point: 47°C. Immiscible with water. 1278
1279 1,2-DICHLOROPROPANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B SGG10 Colourless liquid. Flashpoint: 15°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin and eyes. 1279
1280 PROPYLENE OXIDE 3 I 0 E3 P001 T11 TP2 TP7 F-E, S-D Category E SW2 Colourless, volatile liquid with an ether-like odour. Flashpoint: below −18°C c.c. Explosive limits: 2% to 22%. Boiling point: 34°C. Partially miscible with water. 1280
1281 PROPYL FORMATES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquids with a pleasant odour. Explosive limits: 2.4% to 7.8%. Miscibility with water depends upon the composition. Irritating to skin, eyes and mucous membranes. 1281
1282 PYRIDINE 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-D Category B SW2 Colourless or slightly yellow liquid with a pungent odour. Flashpoint: 17°C c.c. Explosive limits: 1.8% to 12.4%. Miscible with water. Harmful by inhalation. 1282
1286 ROSIN OIL 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-E Category B Colourless to brown viscous liquid. Immiscible with water. 1286
1286 ROSIN OIL 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E Category A See entry above. 1286
1287 RUBBER SOLUTION 3 II 5 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-D Category B Miscibility with water depends upon the composition. 1287
1287 RUBBER SOLUTION 3 III 223 955 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1287
1288 SHALE OIL 3 II 1 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-E Category B Immiscible with water. 1288
1288 SHALE OIL 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E Category A Immiscible with water. 1288
1289 SODIUM METHYLATE SOLUTION in alcohol 3 8 II 1 L E2 P001 IBC02 T7 TP1 TP8 F-E, S-C Category B SGG18 SG35 Reacts violently with water. Causes burns to skin, eyes and mucous membranes. 1289
1289 SODIUM METHYLATE SOLUTION in alcohol 3 8 III 223 5 L E1 P001 IBC03 T4 TP1 F-E, S-C Category A SGG18 SG35 See entry above. Irritating to skin, eyes and mucous membranes. 1289
1292 TETRAETHYL SILICATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A. Colourless liquid. Flashpoint: 37°C c.c. Explosive limits: 1.3% to 23%. Immiscible with water. 1292
1293 TINCTURES, MEDICINAL 3 II 1 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-D Category B Miscibility with water depends upon the composition. 1293
1293 TINCTURES, MEDICINAL 3 III 904 955 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1293
1294 TOLUENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid with a benzene-like odour. Flashpoint: 7°C c.c. Explosive limits: 1.27% to 7%. Immiscible with water. 1294
1295 TRICHLOROSILANE 4.3 3/8 I 0 E0 P401 PP31 T14 TP2 TP7 TP13 F-G, S-O Category D SW2 H1 SGG1 SG5 SG8 SG13 SG25 SG26 SG36 SG49 SG72 Colourless, very volatile, flammable and corrosive liquid. Flashpoint: below −50°C. Explosive limits: 1.2% to 90.5%. Boiling point: 32°C. Reacts with water or steam to produce heat, which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Causes burns to skin, eyes and mucous membranes. 1295
1296 TRIETHYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SW2 SG35 Colourless liquid with a strong ammonia-like odour. Flashpoint: −11°C c.c. Explosive limits: 1.2% to 8%. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 1296
1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 3 8 I 0 E0 P001 T11 TP1 F-E, S-C Category D SW2 SG35 SG54 Aqueous solution of a flammable gas with an ammonia-like odour. Flashpoint depending on percentage of dissolved gas. May react explosively with mercury. Miscible with water. An aqueous solution of 45% TRIMETHYLAMINE, by mass, has a flashpoint of −45°C c.c. and a boiling point of 30°C (applicable to PG I only). Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. 1297
1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SW2 SG35 SG54 See entry above. 1297
1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 3 8 III 223 5 L E1 P001 IBC03 T7 TP1 F-E, S-C Category A SW2 SG35 SG54 See entry above. Irritating to skin, eyes and mucous membranes. 1297
1298 TRIMETHYLCHLOROSILANE 3 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C Category E SW2 SGG1 SG36 SG49 Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.8% to 6%. Boiling point: 57°C. Immiscible with water. Readily hydrolysed by moisture, evolving hydrogen chloride, a toxic and corrosive gas. Causes burns to skin, eyes and mucous membranes. 1298
1299 TURPENTINE 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-E Category A Colourless liquid. Flashpoint: 35°C c.c. Mixture of resin and volatile oils. Immiscible with water. 1299
1300 TURPENTINE SUBSTITUTE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-E Category B Immiscible with water. 1300
1300 TURPENTINE SUBSTITUTE 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E Category A See entry above. 1300
1301 VINYL ACETATE, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category C SW1 Colourless to light yellow liquid. Flashpoint: −8°C c.c. Explosive limits: 2.6% to 14%. Immiscible with water. 1301
1302 VINYL ETHYL ETHER, STABILIZED 3 I 386 0 E3 P001 T11 TP2 F-E, S-D Category D SW1 Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 28%. Boiling point: 33°C. Immiscible with water. Extremely reactive; may polymerize. 1302
1303 VINYLIDENE CHLORIDE, STABILIZED 3 I 386 0 E3 P001 T12 TP2 TP7 F-E, S-D Category D SW1 SW2 SGG10 Colourless to straw-coloured, volatile liquid with a sweet odour. Flashpoint: −28°C c.c. Explosive limits: 6.5% to 15.5%. Boiling point: 32°C. Immiscible with water. 1303
1304 VINYL ISOBUTYL ETHER, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category C SW1 Colourless liquid. Flashpoint: −9°C o.c. Immiscible with water. 1304
1305 VINYLTRICHLOROSILANE 3 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C Category B SW2 SGG1 SG36 SG49 Colourless, pale yellow or pink liquid with a pungent odour. Flashpoint: 11°C c.c. Lower explosive limit: 3%. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Immiscible with water. In the presence of moisture, corrosive to most metals. 1305
1306 WOOD PRESERVATIVES, LIQUID 3 II 5 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-D Category B Miscibility with water depends upon the composition. Harmful by inhalation. 1306
1306 WOOD PRESERVATIVES, LIQUID 3 III 223 955 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. 1306
1307 XYLENES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquids. Flashpoint: 17°C to 23°C c.c. Explosive limits: 1.1% to 7%. Immiscible with water. 1307
1307 XYLENES 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A See entry above. Flashpoint: 23°C to 30°C c.c. 1307
1308 ZIRCONIUM, SUSPENDED IN A FLAMMABLE LIQUID 3 I 0 E0 P001 PP33 F-E, S-D Category D Finely divided zirconium metal in a flammable liquid. Immiscible with water. Spillage is liable to self-ignition. 1308
1308 ZIRCONIUM, SUSPENDED IN A FLAMMABLE LIQUID 3 II 1 L E2 P001 PP33 F-E, S-D Category B See entry above. 1308
1308 ZIRCONIUM, SUSPENDED IN A FLAMMABLE LIQUID 3 III 223 5 L E1 P001 F-E, S-D Category B See entry above. 1308
1309 ALUMINIUM POWDER, COATED 4.1 II 1 kg E2 P002 PP38 PP100 IBC08 B4 B21 T3 TP33 F-G, S-G Category A H1 SGG15 SG17 SG25 SG26 SG32 SG35 SG36 SG52 If uncoated, it possesses the property of evolving hydrogen gas when in contact with water, especially seawater; if treated with oil or wax, it does not at ordinary temperatures. Reacts readily with acids and caustic alkalis, evolving hydrogen, a flammable gas. Reacts readily with iron oxide, producing a thermite effect. May form explosive mixtures with oxidizing substances. In the event of breakage of receptacles, the scattered powder is readily ignited by sparks or open flame and may give rise to an explosive atmosphere. 1309
1309 ALUMINIUM POWDER, COATED 4.1 III 223 5 kg E1 P002 LP02 PP11 L3 IBC08 B4 T1 TP33 F-G, S-G Category A H1 SGG15 SG17 SG25 SG26 SG32 SG35 SG36 SG52 See entry above. 1309
1310 AMMONIUM PICRATE, WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category D SGG2 SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 1310
1312 BORNEOL 4.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-I Category A White, translucent lumps. Camphor-like odour. Insoluble in water. Harmful by ingestion. 1312
1313 CALCIUM RESINATE 4.1 III 5 kg E1 P002 IBC06 T1 TP33 F-A, S-I Category A Yellowish-white, amorphous powder or lumps. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. 1313
1314 CALCIUM RESINATE, FUSED 4.1 III 5 kg E1 P002 IBC04 T1 TP33 F-A, S-I Category A Yellowish-white, amorphous powder or lumps. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. 1314
1318 COBALT RESINATE, PRECIPITATED 4.1 III 5 kg E1 P002 IBC06 T1 TP33 F-A, S-I Category A Dark brownish-black solid. Insoluble in water. Readily combustible; may ignite spontaneously if contaminated with vegetable fibres (such as cotton). Irritating to skin and mucous membranes. 1318
1320 DINITROPHENOL, WETTED with not less than 15% water, by mass 4.1 6.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance when pure consists of yellow crystals. Slightly soluble in water. May form extremely sensitive compounds with heavy metals or their salts. Toxic if swallowed, by skin contact or by inhalation. 1320
1321 DINITROPHENOLATES, WETTED with not less than 15% water, by mass 4.1 6.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosives. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Toxic if swallowed, by skin contact or by inhalation. 1321
1322 DINITRORESORCINOL, WETTED with not less than 15% water, by mass 4.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Explosive when dry. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 1322
1323 FERROCERIUM 4.1 II 249 1 kg E2 P002 PP100 IBC08 B4 B21 T3 TP33 F-G, S-G Category A H1 SG25 SG26 Alloy derived from cerium or mischmetal, with the addition of 10% to 65% iron. Emits sparks when struck. 1323
1324 FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap 4.1 III 5 kg E1 P002 PP15 F-A, S-I Category D SG7 Ignites readily. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. 1324
1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-G Category B SG72 1325
1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 III 223 274 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-G Category B SG72 1325
1326
  • HAFNIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present)
  • (a) mechanically produced, particle size less than 53 microns;
  • (b) chemically produced, particle size less than 840 microns
4.1 II 916 1 kg E2 P410 PP31 PP40 IBC06 B21 T3 TP33 F-A, S-J Category E SGG15 SG17 Insoluble in water. Liable to spontaneous combustion when dry. Forms explosive mixtures with oxidizing substances. 1326
1327 HAY, STRAW or BHUSA 4.1 29 281 954 973 3 kg E0 P003 PP19 IBC08 B6 F-A, S-I Category A SW10 SG23 Ignites readily. Liable to spontaneous combustion when wet, damp or contaminated with oil. Refuse for shipment when loose, damp, wet or contaminated with oil. 1327
1328 HEXAMETHYLENETETRAMINE 4.1 III 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-G Category A White, crystalline powder. Soluble in water. 1328
1330 MANGANESE RESINATE 4.1 III 5 kg E1 P002 IBC06 T1 TP33 F-A, S-I Category A Very dark brown solid. Insoluble in water. Liable to spontaneous heating. Irritating to skin, eyes and mucous membranes. 1330
1331 MATCHES, “STRIKE ANYWHERE” 4.1 III 293 5 kg E0 P407 PP27 F-A, S-I Category B Ignite by friction; prepared surface is not required. 1331
1332 METALDEHYDE 4.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-G Category A White crystals, powder or tablets. Insoluble in water. Harmful if swallowed or by dust inhalation. 1332
1333 CERIUM, slabs, ingots or rods 4.1 II 1 kg E2 P002 PP100 IBC08 B4 B21 F-G, S-P Category A H1 SG17 SG25 SG26 Contains 94−99% rare earth metals. In contact with water or moist air, evolves hydrogen, a flammable gas. Emits sparks when scratched or struck. 1333
1334 NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED 4.1 III 948 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-G Category A SW23 Crystalline flakes or powder with a persistent odour. Evolves flammable vapours at, or below, its melting point. 1334
1336 NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass 4.1 I 28 0 E0 P406 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. White solid. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. 1336
1337 NITROSTARCH, WETTED with not less than 20% water, by mass 4.1 I 28 0 E0 P406 PP31 F-B, S-J Category D SG7 SG30 Desensitized explosive. Orange powder. Explosive and sensitive to friction in the dry state. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. 1337
1338 PHOSPHORUS, AMORPHOUS 4.1 III 5 kg E1 P410 IBC08 B3 T1 TP33 F-A, S-G Category A SG17 Reddish-brown powder. Insoluble in water. Ignites readily by friction. When involved in a fire, evolves irritating fumes. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. 1338
1339 PHOSPHORUS HEPTASULPHIDE, free from yellow or white phosphorus 4.1 II 1 kg E2 P410 PP31 IBC04 T3 TP33 F-G, S-G Category B H1 SG17 SG25 SG26 Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. 1339
1340 PHOSPHORUS PENTASULPHIDE, free from yellow or white phosphorus 4.3 4.1 II 500 g E2 P410 PP31 PP40 IBC04 T3 TP33 F-G, S-N Category D H1 SG26 Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. 1340
1341 PHOSPHORUS SESQUISULPHIDE, free from yellow or white phosphorus 4.1 II 1 kg E2 P410 PP31 IBC04 T3 TP33 F-A, S-G Category B SG17 Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. 1341
1343 PHOSPHORUS TRISULPHIDE, free from yellow or white phosphorus 4.1 II 1 kg E2 P410 PP31 IBC04 T3 TP33 F-G, S-G Category B H1 SG17 SG25 SG26 Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. 1343
1344 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass 4.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 1344
1345 RUBBER SCRAP or RUBBER SHODDY, powdered or granulated, not exceeding 840 microns and rubber content exceeding 45% 4.1 II 223 917 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-I Category A Liable to spontaneous heating. 1345
1346 SILICON POWDER, AMORPHOUS 4.1 III 32 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-G Category A SG17 Dark brown, non-metallic powder. Burns in air, when ignited; readily flammable when mixed with oxidizing substances. 1346
1347 SILVER PICRATE, WETTED with not less than 30% water, by mass 4.1 I 28 900 0 E0 P406 PP25 PP26 PP31 F-B, S-J Category D SGG7 SG7 SG30 Desensitized explosive. Yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. May form extremely sensitive compounds with heavy metals or their salts. Transport of SILVER PICRATE, dry or wetted with less than 30% water, by mass is prohibited. 1347
1348 SODIUM DINITRO--CRESOLATE, WETTED with not less than 15% water, by mass 4.1 6.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow powder. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Toxic if swallowed, by skin contact or by inhalation. 1348
1349 SODIUM PICRAMATE, WETTED with not less than 20% water, by mass 4.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow powder. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Harmful if swallowed or by skin contact. 1349
1350 SULPHUR 4.1 III 242 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-G Category A SW1 SW23 SG17 When involved in a fire, evolves toxic, very irritating and suffocating gas. The dust forms an explosive mixture with air which may be ignited by static electricity. Forms explosive mixtures with oxidizing substances. Corrosive to steel, in particular in the presence of moisture. The provisions of this Code should not apply to sulphur when it is formed to a specific shape (such as prills, granules, pellets, pastilles or flakes). 1350
1352
  • TITANIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present)
  • (a) mechanically produced, particle size less than 53 microns;
  • (b) chemically produced, particle size less than 840 microns
4.1 II 28 916 1 kg E2 P410 PP31 PP40 IBC06 B21 T3 TP33 F-A, S-J Category E SGG15 SG17 Grey powder. Forms explosive mixtures with oxidizing substances. 1352
1353 FIBRES or FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 4.1 III 5 kg E1 P410 IBC08 B3 F-A, S-I Category D Toe board used in the manufacture of boots and shoes. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. 1353
1354 TRINITROBENZENE, WETTED with not less than 30% water, by mass 4.1 I 28 0 E0 P406 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 1354
1355 TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 4.1 I 28 0 E0 P406 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. May form extremely sensitive compounds with heavy metals or their salts. 1355
1356 TRINITROTOLUENE (TNT), WETTED with not less than 30% water, by mass 4.1 I 28 0 E0 P406 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 1356
1357 UREA NITRATE, WETTED with not less than 20% water, by mass 4.1 I 28 227 0 E0 P406 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of white crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. 1357
1358
  • ZIRCONIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present)
  • (a) mechanically produced, particle size less than 53 microns;
  • (b) chemically produced, particle size less than 840 microns
4.1 II 916 1 kg E2 P410 PP31 PP40 IBC06 B21 T3 TP33 F-G, S-J Category E H1 SGG15 SG17 SG25 SG26 Grey powder. Insoluble in water. Liable to spontaneous combustion when dry. Forms explosive mixtures with oxidizing substances. 1358
1360 CALCIUM PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N Category E SW2 SW5 H1 SG26 SG35 Red to brown crystals. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1360
1361 CARBON, animal or vegetable origin 4.2 II 978 0 E0 P002 IBC06 T3 TP33 F-A, S-J Category A SW1 SW27 H2 Black material originating from organic sources. Particularly includes carbon blacks of animal or vegetable origin, other non-activated carbon materials and charcoal produced from materials such as bone, bamboo, coconut shell, jute and wood. Liable to heat slowly and ignite spontaneously in air. 1361
1361 CARBON, animal or vegetable origin 4.2 III 978 0 E0 P002 LP02 IBC08 B3 T1 TP33 F-A, S-J Category A SW1 SW27 H2 See entry above. 1361
1362 CARBON, ACTIVATED 4.2 III 979 0 E1 P002 PP11 PP31 IBC08 B3 T1 TP33 F-A, S-J Category A SW1 SW27 H2 Activated porous black carbon materials not including charcoal (see UN 1361). May be in the form of powder, granules, pellets, fibres or felts. If chemically activated, may self-heat, and may ignite spontaneously in air. 1362
1363 COPRA 4.2 III 29 926 973 0 E0 P003 LP02 PP20 IBC08 B3 B6 BK2 F-A, S-J Category A SW1 SW9 H1 Dried kernels of coconuts, with a penetrating rancid odour which may taint other cargoes. 1363
1364 COTTON WASTE, OILY 4.2 III 29 973 0 E0 P003 LP02 PP19 IBC08 B3 B6 F-A, S-J Category A SG41 Fibres of vegetable origin. 1364
1365 COTTON, WET 4.2 III 29 973 0 E0 P003 PP19 IBC08 B3 B6 F-A, S-J Category A Readily combustible, liable to ignite spontaneously according to moisture content. 1365
1369 -NITROSODIMETHYLANILINE 4.2 II 927 0 E2 P410 IBC06 B21 T3 TP33 F-A, S-J Category D SG29 Dark green, crystalline solid, insoluble in water. Ignites spontaneously in air when dry. Harmful if swallowed. 1369
1372 FIBRES, ANIMAL or FIBRES, VEGETABLE burnt, wet or damp 4.2 III 123 0 E1 P410 F-A, S-J Category A Liable to ignite spontaneously according to moisture content. 1372
1373 FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil 4.2 III 0 E0 P410 PP31 IBC08 B3 T1 TP33 F-A, S-J Category A Liable to ignite spontaneously according to the oil content. 1373
1374 FISH MEAL, UNSTABILIZED or FISH SCRAP, UNSTABILIZED High hazard. Unrestricted moisture content. Unrestricted fat content in excess of 12%, by mass; unrestricted fat content in excess of 15%, by mass, in the case of anti-oxidant treated fish meal or fish scrap 4.2 II 300 928 0 E2 P410 PP31 PP40 IBC08 B4 B21 T3 TP33 F-A, S-J Category B SW1 SW24 SG65 Brown to greenish-brown product derived from oily fish. Strong odour which may affect other cargo. Liable to heat and ignite spontaneously. 1374
1374 FISH MEAL, UNSTABILIZED or FISH SCRAP, UNSTABILIZED Not anti-oxidant treated. Moisture content: more than 5% but not more than 12%, by mass. Fat content: not more than 12%, by mass 4.2 III 29 300 907 928 0 E1 P410 PP31 IBC08 B3 B21 T1 TP33 F-A, S-J Category A SW1 SW24 See entry above. 1374
1376 IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification 4.2 III 223 0 E0 P002 LP02 PP100 L3 IBC08 B4 T1 BK2 TP33 F-G, S-P Category E H1 SG26 Obtained from coal gas purification. Strong odour which may taint other cargo. Liable to heat and ignite spontaneously. May evolve hydrogen sulphide, sulphur dioxide and hydrogen cyanide, which are toxic gases. This substance should have been cooled and weathered for not less than eight weeks before shipment, unless packed in a metal drum. 1376
1378 METAL CATALYST, WETTED with a visible excess of liquid 4.2 II 274 0 E0 P410 PP31 PP39 PP40 IBC01 T3 TP33 F-H, S-M Category C Liable to ignite spontaneously if dry. 1378
1379 PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 4.2 III 0 E0 P410 PP31 IBC08 B3 F-A, S-J Category A Liable to ignite spontaneously. The provisions of this Code should not apply to manufactured articles properly aged. 1379
1380 PENTABORANE 4.2 6.1 I 0 E0 P601 F-G, S-L Category D H1 SG26 Colourless liquid. Boiling point range: 48°C to 63°C. Ignites spontaneously in air. Decomposes in contact with water, evolving hydrogen, a flammable gas. Toxic if swallowed, by skin contact or by inhalation. 1380
1381 PHOSPHORUS, WHITE or YELLOW, DRY or UNDER WATER or IN SOLUTION 4.2 6.1 I 0 E0 P405 PP31 T9 TP3 TP31 F-A, S-J Category E Ignites spontaneously in air. Melting point: 44°C. Toxic if swallowed, by skin contact or by inhalation. Receptacles are usually filled with substance in the liquid state which subsequently solidifies. A sufficient ullage should be allowed. 1381
1382 POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization 4.2 II 0 E2 P410 PP31 PP40 IBC06 B21 T3 TP33 F-A, S-J Category A SGG18 SG35 Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas. Reacts violently with acids. 1382
1383 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. 4.2 I 274 0 E0 P404 PP31 T21 TP7 TP33 F-G, S-M Category D H1 SGG15 SG26 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolves hydrogen, a flammable gas. 1383
1384 SODIUM DITHIONITE (SODIUM HYDROSULPHITE) 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J Category E H1 White or grey crystalline powder. Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. 1384
1385 SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J Category A SGG18 SG35 Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas. Reacts violently with acids. 1385
1386 SEED CAKE, containing vegetable oil (a) mechanically expelled seeds, containing more than 10% oil or more than 20% oil and moisture combined 4.2 III 29 929 973 0 E0 P003 LP02 PP20 IBC08 B3 B6 BK2 F-A, S-J Category E SW1 SW25 H1 Residue remaining after oil has been expelled mechanically from oil-bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal, etc. May self-heat slowly and, if wet or containing an excessive proportion of unoxidized oil, ignite spontaneously. Before shipment, this cargo should be properly aged. The duration of ageing varies with the oil content. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the cargo space(s) at any time. 1386
1386 SEED CAKE, containing vegetable oil (b) solvent extractions and expelled seeds, containing not more than 10% of oil and when the amount of moisture is higher than 10%, not more than 20% of oil and moisture combined 4.2 III 29 929 973 0 E0 P003 LP02 PP20 IBC08 B3 B6 BK2 F-A, S-J Category A SW1 SW25 H1 Residue remaining after oil has been extracted by a solvent process or expelled mechanically from oil-bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal, etc. May self-heat slowly and, if wet or containing an excessive proportion of unoxidized oil, ignite spontaneously. The seed cake should be substantially free from flammable solvent. Before shipment, this cargo should be properly aged. The duration of ageing varies with the oil content. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the cargo space(s) at any other time. 1386
1387 WOOL WASTE, WET 4.2 III 123 0 E1 P410 F-A, S-J Category A Liable to ignite spontaneously in air according to moisture content. 1387
1389 ALKALI METAL AMALGAM, LIQUID 4.3 I 182 0 E0 P402 PP31 F-G, S-N Category D H1 SGG7 SGG11 SG26 SG35 Silvery liquid, consisting of metal alloyed with mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. 1389
1390 ALKALI METAL AMIDES 4.3 II 182 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-O Category E SW2 H1 SG26 SG35 Small crystals. Decomposes in contact with water or acids, evolving ammonia vapour and producing highly caustic alkaline solutions. 1390
1391 ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION 4.3 I 182 183 0 E0 P402 PP31 T13 TP2 TP7 TP42 F-G, S-N Category D H1 SG26 SG35 Finely divided alkali metal or alkaline earth metal, suspended in a liquid. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. 1391
1392 ALKALINE EARTH METAL AMALGAM, LIQUID 4.3 I 183 0 E0 P402 PP31 F-G, S-N Category D H1 SGG7 SGG11 SG26 SG35 Consists of metal alloyed with mercury. Contains 2% to 10% alkaline earth metals and may contain up to 98% mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. 1392
1393 ALKALINE EARTH METAL ALLOY, N.O.S. 4.3 II 183 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category E H1 SG26 SG35 When containing a substantial proportion of alkaline earth metals, readily decomposed by water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. 1393
1394 ALUMINIUM CARBIDE 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category A H1 SG26 SG35 Yellow crystals or powder. In contact with water, rapidly evolves methane, a flammable gas. Reacts violently with acids. 1394
1395 ALUMINIUM FERROSILICON POWDER 4.3 6.1 II 932 500 g E2 P410 PP31 PP40 IBC05 B21 T3 BK2 TP33 F-G, S-N Category A SW2 SW5 H1 SG26 SG32 SG35 SG36 In contact with water, caustic alkalis or acids, evolves hydrogen, a flammable gas. Impurities may, under similar circumstances, produce phosphine and arsine, which are highly toxic gases. 1395
1396 ALUMINIUM POWDER, UNCOATED 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-O Category A H1 SGG15 SG26 SG32 SG35 SG36 In contact with water, caustic alkalis or acids, evolves hydrogen, a flammable gas. When finely divided aluminium dust is scattered, it is easily ignited by naked lights, causing explosion. May explode when in contact with oxidizing substances. Reacts with liquid halogenated hydrocarbons. 1396
1396 ALUMINIUM POWDER, UNCOATED 4.3 III 223 1 kg E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-O Category A H1 SGG15 SG26 SG32 SG35 SG36 See entry above. 1396
1397 ALUMINIUM PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N Category E SW2 SW5 H1 SG26 SG35 Crystals or powder. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1397
1398 ALUMINIUM SILICON POWDER, UNCOATED 4.3 III 37 223 932 1 kg E1 P410 PP31 IBC08 B4 T1 BK2 TP33 F-G, S-N Category A SW2 SW5 H1 SGG15 SG26 SG32 SG35 SG36 In contact with water, caustic alkalis or acids, generates heat and evolves hydrogen, a flammable gas. May also evolve silanes, which are toxic and may ignite spontaneously. 1398
1400 BARIUM 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-O Category E H1 SG26 SG35 Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. Harmful if swallowed or by dust inhalation. 1400
1401 CALCIUM 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-O Category E H1 SG26 SG35 Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. 1401
1402 CALCIUM CARBIDE 4.3 I 0 E0 P403 PP31 IBC04 B1 F-G, S-N Category B H1 SG26 SG35 Solid. In contact with water, rapidly evolves acetylene, a highly flammable gas, which may be ignited by the heat of the reaction. Acetylene forms highly explosive compounds with salts of some heavy metals. Reacts violently with acids. 1402
1402 CALCIUM CARBIDE 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category B H1 SG26 SG26 SG35 See entry above. 1402
1403 CALCIUM CYANAMIDE with more than 0.1% calcium carbide 4.3 III 38 934 1 kg E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category A H1 SG26 SG26 SG35 Powder or granules. Contains calcium carbide as an impurity. In contact with water, evolves ammonia and acetylene, which is a highly flammable gas. Reacts vigorously with acids. 1403
1404 CALCIUM HYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-O Category E H1 SG26 SG26 SG35 Solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1404
1405 CALCIUM SILICIDE 4.3 II 932 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category B SW5 H1 SG26 SG35 In contact with water, evolves hydrogen, a flammable gas. If calcium carbide is present as an impurity, acetylene will also be evolved. In contact with acids, evolves silane, a spontaneously flammable gas. 1405
1405 CALCIUM SILICIDE 4.3 III 223 932 1 kg E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category B SW5 H1 SG26 SG35 See entry above. 1405
1407 CAESIUM 4.3 I 0 E0 P403 PP31 IBC04 B1 F-G, S-N Category D H1 SG26 SG35 White, ductile, soft metal. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1407
1408 FERROSILICON with 30% or more but less than 90% silicon 4.3 6.1 III 39 223 932 1 kg E1 P003 PP20 PP100 IBC08 B4 B6 T1 BK2 TP33 F-G, S-N Category A SW2 SW5 H1 SG26 SG35 SG36 In contact with moisture, water, alkalis or acids, may evolve hydrogen, a flammable gas, which may form explosive mixtures with air, and also arsine and phosphine, which are highly toxic gases. These gases are evolved in proportions which, under mechanically ventilated conditions, make the poison hazard by far predominant over the explosion hazard. The rate of gas evolution is greatest from freshly broken surfaces, so is liable to increase whenever the cargo is disturbed, such as during loading. Toxic if swallowed, by skin contact or by vapour inhalation. 1408
1409 METAL HYDRIDES, WATER-REACTIVE, N.O.S. 4.3 I 274 0 E0 P403 PP31 F-G, S-L Category D H1 SG26 SG35 Solids. React with water, moisture or acids, evolving hydrogen, which may be ignited by the heat of the reaction. 1409
1409 METAL HYDRIDES, WATER-REACTIVE, N.O.S. 4.3 II 274 500 g E2 P410 PP31 PP40 IBC04 T3 TP33 F-G, S-L Category D H1 SG26 SG35 See entry above. 1409
1410 LITHIUM ALUMINIUM HYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-M Category E H1 SG26 SG35 White powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1410
1411 LITHIUM ALUMINIUM HYDRIDE, ETHEREAL 4.3 3 I 0 E0 P402 F-G, S-M Category D SW2 H1 SG26 Clear, colourless solution of lithium aluminium hydride in ether. Reacts readily with water, evolving hydrogen, a flammable gas. Evaporates readily to leave a residue which is easily ignited by a spark or friction. 1411
1413 LITHIUM BOROHYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-O Category E H1 SG26 SG35 Crystalline, hygroscopic solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1413
1414 LITHIUM HYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-N Category E H1 SG26 SG35 Solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1414
1415 LITHIUM 4.3 I 0 E0 P403 PP31 IBC04 B1 T9 TP7 TP33 F-G, S-N Category E H1 SG26 SG35 White, ductile, soft metal. Floats on water. Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. For fire-fighting purposes, dry lithium chloride powder, dry sodium chloride or graphite powder should be carried on board when this substance is transported. 1415
1417 LITHIUM SILICON 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category A SW5 H1 SG26 Shiny lumps, crystals or powder, with sharp irritating odour. Reacts readily with water, evolving hydrogen and silane, flammable gases. Enough heat may be generated to ignite the gas mixture in air. 1417
1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 4.3 4.2 I 0 E0 P403 PP31 F-G, S-O Category A H1 SGG15 SG26 SG32 SG35 In contact with moisture, water or acids, evolves hydrogen, a flammable gas. Magnesium dust is easily ignited, causing explosion. May explode when in contact with oxidizing substances. For fire-fighting purposes, dry lithium chloride powder, dry sodium chloride or graphite powder should be carried on board when this substance is transported. Reacts with liquid halogenated hydrocarbons. 1418
1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 4.3 4.2 II 0 E2 P410 PP31 PP40 IBC05 B21 T3 TP33 F-G, S-O Category A H1 SGG15 SG26 SG32 SG35 See entry above. 1418
1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 4.3 4.2 III 223 0 E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-O Category A H1 SGG15 SG26 SG32 SG35 See entry above. 1418
1419 MAGNESIUM ALUMINIUM PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N Category E SW2 SW5 H1 SG26 SG35 Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1419
1420 POTASSIUM METAL ALLOYS, LIQUID 4.3 I 0 E0 P402 PP31 F-G, S-L Category D H1 SG26 SG35 Soft, silvery metal liquid. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1420
1421 ALKALI METAL ALLOY, LIQUID, N.O.S. 4.3 I 182 0 E0 P402 PP31 F-G, S-L Category D H1 SG26 SG35 Flows like mercury at ordinary temperatures. Not volatile. Reacts violently with moisture, water or acids, evolving hydrogen, a flammable gas, and developing considerable heat, which may ignite the gas. 1421
1422 POTASSIUM SODIUM ALLOYS, LIQUID 4.3 I 0 E0 P402 PP31 T9 TP3 TP7 TP31 F-G, S-L Category D H1 SG26 SG35 Soft, silvery metal liquid. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1422
1423 RUBIDIUM 4.3 I 0 E0 P403 PP31 IBC04 B1 F-G, S-N Category D H1 SG26 SG35 Silvery-white, ductile, soft metal. Melting point: 39°C. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1423
1426 SODIUM BOROHYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-O Category E H1 SG26 SG35 Crystalline powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1426
1427 SODIUM HYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-O Category E H1 SG26 SG35 White powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 1427
1428 SODIUM 4.3 I 0 E0 P403 PP31 IBC04 B1 T9 TP7 TP33 F-G, S-N Category D H1 SG26 SG35 White, ductile, soft metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 1428
1431 SODIUM METHYLATE 4.2 8 II 0 E2 P410 PP31 IBC05 B21 T3 TP33 F-A, S-L Category B SGG18 SG35 White, amorphous, free-flowing, hygroscopic powder. Decomposed by water to form methanol, a flammable liquid, which may be ignited by the heat of the reaction. Causes burns to skin, eyes and mucous membranes. 1431
1432 SODIUM PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N Category E SW2 SW5 H1 SG26 SG35 Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1432
1433 STANNIC PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N Category E SW2 SW5 H1 SG26 SG35 Silver-white solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 1433
1435 ZINC ASHES 4.3 III 223 935 1 kg E1 P002 PP100 IBC08 B4 T1 BK2 TP33 F-G, S-O Category A H1 SGG7 SGG15 SG26 In contact with moisture or water, liable to evolve dangerous gases, including hydrogen, a flammable gas. 1435
1436 ZINC POWDER or ZINC DUST 4.3 4.2 I 0 E0 P403 PP31 F-G, S-O Category A H1 SGG7 SGG15 SG26 SG35 SG36 In contact with water, alkalis or acids, evolves hydrogen, a flammable gas. Zinc dust is easily ignited, causing explosion. May explode when in contact with oxidizing substances. 1436
1436 ZINC POWDER or ZINC DUST 4.3 4.2 II 0 E2 P410 PP31 PP40 IBC07 B21 T3 TP33 F-G, S-O Category A H1 SGG7 SGG15 SG26 SG35 SG36 See entry above. 1436
1436 ZINC POWDER or ZINC DUST 4.3 4.2 III 223 0 E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-O Category A H1 SGG7 SGG15 SG26 SG35 SG36 See entry above. 1436
1437 ZIRCONIUM HYDRIDE 4.1 II 1 kg E2 P410 PP31 PP40 IBC04 T3 TP33 F-A, S-G Category E Black coloured powder. 1437
1438 ALUMINIUM NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 TP33 F-A, S-Q Category A Colourless or white crystals. Deliquescent. Soluble in water. Slightly corrosive. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1438
1439 AMMONIUM DICHROMATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG2 SG35 Orange needles. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. May ignite spontaneously in contact with acids. Harmful if swallowed. 1439
1442 AMMONIUM PERCHLORATE 5.1 II 152 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category E SGG2 SGG13 SG49 SG60 White crystals or powder. Soluble in water. When heated, decomposes readily, even with explosion, evolving toxic fumes. Forms highly explosive mixtures with combustible material or powdered metals. These mixtures are sensitive to friction and are liable to ignite. 1442
1444 AMMONIUM PERSULPHATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A SGG2 White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. 1444
1445 BARIUM CHLORATE, SOLID 5.1 6.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG4 SG38 SG49 Colourless crystals or powder. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. 1445
1446 BARIUM NITRATE 5.1 6.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A White crystals. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. 1446
1447 BARIUM PERCHLORATE, SOLID 5.1 6.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG13 SG38 SG49 White crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. 1447
1448 BARIUM PERMANGANATE 5.1 6.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category D SGG14 SG38 SG49 SG60 Brownish-violet crystals. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. 1448
1449 BARIUM PEROXIDE 5.1 6.1 II 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Toxic if swallowed, by skin contact or by dust inhalation. 1449
1450 BROMATES, INORGANIC, N.O.S. 5.1 II 274 350 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG3 SG38 SG49 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction, and may form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium bromate and mixtures of a bromate with an ammonium salt is prohibited. 1450
1451 CAESIUM NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A White powder. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1451
1452 CALCIUM CHLORATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG4 SG38 SG49 White to yellowish deliquescent crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1452
1453 CALCIUM CHLORITE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG5 SG38 SG49 White deliquescent crystals. Soluble in water. Sensitive to heat. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1453
1454 CALCIUM NITRATE 5.1 III 208 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-Q Category A SW23 White deliquescent solid, soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1454
1455 CALCIUM PERCHLORATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG13 SG38 SG49 White crystals or powder. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1455
1456 CALCIUM PERMANGANATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category D SGG14 SG38 SG49 SG60 Violet deliquescent crystals. Soluble in water. Occurs in hydrated form. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1456
1457 CALCIUM PEROXIDE 5.1 II 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 White or yellowish powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or on contact with water or acids, decomposes, evolving oxygen. 1457
1458 CHLORATE AND BORATE MIXTURE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG4 SG38 SG49 Solid. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1458
1458 CHLORATE AND BORATE MIXTURE 5.1 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-H, S-Q Category A SGG4 SG38 SG49 See entry above. 1458
1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG4 SG38 SG49 Deliquescent solid. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1459
1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 5.1 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-H, S-Q Category A SGG4 SG38 SG49 See entry above. 1459
1461 CHLORATES, INORGANIC, N.O.S. 5.1 II 274 351 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG4 SG38 SG49 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium chlorate and mixtures of a chlorate with an ammonium salt is prohibited. 1461
1462 CHLORITES, INORGANIC, N.O.S. 5.1 II 274 352 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG5 SG38 SG49 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium chlorite and mixtures of a chlorite with an ammonium salt is prohibited. 1462
1463 CHROMIUM TRIOXIDE, ANHYDROUS 5.1 6.1/8 II 1 kg E2 P002 PP31 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A SG6 SG16 SG19 Dark purplish-red deliquescent crystals. Soluble in water. Mixtures with combustible material may ignite spontaneously and may even explode. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1463
1465 DIDYMIUM NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A Hygroscopic solid. Mixture of neodymium nitrate and praseodymium nitrate. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1465
1466 FERRIC NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A Violet deliquescent crystals. Soluble in water. Melting point: 47°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive to most metals. Harmful if swallowed. 1466
1467 GUANIDINE NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A SG45 White granules. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. NITROGUANIDINE is a different substance. 1467
1469 LEAD NITRATE 5.1 6.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A SGG7 SGG9 White crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. 1469
1470 LEAD PERCHLORATE, SOLID 5.1 6.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG7 SGG9 SGG13 SG38 SG49 White crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. 1470
1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SW1 SW8 SGG8 SG35 SG38 SG49 SG53 SG60 White powder with pungent odour. Soluble in water. Critical ambient temperature of decomposition may be as low as 60°C. May cause fire in contact with organic material or ammonium compounds. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. 1471
1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 5.1 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-H, S-Q Category A SW1 SW8 SGG8 SG35 SG38 SG49 SG53 SG60 See entry above. 1471
1472 LITHIUM PEROXIDE 5.1 II 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 White powder. Soluble in water. Solution in water is an alkaline corrosive liquid. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. 1472
1473 MAGNESIUM BROMATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG3 SG38 SG49 White deliquescent crystals or crystalline powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1473
1474 MAGNESIUM NITRATE 5.1 III 332 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-Q Category A SW23 White deliquescent crystals, soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1474
1475 MAGNESIUM PERCHLORATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG13 SG38 SG49 White crystals or powder. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1475
1476 MAGNESIUM PEROXIDE 5.1 II 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Harmful if swallowed. 1476
1477 NITRATES, INORGANIC, N.O.S. 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A SG38 SG49 Solids. Solid mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1477
1477 NITRATES, INORGANIC, N.O.S. 5.1 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A SG38 SG49 See entry above. 1477
1479 OXIDIZING SOLID, N.O.S. 5.1 I 274 900 0 E0 P503 IBC05 B1 F-A, S-Q Category D SG38 SG49 SG60 SG61 1479
1479 OXIDIZING SOLID, N.O.S. 5.1 II 274 900 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category B SG38 SG49 SG60 SG61 1479
1479 OXIDIZING SOLID, N.O.S. 5.1 III 223 274 900 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category B SG38 SG49 SG60 SG61 1479
1481 PERCHLORATES, INORGANIC, N.O.S. 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG13 SG38 SG49 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1481
1481 PERCHLORATES, INORGANIC, N.O.S. 5.1 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-H, S-Q Category A SGG13 SG38 SG49 See entry above. 1481
1482 PERMANGANATES, INORGANIC, N.O.S. 5.1 II 274 353 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category D SGG14 SG38 SG49 SG60 Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium permanganate and mixtures of a permanganate with an ammonium salt is prohibited. 1482
1482 PERMANGANATES, INORGANIC, N.O.S. 5.1 III 223 274 353 5 kg E1 P002 IBC08 B3 T1 TP33 F-H, S-Q Category D SGG14 SG38 SG49 SG60 See entry above. 1482
1483 PEROXIDES, INORGANIC, N.O.S. 5.1 II 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. 1483
1483 PEROXIDES, INORGANIC, N.O.S. 5.1 III 223 5 kg E1 P002 LP02 PP100 L3 IBC08 B4 T1 TP33 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 See entry above. 1483
1484 POTASSIUM BROMATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG3 SG38 SG49 White crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible materials, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1484
1485 POTASSIUM CHLORATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG4 SG38 SG49 White crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1485
1486 POTASSIUM NITRATE 5.1 III 964 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-Q Category A SW23 White crystals or powder. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1486
1487 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A SGG12 SG38 SG49 Deliquescent solid. Soluble in water. May cause fire in contact with organic material such as wood, cotton or straw. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. May be shipped in the form of fused solid block or lumps. 1487
1488 POTASSIUM NITRITE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A SGG12 SG38 SG49 White or slightly yellowish deliquescent crystals or sticks. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. 1488
1489 POTASSIUM PERCHLORATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG13 SG38 SG49 White crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1489
1490 POTASSIUM PERMANGANATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category D SGG14 SG38 SG49 SG60 Dark purple crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1490
1491 POTASSIUM PEROXIDE 5.1 I 0 E0 P503 IBC06 B1 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 Yellow powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. 1491
1492 POTASSIUM PERSULPHATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A SG39 SG49 White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Reacts fiercely with cyanides when heated or by friction. May form explosive mixture with powdered metals or ammonium compounds. 1492
1493 SILVER NITRATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A SGG7 Colourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. Irritating to skin and mucous membranes. 1493
1494 SODIUM BROMATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG3 SG38 SG49 White deliquescent crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1494
1495 SODIUM CHLORATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 BK2 TP33 F-H, S-Q Category A SGG4 SG38 SG49 Colourless deliquescent crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1495
1496 SODIUM CHLORITE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG5 SG38 SG49 Colourless deliquescent solid. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1496
1498 SODIUM NITRATE 5.1 III 964 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-Q Category A SW23 Colourless deliquescent solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. This substance in the impure form is known as Chile Saltpetre. 1498
1499 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE 5.1 III 964 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-Q Category A SW23 Colourless, hygroscopic solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. Mixture prepared as a fertilizer. 1499
1500 SODIUM NITRITE 5.1 6.1 III 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-Q Category A SGG12 SG38 SG49 Colourless deliquescent solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Decomposes if heated, giving off toxic nitrous fumes and gases supporting combustion. Harmful if swallowed or by dust inhalation. 1500
1502 SODIUM PERCHLORATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG13 SG38 SG49 Colourless crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1502
1503 SODIUM PERMANGANATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category D SGG14 SG38 SG49 SG60 Red crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1503
1504 SODIUM PEROXIDE 5.1 I 0 E0 P503 IBC05 B1 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 Pale yellow coarse powder or granules. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. 1504
1505 SODIUM PERSULPHATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A SG39 SG49 Colourless crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Reacts fiercely with cyanides when heated or by friction. May form explosive mixture with powdered metals or ammonium compounds. 1505
1506 STRONTIUM CHLORATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG4 SG38 SG49 Colourless deliquescent solid, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1506
1507 STRONTIUM NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A Colourless solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 1507
1508 STRONTIUM PERCHLORATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category A SGG13 SG38 SG49 Colourless crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1508
1509 STRONTIUM PEROXIDE 5.1 II 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-Q Category C H1 SGG16 SG16 SG26 SG35 SG59 Colourless powder. Particularly if wetted with small quantities of water, a mixture with combustible materials may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. 1509
1510 TETRANITROMETHANE 6.1 5.1 I 354 0 E0 P602 F-H, S-Q Category D SW2 SG16 Colourless liquid with a pungent odour. Freezing point: 12.5°C. Insoluble in water. Mixtures with combustible material are readily ignited, burn fiercely and may also explode by friction or shock. Highly toxic if swallowed, by skin contact or by inhalation. 1510
1511 UREA HYDROGEN PEROXIDE 5.1 8 III 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-Q Category A H1 White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Irritating to skin, eyes and mucous membranes. 1511
1512 ZINC AMMONIUM NITRITE 5.1 900 Transport is prohibited. 1512
1513 ZINC CHLORATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG4 SGG7 SG38 SG49 Colourless or yellowish crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1513
1514 ZINC NITRATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category A SGG7 Colourless solid. Soluble in water. Melting point: 36°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. 1514
1515 ZINC PERMANGANATE 5.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q Category D SGG7 SGG14 SG38 SG49 SG60 Violet-brown or black crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 1515
1516 ZINC PEROXIDE 5.1 II 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-Q Category C H1 SGG7 SGG16 SG16 SG26 SG35 SG59 White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. 1516
1517 ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass 4.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category D SG7 SG30 Desensitized explosive. Highly explosive in the dry state or if insufficiently wetted. May react violently in contact with heavy metals or their salts. 1517
1541 ACETONE CYANOHYDRIN, STABILIZED 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A Category D SW1 SW2 SGG6 SG35 SG36 Colourless to amber liquid evolving toxic vapour. Miscible with water. Unstable in contact with acids and alkalis, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by inhalation. 1541
1544 ALKALOIDS, SOLID, N.O.S. or ALKALOIDS SALTS, SOLID, N.O.S. 6.1 I 43 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A A wide range of toxic solids, generally of vegetable origin. Toxic if swallowed, by skin contact or by inhalation. 1544
1544 ALKALOIDS, SOLID, N.O.S. or ALKALOIDS SALTS, SOLID, N.O.S. 6.1 II 43 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A See entry above. 1544
1544 ALKALOIDS, SOLID, N.O.S. or ALKALOIDS SALTS, SOLID, N.O.S. 6.1 III 43 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 1544
1545 ALLYL ISOTHIOCYANATE, STABILIZED 6.1 3 II 386 100 mL E0 P001 IBC02 T7 TP2 F-E, S-D Category D SW1 SW2 Colourless liquid evolving toxic vapour which is irritating and causes tears. Flashpoint: 46°C c.c. Toxic if swallowed, by skin contact or by inhalation. 1545
1546 AMMONIUM ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG2 SG36 White powder or crystals. Soluble in water. Reacts with alkalis, evolving ammonia gas. Toxic if swallowed, by skin contact or by dust inhalation. 1546
1547 ANILINE 6.1 II 279 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW2 SG35 Colourless, oily, volatile liquid. Reacts with acids. Toxic if swallowed, by skin contact or by inhalation. 1547
1548 ANILINE HYDROCHLORIDE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A White, crystalline solid. Soluble in water. Decomposes to aniline in contact with alkalis. Toxic if swallowed, by skin contact or by inhalation. 1548
1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 6.1 III 45 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 1549
1550 ANTIMONY LACTATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A White powder or crystals. Toxic if swallowed, by skin contact or by dust inhalation. 1550
1551 ANTIMONY POTASSIUM TARTRATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Colourless crystals or white powder. Toxic if swallowed, by skin contact or by dust inhalation. 1551
1553 ARSENIC ACID, LIQUID 6.1 I 0 E5 P001 PP31 T20 TP2 TP7 TP13 F-A, S-A Category B SG33 White, deliquescent crystals which readily become liquid. Melting point: approximately 35°C. Miscible with water. In contact with metals, may evolve arsine, an extremely toxic gas. Highly toxic if swallowed, by skin contact or by inhalation. 1553
1554 ARSENIC ACID, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White crystals with a relatively high melting point. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1554
1555 ARSENIC BROMIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW1 SW2 H2 White, deliquescent crystals. Melting point: approximately 33°C. Decomposed by water, evolving hydrogen bromide, an irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by dust inhalation. 1555
1556 ARSENIC COMPOUND, LIQUID, N.O.S. inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s., and Arsenic sulphides, n.o.s. 6.1 I 43 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 SG70 A wide variety of toxic liquids. In contact with acids, arsenic sulphide evolves hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. 1556
1556 ARSENIC COMPOUND, LIQUID, N.O.S. inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s., and Arsenic sulphides, n.o.s. 6.1 II 43 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 SG70 See entry above. 1556
1556 ARSENIC COMPOUND, LIQUID, N.O.S. inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s., and Arsenic sulphides, n.o.s. 6.1 III 43 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category B SW2 SG70 See entry above. 1556
1557 ARSENIC COMPOUND, SOLID, N.O.S. inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 I 43 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SG70 A wide variety of toxic solids. In contact with acids, arsenic sulphide evolves hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1557
1557 ARSENIC COMPOUND, SOLID, N.O.S. inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 II 43 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SG70 See entry above. 1557
1557 ARSENIC COMPOUND, SOLID, N.O.S. inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 III 43 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SG70 See entry above. 1557
1558 ARSENIC 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Silvery, brittle, crystalline solid with the appearance of a metal. Toxic if swallowed, by skin contact or by dust inhalation. 1558
1559 ARSENIC PENTOXIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White, deliquescent powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1559
1560 ARSENIC TRICHLORIDE 6.1 I 0 E0 P602 T14 TP2 TP13 F-A, S-A Category B SW2 Colourless, oily liquid. Fumes in moist air, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. Reacts with water. Highly toxic if swallowed, by skin contact or by inhalation. 1560
1561 ARSENIC TRIOXIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1561
1562 ARSENICAL DUST 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Fine powder. Toxic if swallowed, by skin contact or by dust inhalation. 1562
1564 BARIUM COMPOUND, N.O.S. 6.1 II 177 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White powder, lumps or crystals. Toxic if swallowed, by skin contact or by inhalation. 1564
1564 BARIUM COMPOUND, N.O.S. 6.1 III 177 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 1564
1565 BARIUM CYANIDE 6.1 I 0 E5 P002 PP31 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 SGG6 SG35 White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1565
1566 BERYLLIUM COMPOUND, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A A wide range of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. 1566
1566 BERYLLIUM COMPOUND, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 1566
1567 BERYLLIUM POWDER 6.1 4.1 II 500 g E4 P002 PP100 IBC08 B4 B21 T3 TP33 F-G, S-G Category A H1 SG25 SG26 White, metallic powder. Toxic if swallowed, by skin contact or by dust inhalation. 1567
1569 BROMOACETONE 6.1 3 II 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW2 When pure, colourless liquid evolving irritating vapour (“Tear Gas”). Flashpoint: approximately 45°C c.c. Toxic if swallowed, by skin contact or by inhalation. 1569
1570 BRUCINE 6.1 I 43 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A White crystals or powder. Highly toxic if swallowed, by skin contact or by dust inhalation. 1570
1571 BARIUM AZIDE, WETTED with not less than 50% water, by mass 4.1 6.1 I 28 0 E0 P406 PP31 F-B, S-J Category D SGG17 SG7 SG30 Desensitized explosive. White crystals or powder. Explosive and sensitive to friction in the dry state. Toxic if swallowed, by skin contact or by dust inhalation. May form extremely sensitive compounds with heavy metals or their salts. 1571
1572 CACODYLIC ACID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category E SGG1 SG35 SG36 SG49 Colourless crystals or white powder with an offensive odour. Soluble in water. May react with acids, evolving dimethylarsine, an extremely toxic gas. Toxic if swallowed, by skin contact or by dust inhalation. 1572
1573 CALCIUM ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1573
1574 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White powder. Toxic if swallowed, by skin contact or by dust inhalation. 1574
1575 CALCIUM CYANIDE 6.1 I 0 E5 P002 PP31 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 SGG6 SG35 White crystals or powder. Decomposes slowly in water to form a weak hydrogen cyanide solution. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1575
1577 CHLORODINITROBENZENES, LIQUID 6.1 II 279 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SG15 Colourless liquids. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 1577
1578 CHLORONITROBENZENES, SOLID 6.1 II 279 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Yellow crystals. Melting point: approximately 30°C to 80°C. Toxic if swallowed, by skin contact or by dust inhalation. 1578
1579 4-CHLORO--TOLUIDINE HYDROCHLORIDE, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Dry solid or paste. Toxic if swallowed, by skin contact or by dust inhalation. 1579
1580 CHLOROPICRIN 6.1 I 354 0 E0 P601 T22 TP2 TP13 F-A, S-A Category D SW2 Colourless, oily liquid. Highly toxic if swallowed, by skin contact or by inhalation. 1580
1581 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 2.3 0 E0 P200 T50 F-C, S-U Category D SW1 SW2 Extremely volatile liquid evolving highly toxic vapours. Highly toxic by skin contact or by inhalation. Causes burns to skin and eyes; vapour irritating to mucous membranes. 1581
1582 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 2.3 0 E0 P200 T50 F-C, S-U Category D SW1 SW2 Extremely volatile liquid evolving highly toxic vapours. Highly toxic by skin contact or by inhalation. Causes burns to skin and eyes; vapour irritating to mucous membranes. 1582
1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 I 43 274 315 0 E0 P602 F-A, S-A Category C SW2 A wide range of liquid mixtures. May evolve highly toxic vapour. Toxic if swallowed, by skin contact or by inhalation. 1583
1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 II 43 274 100 mL E0 P001 IBC02 F-A, S-A Category C SW2 See entry above. 1583
1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 III 43 223 274 5 L E0 P001 LP01 IBC03 F-A, S-A Category C SW2 See entry above. 1583
1585 COPPER ACETOARSENITE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1585
1586 COPPER ARSENITE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Yellowish-green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1586
1587 COPPER CYANIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG6 SGG7 SG35 Green powder. Slightly soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1587
1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 I 47 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SGG6 SG35 Solids. May be soluble in water. On contact with water, may form a weak hydrogen cyanide solution. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. The provisions of this Code shall not apply to complex ferricyanides and ferrocyanides. 1588
1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 II 47 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG6 SG35 See entry above. 1588
1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 III 47 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SGG6 SG35 See entry above. 1588
1589 CYANOGEN CHLORIDE, STABILIZED 2.3 8 386 0 E0 P200 F-C, S-U Category D SW1 SW2 Liquefied, non-flammable, toxic and corrosive gas with an irritating odour. Produces severe tearing of the eyes. On contact with water, reacts violently to give off highly toxic and corrosive fumes. Much heavier than air (2.1). Boiling point: 13°C. Toxic by skin contact or by inhalation. Highly irritating to skin, eyes and mucous membranes. 1589
1590 DICHLOROANILINES, LIQUID 6.1 II 279 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW2 Colourless liquid with a penetrating odour. Liquid mixtures of various isomers of dichloroanilines, some of which in the pure state may be solid, with a melting point varying from 24°C to 72°C. Toxic if swallowed, by skin contact or by inhalation. 1590
1591 -DICHLOROBENZENE 6.1 III 279 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SGG10 Volatile liquid. Melting point: approximately −17°C. Toxic if swallowed, by skin contact or by inhalation. 1591
1593 DICHLOROMETHANE 6.1 III 5 L E1 P001 LP01 IBC03 B8 T7 TP2 F-A, S-A Category A SGG10 Colourless, volatile liquid with heavy vapours. Boiling point: 40°C. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 1593
1594 DIETHYL SULPHATE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category C Colourless, oily liquid. Readily hydrolysed by moisture to sulphuric acid, which is a corrosive liquid. Toxic if swallowed, by skin contact or by inhalation. 1594
1595 DIMETHYL SULPHATE 6.1 8 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-B Category D SW2 SGG1 SG36 SG49 Colourless, volatile liquid evolving toxic vapours. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1595
1596 DINITROANILINES 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SG15 Yellow crystals in pure form. Insoluble in water. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 1596
1597 DINITROBENZENES, LIQUID 6.1 II 100 mL E4 P001 IBC03 T7 TP2 F-A, S-A Category A SG15 Yellow solutions. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 1597
1597 DINITROBENZENES, LIQUID 6.1 III 223 5 L E1 P001 LP01 IBC03 T7 TP2 F-A, S-A Category A SG15 See entry above. 1597
1598 DINITRO--CRESOL 6.1 II 43 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Yellow crystals or crystallized mass. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1598
1599 DINITROPHENOL SOLUTION 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SG30 Substance when pure consists of yellow crystals. Slightly soluble in water. May form extremely sensitive compounds with heavy metals or their salts. Toxic if swallowed, by skin contact or by inhalation. 1599
1599 DINITROPHENOL SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SG30 See entry above. 1599
1600 DINITROTOLUENES, MOLTEN 6.1 II 0 E0 T7 TP3 F-A, S-A Category C Molten liquid. This entry covers the 2,3-, 2,4-, 2,5-, 2,6-, 3,4- and 3,5-isomers having melting points between 52°C and 93°C. Toxic if swallowed, by skin contact or by inhalation. 1600
1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 1601
1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 1601
1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 1601
1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 6.1 I 274 0 E5 P001 F-A, S-A Category A A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 1602
1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 F-A, S-A Category A See entry above. 1602
1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 F-A, S-A Category A See entry above. 1602
1603 ETHYL BROMOACETATE 6.1 3 II 100 mL E0 P001 IBC02 T7 TP2 F-E, S-D Category D SW2 Colourless, flammable liquid evolving irritating vapour (“Tear Gas”). Flashpoint: 58°C c.c. Toxic if swallowed, by skin contact or by inhalation. 1603
1604 ETHYLENEDIAMINE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C Category A SW2 SGG18 SG35 Volatile, colourless, hygroscopic flammable liquid with an ammonia-like odour. Flashpoint: 34°C c.c. Miscible with water. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1604
1605 ETHYLENE DIBROMIDE 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A Category D SW2 SGG10 Colourless, volatile liquid. Highly toxic if swallowed, by skin contact or by inhalation. 1605
1606 FERRIC ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Green crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1606
1607 FERRIC ARSENITE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Brown or yellow powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1607
1608 FERROUS ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1608
1611 HEXAETHYL TETRAPHOSPHATE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category E SW2 Yellow liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1611
1612 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 2.3 0 E0 P200 F-C, S-U Category D SW2 Toxic if swallowed, by skin contact or by inhalation. 1612
1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with not more than 20% hydrogen cyanide 6.1 I 900 0 E0 P601 T14 TP2 TP13 F-A, S-A Category D SW2 Colourless liquid evolving extremely toxic vapour with a bitter almond odour. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Transport of HYDROCYANIC ACID, AQUEOUS SOLUTION with more than 20% hydrogen cyanide and of HYDROGEN CYANIDE, AQUEOUS SOLUTION with more than 20% hydrogen cyanide is prohibited. 1613
1614 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material 6.1 I 386 0 E0 P099 F-A, S-U Category D SW1 SW2 Very volatile, colourless liquid, evolving extremely toxic flammable vapours, absorbed in a porous inert material. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 1614
1616 LEAD ACETATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SGG7 SGG9 White crystals, or brown or grey lumps. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1616
1617 LEAD ARSENATES 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG9 White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1617
1618 LEAD ARSENITES 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG9 White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1618
1620 LEAD CYANIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG6 SGG7 SGG9 SG35 White powder. Slightly soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1620
1621 LONDON PURPLE 6.1 II 43 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Mixture of arsenic trioxide, lime and ferric oxide, used as an insecticide. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1621
1622 MAGNESIUM ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1622
1623 MERCURIC ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Yellow crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1623
1624 MERCURIC CHLORIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1624
1625 MERCURIC NITRATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White, deliquescent crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1625
1626 MERCURIC POTASSIUM CYANIDE 6.1 I 0 E5 P002 PP31 IBC07 B1 T6 TP33 F-A, S-A Category A SGG6 SGG7 SGG11 SG35 Colourless crystals. Soluble in water. Reacts with acids, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1626
1627 MERCUROUS NITRATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1627
1629 MERCURY ACETATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1629
1630 MERCURY AMMONIUM CHLORIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG2 SGG7 SGG11 White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1630
1631 MERCURY BENZOATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White crystals. Toxic if swallowed, by skin contact or by dust inhalation. 1631
1634 MERCURY BROMIDES 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1634
1636 MERCURY CYANIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG6 SGG7 SGG11 SG35 White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1636
1637 MERCURY GLUCONATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Solid. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1637
1638 MERCURY IODIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Red crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1638
1639 MERCURY NUCLEATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Brown powder containing about 20% mercury. Toxic if swallowed, by skin contact or by dust inhalation. 1639
1640 MERCURY OLEATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Yellow oily paste. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 1640
1641 MERCURY OXIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Orange powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1641
1642 MERCURY OXYCYANIDE, DESENSITIZED 6.1 II 900 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG6 SGG7 SGG11 SG15 SG35 White crystals or powder. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. May explode if involved in a fire. Toxic if swallowed, by skin contact or by dust inhalation. Should be sufficiently phlegmatized (mercury oxycyanide–mercury cyanide mixtures containing not less than 65% by mass of mercury cyanide can be regarded as adequately phlegmatized). Transport of MERCURY OXYCYANIDE pure is prohibited. 1642
1643 MERCURY POTASSIUM IODIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 Yellow, deliquescent crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1643
1644 MERCURY SALICYLATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1644
1645 MERCURY SULPHATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White crystals or powder. Decomposes in water, forming sulphuric acid. Toxic if swallowed, by skin contact or by dust inhalation. 1645
1646 MERCURY THIOCYANATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 SGG11 White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1646
1647 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A Category D SW2 SGG10 Solutions of methyl bromide gas, evolving toxic vapour. Methyl bromide has a boiling point of approximately 4°C. Highly toxic if swallowed, by skin contact or by inhalation. 1647
1648 ACETONITRILE 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-D Category B SW2 Colourless, volatile liquid. Flashpoint: 2°C c.c. Explosive limits: 3% to 16%. Miscible with water. When involved in a fire, evolves toxic cyanide fumes. Harmful if swallowed, by skin contact or by inhalation. 1648
1649 MOTOR FUEL ANTI-KNOCK MIXTURE 6.1 I 0 E0 P602 T14 TP2 TP13 F-A, S-A Category D SW1 SW2 SGG7 SGG9 Volatile liquids evolving toxic vapour. Mixture of tetraethyllead or tetramethyllead with ethylene dibromide and ethylene dichloride. Insoluble in water. Highly toxic if swallowed, by skin contact or by inhalation. 1649
1650 -NAPHTHYLAMINE, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White crystals. Toxic if swallowed, by skin contact or by inhalation. 1650
1651 NAPHTHYLTHIOUREA 6.1 II 43 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1651
1652 NAPHTHYLUREA 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1652
1653 NICKEL CYANIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG6 SGG7 SG35 Green crystals or powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1653
1654 NICOTINE 6.1 II 100 mL E4 P001 IBC02 F-A, S-A Category A Thick colourless oil, turning brown on exposure to air. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1654
1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 6.1 I 43 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B A wide variety of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. 1655
1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 6.1 II 43 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A See entry above. 1655
1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 6.1 III 43 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 1655
1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 6.1 II 43 100 mL E4 P001 IBC02 F-A, S-A Category A Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1656
1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 6.1 III 43 223 5 L E1 P001 LP01 IBC03 F-A, S-A Category A See entry above. 1656
1657 NICOTINE SALICYLATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1657
1658 NICOTINE SULPHATE SOLUTION 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 1658
1658 NICOTINE SULPHATE SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T7 TP2 F-A, S-A Category A See entry above. 1658
1659 NICOTINE TARTRATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1659
1660 NITRIC OXIDE, COMPRESSED 2.3 5.1/8 0 E0 P200 F-C, S-W Category D SW2 SG6 SG19 Non-flammable, toxic and corrosive gas. Strong oxidizing agent. On contact with air, gives off brown fumes which are toxic by inhalation, with delayed effect similar to phosgene. Heavier than air (1.04). Highly irritating to skin, eyes and mucous membranes. 1660
1661 NITROANILINES (-, -, -) 6.1 II 279 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Yellow crystals. Toxic if swallowed, by skin contact or by dust inhalation. -NITROANILINES may be carried in the molten state. 1661
1662 NITROBENZENE 6.1 II 279 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW2 Oily liquid, evolving toxic vapour. Melting point: approximately 6°C. Toxic if swallowed, by skin contact or by inhalation. 1662
1663 NITROPHENOLS (-, -, -) 6.1 III 279 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Yellow crystals. Some isomers may have a melting point as low as 44°C. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. 1663
1664 NITROTOLUENES, LIQUID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Yellow liquids. Melting points: -NITROTOLUENE: −4°C, -NITROTOLUENE: 15°C. Toxic if swallowed, by skin contact or by inhalation. 1664
1665 NITROXYLENES, LIQUID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Yellow liquids. Melting points: 2-NITRO−3-XYLENE: 14°C to 16°C, 3-NITRO−2-XYLENE: 7°C to 9°C, 4-NITRO−3-XYLENE: 2°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 1665
1669 PENTACHLOROETHANE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW2 SGG10 Colourless liquid. Toxic if swallowed, by skin contact or by inhalation. 1669
1670 PERCHLOROMETHYL MERCAPTAN 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A Category D SW2 Yellow, oily, volatile liquid evolving irritating vapour (“Tear Gas”). Slowly decomposes in contact with water, producing hydrochloric acid. Reacts with iron or steel, evolving carbon tetrachloride. Corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. 1670
1671 PHENOL, SOLID 6.1 II 279 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Colourless or white crystals or crystallized mass. Melting point: 43°C (pure product). Soluble in water. Toxic if swallowed, by skin contact or by vapour inhalation. Rapidly absorbed through the skin. 1671
1672 PHENYLCARBYLAMINE CHLORIDE 6.1 I 0 E0 P602 T14 TP2 TP13 F-A, S-A Category D SW2 Pale yellow, oily liquid with an irritating unpleasant odour. Highly toxic if swallowed, by skin contact or by inhalation. 1672
1673 PHENYLENEDIAMINES (-, -, ) 6.1 III 279 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. 1673
1674 PHENYLMERCURIC ACETATE 6.1 II 43 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 Toxic if swallowed, by skin contact or by dust inhalation. 1674
1677 POTASSIUM ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Colourless crystals or white powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1677
1678 POTASSIUM ARSENITE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1678
1679 POTASSIUM CUPROCYANIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG6 SG35 White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1679
1680 POTASSIUM CYANIDE, SOLID 6.1 I 0 E5 P002 PP31 IBC07 B1 T6 TP33 F-A, S-A Category B SGG6 SG35 White, deliquescent crystals or lumps. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1680
1683 SILVER ARSENITE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG7 Yellow powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1683
1684 SILVER CYANIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SW2 SGG6 SGG7 SG35 White powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. 1684
1685 SODIUM ARSENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA Colourless crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1685
1686 SODIUM ARSENITE, AQUEOUS SOLUTION 6.1 II 43 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Colourless. Toxic if swallowed, by skin contact or by inhalation. 1686
1686 SODIUM ARSENITE, AQUEOUS SOLUTION 6.1 III 43 223 5 L E1 P001 LP01 IBC03 T4 TP2 F-A, S-A CategoryA See entry above. 1686
1687 SODIUM AZIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 F-A, S-A CategoryA SGG17 SG15 SG30 SG35 Colourless crystals. May react vigorously with acids to form hydrazoic acid, which is an explosive. May form extremely sensitive compounds with heavy metals or their salts. May explode if involved in a fire. Toxic if swallowed, by skin contact or by dust inhalation. 1687
1688 SODIUM CACODYLATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SG35 White, deliquescent solid with a foul odour. Reacts with acids, evolving dimethylarsine, an extremely toxic gas. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1688
1689 SODIUM CYANIDE, SOLID 6.1 I 0 E5 P002 PP31 IBC07 B1 T6 TP33 F-A, S-A CategoryB SGG6 SG35 White, deliquescent crystals or lumps. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1689
1690 SODIUM FLUORIDE, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SG35 White crystals or powder. React with acids, evolving hydrogen fluoride, a toxic, irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. 1690
1691 STRONTIUM ARSENITE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1691
1692 STRYCHNINE or STRYCHNINE SALTS 6.1 I 43 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryA White crystals or powder. Strychnine is slightly soluble; the salts are soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 1692
1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 I 274 0 E0 P001 PP31 F-A, S-A CategoryD SW2 “Tear gas substance” is a generic term for substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. Toxic if swallowed, by skin contact or by inhalation. 1693
1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 II 274 0 E0 P001 PP31 IBC02 F-A, S-A CategoryD SW2 See entry above. 1693
1694 BROMOBENZYL CYANIDES, LIQUID 6.1 I 138 0 E0 P001 PP31 T14 TP2 TP13 F-A, S-A CategoryD SW1 SW2 H2 SGG6 SG35 Volatile liquids evolving irritating vapour (“Tear Gas”). Melting points: -BROMOBENZYL CYANIDE 1°C. Highly toxic if swallowed, by skin contact or by inhalation. 1694
1695 CHLOROACETONE, STABILIZED 6.1 3/8 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-C CategoryD SW2 SG5 SG8 Flammable, corrosive, colourless liquid, evolving irritating vapour (“Tear Gas”). Miscible with water. Flashpoint: 25°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. 1695
1697 CHLOROACETOPHENONE, SOLID 6.1 II 0 E0 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryD SW1 SW2 H2 White crystals evolving irritating vapour (“Tear Gas”). Melting point may be as low as 20°C. Toxic if swallowed, by skin contact or by inhalation. 1697
1698 DIPHENYLAMINE CHLOROARSINE 6.1 I 0 E0 P002 PP31 T6 TP33 F-A, S-A CategoryD SW2 Volatile, yellow crystals evolving irritating vapour (“Tear Gas”). Highly toxic if swallowed, by skin contact or by inhalation. 1698
1699 DIPHENYLCHLOROARSINE, LIQUID 6.1 I 0 E0 P001 PP31 F-A, S-A CategoryD SW2 When pure, colourless liquid. The commercial product may be a dark brown liquid. Volatile liquid evolving an irritating vapour (“Tear Gas”). Highly toxic if swallowed, by skin contact or by inhalation. 1699
1700 TEAR GAS CANDLES 6.1 4.1 0 E0 P600 F-A, S-G CategoryD SW2 Devices containing tear-producing substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. 1700
1701 XYLYL BROMIDE, LIQUID 6.1 II 0 E0 P001 PP31 IBC02 T7 TP2 TP13 F-A, S-A CategoryD SW2 SGG10 Colourless liquid, evolving irritating vapour (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. 1701
1702 1,1,2,2-TETRACHLOROETHANE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW2 SGG10 Colourless liquid with a chloroform-like odour. Toxic if swallowed, by skin contact or by inhalation. 1702
1704 TETRAETHYL DITHIOPYROPHOSPHATE 6.1 II 43 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryD SW2 Colourless liquid. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. 1704
1707 THALLIUM COMPOUND, N.O.S. 6.1 II 43 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1707
1708 TOLUIDINES, LIQUID 6.1 II 279 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Colourless liquids. Toxic if swallowed, by skin contact or by inhalation. 1708
1709 2,4-TOLUYLENEDIAMINE, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 1709
1710 TRICHLOROETHYLENE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SW2 SGG10 Colourless liquid with a chloroform-like odour. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 1710
1711 XYLIDINES, LIQUID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Toxic if swallowed, by skin contact or by inhalation. 1711
1712 ZINC ARSENATE, ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SGG7 Crystalline solid. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1712
1713 ZINC CYANIDE 6.1 I 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryA SGG6 SGG7 SG35 White crystals or powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 1713
1714 ZINC PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N CategoryE SW2 SW5 H1 SGG7 SG26 SG35 Grey crystals or powder. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. 1714
1715 ACETIC ANHYDRIDE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SW2 SGG1 SG36 SG49 Colourless, flammable liquid with an irritating odour. Flashpoint: 54°C c.c. Immiscible with water. In the presence of moisture, corrosive to most metals. Vapour irritates mucous membranes. 1715
1716 ACETYL BROMIDE 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1716
1717 ACETYL CHLORIDE 3 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-E, S-C CategoryB SW2 SGG1 SG36 SG49 Colourless liquid. Flashpoint: 5°C c.c. Boiling point: 51°C. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1717
1718 BUTYL ACID PHOSPHATE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Yellow liquid. Insoluble in water. Mildly corrosive to most metals. 1718
1719 CAUSTIC ALKALI LIQUID, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B CategoryA SGG18 SG22 SG35 Corrosive to aluminium, zinc and tin. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. 1719
1719 CAUSTIC ALKALI LIQUID, N.O.S. 8 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-A, S-B CategoryA SGG18 SG22 SG35 See entry above. 1719
1722 ALLYL CHLOROFORMATE 6.1 3/8 I 0 E0 P001 T14 TP2 TP13 F-E, S-C CategoryD SW2 SGG1 SG5 SG8 SG36 SG49 Colourless, flammable liquid, extremely irritating odour, causes tears. Flashpoint: 31°C c.c. When involved in a fire, evolves toxic gases. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1722
1723 ALLYL IODIDE 3 8 II 1 L E2 P001 IBC02 T7 TP2 TP13 F-E, S-C CategoryB SW2 SGG1 SGG10 SG36 SG49 Yellow liquid with an irritating odour. Flashpoint: 5°C c.c. Immiscible with water. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1723
1724 ALLYLTRICHLOROSILANE, STABILIZED 8 3 II 386 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C CategoryC SW1 SW2 SGG1 SG36 SG49 Colourless, flammable liquid with a pungent odour. Flashpoint: 35°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1724
1725 ALUMINIUM BROMIDE, ANHYDROUS 8 II 937 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 White to yellowish hygroscopic crystals. Forms corrosive vapours in moist air. Reacts violently with water, evolving heat and hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly irritating to skin, eyes and mucous membranes. The solid hydrated form of this substance is not subject to the provisions of this Code. 1725
1726 ALUMINIUM CHLORIDE, ANHYDROUS 8 II 937 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 White to yellowish hygroscopic crystals. Forms corrosive vapours in moist air. Reacts violently with water, evolving heat and hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly irritating to skin, eyes and mucous membranes. The solid hydrated form of this substance is not subject to the provisions of this Code. 1726
1727 AMMONIUM HYDROGENDIFLUORIDE, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW1 SW2 SGG1 SGG2 SG35 SG36 SG49 White deliquescent crystals. Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin and mucous membranes. 1727
1728 AMYLTRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1728
1729 ANISOYL CHLORIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Crystalline powder. Melting point: 22°C. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1729
1730 ANTIMONY PENTACHLORIDE, LIQUID 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Yellow, oily liquid with an offensive odour. May solidify by absorption of moisture. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1730
1731 ANTIMONY PENTACHLORIDE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Yellow liquid with an offensive odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1731
1731 ANTIMONY PENTACHLORIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 See entry above. 1731
1732 ANTIMONY PENTAFLUORIDE 8 6.1 II 1 L E0 P001 IBC02 T7 TP2 F-A, S-B CategoryD SW2 SGG1 SG6 SG8 SG10 SG12 SG36 SG49 Colourless liquid with a pungent odour. When anhydrous, mildly corrosive to glass, other siliceous materials and most metals. Reacts violently with water, evolving hydrogen fluoride, an irritating gas, highly corrosive to glass and other siliceous materials and most metals. Powerful oxidant, may cause fire in contact with readily flammable organic substances. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin and mucous membranes. 1732
1733 ANTIMONY TRICHLORIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Reacts slowly with water, evolving hydrogen chloride, an irritating and corrosive gas. In the presence of moisture, corrosive to most metals. 1733
1736 BENZOYL CHLORIDE 8 II 1 L E2 P001 IBC02 B20 T8 TP2 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid, very irritating odour, causes tears. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1736
1737 BENZYL BROMIDE 6.1 8 II 0 E4 P001 IBC02 B20 T8 TP2 TP13 F-A, S-B CategoryD SW2 H1 SGG1 SGG10 SG36 SG49 Colourless liquid with a pungent odour, causes tears. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1737
1738 BENZYL CHLORIDE 6.1 8 II 0 E4 P001 IBC02 B20 T8 TP2 TP13 F-A, S-B CategoryD SW2 H1 SGG1 SGG10 SG36 SG49 Colourless liquid with a pungent odour. Causes tears. Immiscible with water, but hydrolyses slowly in contact with it. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by vapour inhalation. Causes burns to skin, eyes and mucous membranes. 1738
1739 BENZYL CHLOROFORMATE 8 I 0 E0 P001 T10 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless liquid with an irritating odour. Reacts with water. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1739
1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW1 SW2 SGG1 SG35 SG36 SG49 Crystalline solids. Decomposed by heat or acid, evolving hydrogen fluoride, an extremely irritating and corrosive gas. In the presence of moisture, corrosive to glass, other siliceous materials and most metals. Cause burns to skin, eyes and mucous membranes. 1740
1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 8 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SW1 SW2 SGG1 SG35 SG36 SG49 See entry above. 1740
1741 BORON TRICHLORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW1 SW2 Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Much heavier than air (2.35). Highly irritating to skin, eyes and mucous membranes. 1741
1742 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1742
1743 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID 8 II 500 mL E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1743
1744 BROMINE or BROMINE SOLUTION 8 6.1 I 0 E0 P804 T22 TP2 TP10 TP13 F-A, S-B CategoryD SW1 SW2 H2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Very dark brown, heavy liquid with an extremely irritating odour. Density: 3.1 (pure product). Boiling point: 59°C. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Solutions have the same properties to a lesser degree, depending on concentration. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1744
1745 BROMINE PENTAFLUORIDE 5.1 6.1/8 I 0 E0 P200 T22 TP2 TP13 F-A, S-B CategoryD SW1 SW2 SGG1 SG6 SG16 SG19 SG36 SG49 Colourless, heavy liquid with an extremely irritating odour. Boiling point: 40°C. Powerful oxidant; may cause fire in contact with organic material such as wood, cotton or straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely corrosive gas apparent as white fumes. In contact with acids or acid fumes, evolves highly toxic fumes of bromine, fluorine and their compounds. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1745
1746 BROMINE TRIFLUORIDE 5.1 6.1/8 I 0 E0 P200 T22 TP2 TP13 F-A, S-B CategoryD SW1 SW2 SGG1 SG6 SG16 SG19 SG36 SG49 Colourless, heavy liquid with an extremely irritating odour. Powerful oxidant; may cause fire in contact with organic material such as wood, cotton or straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely corrosive gas apparent as white fumes. In contact with acids or acid fumes, evolves highly toxic fumes of bromine, fluorine and their compounds. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1746
1747 BUTYLTRICHLOROSILANE 8 3 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C CategoryC SW2 SGG1 SG36 SG49 Colourless, flammable liquid with a pungent odour. Flashpoint: 52°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1747
1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 5.1 II 314 1 kg E2 P002 PP85 F-H, S-Q CategoryD SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 White or yellowish solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. 1748
1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 5.1 III 316 5 kg E1 P002 PP85 F-H, S-Q CategoryD SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 See entry above. 1748
1749 CHLORINE TRIFLUORIDE 2.3 5.1/8 0 E0 P200 F-C, S-W CategoryD SW2 SG6 SG19 Non-flammable, toxic and corrosive gas. Forms dense, white, corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. Corrosive to glass and to most metals. Powerful oxidizing agent which may cause fires with combustible materials. Much heavier than air. Highly irritating to skin, eyes and mucous membranes. 1749
1750 CHLOROACETIC ACID SOLUTION 6.1 8 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid. Corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1750
1751 CHLOROACETIC ACID, SOLID 6.1 8 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless, very deliquescent crystals. Melting point may be as low as 50°C. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by dust inhalation. Causes burns to skin, eyes and mucous membranes. 1751
1752 CHLOROACETYL CHLORIDE 6.1 8 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless liquid, with extremely irritating odour, causing tears. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1752
1753 CHLOROPHENYL-TRICHLOROSILANE 8 II 0 E2 P010 T10 TP2 TP7 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Irritating to skin, eyes and mucous membranes. 1753
1754 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 8 I 0 E0 P001 T20 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1754
1755 CHROMIC ACID SOLUTION 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryC SW2 SGG1 SG6 SG8 SG10 SG12 SG36 SG49 Orange liquid. Powerful oxidant. May cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1755
1755 CHROMIC ACID SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryC SW2 SGG1 SG6 SG8 SG10 SG12 SG36 SG49 See entry above. 1755
1756 CHROMIC FLUORIDE, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG1 SG35 SG36 SG49 Green or violet crystals. Slightly soluble in water. Reacts with acids, evolving hydrogen fluoride, an extremely irritating and corrosive gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1756
1757 CHROMIC FLUORIDE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Green liquid. Reacts with acids, evolving hydrogen fluoride, an extremely irritating and corrosive gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1757
1757 CHROMIC FLUORIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 See entry above. 1757
1758 CHROMIUM OXYCHLORIDE 8 I 0 E0 P001 T10 TP2 F-A, S-B CategoryC SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Dark red liquid. Reacts violently with water, evolving hydrogen chloride and chlorine, both highly irritating and corrosive gases apparent as white fumes. Oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1758
1759 CORROSIVE SOLID, N.O.S. 8 I 274 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B CategoryB Causes burns to skin, eyes and mucous membranes. 1759
1759 CORROSIVE SOLID, N.O.S. 8 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA See entry above. 1759
1759 CORROSIVE SOLID, N.O.S. 8 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA See entry above. 1759
1760 CORROSIVE LIQUID, N.O.S. 8 I 274 0 E0 P001 T14 TP2 TP7 F-A, S-B CategoryB SW2 Causes burns to skin, eyes and mucous membranes. 1760
1760 CORROSIVE LIQUID, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B CategoryB SW2 See entry above. 1760
1760 CORROSIVE LIQUID, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B CategoryA SW2 See entry above. 1760
1761 CUPRIETHYLENEDIAMINE SOLUTION 8 6.1 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SG35 Dark purple liquid with an ammonia-like odour. Corrosive to copper, aluminium, zinc and tin. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1761
1761 CUPRIETHYLENEDIAMINE SOLUTION 8 6.1 III 223 5 L E1 P001 IBC03 T7 TP1 TP28 F-A, S-B CategoryA SG35 See entry above. 1761
1762 CYCLOHEXENYLTRICHLORO-SILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1762
1763 CYCLOHEXYLTRICHLORO-SILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1763
1764 DICHLOROACETIC ACID 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless liquid. Melting point: −4°C. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1764
1765 DICHLOROACETYL CHLORIDE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless liquid with an extremely irritating odour, causing tears. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1765
1766 DICHLOROPHENYL-TRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Irritating to skin, eyes and mucous membranes. 1766
1767 DIETHYLDICHLOROSILANE 8 3 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C CategoryC SW2 SGG1 SG36 SG49 Colourless, flammable liquid with a pungent odour. Flashpoint: 25°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1767
1768 DIFLUOROPHOSPHORIC ACID, ANHYDROUS 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 Colourless liquid. In the presence of moisture, highly corrosive to glass and other siliceous materials. Harmful if swallowed. 1768
1769 DIPHENYLDICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1769
1770 DIPHENYLMETHYL BROMIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Solid with an irritating odour. Causes tears. Melting point: 45°C. In the presence of moisture, corrosive to most metals. Vapour irritates mucous membranes. 1770
1771 DODECYLTRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1771
1773 FERRIC CHLORIDE, ANHYDROUS 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 Brown solid. In the presence of moisture, highly corrosive to most metals. The provisions of this Code should not apply to the solid hydrated form. 1773
1774 FIRE EXTINGUISHER CHARGES, corrosive liquid 8 II 1 L E0 P001 PP4 F-A, S-B CategoryA Usually, diluted sulphuric acid in small glass receptacles. 1774
1775 FLUOROBORIC ACID 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless, clear liquid. Corrosive to most metals. May cause severe burns to skin, eyes and mucous membranes if containing free hydrofluoric acid. 1775
1776 FLUOROPHOSPHORIC ACID, ANHYDROUS 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless liquid. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. 1776
1777 FLUOROSULPHONIC ACID 8 I 0 E0 P001 T10 TP2 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen fluoride, an extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes severe burns to skin, eyes and mucous membranes. 1777
1778 FLUOROSILICIC ACID 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless liquid. Highly corrosive to most metals. May cause severe burns to skin, eyes and mucous membranes if containing free hydrofluoric acid. 1778
1779 FORMIC ACID with more than 85% acid, by mass 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SW2 SGG1 SG36 SG49 Colourless flammable liquid with a pungent odour. Pure FORMIC ACID: flashpoint 42°C c.c. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1779
1780 FUMARYL CHLORIDE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Yellow liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1780
1781 HEXADECYLTRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1781
1782 HEXAFLUOROPHOSPHORIC ACID 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless liquid. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. Harmful if swallowed. 1782
1783 HEXAMETHYLENEDIAMINE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SG35 Colourless liquid. Causes burns to skin, eyes and mucous membranes. 1783
1783 HEXAMETHYLENEDIAMINE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SG35 See entry above. 1783
1784 HEXYLTRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1784
1786 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 8 6.1 I 0 E0 P001 T10 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless syrupy liquid with a pungent odour. Mixture consists of between 70% and 80% by mass of acids and contains not less than 25% by mass of hydrofluoric acid. Reacts violently with water, developing heat. Highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin and mucous membranes. 1786
1787 HYDRIODIC ACID 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SGG1 SG36 SG49 Colourless liquid. An aqueous solution of the gas hydrogen iodide. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1787
1787 HYDRIODIC ACID 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryC SGG1 SG36 SG49 See entry above. 1787
1788 HYDROBROMIC ACID 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SGG1 SG36 SG49 Colourless liquid. An aqueous solution of the gas hydrogen bromide. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1788
1788 HYDROBROMIC ACID 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryC SGG1 SG36 SG49 See entry above. 1788
1789 HYDROCHLORIC ACID 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryC SGG1 SG36 SG49 Colourless liquid. An aqueous solution of the gas hydrogen chloride. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1789
1789 HYDROCHLORIC ACID 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryC SGG1 SG36 SG49 See entry above. 1789
1790 HYDROFLUORIC ACID, with more than 60% hydrogen fluoride 8 6.1 I 0 E0 P802 PP79 PP81 T10 TP2 TP13 F-A, S-B CategoryD SW1 SW2 H2 SGG1 SG36 SG49 Colourless liquid with an irritating odour. Highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Both the liquid and its fumes cause severe burns to skin, eyes and mucous membranes. 1790
1790 HYDROFLUORIC ACID, with not more than 60% hydrogen fluoride 8 6.1 II 1 L E2 P001 PP81 IBC02 B20 T8 TP2 F-A, S-B CategoryD SW1 SW2 H2 SGG1 SG36 SG49 See entry above. 1790
1791 HYPOCHLORITE SOLUTION 8 II 274 900 1 L E2 P001 PP10 IBC02 B5 T7 TP2 TP24 F-A, S-B CategoryB SGG8 SG20 Liquid with chlorine odour. In contact with acids, evolves very irritating and corrosive gases. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1791
1791 HYPOCHLORITE SOLUTION 8 III 223 274 900 5 L E1 P001 LP01 IBC03 T4 TP2 TP24 F-A, S-B CategoryB SGG8 SG20 Liquid with chlorine odour. In contact with acids, evolves very irritating and corrosive gases. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1791
1792 IODINE MONOCHLORIDE, SOLID 8 II 1 kg E0 P002 IBC08 B4 B21 T7 TP2 F-A, S-B CategoryD SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Red, brown or black crystals. Reacts violently with water, evolving irritating and corrosive gases apparent as white fumes. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1792
1793 ISOPROPYL ACID PHOSPHATE 8 III 5 L E1 P001 LP01 IBC02 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Oily liquid. Mildly corrosive to most metals. 1793
1794 LEAD SULPHATE with more than 3% free acid 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG1 SGG7 SGG9 SG36 SG49 May be dry solid or slurry. Corrosive to most metals. Harmful if swallowed. 1794
1796 NITRATING ACID MIXTURE with more than 50% nitric acid 8 5.1 I 0 E0 P001 T10 TP2 TP13 F-A, S-Q CategoryD SW2 SGG1 SG16 SG36 SG49 Mixture of concentrated nitric and sulphuric acids. Oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, developing highly toxic gas (brown fumes). Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1796
1796 NITRATING ACID MIXTURE with not more than 50% nitric acid 8 II 1 L E0 P001 IBC02 B20 T8 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 See entry above. 1796
1798 NITROHYDROCHLORIC ACID 8 I 0 E0 P802 T10 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Yellow liquid; a mixture of nitric acid and hydrochloric acid, usually in the proportion of 1:3. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, evolving suffocating and highly toxic gases. Highly corrosive to all metals. Causes severe burns to skin, eyes and mucous membranes. 1798
1799 NONYLTRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1799
1800 OCTADECYLTRICHLORO- SILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1800
1801 OCTYLTRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1801
1802 PERCHLORIC ACID with not more than 50% acid, by mass 8 5.1 II 1 L E0 P001 IBC02 T7 TP2 F-H, S-Q CategoryC SGG1 SG16 SG36 SG49 Colourless liquid. Oxidant. Highly corrosive to most metals. 1802
1803 PHENOLSULPHONIC ACID, LIQUID 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW15 SGG1 SG36 SG49 Yellow, oily liquid. Corrosive to most metals. 1803
1804 PHENYLTRICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1804
1805 PHOSPHORIC ACID, SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Miscible in water. Mildly corrosive to most metals. 1805
1806 PHOSPHORUS PENTACHLORIDE 8 II 1 kg E0 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryC SW2 SGG1 SG6 SG8 SG10 SG12 SG36 SG49 Colourless, crystalline powder. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. 1806
1807 PHOSPHORUS PENTOXIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 Crystalline powder, very deliquescent. Reacts violently with water and organic materials such as wood, cotton or straw, generating heat. In the presence of moisture, mildly corrosive to most metals. 1807
1808 PHOSPHORUS TRIBROMIDE 8 II 1 L E0 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1808
1809 PHOSPHORUS TRICHLORIDE 6.1 8 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1809
1810 PHOSPHORUS OXYCHLORIDE 6.1 8 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Highly toxic if swallowed, by skin contact or by inhalation. 1810
1811 POTASSIUM HYDROGEN DIFLUORIDE, SOLID 8 6.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW1 SW2 SGG1 SG35 SG36 SG49 White crystalline solid. Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1811
1812 POTASSIUM FLUORIDE, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SG35 White, deliquescent crystals or powder. Decomposed by acids, evolving hydrogen fluoride, an irritating and corrosive gas. Toxic if swallowed, by skin contact or by inhalation. 1812
1813 POTASSIUM HYDROXIDE, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG35 White pellets, flakes, lumps or solid blocks, deliquescent. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1813
1814 POTASSIUM HYDROXIDE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG18 SG35 Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1814
1814 POTASSIUM HYDROXIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG18 SG35 See entry above. 1814
1815 PROPIONYL CHLORIDE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SW2 SGG1 SG36 SG49 Colourless liquid. Flashpoint: 12°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1815
1816 PROPYLTRICHLOROSILANE 8 3 II 0 E0 P010 T10 TP2 TP7 TP13 F-E, S-C CategoryC SW2 SGG1 SG36 SG49 Colourless, flammable liquid, with a pungent odour. Flashpoint: 38°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1816
1817 PYROSULPHURYL CHLORIDE 8 II 1 L E2 P001 IBC02 T8 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1817
1818 SILICON TETRACHLORIDE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 SG72 Colourless, extremely mobile liquid with a suffocating odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1818
1819 SODIUM ALUMINATE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG18 SG35 Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1819
1819 SODIUM ALUMINATE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG18 SG35 See entry above. 1819
1823 SODIUM HYDROXIDE, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG35 White pellets, flakes, lumps or solid blocks, deliquescent. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1823
1824 SODIUM HYDROXIDE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG18 SG35 Colourless liquid. Corrosive to aluminium, zinc and tin. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 1824
1824 SODIUM HYDROXIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG18 SG35 See entry above. 1824
1825 SODIUM MONOXIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG35 Deliquescent crystalline solid. Reacts violently with water and acids, generating heat. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 1825
1826 NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid 8 5.1 I 113 0 E0 P001 T10 TP2 TP13 F-A, S-Q CategoryD SW2 SGG1 SG16 SG36 SG49 Usually a mixture of acids which has been used for nitration processes. Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. Prohibited for shipment unless the mixture is (1) chemically stable; and (2) certified as containing no explosive impurities. 1826
1826 NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid 8 II 113 1 L E0 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 See entry above. 1826
1827 STANNIC CHLORIDE, ANHYDROUS 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SGG1 SG36 SG49 Colourless liquid. In the presence of water, corrosive to most metals. Vapour irritates mucous membranes. 1827
1828 SULPHUR CHLORIDES 8 I 0 E0 P602 T20 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Red liquids with a suffocating odour. React violently with water, evolving hydrogen chloride and sulphur dioxide, irritating and corrosive gases. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1828
1829 SULPHUR TRIOXIDE, STABILIZED 8 I 386 0 E0 P001 T20 TP4 TP13 TP25 TP26 F-A, S-B CategoryC SW1 SW2 SGG1 SG36 SG49 Very deliquescent solid. Melting point may be as low as 17°C. Reacts violently with water, generating heat. May cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1829
1830 SULPHURIC ACID with more than 51% acid 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryC SW15 SGG1 SG36 SG49 Colourless, oily liquid, mixture over 1.41 up to 1.84 relative density. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1830
1831 SULPHURIC ACID, FUMING 8 6.1 I 0 E0 P602 T20 TP2 TP13 F-A, S-B CategoryC SW2 SW15 SGG1 SG36 SG49 Colourless, oily liquid, may be partly crystallized. Solution of varying quantities of sulphur trioxide in sulphuric acid. Reacts violently with water and organic material, generating heat. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. 1831
1832 SULPHURIC ACID, SPENT 8 II 113 1 L E0 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryC SW15 SGG1 SG36 SG49 Sulphuric acid, usually of high concentration, which has been used for chemical processes. Highly corrosive to most metals. 1832
1833 SULPHUROUS ACID 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryB SW2 SGG1 SG36 SG49 Solution of sulphur dioxide in water, with a suffocating odour. Corrosive to most metals. Vapour irritates mucous membranes. 1833
1834 SULPHURYL CHLORIDE 6.1 8 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Boiling point: 69°C. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. Highly toxic if swallowed, by skin contact or by inhalation. 1834
1835 TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with more than 2.5% but less than 25% tetramethylammonium hydroxide 8 6.1 II 279 408 409 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG2 SGG18 SG35 Colourless liquid with a strong ammonia-like odour that is miscible with water. Corrosive to metal. When heated emits toxic fumes of nitrogen oxides and ammonia. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes, and mucous membranes. Reacts violently with acids. 1835
1835 TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with not more than 2.5% tetramethylammonium hydroxide 8 III 223 408 409 5 L E1 P001 LP01 IBC03 T7 TP2 F-A, S-B CategoryA SGG2 SGG18 SG35 See entry above. 1835
1836 THIONYL CHLORIDE 8 I 0 E0 P802 T10 TP2 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Yellow or red liquid. Boiling point: 79°C. Reacts violently with water, evolving hydrogen chloride and sulphur dioxide, irritating and corrosive gases. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1836
1837 THIOPHOSPHORYL CHLORIDE 8 II 1 L E0 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1837
1838 TITANIUM TETRACHLORIDE 6.1 8 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-B CategoryD SW2 SGG1 SGG7 SG36 SG49 Colourless liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1838
1839 TRICHLOROACETIC ACID, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless, deliquescent crystals. Melting point of the pure substance: 58°C. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1839
1840 ZINC CHLORIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP2 F-A, S-B CategoryA SGG1 SGG7 SG36 SG49 Colourless liquid. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1840
1841 ACETALDEHYDE AMMONIA 9 III 5 kg E1 P002 LP02 IBC08 B3 B6 T1 TP33 F-A, S-B CategoryA SG29 White crystalline solid. Soluble in water. When heated, decomposes into ammonia and acetaldehyde. 1841
1843 AMMONIUM DINITRO--CRESOLATE, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryB SGG2 SG15 SG16 SG30 SG63 May support combustion and burn without oxygen. When involved in a fire, evolves toxic fumes. Forms extremely sensitive explosive compounds with lead, silver or other heavy metals and their compounds. Toxic if swallowed, by skin contact or by inhalation. 1843
1845 CARBON DIOXIDE, SOLID (DRY ICE) 9 0 E0 P003 PP18 F-C, S-V CategoryC SW2 Non-flammable gas in a white solid form. Slowly evolves vapours which are heavier than air (1.5). Inhalation of vapours may lead to unconsciousness. Can cause severe burns when in contact with the skin. 1845
1846 CARBON TETRACHLORIDE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW2 SGG10 Colourless, volatile liquid with a heavy anaesthetic vapour. Non-flammable; when involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 1846
1847 POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG35 Crystalline solid. Melting point: 60°C. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1847
1848 PROPIONIC ACID with not less than 10% and less than 90% acid, by mass 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Burns skin. Vapours irritate mucous membranes. 1848
1849 SODIUM SULPHIDE, HYDRATED with not less than 30% water 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG35 Yellow-pink or white deliquescent crystals, flakes or lumps. Melting point: 50°C. Soluble in water. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1849
1851 MEDICINE, LIQUID, TOXIC, N.O.S. 6.1 II 221 100 mL E4 P001 F-A, S-A CategoryC SW2 Toxic if swallowed, by skin contact or by inhalation. 1851
1851 MEDICINE, LIQUID, TOXIC, N.O.S. 6.1 III 221 223 5 L E1 P001 LP01 F-A, S-A CategoryC SW2 See entry above. 1851
1854 BARIUM ALLOYS, PYROPHORIC 4.2 I 0 E0 P404 PP31 T21 TP7 TP33 F-G, S-M CategoryD H1 SGG15 SG26 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. 1854
1855 CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC 4.2 I 0 E0 P404 PP31 F-G, S-M CategoryD H1 SG26 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. 1855
1856 RAGS, OILY 4.2 29 123 973 0 E0 P003 PP19 IBC08 B3 B6 F-A, S-J CategoryA Liable to ignite spontaneously in air according to oil content. 1856
1857 TEXTILE WASTE, WET 4.2 III 123 0 E1 P410 F-A, S-J CategoryA Liable to ignite spontaneously in air according to moisture content. 1857
1858 HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Non-flammable gas. Much heavier than air (5.2). 1858
1859 SILICON TETRAFLUORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic and corrosive gas with a pungent odour. Corrosive to metals. In moist air, produces hydrogen fluoride. Much heavier than air (3.6). Highly irritating to skin, eyes and mucous membranes. 1859
1860 VINYL FLUORIDE, STABILIZED 2.1 386 0 E0 P200 F-D, S-U CategoryE SW1 SW2 Flammable gas. Explosive limits: 2.9% to 29%. Heavier than air (1.6). 1860
1862 ETHYL CROTONATE 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-D CategoryB Colourless liquid with a pungent odour. Flashpoint: 2°C c.c. Immiscible with water. 1862
1863 FUEL, AVIATION, TURBINE ENGINE 3 I 500 mL E3 P001 T11 TP1 TP8 TP28 F-E, S-E CategoryE Boiling range: −14°C upwards. Immiscible with water. 1863
1863 FUEL, AVIATION, TURBINE ENGINE 3 II 1 L E2 P001 IBC02 T4 TP1 TP8 F-E, S-E CategoryB Immiscible with water. 1863
1863 FUEL, AVIATION, TURBINE ENGINE 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E CategoryA See entry above. 1863
1865 -PROPYL NITRATE 3 II 26 1 L E2 P001 F-E, S-D CategoryD SG6 SG8 SG10 SG12 White to straw-coloured liquid with an ether-like odour. Flashpoint: 20°C c.c. Explosive limits: 2% to 100%. Immiscible with water. Oxidizing material. May explode on heating. Harmful if swallowed or by inhalation. 1865
1866 RESIN SOLUTION, flammable 3 I 500 mL E3 P001 T11 TP1 TP8 TP28 F-E, S-E CategoryE Miscibility with water depends upon the composition. 1866
1866 RESIN SOLUTION, flammable 3 II 5 L E2 P001 PP1 IBC02 T4 TP1 TP8 F-E, S-E CategoryB See entry above. 1866
1866 RESIN SOLUTION, flammable 3 III 223 955 5 L E1 P001 LP01 PP1 IBC03 T2 TP1 F-E, S-E CategoryA See entry above. 1866
1868 DECABORANE 4.1 6.1 II 1 kg E0 P002 PP31 IBC06 B21 T3 TP33 F-A, S-G CategoryA SG17 Colourless crystals. Slightly soluble in water. Vapours may form explosive mixture in air. Forms explosive and extremely sensitive mixtures with oxidizing substances. Toxic if swallowed, by skin contact or by dust inhalation. 1868
1869 MAGNESIUM or MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons 4.1 III 59 920 5 kg E1 P002 LP02 PP100 L3 IBC08 B4 T1 TP33 F-G, S-G CategoryA H1 SG17 SG25 SG26 SG32 SG35 SG36 SG52 Silvery white metal. Burns with an intense white light and heat. In contact with water, especially seawater, may evolve hydrogen, a flammable gas. Reacts readily with acids and caustic alkali, evolving hydrogen. Reacts readily with iron oxide, producing a thermite effect. Forms explosive mixtures with oxidizing substances. 1869
1870 POTASSIUM BOROHYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-O CategoryE H1 SG26 SG35 White, crystalline powder. In contact with water, acids or moisture evolves hydrogen, which may be ignited by the heat of the reaction. 1870
1871 TITANIUM HYDRIDE 4.1 II 1 kg E2 P410 PP31 PP40 IBC04 T3 TP33 F-A, S-G CategoryE Dark grey powder or crystals. 1871
1872 LEAD DIOXIDE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q CategoryA SGG7 SGG9 Brown powder or crystals. Insoluble in water. Harmful if swallowed. 1872
1873 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 5.1 8 I 900 0 E0 P502 PP28 T10 TP1 F-A, S-Q CategoryD SGG1 SG16 SG36 SG49 Colourless liquid. Mixtures with combustible material may ignite spontaneously and, when involved in a fire, by shock or by friction, may cause an explosion. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Transport of PERCHLORIC ACID with more than 72% acid, by mass, is prohibited. 1873
1884 BARIUM OXIDE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA White solid. Evolves heat in contact with water. Toxic if swallowed, by skin contact or by dust inhalation. 1884
1885 BENZIDINE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA White, crystalline solid. Toxic if swallowed, by skin contact or by inhalation. 1885
1886 BENZYLIDENE CHLORIDE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryD SW2 Colourless liquid evolving vapour which is irritating to eyes and skin (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. 1886
1887 BROMOCHLOROMETHANE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SGG10 Clear, colourless, volatile liquid with a chloroform-like odour. Immiscible with water. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 1887
1888 CHLOROFORM 6.1 III 5 L E1 P001 LP01 IBC03 T7 TP2 F-A, S-A CategoryA SW2 SGG10 Colourless, volatile liquid. Boiling point: 61°C. Non-flammable. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. Anaesthetic. 1888
1889 CYANOGEN BROMIDE 6.1 8 I 0 E0 P002 PP31 T6 TP33 F-A, S-B CategoryD SW2 SGG6 SG35 Colourless crystals evolving toxic vapour which is irritating and causes tears. Melting point: approximately 52°C. Boiling point: approximately 62°C. In contact with water evolves hydrogen bromide and hydrogen cyanide, which are highly toxic, flammable and corrosive gases. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 1889
1891 ETHYL BROMIDE 3 6.1 II 1 L E2 P001 IBC02 B8 T7 TP2 TP13 F-E, S-D CategoryB SW2 SW5 SGG10 Colourless volatile liquid evolving irritating vapour with a narcotic effect. Flashpoint −20°C c.c. Boiling point: 38°C. Vapour can be ignited by an electric spark or similar sources of ignition. Toxic if swallowed, by skin contact or by inhalation. 1891
1892 ETHYLDICHLOROARSINE 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A CategoryD SW2 Colourless liquid evolving irritating vapour (“Tear Gas”). Highly toxic if swallowed, by skin contact or by inhalation. 1892
1894 PHENYLMERCURIC HYDROXIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SGG7 SGG11 White crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 1894
1895 PHENYLMERCURIC NITRATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SGG7 SGG11 White crystals or powder. Toxic if swallowed, by skin contact or by inhalation. 1895
1897 TETRACHLOROETHYLENE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SW2 SGG10 Colourless liquid with an ethereal odour. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 1897
1898 ACETYL IODIDE 8 II 1 L E2 P001 IBC02 T7 TP2 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid. Reacts violently with water, evolving hydrogen iodide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 1898
1902 DIISOOCTYL ACID PHOSPHATE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Oily liquid. Mildly corrosive to most metals. 1902
1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 I 274 0 E0 P001 F-A, S-B CategoryB A wide variety of corrosive liquids. Cause burns to skin, eyes and mucous membranes. 1903
1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 II 274 1 L E2 P001 IBC02 F-A, S-B CategoryB See entry above. 1903
1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 F-A, S-B CategoryA See entry above. 1903
1905 SELENIC ACID 8 I 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 White, very deliquescent crystalline solid. Melting point: 50°C. Soluble in water. Reacts violently with organic materials such as wood, cotton or straw. In the presence of moisture, corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 1905
1906 SLUDGE ACID 8 II 1 L E0 P001 IBC02 T8 TP2 TP28 F-A, S-B CategoryC SW15 SGG1 SG36 SG49 Waste or spent sulphuric acid, usually a by-product of refining petroleum oils or crude benzenes. Highly corrosive to most metals. 1906
1907 SODA LIME with more than 4% sodium hydroxide 8 III 62 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG18 SG35 Deliquescent, granulated mixture of sodium hydroxide and calcium hydroxide. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 1907
1908 CHLORITE SOLUTION 8 II 274 352 1 L E2 P001 IBC02 T7 TP2 TP24 F-A, S-B CategoryB SGG5 SG6 SG8 SG10 SG12 SG20 Colourless liquid. In contact with acids, evolves very irritating and corrosive gases. Oxidizing solution. May cause fire in contact with organic materials such as wood, cotton or straw. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1908
1908 CHLORITE SOLUTION 8 III 223 274 352 5 L E1 P001 LP01 IBC03 T4 TP2 TP24 F-A, S-B CategoryB SGG5 SG6 SG8 SG10 SG12 SG20 See entry above. 1908
1910 CALCIUM OXIDE 8 960 Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. 1910
1911 DIBORANE 2.3 2.1 0 E0 P200 F-D, S-U CategoryD SW2 SG46 Liquefied, flammable, toxic, colourless gas with an unpleasant odour. Explosive limits: 0.9% to 98%. Lighter than air (0.95). May decompose above −18°C with the formation of hydrogen and boron hydrides. Autoignition temperature: 90°C. Toxic by inhalation; forms boric acid and water by hydrolysis within the lungs. 1911
1912 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 2.1 228 0 E0 P200 T50 F-D, S-U CategoryD SW2 Solution of the flammable gas methyl chloride, UN No. 1063, in the liquid methylene chloride. 1912
1913 NEON, REFRIGERATED LIQUID 2.2 120 mL E1 P203 T75 TP5 F-C, S-V CategoryD Liquefied, inert gas. Lighter than air (0.7). 1913
1914 BUTYL PROPIONATES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids. Flashpoint: 32°C c.c. Immiscible with water. 1914
1915 CYCLOHEXANONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 38°C to 44°C c.c. Explosive limits: 1.1% to 9.4%. Immiscible with water. 1915
1916 2,2’-DICHLORODIETHYL ETHER 6.1 3 II 100 mL E4 P001 IBC02 T7 TP2 F-E, S-D CategoryA Colourless flammable liquid. Flashpoint: 55°C c.c. Immiscible with water, but reacts with it, forming corrosive and toxic fumes. Toxic if swallowed, by skin contact or by inhalation. 1916
1917 ETHYL ACRYLATE, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 TP13 F-E, S-D CategoryC SW1 SW2 Colourless liquid with a pungent odour. Flashpoint: 16°C c.c. Explosive limits: 1.8% to 14%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1917
1918 ISOPROPYLBENZENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E CategoryA Colourless liquid with a chloroform-like odour. Flashpoint: 31°C c.c. Explosive limits: 0.9% to 6.5%. Immiscible with water. 1918
1919 METHYL ACRYLATE, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 TP13 F-E, S-D CategoryC SW1 Colourless, volatile liquid with a pungent odour. Flashpoint: −3°C c.c. Explosive limits: 1.2% to 25%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 1919
1920 NONANES 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-E CategoryA Colourless liquids. Explosive limits: 0.8% to 2.9%. -NONANE: flashpoint 31°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1920
1921 PROPYLENEIMINE, STABILIZED 3 6.1 I 386 0 E0 P001 T14 TP2 TP13 F-E, S-D CategoryD SW1 SW2 Colourless liquid with an ammoniacal odour. Flashpoint: −4°C o.c. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin and eyes. 1921
1922 PYRROLIDINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SW2 SGG18 SG35 Colourless to pale yellow liquid with an ammoniacal odour. Reacts violently with acids. Flashpoint: 3°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. 1922
1923 CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J CategoryE H1 Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. 1923
1928 METHYLMAGNESIUM BROMIDE IN ETHYL ETHER 4.3 3 I 0 E0 P402 F-G, S-L CategoryD H1 SG26 Colourless, yellowish liquid. Decomposes violently in contact with water. Spillage will ignite spontaneously. 1928
1929 POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE) 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J CategoryE H1 Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. 1929
1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 9 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-J CategoryA H1 SGG7 SG11 SG20 White, amorphous solid material. Soluble in water. Liable to heat on contact with moisture and heating results in evolution of sulphur dioxide, an intensely irritating gas. Also evolves sulphur dioxide on contact with acids. 1931
1932 ZIRCONIUM SCRAP 4.2 III 223 0 E0 P002 LP02 PP31 L4 IBC08 B4 T1 TP33 F-G, S-L CategoryD H1 SG26 Particle size larger than 840 microns. Readily flammable; may ignite spontaneously in air. In contact with water, may evolve hydrogen, a flammable gas. 1932
1935 CYANIDE SOLUTION, N.O.S. 6.1 I 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A CategoryB SW2 SGG6 SG35 Liquid evolving toxic vapour. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. 1935
1935 CYANIDE SOLUTION, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A CategoryA SW2 SGG6 SG35 See entry above. 1935
1935 CYANIDE SOLUTION, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP13 TP28 F-A, S-A CategoryA SW2 SGG6 SG35 See entry above. 1935
1938 BROMOACETIC ACID SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 Corrosive to most metals. Harmful if swallowed. Causes burns to eyes and skin. 1938
1938 BROMOACETIC ACID SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T7 TP2 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 See entry above. 1938
1939 PHOSPHORUS OXYBROMIDE 8 II 1 kg E0 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryC SW1 SW2 H2 SGG1 SG36 SG49 Colourless crystals. Melting point: 56°C. Reacts violently with water, evolving hydrogen bromide, a toxic and corrosive gas apparent as white fumes. Reacts violently with organic materials (such as wood, cotton, straw), causing fire. Decomposes when heated, evolving toxic and corrosive gases. When involved in a fire, evolves toxic and corrosive gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 1939
1940 THIOGLYCOLIC ACID 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless liquid with a strong, very unpleasant odour. Corrosive to most metals. Harmful if swallowed. 1940
1941 DIBROMODIFLUOROMETHANE 9 III 5 L E1 P001 LP01 T11 TP2 F-A, S-A CategoryA SW1 Colourless, heavy liquid. Boiling point: 24°C. Immiscible with water. When involved in a fire, may evolve toxic fumes. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 1941
1942 AMMONIUM NITRATE with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 5.1 III 900 952 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-H, S-Q CategoryC SW1 SW14 SW23 SGG2 SG16 SG42 SG45 SG47 SG48 SG51 SG56 SG58 SG59 SG61 Crystals, granules or prills. Soluble in water. Supporter of combustion. A major fire aboard a ship carrying this substance may involve a risk of explosion in the event of contamination (e.g. by fuel oil) or strong confinement. An adjacent detonation may also involve the risk of explosion. If heated strongly, decomposes, giving off toxic gases and gases which support combustion. Transport of AMMONIUM NITRATE liable to self-heating sufficient to initiate decomposition is prohibited. 1942
1944 MATCHES, SAFETY (book, card or strike on box) 4.1 III 293 294 5 kg E1 P407 F-A, S-I CategoryA Intended to be ignited on a specially prepared surface. 1944
1945 MATCHES, WAX ‘VESTA’ 4.1 III 293 294 5 kg E1 P407 F-A, S-I CategoryB Ignite by friction; a prepared surface may be required. 1945
1950 AEROSOLS 2 See SP63 63 190 277 327 344 381 959 See SP277 E0 P207 LP200 PP87 L2 F-D, S-U – SW1 SW22 SG69 1950
1951 ARGON, REFRIGERATED LIQUID 2.2 120 mL E1 P203 T75 TP5 F-C, S-V CategoryD Liquefied, inert gas. Heavier than air (1.4). 1951
1952 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide 2.2 392 120 mL E1 P200 F-C, S-V CategoryA Liquefied, non-flammable gas with an ether-like odour. Explosive limits: 31% to 52%. Heavier than air (1.5). 1952
1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 2.1 274 0 E0 P200 F-D, S-U CategoryD SW2 1953
1954 COMPRESSED GAS, FLAMMABLE, N.O.S. 2.1 274 392 0 E0 P200 F-D, S-U CategoryD SW2 1954
1955 COMPRESSED GAS, TOXIC, N.O.S. 2.3 274 0 E0 P200 F-C, S-U CategoryD SW2 1955
1956 COMPRESSED GAS, N.O.S. 2.2 274 378 392 120 mL E1 P200 F-C, S-V CategoryA 1956
1957 DEUTERIUM, COMPRESSED 2.1 0 E0 P200 F-D, S-U CategoryE SW2 Flammable, odourless gas. Much lighter than air (0.14). 1957
1958 1,2-DICHLORO−1,1,2,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 114) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (5.9). Boiling point: 4°C. 1958
1959 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) 2.1 0 E0 P200 F-D, S-U CategoryE SW2 Flammable gas. Explosive limits: 2.3% to 25%. Much heavier than air (2.2). 1959
1961 ETHANE, REFRIGERATED LIQUID 2.1 0 E0 P203 T75 TP5 F-D, S-U CategoryD SW2 Liquefied, flammable gas with a faint odour. Explosive limits: 3% to 16%. Slightly heavier than air (1.05). 1961
1962 ETHYLENE 2.1 0 E0 P200 F-D, S-U CategoryE SW2 Flammable gas. Explosive limits: 3% to 34%. Slightly lighter than air (0.98). 1962
1963 HELIUM, REFRIGERATED LIQUID 2.2 120 mL E1 P203 T75 TP5 TP34 F-C, S-V CategoryD Liquefied, inert gas. Much lighter than air (0.14). 1963
1964 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. 2.1 274 0 E0 P200 F-D, S-U CategoryE SW2 Flammable hydrocarbon gas mixture obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air. 1964
1965 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. 2.1 274 392 0 E0 P200 T50 F-D, S-U CategoryE SW2 Liquefied flammable hydrocarbon gas obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air. 1965
1966 HYDROGEN, REFRIGERATED LIQUID 2.1 0 E0 P203 T75 TP5 TP34 F-D, S-U CategoryD SW2 SG46 Liquefied, flammable, odourless gas. Explosive limits: 4% to 75%. Much lighter than air (0.07). 1966
1967 INSECTICIDE GAS, TOXIC, N.O.S. 2.3 274 0 E0 P200 F-C, S-U CategoryD SW2 Toxic mixtures of insecticides with liquefied gases. These mixtures may be flammable. 1967
1968 INSECTICIDE GAS, N.O.S. 2.2 274 120 mL E1 P200 F-C, S-V CategoryA Non-flammable and non-toxic mixtures of insecticides with liquefied gases. 1968
1969 ISOBUTANE 2.1 392 0 E0 P200 T50 F-D, S-U CategoryE SW2 Flammable hydrocarbon. Heavier than air. 1969
1970 KRYPTON, REFRIGERATED LIQUID 2.2 120 mL E1 P203 T75 TP5 F-C, S-V CategoryD Liquefied, inert gas. Much heavier than air (2.9). 1970
1971 METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 2.1 392 974 0 E0 P200 F-D, S-U CategoryE SW2 Flammable gas. Explosive limits: 5% to 16%. Lighter than air (methane 0.55). 1971
1972 METHANE, REFRIGERATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID with high methane content 2.1 0 E0 P203 T75 TP5 F-D, S-U CategoryD SW2 Liquefied, flammable gas. Explosive limits: 5% to 16%. Lighter than air (methane 0.55). 1972
1973 CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUORO-ETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Liquefied, non-flammable gas. Much heavier than air (4.2.) 1973
1974 CHLORODIFLUOROBROMO-METHANE (REFRIGERANT GAS R 12B1) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Liquefied, non-flammable gas. Much heavier than air (5.7). 1974
1975 NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) 2.3 5.1/8 0 E0 P200 F-C, S-W CategoryD SW2 SG6 SG19 Non-flammable, toxic and corrosive, brown gas mixtures of varying composition with a pungent odour. Strong oxidizing agent. Heavier than air. Highly irritating to skin, eyes and mucous membranes. Toxic by inhalation, with delayed effect similar to phosgene. 1975
1976 OCTAFLUOROCYCLOBUTANE (REFRIGERANT GAS RC 318) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Liquefied, non-flammable gas. Much heavier than air (7.0). 1976
1977 NITROGEN, REFRIGERATED LIQUID 2.2 345 346 120 mL E1 P203 T75 TP5 F-C, S-V CategoryD Liquefied, non-flammable, odourless gas. Lighter than air (0.97). Arrangements for the containment of the liquid nitrogen and fittings in use should be appropriate to the potential danger to the structure of the freight container or ship from the effect of misuse or accidental spillage. 1977
1978 PROPANE 2.1 392 0 E0 P200 T50 F-D, S-U CategoryE SW2 Flammable hydrocarbon gas. Explosive limits: 2.3% to 9.5%. Heavier than air (1.56). 1978
1982 TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) 2.2 120 mL E1 P200 F-C, S-V CategoryA Non-flammable gas. Much heavier than air (3.1). 1982
1983 1-CHLORO−2,2,2-TRIFLUORO-ETHANE (REFRIGERANT GAS R 133a) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Liquefied, non-flammable gas. Much heavier than air (4.1). Boiling point: 7°C. 1983
1984 TRIFLUOROMETHANE (REFRIGERANT GAS R 23) 2.2 120 mL E1 P200 F-C, S-V CategoryA Liquefied, non-flammable gas. Much heavier than air (2.4). 1984
1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 6.1 I 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D CategoryE SW2 Toxic if swallowed, by skin contact or by inhalation. 1986
1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 6.1 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-E, S-D CategoryB SW2 See entry above. 1986
1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 6.1 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-E, S-D CategoryA See entry above. 1986
1987 ALCOHOLS, N.O.S. 3 II 274 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-D CategoryB 1987
1987 ALCOHOLS, N.O.S. 3 III 223 274 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D CategoryA 1987
1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3 6.1 I 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D CategoryE SW2 Toxic if swallowed, by skin contact or by inhalation. 1988
1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3 6.1 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-E, S-D CategoryB SW2 See entry above. 1988
1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3 6.1 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-E, S-D CategoryA See entry above. 1988
1989 ALDEHYDES, N.O.S. 3 I 274 0 E3 P001 T11 TP1 TP27 F-E, S-D CategoryE 1989
1989 ALDEHYDES, N.O.S. 3 II 274 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-D CategoryB 1989
1989 ALDEHYDES, N.O.S. 3 III 223 274 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D CategoryA 1989
1990 BENZALDEHYDE 9 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-A, S-A CategoryA Colourless or yellowish volatile oil with a bitter almond odour. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. 1990
1991 CHLOROPRENE, STABILIZED 3 6.1 I 386 0 E0 P001 T14 TP2 TP6 TP13 F-E, S-D CategoryD SW1 SW2 SGG10 Colourless liquid. Flashpoint: −20°C c.c. Explosive limits: 2.5% to 12%. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 1991
1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 6.1 I 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D CategoryE SW2 Flammable toxic liquid which is not specified by name in this class or, on account of its characteristics, in some other class. Toxic if swallowed, by skin contact or by inhalation. 1992
1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 6.1 II 274 1 L E2 P001 IBC02 T7 TP2 TP13 F-E, S-D CategoryB SW2 See entry above. 1992
1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 6.1 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-E, S-D CategoryA See entry above. 1992
1993 FLAMMABLE LIQUID, N.O.S. 3 I 274 0 E3 P001 T11 TP1 TP27 F-E, S-E CategoryE 1993
1993 FLAMMABLE LIQUID, N.O.S. 3 II 274 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-E CategoryB 1993
1993 FLAMMABLE LIQUID, N.O.S. 3 III 223 274 955 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-E CategoryA 1993
1994 IRON PENTACARBONYL 6.1 3 I 354 0 E0 P601 T22 TP2 TP13 F-E, S-D CategoryD SW2 Yellow to dark red, volatile flammable liquid. Flashpoint: −15°C c.c. Explosive limits: 3.7% to 12.5%. May react with water or steam, evolving carbon monoxide, which is a toxic gas. Highly toxic if swallowed, by skin contact or by inhalation. 1994
1999 TARS, LIQUID, including road oils, and cutback bitumens 3 II 5 L E2 P001 IBC02 T3 TP3 TP29 F-E, S-E CategoryB Mobile liquids prepared by mixing asphalt with petroleum distillate. Pungent odour. Immiscible with water. 1999
1999 TARS, LIQUID, including road oils, and cutback bitumens 3 III 955 5 L E1 P001 LP01 IBC03 T1 TP3 F-E, S-E CategoryA See entry above. 1999
2000 CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap 4.1 III 223 383 5 kg E1 P002 LP02 PP7 F-A, S-I CategoryA Ignites readily. When involved in a fire, evolves toxic fumes; in enclosed cargo spaces, these fumes may form an explosive mixture with air. 2000
2001 COBALT NAPHTHENATES, POWDER 4.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-I CategoryA Brown, amorphous powder. Insoluble in water. Readily combustible. 2001
2002 CELLULOID, SCRAP 4.2 III 223 0 E0 P002 LP02 PP8 IBC08 B3 F-A, S-J CategoryD Ignites readily. When involved in a fire, evolves toxic fumes; in enclosed cargo spaces, these fumes may form an explosive mixture with air. 2002
2004 MAGNESIUM DIAMIDE 4.2 II 0 E2 P410 PP31 IBC06 T3 TP33 F-G, S-M CategoryC H1 SG26 White powder. Ignites spontaneously in air. Reacts violently in contact with water. 2004
2006 PLASTICS, NITROCELLULOSE-BASED, SELF-HEATING, N.O.S. 4.2 III 274 0 E0 P002 F-A, S-G CategoryC 2006
2008 ZIRCONIUM POWDER, DRY 4.2 I 0 E0 P404 PP31 T21 TP7 TP33 F-G, S-M CategoryD H1 SGG15 SG26 Amorphous powder. Liable to ignite spontaneously in air. Forms explosive mixtures with oxidizing substances. 2008
2008 ZIRCONIUM POWDER, DRY 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-G, S-M CategoryD H1 SGG15 SG26 See entry above. 2008
2008 ZIRCONIUM POWDER, DRY 4.2 III 223 0 E1 P002 LP02 PP31 L4 IBC08 B4 T1 TP33 F-G, S-M CategoryD H1 SGG15 SG26 See entry above. 2008
2009 ZIRCONIUM, DRY, finished sheets, strip or coiled wire 4.2 III 223 0 E1 P002 LP02 PP31 L4 F-G, S-M CategoryD H1 SGG15 SG26 Hard, silvery metal, liable to ignite spontaneously in air. 2009
2010 MAGNESIUM HYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-O CategoryE H1 SG26 SG35 White crystals. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 2010
2011 MAGNESIUM PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N CategoryE SW2 SW5 H1 SG26 SG35 Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2011
2012 POTASSIUM PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N CategoryE SW2 SW5 H1 SG26 SG35 Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2012
2013 STRONTIUM PHOSPHIDE 4.3 6.1 I 0 E0 P403 PP31 F-G, S-N CategoryE SW2 SW5 H1 SG26 SG35 Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2013
2014 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) 5.1 8 II 1 L E2 P504 PP10 IBC02 B5 T7 TP2 TP6 TP24 F-H, S-Q CategoryD SW1 SGG16 SG16 SG59 SG72 Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, except aluminium. In contact with combustible material, may cause fire or explosion. Causes burns to skin, eyes and mucous membranes. Even though stabilized, these solutions may evolve oxygen. 2014
2015 HYDROGEN PEROXIDE, STABILIZED or HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide 5.1 8 I 0 E0 P501 T9 TP2 TP6 TP24 F-H, S-Q CategoryD SW1 SGG16 SG16 SG59 Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, except aluminium. Decomposes vigorously in contact with permanganates. When involved in a fire, mixtures with combustible material may be explosive. Causes burns to skin, eyes and mucous membranes. Even though stabilized, these solutions may evolve oxygen. 2015
2016 AMMUNITION, TOXIC, NON- EXPLOSIVE without burster or expelling charge, non-fuzed 6.1 0 E0 P600 F-A, S-A CategoryE SW2 H1 Contents may evolve toxic fumes or vapour. Gases evolved are toxic by skin contact or by inhalation. 2016
2017 AMMUNITION, TEAR-PRODUCING, NON-EXPLOSIVE without burster or expelling charge, non-fuzed 6.1 8 0 E0 P600 F-A, S-B CategoryE SW2 H1 Contents may evolve irritant gas or vapour with lachrymatory effects. 2017
2018 CHLOROANILINES, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA Crystalline solid. Melting point of pure -chloroaniline: 70°C approximately. Toxic if swallowed, by skin contact or by dust inhalation. 2018
2019 CHLOROANILINES, LIQUID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SG35 Colourless liquid. May be a mixture of two of the isomers (e.g. - and -) of chloroaniline. Reacts with acids. Toxic if swallowed, by skin contact or by inhalation. 2019
2020 CHLOROPHENOLS, SOLID 6.1 III 205 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA A wide range of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. 2020
2021 CHLOROPHENOLS, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 2021
2022 CRESYLIC ACID 6.1 8 II 100 mL E4 P001 IBC02 T7 TP2 TP13 F-A, S-B CategoryB Colourless to brownish-yellow liquid mixture with a phenolic odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. “Cresylic acid” is a generic name for mixtures of cresols and higher alkylphenols, in varying proportions. It generally contains more than 95% phenolic compounds. 2022
2023 EPICHLOROHYDRIN 6.1 3 II 279 100 mL E4 P001 IBC02 T7 TP2 TP13 F-E, S-D CategoryA SW2 Colourless flammable liquid with a chloroform-like odour. Flashpoint: approximately 32°C c.c. Toxic if swallowed, by skin contact or by inhalation. 2023
2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 I 43 66 274 0 E5 P001 F-A, S-A CategoryB SW2 SGG7 SGG11 Toxic if swallowed, by skin contact or by inhalation. 2024
2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 II 43 66 274 100 mL E4 P001 IBC02 F-A, S-A CategoryB SW2 SGG7 SGG11 See entry above. 2024
2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 III 43 66 223 274 5 L E1 P001 LP01 IBC03 F-A, S-A CategoryB SW2 SGG7 SGG11 See entry above. 2024
2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 I 43 66 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryA SGG7 SGG11 Toxic if swallowed, by skin contact or by dust inhalation. 2025
2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 II 43 66 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SGG7 SGG11 See entry above. 2025
2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 III 43 66 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SGG7 SGG11 See entry above. 2025
2026 PHENYLMERCURIC COMPOUND, N.O.S. 6.1 I 43 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryA SGG7 SGG11 Usually white crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. 2026
2026 PHENYLMERCURIC COMPOUND, N.O.S. 6.1 II 43 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SGG7 SGG11 See entry above. 2026
2026 PHENYLMERCURIC COMPOUND, N.O.S. 6.1 III 43 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SGG7 SGG11 See entry above. 2026
2027 SODIUM ARSENITE, SOLID 6.1 II 43 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA Greyish-white powder. Soluble in water. Reacts with oxidizing substances, evolving heat. Toxic if swallowed, by skin contact or by dust inhalation. 2027
2028 BOMBS, SMOKE, NON-EXPLOSIVE with corrosive liquid, without initiating device 8 0 E0 P803 F-A, S-B CategoryE SW2 Corrosive content evolves dense smoke when in contact with air. Corrosive content may cause acid burns to skin. 2028
2029 HYDRAZINE, ANHYDROUS 8 3/6.1 I 0 E0 P001 F-E, S-C CategoryD SW2 SGG18 SG5 SG8 SG35 Colourless, flammable liquid with an ammoniacal odour. Reacts violently with acids. Flashpoint: 52°C c.c. Miscible with water. Highly reactive reducing agent. Ignites spontaneously when in contact with porous materials such as earth, wood or cloth. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. 2029
2030 HYDRAZINE, AQUEOUS SOLUTION with more than 37% hydrazine, by mass 8 6.1 I 0 E0 P001 T10 TP2 TP13 F-A, S-B CategoryD SW2 SGG18 SG35 Colourless liquid. Powerful reducing agent, burns readily. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 2030
2030 HYDRAZINE, AQUEOUS SOLUTION with more than 37% hydrazine, by mass 8 6.1 II 1 L E0 P001 IBC02 T7 TP2 TP13 F-A, S-B CategoryD SW2 SGG18 SG35 See entry above. 2030
2030 HYDRAZINE, AQUEOUS SOLUTION with more than 37% hydrazine, by mass 8 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryD SW2 SGG18 SG35 See entry above. 2030
2031 NITRIC ACID other than red fuming, with more than 70% nitric acid 8 5.1 I 0 E0 P001 PP81 T10 TP2 TP13 F-A, S-Q CategoryD SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Colourless liquid. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, evolving highly toxic gases (brown fumes). Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 2031
2031 NITRIC ACID other than red fuming, with at least 65% but with not more than 70% nitric acid 8 5.1 II 1 L E2 P001 PP81 IBC02 B15 B20 T8 TP2 F-A, S-Q CategoryD SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Colourless liquid. Oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, evolving highly toxic gases (brown fumes). Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 2031
2031 NITRIC ACID other than red fuming, with less than 65% nitric acid 8 II 1 L E2 P001 PP81 IBC02 B15 B20 T8 TP2 F-A, S-B CategoryD SGG1 SG36 SG49 See entry above. 2031
2032 NITRIC ACID, RED FUMING 8 5.1/6.1 I 0 E0 P602 T20 TP2 TP13 F-A, S-Q CategoryD SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Brown liquid. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by vapour inhalation. Causes severe burns to skin, eyes and mucous membranes. 2032
2033 POTASSIUM MONOXIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG22 SG35 Deliquescent crystalline solid. Reacts violently with water, generating heat. Reacts with ammonium salts, evolving ammonia gas. Reacts violently with acids. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 2033
2034 HYDROGEN AND METHANE MIXTURE, COMPRESSED 2.1 0 E0 P200 F-D, S-U CategoryE SW2 SG46 Flammable, odourless gas mixtures. Much lighter than air. 2034
2035 1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) 2.1 0 E0 P200 T50 F-D, S-U CategoryB SW2 Flammable gas with a slight odour. Much heavier than air (2.9). 2035
2036 XENON 2.2 378 392 120 mL E1 P200 F-C, S-V CategoryA Liquefied, inert gas. Much heavier than air (4.5). 2036
2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2 191 277 303 327 344 959 see SP277 E0 P003 LP200 PP17 PP96 L2 F-D, S-U CategoryB SW2 SW22 Normally contain mixtures of liquefied butane and propane in various proportions for use in camping stoves, etc. 2037
2038 DINITROTOLUENES, LIQUID 6.1 II 100 mL E4 P001 IBC02 B20 T7 TP2 F-A, S-A CategoryA Immiscible with water. A commercial grade consisting of a mixture of the 2,4-, 3,4- and 3,5-isomers is an oily liquid. Toxic if swallowed, by skin contact or by inhalation. 2038
2044 2,2-DIMETHYLPROPANE 2.1 0 E0 P200 F-D, S-U CategoryE SW2 Flammable hydrocarbon gas. Explosive limits: 1.4% to 7.2%. Heavier than air (2.48). 2044
2045 ISOBUTYL ALDEHYDE (ISOBUTYRALDEHYDE) 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryE SW2 Colourless liquid with a characteristic pungent odour. Flashpoint: −24°C c.c. Explosive limits: 1% to 12%. Immiscible with water. 2045
2046 CYMENES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids with an aromatic odour. Immiscible with water. Explosive limits: 0.7% to 5.6%. 2046
2047 DICHLOROPROPENES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless or yellow liquids with a sweet odour. Explosive limits: 5% to 14%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2047
2047 DICHLOROPROPENES 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA See entry above. 2047
2048 DICYCLOPENTADIENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA The pure substance is a solid with a melting point of 34°C. Flashpoint: 26°C to 38°C o.c. Commercial products are liquids. Immiscible with water. Harmful if swallowed. 2048
2049 DIETHYLBENZENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids. Flashpoint: 49°C to 56°C c.c. Immiscible with water. The commercial product is a mixture of isomers. 2049
2050 DIISOBUTYLENES, ISOMERIC COMPOUNDS 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquids. Flashpoint: −18°C to 21°C c.c. Explosive limits: 0.8% to 4.8%. Immiscible with water. 2050
2051 2-DIMETHYLAMINOETHANOL 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SG35 Colourless, flammable liquid with a fishy odour. Flashpoint: 31°C o.c. Miscible with water. Causes burns to skin, eyes and mucous membranes. 2051
2052 DIPENTENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E CategoryA Colourless liquid with a lemon-like odour. Flashpoint: 43°C c.c. Explosive limits: 0.7% to 6.1%. Immiscible with water. 2052
2053 METHYL ISOBUTYL CARBINOL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 41°C c.c. Explosive limits: 1% to 5.5%. Miscible with water. Harmful by inhalation. 2053
2054 MORPHOLINE 8 3 I 0 E0 P001 T10 TP2 F-E, S-C CategoryA Colourless liquid with a fishy odour. Flashpoint: 38°C o.c. Explosive limits: 2% to 11.2%. Miscible with water. Harmful by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes. 2054
2055 STYRENE MONOMER, STABILIZED 3 III 386 5 L E1 P001 IBC03 T2 TP1 F-E, S-D CategoryC SW1 Colourless, oily liquid. Flashpoint: 32°C c.c. Explosive limits: 1.1% to 6.1%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2055
2056 TETRAHYDROFURAN 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid with an ethereal odour. Flashpoint: below −18°C c.c. Explosive limits: 1.5% to 12%. Miscible with water. 2056
2057 TRIPROPYLENE 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-D CategoryB Colourless liquid. Immiscible with water. 2057
2057 TRIPROPYLENE 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-D CategoryA See entry above. 2057
2058 VALERALDEHYDE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 12°C c.c. Partially miscible with water. Irritating to skin, eyes and mucous membranes. 2058
2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 3 I 28 198 0 E0 P001 T11 TP1 TP8 TP27 F-E, S-D CategoryE When involved in a fire, evolves toxic nitrous fumes. 2059
2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 3 II 28 198 1 L E0 P001 IBC02 T4 TP1 TP8 F-E, S-D CategoryB See entry above. 2059
2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 3 III 28 198 223 5 L E0 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA See entry above. 2059
2067 AMMONIUM NITRATE BASED FERTILIZER 5.1 III 306 307 900 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-H, S-Q CategoryC SW1 SW14 SW23 SGG2 SG16 SG42 SG45 SG47 SG48 SG51 SG56 SG58 SG59 SG61 Crystals, granules or prills. Wholly or partly soluble in water. Supporters of combustion. A major fire aboard a ship carrying these substances may involve a risk of explosion in the event of contamination (e.g. by fuel oil) or strong confinement. An adjacent detonation may also involve a risk of explosion. If heated strongly, decompose, giving off toxic gases and gases which support combustion. Transport of AMMONIUM NITRATE liable to self-heating sufficient to initiate decomposition is prohibited. 2067
2071 AMMONIUM NITRATE BASED FERTILIZER 9 III 193 5 kg E1 P002 LP02 IBC08 B3 BK2 F-H, S-Q CategoryA SW26 SGG2 Usually granules. Wholly or partly soluble in water. These mixtures may be subject to self-sustaining decomposition if heated. The temperature in such a reaction can reach 500°C. Decomposition, once initiated, may spread throughout the remainder, producing gases which are toxic. None of these mixtures is subject to the explosion hazard. Transport of AMMONIUM NITRATE liable to self-heating sufficient to initiate decomposition is prohibited. 2071
2073 AMMONIA SOLUTION, relative density less than 0.880 at 15°C in water, with more than 35% but not more than 50% ammonia 2.2 120 mL E0 P200 F-C, S-U CategoryE SW2 SGG2 SGG18 SG35 SG46 Solution in water of non-flammable gas with a pungent odour. Reacts violently with acids. Extremely dangerous to the eyes. 2073
2074 ACRYLAMIDE, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SW1 H2 Crystals or powder. Soluble in water. May polymerise violently on melting. Toxic if swallowed, by skin contact or by inhalation. 2074
2075 CHLORAL, ANHYDROUS, STABILIZED 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryD SW2 Colourless, mobile liquid, evolving toxic vapours which are considerably heavier than air. Toxic if swallowed, by skin contact or by inhalation. 2075
2076 CRESOLS, LIQUID 6.1 8 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-B CategoryB Colourless to light yellow liquids. Miscible with water. Melting point of -CRESOL: 12°C. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2076
2077 -NAPHTHYLAMINE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA White crystals. Toxic if swallowed, by skin contact or by inhalation. 2077
2078 TOLUENE DIISOCYANATE 6.1 II 279 100 mL E4 P001 IBC02 T7 TP2 TP13 F-A, S-A CategoryC SW1 SW2 Colourless to pale yellow liquid with a pungent odour. Immiscible with water but reacts with it to form carbon dioxide. Melting point: 20°C (pure product). Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2078
2079 DIETHYLENETRIAMINE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SW2 SGG18 SG35 Yellow hygroscopic liquid with ammoniacal odour. Soluble in water. Strongly alkaline, corrosive. Can form explosive mixtures with nitric acid. Reacts with oxidizing substances. Corrosive to copper and its alloys. Reacts violently with acids. Liquid and vapour can cause severe damage to skin and eyes. 2079
2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID 2.3 8 900 Transport is prohibited. 2186
2187 CARBON DIOXIDE, REFRIGERATED LIQUID 2.2 120 mL E1 P203 T75 TP5 F-C, S-V CategoryD Non-flammable, liquefied gas, colourless and odourless. Heavier than air (1.5). Cannot remain in the liquid state above 31°C. 2187
2188 ARSINE 2.3 2.1 0 E0 P200 F-D, S-U CategoryD SW2 Flammable, toxic, colourless gas with a garlic odour. Explosive limits: 3.9% to 77.8%. Much heavier than air (2.8). 2188
2189 DICHLOROSILANE 2.3 2.1/8 0 E0 P200 F-D, S-U CategoryD SW2 SG4 SG9 SG72 Flammable, toxic and corrosive gas. Reacts with water, evolving hydrogen chloride. Highly irritating to skin, eyes and mucous membranes. 2189
2190 OXYGEN DIFLUORIDE, COMPRESSED 2.3 5.1/8 0 E0 P200 F-C, S-W CategoryD SW2 H1 SG6 SG19 Non-flammable, toxic and corrosive, colourless gas with a foul odour. Strong oxidizing agent. Reacts slowly with water or moist air to produce poisonous and corrosive fumes. Corrosive to glass and to most metals. Heavier than air (1.9). Highly irritating to skin, eyes and mucous membranes. 2190
2191 SULPHURYL FLUORIDE 2.3 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic, colourless, odourless gas. Reacts with water or moist air to produce toxic and corrosive fumes. Much heavier than air (3.5). Irritating to skin, eyes and mucous membranes. 2191
2192 GERMANE 2.3 2.1 0 E0 P200 F-D, S-U CategoryD SW2 Flammable, toxic, colourless gas with a pungent odour. Much heavier than air (2.6). 2192
2193 HEXAFLUOROETHANE (REFRIGERANT GAS R 116) 2.2 120 mL E1 P200 F-C, S-V CategoryA Non-flammable, colourless and odourless gas. Much heavier than air (4.8). Cannot remain in liquid state above 24.3°C. 2193
2194 SELENIUM HEXAFLUORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Colourless, toxic and corrosive gas. Corrosive to glass and to most metals. Heavier than air. Highly irritating to skin, eyes and mucous membranes. 2194
2195 TELLURIUM HEXAFLUORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic and corrosive colourless gas with an unpleasant odour. Decomposes in water, evolving highly toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (7.2). Highly irritating to skin, eyes and mucous membranes. 2195
2196 TUNGSTEN HEXAFLUORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic and corrosive, colourless gas, or yellow liquid. Decomposes in water or moist air, evolving highly toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (10.3). Boiling point: 19.5°C. Highly irritating to skin, eyes and mucous membranes. 2196
2197 HYDROGEN IODIDE, ANHYDROUS 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic and corrosive colourless gas with a pungent odour. Highly corrosive in the presence of water. Much heavier than air (4.4). Highly irritating to skin, eyes and mucous membranes. 2197
2198 PHOSPHORUS PENTAFLUORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic and corrosive gas with an irritating odour. Reacts with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (4.3). Highly irritating to skin, eyes and mucous membranes. 2198
2199 PHOSPHINE 2.3 2.1 0 E0 P200 F-D, S-U CategoryD SW2 Flammable, toxic, colourless gas with a garlic odour. Ignites spontaneously in air. Heavier than air (1.2). Irritating to skin, eyes and mucous membranes. 2199
2200 PROPADIENE, STABILIZED 2.1 386 0 E0 P200 F-D, S-U CategoryB SW1 SW2 Liquefied, flammable, colourless gas. Explosive limits: 1.7% to 12%. Heavier than air (1.4). Boiling point: −34°C. Irritating to skin, eyes and mucous membranes. 2200
2201 NITROUS OXIDE, REFRIGERATED LIQUID 2.2 5.1 0 E0 P203 T75 TP5 TP22 F-C, S-W CategoryD SW2 Liquefied, non-flammable, colourless gas with a slightly sweet odour. Strong oxidizing agent. Heavier than air (1.5). Cannot remain in liquid state above 36.5°C. 2201
2202 HYDROGEN SELENIDE, ANHYDROUS 2.3 2.1 0 E0 P200 F-D, S-U CategoryD SW2 Flammable, toxic, colourless gas with a disagreeable odour. Much heavier than air (2.8). Highly irritating to skin, eyes and mucous membranes. 2202
2203 SILANE 2.1 0 E0 P200 F-D, S-U CategoryE SW2 SG43 SG46 Flammable, colourless gas with a foul odour. Explosive limits: 1% to 100%. Ignites spontaneously in air. Strong reducing agent which reacts violently with oxidizing substances. Heavier than air (1.1). 2203
2204 CARBONYL SULPHIDE 2.3 2.1 0 E0 P200 F-D, S-U CategoryD SW2 Flammable, toxic, colourless gas with a foul odour. Much heavier than air (2.1). 2204
2205 ADIPONITRILE 6.1 III 5 L E1 P001 LP01 IBC03 T3 TP1 F-A, S-A CategoryA SGG6 Colourless, odourless oil. Decomposes above 93°C, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. 2205
2206 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A CategoryE SW1 SW2 Liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. If under deck, with mechanical ventilation, six air changes per hour, except when carried in closed containers, when two air changes per hour are required. Irritating to skin, eyes and mucous membranes. 2206
2206 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP13 TP28 F-A, S-A CategoryE SW1 SW2 Liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. If under deck, with mechanical ventilation, six air changes per hour, except when carried in closed containers, when two air changes per hour are required. Irritating to skin, eyes and mucous membranes. 2206
2208 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine 5.1 III 314 5 kg E1 P002 PP85 F-H, S-Q CategoryD SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 White or yellowish solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. 2208
2209 FORMALDEHYDE SOLUTION with not less than 25% formaldehyde 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA Colourless, clear liquid, with a suffocating pungent odour. Usually stabilized with methyl alcohol. Miscible with water. Causes burns to skin, eyes and mucous membranes. 2209
2210 MANEB or MANEB PREPARATION with not less than 60% maneb 4.2 4.3 III 273 0 E1 P002 PP100 IBC06 T1 TP33 F-G, S-L CategoryA H1 SG26 SG29 Yellow powder, liable to heat and to ignite spontaneously in air. May evolve toxic, irritating or flammable fumes when wet, when involved in a fire or in contact with acids. Used as fungicide. 2210
2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour 9 III 382 965 5 kg E1 P002 PP14 IBC08 B3 B6 T1 TP33 F-A, S-I CategoryE SW1 SW6 SG5 SG14 A moulding material in bead or granular form consisting predominantly of polystyrene, poly(methyl methacrylate) or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predominantly pentane. During storage, a small proportion of this pentane is released to the atmosphere; this proportion increases at elevated temperatures. 2211
2212 ASBESTOS, AMPHIBOLE (amosite, tremolite, actinolite, anthophyllite, crocidolite) 9 II 168 274 1 kg E0 P002 PP37 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SW2 H4 SG29 Mineral fibres of varying length. Non-combustible. Inhalation of the dust of asbestos fibres is dangerous and therefore exposure should be avoided at all times. Always prevent the generation of asbestos dust. A safe level of airborne concentration of asbestos fibres may be obtained through effective packing. Cargo spaces or freight containers that have contained any type of raw asbestos should be carefully cleaned before discharging any remaining cargo, loading other cargo or carrying out repair or maintenance work. Whenever possible, cleaning of cargo spaces should be carried out whilst the ship is in a port where proper facilities and equipment, including proper respiratory apparatus and protective clothing, is available. Parts of the body that may have been exposed should be immediately and thoroughly washed. All waste material should be collected in impermeable and sealed bags for safe disposal ashore. If cleaning cannot be carried out at the discharge port, arrangements should be made in advance for cleaning to be carried out at the next port where necessary facilities are available. 2212
2213 PARAFORMALDEHYDE 4.1 III 223 967 5 kg E1 P002 LP02 PP12 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-G CategoryA SW23 White powder with a pungent odour. Evolves formaldehyde, particularly when heated, which is irritating to eyes and mucous membranes. 2213
2214 PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride 8 III 169 939 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 White powder or flakes and lumps containing a high proportion of dust. Melting point: 131°C. The vapour of the molten substance has a flashpoint of 152°C c.c. and forms a flammable atmosphere with explosive limits of 1.7% to 10.4%. Causes burns to skin, eyes and mucous membranes. May be carried in the molten state. The molten substance can cause severe skin burns. 2214
2215 MALEIC ANHYDRIDE 8 III 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 SG50 SG57 White powder, needles, flakes, pellets, rods, briquettes, lumps or fused mass. Melting point: about 53°C. Fumes and dust are irritating to skin, eyes and mucous membranes. Inhalation can cause respiratory trouble. 2215
2215 MALEIC ANHYDRIDE, MOLTEN 8 III 0 E0 T4 TP3 F-A, S-B CategoryA SGG1 SG36 SG49 SG50 SG57 Melting point: about 53°C. The vapour of the molten substance has a flashpoint of 103°C c.c. and forms a flammable atmosphere with explosive limits of 1.4% to 7.1%. Fumes are irritating to skin, eyes and mucous membranes. 2215
2216 FISH MEAL (FISH SCRAP), STABILIZED Anti-oxidant treated. Moisture content greater than 5% but not exceeding 12%, by mass. Fat content not more than 15% 9 III 29 117 300 308 907 928 973 0 E1 P900 IBC08 B3 T1 BK2 TP33 F-A, S-J CategoryB SW24 SG18 SG65 Brown to greenish-brown product obtained through heating and drying of oily fish. Strong odour which may affect other cargo. Liable to heat spontaneously unless of low fat content or effectively anti-oxidant treated. 2216
2217 SEED CAKE with not more than 1.5% oil and not more than 11% moisture 4.2 III 29 142 973 0 E0 P002 LP02 PP20 IBC08 B3 B6 BK2 F-A, S-J CategoryA SW1 SW4 H1 Residue remaining after oil has been extracted by a solvent process from oil-bearing seeds. Used mainly as an animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal, etc. May self-heat slowly if wet and ignite spontaneously. Before shipment, this cargo should be properly aged. The duration of ageing varies with the oil content. The seed cake should be substantially free from flammable solvent. Smoking and the use of naked lights should not be allowed during loading and unloading, and on entry to cargo spaces at any other time. 2217
2218 ACRYLIC ACID, STABILIZED 8 3 II 386 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryC SW1 SW2 SGG1 SG36 SG49 Colourless, flammable liquid with an acrid odour. Melting point: 13°C. Flashpoint: 54°C o.c. Miscible with water. May polymerize violently, which may cause fire and explosion, unless properly stabilized. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. 2218
2219 ALLYL GLYCIDYL ETHER 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 48°C c.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2219
2222 ANISOLE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless to yellow liquid. Flashpoint: 41°C c.c. Explosive limits: 0.3% to 6.3%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2222
2224 BENZONITRILE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW2 SG35 Colourless liquid with an odour similar to oil of bitter almonds. Reacts with acids, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. 2224
2225 BENZENESULPHONYL CHLORIDE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SW2 SGG1 Colourless to slightly yellow liquid with a pungent odour. Melting point: 12°C. Immiscible with water. Decomposes slowly in water. Harmful if swallowed or by skin contact. Highly irritating to skin, eyes and mucous membranes. 2225
2226 BENZOTRICHLORIDE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 Colourless to slightly yellow or brown fuming liquid. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Harmful if swallowed, by skin contact or by inhalation. Burns skin and eyes. Vapour irritates eyes and mucous membranes. 2226
2227 -BUTYL METHACRYLATE, STABILIZED 3 III 386 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryC SW1 Colourless liquid. Flashpoint: 41°C c.c. Explosive limits: 2% to 8%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2227
2232 2-CHLOROETHANAL 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A CategoryD SW2 Clear colourless liquid with a pungent odour. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 2232
2233 CHLOROANISIDINES 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA Crystalline solid. Melting point: 52°C. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2233
2234 CHLOROBENZOTRIFLUORIDES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA SW2 SGG10 Colourless liquids with an aromatic odour. Flashpoint: 36°C to 59°C c.c. On contact with moisture, can evolve hydrogen fluoride, which is a toxic and corrosive gas. Harmful by inhalation. 2234
2235 CHLOROBENZYL CHLORIDES, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2235
2236 3-CHLORO−4-METHYLPHENYL ISOCYANATE, LIQUID 6.1 II 100 mL E4 P001 IBC02 F-A, S-A CategoryB SW2 Colourless liquid with a pungent odour. Immiscible with water. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2236
2237 CHLORONITROANILINES 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA Yellow or orange crystalline powders or needles. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2237
2238 CHLOROTOLUENES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA SGG10 Colourless to brown liquids. Flashpoint: 43°C to 47°C c.c. Immiscible with water. When involved in a fire, evolve toxic gases. Harmful by skin contact or by inhalation. Irritating to eyes and mucous membranes. 2238
2239 CHLOROTOLUIDINES, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA Crystalline solids. Some isomers may melt at low temperature: melting range between 0°C and 24°C. Toxic if swallowed, by skin contact or by inhalation. 2239
2240 CHROMOSULPHURIC ACID 8 I 0 E0 P001 T10 TP2 TP13 F-A, S-B CategoryB SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 A liquid mixture of sulphuric acid and a chromium compound (e.g. chromium trioxide or sodium dichromate) and sometimes also water. Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. 2240
2241 CYCLOHEPTANE 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-D CategoryB SW2 Oily liquid. Immiscible with water. Narcotic. 2241
2242 CYCLOHEPTENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Oily liquid. Immiscible with water. 2242
2243 CYCLOHEXYL ACETATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 56°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2243
2244 CYCLOPENTANOL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless, oily liquid. Flashpoint: 51°C c.c. Immiscible with water. 2244
2245 CYCLOPENTANONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 31°C c.c. Immiscible with water. 2245
2246 CYCLOPENTENE 3 II 1 L E2 P001 IBC02 B8 T7 TP2 F-E, S-D CategoryE Colourless liquid. Flashpoint: −30°C c.c. Boiling point: 44°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic. 2246
2247 -DECANE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E CategoryA Colourless liquid. Flashpoint: 47°C c.c. Explosive limits: 0.6% to 5.5%. Immiscible with water. 2247
2248 DI--BUTYLAMINE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SG35 Colourless, flammable liquid with an amine odour. Flashpoint: 39°C c.c. Partially miscible with water. Decomposes when heated, evolving flammable and toxic gases. Liquid is corrosive to skin, eyes and mucous membranes. Vapour irritates mucous membranes. 2248
2249 DICHLORODIMETHYL ETHER, SYMMETRICAL 6.1 3 I 976 0 E0 P099 F-E, S-D CategoryD SW2 Colourless, volatile, flammable liquid. Flashpoint: 42°C c.c. Immiscible with water. Decomposed by heat and water. Highly toxic if swallowed, by skin contact or by inhalation. The transport of this substance is prohibited except with special authorization granted by the competent authorities. 2249
2250 DICHLOROPHENYL ISOCYANATES 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryB SW1 SW2 Colourless to yellowish crystalline solid with an irritating odour. Insoluble in water. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. May be carried in the molten state. Irritating to skin, eyes and mucous membranes. 2250
2251 BICYCLO[2.2.1]-HEPTA−2,5-DIENE, STABILIZED (2,5-NORBORNADIENE, STABILIZED) 3 II 386 1 L E2 P001 IBC02 T7 TP2 F-E, S-D CategoryD SW1 Colourless, volatile liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 6.3%. Immiscible with water. 2251
2252 1,2-DIMETHOXYETHANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid with an ethereal odour. Flashpoint: 1°C c.c. Miscible with water. 2252
2253 ,-DIMETHYLANILINE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Yellowish to brownish oily liquid. Combustible. Toxic if swallowed, by skin contact or by inhalation. 2253
2254 MATCHES, FUSEE 4.1 III 293 5 kg E0 P407 F-A, S-I CategoryA Matches, the heads of which are prepared with a friction-sensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat, regardless of wind or other weather conditions. 2254
2256 CYCLOHEXENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryE Colourless liquid with an aromatic odour. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. 2256
2257 POTASSIUM 4.3 I 0 E0 P403 PP31 IBC04 B1 T9 TP7 TP33 F-G, S-N CategoryD H1 SG26 SG35 Soft, silvery metal, solid or liquid. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 2257
2258 1,2-PROPYLENEDIAMINE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SW2 SG35 Colourless, flammable liquid with an ammoniacal odour. Flashpoint range: 33°C to 48°C c.c. Miscible with water. When involved in a fire, evolves toxic gases. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2258
2259 TRIETHYLENETETRAMINE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryB SW2 SGG18 SG35 Moderately viscous, yellow combustible liquid with an ammoniacal odour. Miscible with water. Strongly alkaline. Can form explosive mixtures with nitric acid. When involved in a fire, evolves toxic gases. Corrosive to copper and copper alloys. Reacts violently with acids. Liquid and vapours cause burns to skin, eyes and mucous membranes. Causes skin allergy. 2259
2260 TRIPROPYLAMINE 3 8 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-C CategoryA SW2 SG35 Colourless liquid. Flashpoint: 35°C c.c. Partially miscible with water. When involved in a fire, evolves toxic gases. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2260
2261 XYLENOLS, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA Crystals or needles. Toxic if swallowed, by skin contact or by inhalation. 2261
2262 DIMETHYLCARBAMOYL CHLORIDE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 Colourless to yellow liquid with a pungent odour. Immiscible with water. Reacts with water, evolving toxic and corrosive fumes. Causes tears. Causes burns to skin, eyes and mucous membranes. 2262
2263 DIMETHYLCYCLOHEXANES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquids. Flashpoint: 5°C to 16°C c.c. Immiscible with water. 2263
2264 ,-DIMETHYL-CYCLOHEXYLAMINE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SW2 SG35 Colourless, flammable liquid. Flashpoint: 43°C c.c. Partially miscible with water. Causes burns to skin, eyes and mucous membranes. 2264
2265 ,-DIMETHYLFORMAMIDE 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-D CategoryA Colourless liquid. Flashpoint: 58°C c.c. Explosive limits: 2.2% to 16%. Miscible with water. May react violently with oxidizing materials. 2265
2266 DIMETHYLPROPYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP2 TP13 F-E, S-C CategoryB SW2 SG35 Colourless liquid with a fishy odour. Flashpoint: −11°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. 2266
2267 DIMETHYL THIOPHOSPHORYL CHLORIDE 6.1 8 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-B CategoryB SW1 SGG1 SG36 SG49 Colourless, combustible liquid with a pungent odour. Reacts slowly with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. May decompose above 60°C, evolving flammable gases. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2267
2269 3,3’-IMINODIPROPYLAMINE 8 III 5 L E1 P001 LP01 IBC03 - T4 TP2 F-A, S-B CategoryA SG35 Colourless combustible liquid. Miscible with water. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. 2269
2270 ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamine 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SW2 SGG18 SG35 Aqueous solution of a flammable gas with an ammonia-like odour. Explosive limits: 3.5% to 14%. ETHYLAMINE SOLUTION, concentration 50%: flashpoint −11°C c.c.; boiling point 56°C. Pure ETHYLAMINE: boiling point 17°C. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 2270
2271 ETHYL AMYL KETONES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids. Vapour is much heavier than air (4.4). ETHYL -AMYL KETONE: flashpoint 43°C c.c. ETHYL -AMYL KETONE: flashpoint 57°C c.c. Immiscible with water. Dissolves some types of plastics. Irritating to skin, eyes and mucous membranes. 2271
2272 -ETHYLANILINE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SG17 SG35 Colourless to yellowish oily liquid. Reacts with acids, evolving highly toxic fumes of aniline and oxides of nitrogen. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2272
2273 2-ETHYLANILINE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SG17 SG35 Brown liquid. Immiscible with water. Reacts with acids, evolving highly toxic fumes of aniline and oxides of nitrogen. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2273
2274 -ETHYL--BENZYLANILINE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Light yellow, oily liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2274
2275 2-ETHYLBUTANOL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 57°C o.c. Immiscible with water. 2275
2276 2-ETHYLHEXYLAMINE 3 8 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-C CategoryA SW2 SG35 Colourless liquid. Flashpoint: 50°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. 2276
2277 ETHYL METHACRYLATE, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryC SW1 Colourless liquid with a pungent odour. Flashpoint: 20°C o.c. Lower explosive limit: 1.8%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2277
2278 -HEPTENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: −3°C c.c. Immiscible with water. 2278
2279 HEXACHLOROBUTADIENE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SGG10 Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2279
2280 HEXAMETHYLENEDIAMINE, MOLTEN 8 III 0 E0 T4 TP1 F-A, S-B CategoryA SW1 H2 SG35 White crystals or shiny flakes with a specific odour. Melting point: 29°C. Soluble in water; solution in water is a strong alkali. Decomposes when heated, evolving flammable and toxic gases. Causes burns to skin, eyes and mucous membranes. 2280
2280 HEXAMETHYLENEDIAMINE, SOLID 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SW1 H2 SG35 See entry above. 2280
2281 HEXAMETHYLENE DIISOCYANATE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 TP13 F-A, S-A CategoryC SW2 H1 Colourless to light yellow liquid with a pungent odour. Immiscible with water but reacts with it, evolving heat and carbon dioxide gas. When heated, evolves toxic nitrous fumes. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2281
2282 HEXANOLS 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids. -HEXANOL: flashpoint 57°C c.c. Miscible with water. 2282
2283 ISOBUTYL METHACRYLATE, STABILIZED 3 III 386 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryC SW1 Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2283
2284 ISOBUTYRONITRILE 3 6.1 II 1 L E2 P001 IBC02 T7 TP2 TP13 F-E, S-D CategoryE SW2 Colourless liquid. Flashpoint: 8°C c.c. Immiscible with water. Toxic by skin contact or by inhalation. 2284
2285 ISOCYANATOBENZO-TRIFLUORIDES 6.1 3 II 100 mL E4 P001 IBC02 T7 TP2 F-E, S-D CategoryD SW1 SW2 Colourless or yellowish liquids with a pungent odour. Flashpoint of - and -isomers: 56°C. Immiscible with water, but reacts with it to form carbon dioxide gas. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2285
2286 PENTAMETHYLHEPTANE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 43°C c.c. Immiscible with water. 2286
2287 ISOHEPTENES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquids. Immiscible with water. 2287
2288 ISOHEXENES 3 II 1 L E2 P001 IBC02 B8 T11 TP1 F-E, S-D CategoryE Colourless liquids. Boiling range: 54°C to 69°C. Immiscible with water. 2288
2289 ISOPHORONEDIAMINE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SG35 Colourless, slightly hygroscopic liquid with a slight amine odour. Combustible. Miscible with water. Harmful if swallowed. Irritating to skin, eyes and mucous membranes. 2289
2290 ISOPHORONE DIISOCYANATE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP2 F-A, S-A CategoryB SW2 Colourless or yellowish liquid. Immiscible with water. When involved in a fire, evolves nitrous fumes. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2290
2291 LEAD COMPOUND, SOLUBLE, N.O.S. 6.1 III 199 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SGG7 SGG9 Colourless crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2291
2293 4-METHOXY−4-METHYL-PENTAN−2-ONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. 2293
2294 -METHYLANILINE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP2 F-A, S-A CategoryA Colourless to brown combustible liquid. Toxic if swallowed, by skin contact or by inhalation. 2294
2295 METHYL CHLOROACETATE 6.1 3 I 0 E0 P001 T14 TP2 TP13 F-E, S-D CategoryD Colourless, flammable liquid with a pungent odour. Flashpoint: 47°C c.c. Vapour much heavier than air (vapour density relative to air: 3.8). Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 2295
2296 METHYLCYCLOHEXANE 3 II 1 L E2 P001 IBC02 T4 TP2 F-E, S-D CategoryB Colourless liquid. Flashpoint: −4°C c.c. Explosive limits: 1.2% to 6.7%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2296
2297 METHYLCYCLOHEXANONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless to pale yellow liquids with a sweet odour. 2-METHYLCYCLOHEXANONE: flashpoint 46°C c.c. 3-METHYLCYCLOHEXANONE: flashpoint 51°C c.c. 4-METHYLCYCLOHEXANONE: flashpoint 40°C c.c. Immiscible with water. 2297
2298 METHYLCYCLOPENTANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: below −10°C c.c. Explosive limits: 1% to 8.4%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2298
2299 METHYL DICHLOROACETATE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Liquid. Toxic if swallowed, by skin contact or by inhalation. 2299
2300 2-METHYL−5-ETHYLPYRIDINE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless liquid with a pungent odour. Toxic if swallowed, by skin contact or by inhalation. 2300
2301 2-METHYLFURAN 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryE Colourless liquid with a sweetish odour. Flashpoint: −30°C c.c. Immiscible with water. When involved in a fire, evolves toxic gases. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. 2301
2302 5-METHYLHEXAN−2-ONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 43°C c.c. Immiscible with water. 2302
2303 ISOPROPENYLBENZENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA SW1 Colourless liquid. Flashpoint: 38°C to 54°C c.c. Explosive limits: 0.7% to 6.6%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2303
2304 NAPHTHALENE, MOLTEN 4.1 III 0 E0 T1 TP3 F-A, S-H CategoryC Molten liquid with a persistent odour. Melting point: 80°C. Evolves flammable vapours. As the melting point of naphthalene approximates very closely its flashpoint, care should be taken to avoid all possible causes of ignition. Contact between water and molten naphthalene above 110°C must be avoided, as the addition of water will cause violent foaming or even an explosion. 2304
2305 NITROBENZENESULPHONIC ACID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 Crystals. Soluble in water. Causes burns to skin, eyes and mucous membranes. 2305
2306 NITROBENZOTRIFLUORIDES, LIQUID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW2 Pale straw-coloured, oily liquids with an aromatic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2306
2307 3-NITRO−4-CHLORO-BENZOTRIFLUORIDE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW2 Yellowish, oily liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2307
2308 NITROSYLSULPHURIC ACID, LIQUID 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryD SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Clear, straw-coloured, oily liquid. Oxidant which may cause fire with organic materials (such as wood, straw, etc.). When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2308
2309 OCTADIENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 9°C to 15°C c.c. Immiscible with water. 2309
2310 PENTANE−2,4-DIONE 3 6.1 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 34°C c.c. Lower explosive limit: 1.7%. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2310
2311 PHENETIDINES 6.1 III 279 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless to yellowish liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2311
2312 PHENOL, MOLTEN 6.1 II 0 E0 T7 TP3 F-A, S-A CategoryB SW2 Molten liquid with a distinctive strong odour. Melting point: 10°C to 43°C (pure product). Toxic if swallowed, by skin contact or by inhalation. Rapidly absorbed through the skin. 2312
2313 PICOLINES 3 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-E, S-D CategoryA SW2 Colourless to yellow liquids with a pungent or sweet odour. Explosive limits: 1.3% to 8.7%. Miscible with water. Harmful by inhalation. -Picoline flashpoint: 28°C c.c. -Picoline flashpoint: 40°C c.c. -Picoline flashpoint 40°C c.c. Irritating to skin, eyes and mucous membranes. 2313
2315 POLYCHLORINATED BIPHENYLS, LIQUID 9 II 305 1 L E2 P906 IBC02 T4 TP1 F-A, S-A CategoryA SG50 Colourless liquid (pure product) with perceptible odours. Immiscible with water. Harmful by ingestion or by skin contact. If spilled, can be a persistent hazard to the environment. This entry also covers articles, such as transformers and condensers, containing free liquid polychlorinated biphenyls. 2315
2316 SODIUM CUPROCYANIDE, SOLID 6.1 I 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryA SGG6 SG35 White powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. 2316
2317 SODIUM CUPROCYANIDE SOLUTION 6.1 I 0 E5 P001 T14 TP2 TP13 F-A, S-A CategoryB SW2 SGG6 SG35 Colourless liquid. Miscible with water. Decomposed by acids, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by inhalation. 2317
2318 SODIUM HYDROSULPHIDE with less than 25% water of crystallization 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J CategoryA SGG18 SG35 Colourless needles to lemon-coloured flakes. Soluble in water. Reacts violently with acids. 2318
2319 TERPENE HYDROCARBONS, N.O.S. 3 III 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D CategoryA Colourless or yellowish liquids. Flashpoint: 32°C to 49°C c.c. Immiscible with water. 2319
2320 TETRAETHYLENEPENTAMINE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG18 SG35 Viscous liquid. Miscible with water. When involved in a fire, evolves toxic gases. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 2320
2321 TRICHLOROBENZENES, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SGG10 Colourless liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2321
2322 TRICHLOROBUTENE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW1 SW2 SGG10 Colourless liquid. Immiscible with water. When heated, develops toxic and irritant gases such as phosgene and hydrogen chloride and may also explode. Toxic if swallowed, by skin contact or by inhalation. 2322
2323 TRIETHYL PHOSPHITE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 44°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2323
2324 TRIISOBUTYLENE 3 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-E, S-D CategoryA Colourless liquid. Immiscible with water. 2324
2325 1,3,5-TRIMETHYLBENZENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-D CategoryA Colourless liquid. Flashpoint: 44°C c.c. Immiscible with water. Harmful by inhalation. 2325
2326 TRIMETHYLCYCLOHEXYL- AMINE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SG35 Colourless, slightly hygroscopic, combustible liquid with a slight amine odour. Immiscible with water. Causes burns to skin, eyes and mucous membranes. 2326
2327 TRIMETHYLHEXAMETHYLENE-DIAMINES 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SG35 Colourless, slightly hygroscopic, combustible liquids. Miscible with water. Irritating to skin, eyes and mucous membranes. 2327
2328 TRIMETHYLHEXAMETHYLENE DIISOCYANATE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP2 TP13 F-A, S-A CategoryB Colourless or yellowish liquid. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2328
2329 TRIMETHYL PHOSPHITE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 23°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2329
2330 UNDECANE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E CategoryA Colourless liquid. Flashpoint: 60°C c.c. Immiscible with water. 2330
2331 ZINC CHLORIDE, ANHYDROUS 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SGG7 SG36 SG49 White, deliquescent crystals. Soluble in water. Dust causes burns to skin, eyes and mucous membranes. 2331
2332 ACETALDEHYDE OXIME 3 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 40°C c.c. Explosive limits: 4.2% to 52%. Freezing point 12°C. Miscible with water. Irritating to skin, eyes and mucous membranes. 2332
2333 ALLYL ACETATE 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE SW2 Colourless liquid. Flashpoint: 7°C c.c. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Harmful if swallowed. 2333
2334 ALLYLAMINE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 SG35 Colourless to light yellow volatile liquid with a pungent odour. Flashpoint: −29°C c.c. Explosive limits: 2.2% to 22%. Boiling range: 55°C to 58°C. Miscible with water. When involved in a fire, evolves highly toxic gases. Highly toxic if swallowed, by skin contact or by inhalation. 2334
2335 ALLYL ETHYL ETHER 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE SW2 Colourless liquid. Flashpoint: −11°C c.c. Vapour heavier than air. Immiscible with water. Narcotic. Toxic if swallowed, by skin contact or by inhalation. 2335
2336 ALLYL FORMATE 3 6.1 I 0 E0 P001 T14 TP2 TP13 F-E, S-D CategoryE SW2 Colourless liquid. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 2336
2337 PHENYL MERCAPTAN 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 SG35 Colourless flammable liquid with a foul odour. Flashpoint: 50°C c.c. Immiscible with water. In contact with acids or when involved in a fire, evolves highly toxic sulphurous fumes. Highly toxic if swallowed, by skin contact or by inhalation. 2337
2338 BENZOTRIFLUORIDE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SW2 Colourless liquid with an aromatic odour. Flashpoint: 12°C c.c. Lower explosive limit: 2.1%. Immiscible with water. On contact with moisture or air evolves hydrogen fluoride, which is a toxic and corrosive gas. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2338
2339 2-BROMOBUTANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SW2 SGG10 Colourless liquid with a pleasant odour. Flashpoint: 21°C c.c. Immiscible with water. When involved in a fire, evolves toxic fumes. Narcotic. 2339
2340 2-BROMOETHYL ETHYL ETHER 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SW2 Colourless liquid with an ethereal odour. Partially miscible with water. Harmful by inhalation. 2340
2341 1-BROMO−3-METHYLBUTANE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA SGG10 Colourless liquid. Flashpoint: 23°C to 32°C c.c. Immiscible with water. 2341
2342 BROMOMETHYLPROPANES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SGG10 Colourless liquids. Immiscible with water. Harmful by inhalation. 2342
2343 2-BROMOPENTANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SGG10 Colourless or yellow liquid with a strong odour. Flashpoint: 21°C c.c. Immiscible with water. Harmful by inhalation. 2343
2344 BROMOPROPANES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SW2 SGG10 Colourless liquids. Immiscible with water. When involved in a fire, evolve toxic fumes. Harmful by inhalation. 2344
2344 BROMOPROPANES 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA SGG10 See entry above. 2344
2345 3-BROMOPROPYNE 3 II 905 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryD SW2 Colourless to light amber liquid with a sharp odour. Flashpoint: 10°C c.c. Lower explosive limit: 3%. Vapour much heavier than air (4.1). The pure product is shock-sensitive and decomposes with explosive violence, and the possibility of detonation, when heated under confinement. Can be ignited by impact. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Causes tears. 2345
2346 BUTANEDIONE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Greenish-yellow liquid with a strong odour. Flashpoint: 6°C c.c. Miscible with water. 2346
2347 BUTYL MERCAPTAN 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SG35 SG50 SG57 Colourless liquids with a foul odour. -BUTYL MERCAPTAN: flashpoint −26°C c.c. -BUTYL MERCAPTAN: flashpoint −23°C c.c. 1-BUTANETHIOL (-BUTYL MERCAPTAN): flashpoint 12°C c.c. ISOBUTYL MERCAPTAN: flashpoint −9°C c.c. Immiscible with water. On contact with acids, emit highly toxic fumes. 2347
2348 BUTYL ACRYLATES, STABILIZED 3 III 386 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryC SW1 Colourless liquid with an unpleasant odour. Flashpoint: 36°C to 41°C c.c. Explosive limits: 1.2% to 9.9%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2348
2350 BUTYL METHYL ETHER 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Immiscible with water. 2350
2351 BUTYL NITRITES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SW2 Yellowish, volatile, oily liquids. Partially miscible with water. Decompose on exposure to air, light, water or heat, evolving toxic nitrous fumes. Harmful by inhalation. 2351
2351 BUTYL NITRITES 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA SW2 See entry above. 2351
2352 BUTYL VINYL ETHER, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryC SW1 SW2 Colourless, volatile liquid with a sharp ethereal odour. Flashpoint: −9°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2352
2353 BUTYRYL CHLORIDE 3 8 II 1 L E2 P001 IBC02 B20 T8 TP2 TP13 F-E, S-C CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2353
2354 CHLOROMETHYL ETHYL ETHER 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE SW2 Colourless liquid with a pungent odour. Partially miscible with water. Fumes in air, evolving hydrogen chloride, which is an irritating and corrosive gas. Toxic by inhalation. Strong lachrymator. 2354
2356 2-CHLOROPROPANE 3 I 0 E3 P001 T11 TP2 TP13 F-E, S-D CategoryE SGG10 Colourless liquid. Flashpoint: −32°C c.c. Explosive limits: 2.8% to 10.7%. Boiling point: 35°C. Immiscible with water. On contact with heat or flame, emits highly toxic phosgene gas. Can react vigorously with oxidizing materials. 2356
2357 CYCLOHEXYLAMINE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SW2 SG35 Colourless or yellowish flammable liquid with a fishy odour. Flashpoint: 27°C c.c. Explosive limits: 0.5% to 21.7%. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2357
2358 CYCLOOCTATETRAENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Freezing point: −4°C. Immiscible with water. 2358
2359 DIALLYLAMINE 3 6.1/8 II 1 L E2 P001 IBC99 T7 TP1 F-E, S-C CategoryB SW2 SG5 SG8 SG35 Colourless, volatile liquid with a disagreeable odour. Flashpoint: 7°C c.c. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2359
2360 DIALLYL ETHER 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE Colourless, volatile liquid with a perceptible odour. Flashpoint: −11°C c.c. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2360
2361 DIISOBUTYLAMINE 3 8 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-C CategoryA SG35 Colourless liquid with a fishy odour. Flashpoint: 29°C c.c. Immiscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2361
2362 1,1-DICHLOROETHANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SW2 SGG10 Colourless liquid with an aromatic, ethereal odour. Flashpoint: −10°C c.c. Lower explosive limit: 5.6%. Immiscible with water. When involved in a fire, emits toxic fumes of phosgene. Harmful by inhalation. 2362
2363 ETHYL MERCAPTAN 3 I 0 E0 P001 T11 TP2 TP13 F-E, S-D CategoryE SG50 SG57 Volatile liquid with a strong unpleasant odour. Flashpoint: −45°C c.c. Explosive limits: 2.8% to 18.2%. Boiling point: 35°C. Immiscible with water. 2363
2364 -PROPYLBENZENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 39°C c.c. Explosive limits: 0.8% to 6%. Immiscible with water. 2364
2366 DIETHYL CARBONATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 25°C to 31°C c.c. Vapour much heavier than air (4.1). Immiscible with water. Irritating to skin, eyes and mucous membranes. 2366
2367 -METHYL-VALERALDEHYDE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 13°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2367
2368 -PINENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-E CategoryA Colourless liquid with an odour of turpentine. Flashpoint: 33°C c.c. Explosive limits: 0.8% to 6%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2368
2370 1-HEXENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryE Colourless liquid. Explosive limits: 1.2% to 6.9%. Immiscible with water. 2370
2371 ISOPENTENES 3 I 0 E3 P001 T11 TP2 F-E, S-D CategoryE Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2371
2372 1,2-DI-(DIMETHYLAMINO)ETHANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 21°C c.c. Miscible with water. Irritability to skin, eyes and mucous membranes. 2372
2373 DIETHOXYMETHANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: below −5°C c.c. Miscible with water. 2373
2374 3,3-DIETHOXYPROPENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 15°C c.c. Partially miscible with water. Harmful by inhalation. 2374
2375 DIETHYL SULPHIDE 3 II 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE Colourless, volatile liquid with an odour of garlic. Flashpoint: −10°C c.c. Immiscible with water. 2375
2376 2,3-DIHYDROPYRAN 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless, volatile liquid with an ethereal odour. Flashpoint: −16°C c.c. Miscible with water. 2376
2377 1,1-DIMETHOXYETHANE 3 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D CategoryB Colourless liquid with a strong aromatic odour. Miscible with water. 2377
2378 2-DIMETHYLAMINO-ACETONITRILE 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D CategoryA SW2 SG35 Colourless liquid. Flashpoint: 35°C c.c. Immiscible with water. On contact with water and acids, evolves toxic fumes. Toxic if swallowed, by skin contact or by inhalation. 2378
2379 1,3-DIMETHYLBUTYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SGG18 SG35 Colourless liquid with an ammonia-like odour. Flashpoint: 9°C to 13°C c.c. Immiscible with water. Reacts violently with acids. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2379
2380 DIMETHYLDIETHOXYSILANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 13°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. 2380
2381 DIMETHYL DISULPHIDE 3 6.1 II 1 L E0 P001 IBC02 T7 TP2 TP13 F-E, S-D CategoryB SW2 Yellow liquid with an unpleasant odour. Flashpoint: 15°C c.c. Immiscible with water. When involved in a fire, evolves toxic gases. Toxic if swallowed, by skin contact or by inhalation. 2381
2382 DIMETHYLHYDRAZINE, SYMMETRICAL 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 SGG18 SG17 SG35 Colourless, flammable, volatile liquid with an ammonia-like odour. Miscible with water. Reacts violently with acids. May react dangerously with oxidizing substances. Flashpoint: −17°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. 2382
2383 DIPROPYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SW1 SG35 Colourless liquid with a fishy odour. Flashpoint: 7°C c.c. Immiscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. 2383
2384 DI--PROPYL ETHER 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint (pure product): −21°C c.c. Lower explosive limit: 1.7%. Immiscible with water. 2384
2385 ETHYL ISOBUTYRATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless, volatile liquid with an aromatic odour. Flashpoint: 21°C c.c. Immiscible with water. 2385
2386 1-ETHYLPIPERIDINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SGG18 SG35 Colourless liquid. Flashpoint: 19°C c.c. Immiscible with water. Reacts violently with acids. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. May cause lung damage. 2386
2387 FLUOROBENZENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SGG10 Colourless liquid with a benzene odour. Flashpoint: −15°C c.c. Immiscible with water. Harmful by inhalation. 2387
2388 FLUOROTOLUENES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SGG10 Colourless liquids. -FLUOROTOLUENE: flashpoint 9°C c.c. -FLUOROTOLUENE: flashpoint 12°C c.c. -FLUOROTOLUENE: flashpoint 10°C c.c. Immiscible with water. 2388
2389 FURAN 3 I 0 E3 P001 T12 TP2 TP13 F-E, S-D CategoryE SW2 Colourless liquid with a strong odour. Flashpoint: below −18°C c.c. Explosive limits: 1.3% to 14.3%. Boiling point: 31°C. Immiscible with water. Harmful if swallowed, by skin contact or by inhalation. 2389
2390 2-IODOBUTANE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SGG10 Colourless liquid. Flashpoint: 21°C c.c. Immiscible with water. 2390
2391 IODOMETHYLPROPANES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SGG10 Colourless liquids. Immiscible with water. 2391
2392 IODOPROPANES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA SGG10 Colourless liquids. 1-IODOPROPANE: flashpoint 34°C c.c. 2-IODOPROPANE: flashpoint approx. 25°C c.c. Immiscible with water. 2392
2393 ISOBUTYL FORMATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 5°C c.c. Explosive limits: 1.7% to 8%. Irritating to skin, eyes and mucous membranes. 2393
2394 ISOBUTYL PROPIONATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 31°C c.c. Immiscible with water. 2394
2395 ISOBUTYRYL CHLORIDE 3 8 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2395
2396 METHACRYLALDEHYDE, STABILIZED 3 6.1 II 386 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryD SW1 SW2 Colourless liquid. Flashpoint: 2°C c.c. Miscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. 2396
2397 3-METHYLBUTAN−2-ONE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: −3°C c.c. Explosive limits: 1.5% to 8%. Immiscible with water. 2397
2398 METHYL -BUTYL ETHER 3 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D CategoryE Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 8.4%. Boiling point: 55°C. Immiscible with water. 2398
2399 1-METHYLPIPERIDINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SGG18 SG35 Colourless liquid. Flashpoint: 3°C c.c. Miscible with water. Reacts violently with acids. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. 2399
2400 METHYL ISOVALERATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Immiscible with water. 2400
2401 PIPERIDINE 8 3 I 0 E0 P001 T10 TP2 F-E, S-C CategoryD SGG18 SG35 Colourless liquid with a fish-like odour. Miscible with water. Reacts violently with acids. Solution in water is a strong alkali and is corrosive. When involved in fire, evolves toxic nitrous fumes. 2401
2402 PROPANETHIOLS 3 II 1 L E2 P001 IBC02 T4 TP1 TP13 F-E, S-D CategoryE SG50 SG57 Colourless or yellowish liquids with a strong unpleasant odour. Flashpoint: below −18°C c.c. Boiling range: 53°C to 67°C. Immiscible with water. 2402
2403 ISOPROPENYL ACETATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 10°C c.c. Immiscible with water. 2403
2404 PROPIONITRILE 3 6.1 II 1 L E0 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE SW2 Colourless, volatile liquid with an ether-like odour. Flashpoint: 2°C c.c. Lower explosive limit: 3.1%. Miscible with water. When involved in a fire, evolves highly toxic cyanide fumes. Toxic if swallowed, by skin contact or by inhalation. 2404
2405 ISOPROPYL BUTYRATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 25°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2405
2406 ISOPROPYL ISOBUTYRATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 20°C c.c. Immiscible with water. Narcotic. Irritating to skin, eyes and mucous membranes. 2406
2407 ISOPROPYL CHLOROFORMATE 6.1 3/8 I 354 0 E0 P602 F-E, S-C CategoryD SW2 SGG1 SG5 SG8 SG36 SG49 Colourless flammable liquid. Flashpoint: 16°C c.c. Decomposed by water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2407
2409 ISOPROPYL PROPIONATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 21°C c.c. Immiscible with water. 2409
2410 1,2,3,6-TETRAHYDROPYRIDINE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 16°C c.c. Miscible with water. Harmful by inhalation. 2410
2411 BUTYRONITRILE 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE SW2 Colourless liquid. Flashpoint: 21°C c.c. Lower explosive limit: 1.6%. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2411
2412 TETRAHYDROTHIOPHENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid with a pleasant odour. Flashpoint: 13°C c.c. Immiscible with water. 2412
2413 TETRAPROPYL ORTHOTITANATE 3 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 38°C c.c. 2413
2414 THIOPHENE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB SW2 Colourless liquid with an unpleasant odour. Flashpoint: −9°C c.c. Explosive limits: 1.5% to 12.5%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2414
2416 TRIMETHYL BORATE 3 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D CategoryB Colourless liquid. Reacts with water, evolving flammable vapours. 2416
2417 CARBONYL FLUORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic and corrosive colourless gas with a pungent odour. Corrosive to glass and to most metals. Corrosive in the presence of water. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. 2417
2418 SULPHUR TETRAFLUORIDE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 SG35 Non-flammable, toxic and corrosive, colourless gas with a pungent odour. Reacts with water, moist air or acids to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (3.7). Highly irritating to skin, eyes and mucous membranes. 2418
2419 BROMOTRIFLUOROETHYLENE 2.1 0 E0 P200 F-D, S-U CategoryB SW2 Liquefied, flammable, colourless gas. Much heavier than air (5.6). Boiling point: −3°C. 2419
2420 HEXAFLUOROACETONE 2.3 8 0 E0 P200 F-C, S-U CategoryD SW2 Non-flammable, toxic and corrosive, colourless, hygroscopic gas with an unpleasant odour. Reacts vigorously with water, evolving heat. Corrosive to glass and to most metals. Fumes in moist air. Much heavier than air (5.7). Highly irritating to skin, eyes and mucous membranes. 2420
2421 NITROGEN TRIOXIDE 2.3 5.1/8 0 E0 P200 F-C, S-W CategoryD SW2 SG6 SG19 Liquefied, non-flammable, toxic and corrosive gas. At lower temperatures, present as a blue liquid. Strong oxidizing agent. Much heavier than air (2.6). Boiling point: 3.5°C. Highly irritating to skin, eyes and mucous membranes. 2421
2422 OCTAFLUOROBUT−2-ENE (REFRIGERANT GAS R 1318) 2.2 120 mL E1 P200 F-C, S-V CategoryA Liquefied, non-flammable, colourless gas. Much heavier than air (6.9). Boiling point: 1.2°C. 2422
2424 OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Liquefied, non-flammable, colourless gas. Much heavier than air (6.6). Boiling point: −36°C. 2424
2426 AMMONIUM NITRATE, LIQUID (hot concentrated solution) 5.1 252 942 0 E0 T7 TP1 TP16 TP17 F-H, S-Q CategoryD SGG2 SG42 SG45 SG47 SG48 SG51 SG56 SG58 SG59 SG61 Hot aqueous solution of not more than 93% ammonium nitrate with not more than 0.2% combustible material (including organic material calculated as carbon) and free from any other added matter, containing at least 7% water, while the maximum content of chloride ions should not exceed 0.02%. May cause fire and explosion in contact with combustible material (e.g. wood, straw, cotton, oil, sugar, etc.), acids, and other class 5.1 substances and burn fiercely. Maximum allowable transport temperature of the solution 140°C. This temperature should be indicated on the transport unit. The acidity (pH) of the cargo when diluted with ten parts of water to one part of cargo, by mass, should be between 5.0 and 7.0. The concentration and temperature of the solution at the time of loading, its percentage of combustible materials and of chlorides, and the contents of free acid should be certified. 2426
2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 5.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q CategoryB SGG4 SG38 SG49 SG62 Colourless liquid. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 2427
2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 5.1 III 223 5 L E1 P504 IBC02 T4 TP1 F-H, S-Q CategoryB SGG4 SG38 SG49 SG62 See entry above. 2427
2428 SODIUM CHLORATE, AQUEOUS SOLUTION 5.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q CategoryB SGG4 SG38 SG49 SG62 Colourless liquid. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 2428
2428 SODIUM CHLORATE, AQUEOUS SOLUTION 5.1 III 223 5 L E1 P504 IBC02 T4 TP1 F-H, S-Q CategoryB SGG4 SG38 SG49 SG62 See entry above. 2428
2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q CategoryB SGG4 SG38 SG49 SG62 Colourless liquid. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 2429
2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 III 223 5 L E1 P504 IBC02 T4 TP1 F-H, S-Q CategoryB SGG4 SG38 SG49 SG62 See entry above. 2429
2430 ALKYLPHENOLS, SOLID, N.O.S. (including C–C homologues) 8 I 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B CategoryB A wide range of colourless to pale straw-coloured solids with penetrating odours (sometimes camphor-like). Some have low melting points. Insoluble in water. Cause burns to skin, eyes and mucous membranes. 2430
2430 ALKYLPHENOLS, SOLID, N.O.S. (including C–C homologues) 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryB See entry above. 2430
2430 ALKYLPHENOLS, SOLID, N.O.S. (including C–C homologues) 8 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA See entry above. 2430
2431 ANISIDINES 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Reddish or yellowish oily liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2431
2432 ,-DIETHYLANILINE 6.1 III 279 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless to yellow-brown oily liquid. Combustible. Toxic if swallowed, by skin contact or by inhalation. 2432
2433 CHLORONITROTOLUENES, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SG6 SG8 SG10 SG12 Immiscible with water. Oxidizing substance which may explode or burn fiercely when in contact with organic materials. Toxic if swallowed, by skin contact or by inhalation. 2433
2434 DIBENZYLDICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritating to skin, eyes and mucous membranes. 2434
2435 ETHYLPHENYL-DICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2435
2436 THIOACETIC ACID 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless or yellow liquid with a pungent odour. Miscible with water. Harmful by inhalation. 2436
2437 METHYLPHENYL-DICHLOROSILANE 8 II 0 E0 P010 T10 TP2 TP7 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2437
2438 TRIMETHYLACETYL CHLORIDE 6.1 3/8 I 0 E0 P001 T14 TP2 TP13 F-E, S-C CategoryD SW1 SW2 SGG1 SG5 SG8 SG36 SG49 Flammable liquid. Flashpoint: 19°C c.c. Boiling point: 108°C. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2438
2439 SODIUM HYDROGENDIFLUORIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW1 SW2 H2 SGG1 SG35 SG36 SG49 White, crystalline powder. Soluble in water. Decomposed by heat or acids, evolving hydrogen fluoride, a toxic extremely irritating and corrosive gas. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. 2439
2440 STANNIC CHLORIDE PENTAHYDRATE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 White, deliquescent solid. Melting point: about 60°C. Soluble in water. In the presence of water, corrosive to most metals. Irritating to skin, eyes and mucous membranes. 2440
2441 TITANIUM TRICHLORIDE, PYROPHORIC or TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC 4.2 8 I 0 E0 P404 PP31 F-G, S-M CategoryD SW2 H1 SGG7 SG26 Finely divided, violet, crystalline solid. May ignite on exposure to air or moisture. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2441
2442 TRICHLOROACETYL CHLORIDE 8 II 0 E0 P001 T7 TP2 F-A, S-B CategoryD SW2 SGG1 SG36 SG49 Liquid with a pungent odour, which fumes in moist air. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, corrosive to most metals. Liquid and vapours cause burns to skin, eyes and mucous membranes. 2442
2443 VANADIUM OXYTRICHLORIDE 8 II 1 L E0 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Yellow liquid. Decomposition occurs on exposure to moist air, forming red fumes of vanadic acid and hydrogen chloride, a corrosive gas apparent as white fumes. Reacts with, or dissolves, many organic compounds. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2443
2444 VANADIUM TETRACHLORIDE 8 I 0 E0 P802 T10 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Reddish-brown liquid. Decomposes under the influence of light, evolving chlorine, a highly toxic and irritating gas. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Liquid and vapours cause burns to skin, eyes and mucous membranes. 2444
2446 NITROCRESOLS, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA Yellow crystals. Melting point: 32°C or above. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2446
2447 PHOSPHORUS, WHITE, MOLTEN 4.2 6.1 I 0 E0 T21 TP3 TP7 TP26 F-A, S-M CategoryD Molten liquid. Melting point: 44°C. Ignites spontaneously in air. Toxic if swallowed, by skin contact or by inhalation. Shipped molten above its melting point. 2447
2448 SULPHUR, MOLTEN 4.1 III 0 E0 IBC01 T1 TP3 F-A, S-H CategoryC SG17 Melting point: 119°C. Molten sulphur may contain hydrogen sulphide, which is highly poisonous in low concentrations. When involved in a fire, evolves toxic, very irritating and suffocating gas. Forms explosive and extremely sensitive mixtures with oxidizing substances. Shipped molten above its melting point. 2448
2451 NITROGEN TRIFLUORIDE 2.2 5.1 0 E0 P200 F-C, S-W CategoryD SW2 Non-flammable, non-toxic, colourless, odourless gas. Strong oxidizing agent; reacts violently with many substances, e.g. grease, oil, etc. Much heavier than air (2.4). May cause slight eye irritation. 2451
2452 ETHYLACETYLENE, STABILIZED 2.1 386 0 E0 P200 F-D, S-U CategoryB SW1 SW2 Liquefied, flammable, colourless gas with an odour similar to acetylene. Heavier than air (1.9). Boiling point: 8°C. Irritating to skin, eyes and mucous membranes. 2452
2453 ETHYL FLUORIDE (REFRIGERANT GAS R 161) 2.1 0 E0 P200 F-D, S-U CategoryE SW2 Liquefied, flammable, colourless gas. Explosive limits: 5% to 10%. Heavier than air (1.7). Boiling point: −37°C. 2453
2454 METHYL FLUORIDE (REFRIGERANT GAS R 41) 2.1 0 E0 P200 F-D, S-U CategoryE SW2 Flammable, colourless gas. Heavier than air (1.2). 2454
2455 METHYL NITRITE 2.2 900 Transport is prohibited. 2455
2456 2-CHLOROPROPENE 3 I 0 E3 P001 T11 TP2 F-E, S-D CategoryE SGG10 Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 2.5% to 12%. Boiling point: 23°C. Immiscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. 2456
2457 2,3-DIMETHYLBUTANE 3 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-D CategoryE Colourless liquid. Flashpoint: −29°C c.c. Explosive limits: 1.2% to 7%. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. 2457
2458 HEXADIENES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquids. 1,3-HEXADIENE: flashpoint −3°C c.c. 1,4-HEXADIENE: flashpoint −25°C c.c. 1,5-HEXADIENE: flashpoint −27°C c.c. 2,4-HEXADIENE: flashpoint −7°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2458
2459 2-METHYL−1-BUTENE 3 I 0 E3 P001 T11 TP2 F-E, S-D CategoryE Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2459
2460 2-METHYL−2-BUTENE 3 II 1 L E2 P001 IBC02 B8 T7 TP1 F-E, S-D CategoryE Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2460
2461 METHYLPENTADIENES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryE Colourless liquids. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2461
2463 ALUMINIUM HYDRIDE 4.3 I 0 E0 P403 PP31 F-G, S-O CategoryE H1 SG26 White to grey powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. 2463
2464 BERYLLIUM NITRATE 5.1 6.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q CategoryA White or light yellow deliquescent crystals, or fine dust. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. 2464
2465 DICHLOROISOCYANURIC ACID, DRY or DICHLOROISOCYANURIC ACID SALTS 5.1 II 135 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q CategoryA H1 White crystalline powder or granules; slightly hygroscopic. Partially soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2465
2466 POTASSIUM SUPEROXIDE 5.1 I 0 E0 P503 IBC06 B1 F-G, S-Q CategoryD H1 SGG16 SG16 SG26 SG35 SG59 Yellow flakes. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. 2466
2468 TRICHLOROISOCYANURIC ACID, DRY 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q CategoryA H1 Colourless powder or granules. Mixtures with combustible material are sensitive to friction and are liable to ignite. On contact with nitrogen compounds, fumes of nitrogen trichloride can be formed, which are very explosive. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2468
2469 ZINC BROMATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-H, S-Q CategoryA SGG3 SGG7 SG38 SG49 Colourless powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 2469
2470 PHENYLACETONITRILE, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SG35 Colourless to light brown liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2470
2471 OSMIUM TETROXIDE 6.1 I 0 E5 P002 PP30 PP31 IBC07 B1 T6 TP33 F-A, S-A CategoryB SW2 Pale yellow, crystalline, volatile solid with an irritating odour. Highly toxic if swallowed, by skin contact or by inhalation. 2471
2473 SODIUM ARSANILATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA White, crystalline powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2473
2474 THIOPHOSGENE 6.1 I 279 354 0 E0 P602 T20 TP2 TP13 F-A, S-A CategoryD SW2 SG35 Red fuming liquid with a foul phosgene-like odour. Decomposes slowly in water. Reacts with acids, evolving toxic and corrosive fumes. Highly toxic if swallowed, by skin contact or by inhalation. 2474
2475 VANADIUM TRICHLORIDE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SW2 SGG1 SG36 SG49 Pink, deliquescent crystals. Decomposes in water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Irritating to skin, eyes and mucous membranes. 2475
2477 METHYL ISOTHIOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 White crystals. Usually shipped as an oily liquid with a flashpoint below 60°C c.c. Melting point: 36°C (pure substance). Flashpoint: 32°C c.c. (pure substance). Insoluble in water. When involved in a fire, evolves toxic gases. Highly toxic if swallowed, by skin contact or by inhalation. 2477
2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 3 6.1 II 274 1 L E2 P001 PP31 IBC02 T11 TP2 TP13 TP27 F-E, S-D CategoryD SW2 Flammable toxic liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2478
2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 3 6.1 III 223 274 5 L E1 P001 PP31 IBC03 T7 TP1 TP13 TP28 F-E, S-D CategoryA See entry above. 2478
2480 METHYL ISOCYANATE 6.1 3 I 354 0 E0 P601 T22 TP2 TP13 F-E, S-D CategoryD SW2 SG35 Flammable liquid with a pungent odour. Flashpoint: −7°C c.c. (pure product). Boiling point: 38°C (pure product). Vapour heavier than air. Immiscible with water but reacts violently with it. In contact with water or acids, evolves highly toxic nitrous fumes. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2480
2481 ETHYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 SG35 Liquid with a pungent odour. Flashpoint: −18°C to 0°C c.c. Boiling point: 60°C. Immiscible with water but reacts violently with it. On contact with water or acids, or when heated above boiling point, evolves highly toxic nitrous fumes. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2481
2482 -PROPYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Flammable liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Flashpoint: −18°C to 23°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2482
2483 ISOPROPYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Liquid with a pungent odour. Flashpoint: −10°C to 0°C c.c. Immiscible with water but reacts violently with it, evolving gases. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2483
2484 -BUTYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Colourless liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Flashpoint: 11°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2484
2485 -BUTYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Colourless liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Flashpoint: 19°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2485
2486 ISOBUTYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2486
2487 PHENYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Colourless to yellowish liquid with a pungent odour. Flashpoint: 51°C c.c. Immiscible with water. Reacts with water, evolving carbon dioxide. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2487
2488 CYCLOHEXYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Yellowish liquid with an irritating odour. Flashpoint: 53°C c.c. Immiscible with water. Reacts with water, evolving carbon dioxide. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2488
2490 DICHLOROISOPROPYL ETHER 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryB Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2490
2491 ETHANOLAMINE or ETHANOLAMINE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG18 SG35 Colourless. Miscible with water. Corrosive to copper, copper compounds, copper alloys and rubber. Reacts violently with acids. Liquid and vapour cause burns to skin, eyes and mucous membranes. 2491
2493 HEXAMETHYLENEIMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SW2 Yellowish liquid with an ammoniacal odour. Flashpoint: 18°C c.c. Miscible with water. Harmful by inhalation. Absorbed through the skin. Causes burns to skin, eyes and mucous membranes. 2493
2495 IODINE PENTAFLUORIDE 5.1 6.1/8 I 0 E0 P200 F-A, S-Q CategoryD SW1 SW2 SGG1 SG6 SG16 SG19 SG35 SG36 SG49 Colourless, fuming liquid (density 3.75). Powerful oxidant; may cause fire in contact with organic material such as wood, cotton or straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely corrosive gas apparent as white fumes. In contact with acids or acid fumes, evolves highly toxic fumes of iodine, fluorine and their compounds. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2495
2496 PROPIONIC ANHYDRIDE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless, combustible liquid with a pungent odour. Reacts with water, forming propionic acid. Corrosive to skin, eyes and mucous membranes. 2496
2498 1,2,3,6-TETRAHYDRO-BENZALDEHYDE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 57°C o.c. Immiscible with water. 2498
2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Aqueous solution. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2501
2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA See entry above. 2501
2502 VALERYL CHLORIDE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryC SW2 SGG1 SG36 SG49 Liquid with a penetrating odour. Flashpoint: 23°C c.c. or above. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2502
2503 ZIRCONIUM TETRACHLORIDE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 White, lustrous crystals. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Irritating to mucous membranes. 2503
2504 TETRABROMOETHANE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SGG10 Colourless to yellowish liquid with a camphor-like odour. Toxic if swallowed, by skin contact or by inhalation. 2504
2505 AMMONIUM FLUORIDE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SGG2 SG35 Colourless crystals or powder with an ammonia-like odour. Readily soluble in water. Decomposes in contact with acids, evolving hydrogen fluoride, a corrosive gas. Toxic if swallowed, by skin contact or by dust inhalation. 2505
2506 AMMONIUM HYDROGEN SULPHATE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW2 SGG1 SGG2 SG36 SG49 White, rhombic crystals. Soluble in water. When involved in a fire, evolves extremely irritating and corrosive fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2506
2507 CHLOROPLATINIC ACID, SOLID 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 Red-brown crystals. Soluble in water. 2507
2508 MOLYBDENUM PENTACHLORIDE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Black or green-black crystals. Hygroscopic. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. Harmful if swallowed. Dust and vapour irritate skin, eyes and mucous membranes. 2508
2509 POTASSIUM HYDROGEN SULPHATE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless crystals. Soluble in water. When involved in a fire, evolves extremely irritating and corrosive fumes. In the presence of moisture, corrosive to most metals. Irritating to skin, eyes and mucous membranes. 2509
2511 2-CHLOROPROPIONIC ACID 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP2 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless, aqueous solution with a specific odour. Causes burns to skin, eyes and mucous membranes. 2511
2512 AMINOPHENOLS (-, -, -) 6.1 III 279 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA White or brownish (- and -) or reddish-yellow (-) crystals. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2512
2513 BROMOACETYL BROMIDE 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Clear liquid, colourless. Boiling point: 150°C. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Reacts violently with alkalis such as ammonia and hydrazine. Causes very severe burns to skin, eyes and mucous membranes. Vapour causes tears. 2513
2514 BROMOBENZENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid with a characteristic odour. Flashpoint: 51°C c.c. Explosive limits: 0.5% to 2.8%. Immiscible with water. 2514
2515 BROMOFORM 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SW1 SW2 H2 SGG10 Colourless liquid or crystals (melting point 9°C) with a chloroform-like odour. Toxic if swallowed, by skin contact or by inhalation. Narcotic effect. 2515
2516 CARBON TETRABROMIDE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SW1 Colourless crystals. Melting point: 48°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation of dust and vapour. 2516
2517 1-CHLORO−1,1-DIFLUORO-ETHANE (REFRIGERANT GAS R 142b) 2.1 0 E0 P200 T50 F-D, S-U CategoryB SW2 Flammable gas. Explosive limits: 8.5% to 14%. Much heavier than air (3.5). 2517
2518 1,5,9-CYCLODODECATRIENE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SW2 Colourless liquid. Toxic if swallowed, by skin contact or by inhalation. 2518
2520 CYCLOOCTADIENES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids. Immiscible with water. 1,5-CYCLOOCTADIENE: flashpoint 38°C c.c. Irritating to skin, eyes and mucous membranes. 2520
2521 DIKETENE, STABILIZED 6.1 3 I 354 386 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW1 SW2 SG20 SG21 Colourless flammable liquid with a pungent odour. Flashpoint: 44°C c.c. Immiscible with water, but hydrolyses slowly in contact with it. The presence of acids, bases or amines can initiate explosive polymerization. Highly toxic if swallowed, by skin contact or by inhalation. 2521
2522 2-DIMETHYLAMINOETHYL METHACRYLATE, STABILIZED 6.1 II 386 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryD SW2 Combustible liquid. Causes tears. Toxic if swallowed, by skin contact or by inhalation. 2522
2524 ETHYL ORTHOFORMATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Combustible liquid. Causes tears. Toxic if swallowed, by skin contact or by inhalation. 2524
2524 ETHYL ORTHOFORMATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid with an ethereal odour. Flashpoint: 30°C c.c. Immiscible with water. 2524
2525 ETHYL OXALATE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless, oily, aromatic liquid. Slowly decomposed by water. Toxic if swallowed, by skin contact or by dust inhalation. 2525
2526 FURFURYLAMINE 3 8 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-C CategoryA SW2 SG35 Pale yellow, oily liquid. Flashpoint: 37°C o.c. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2526
2527 ISOBUTYL ACRYLATE, STABILIZED 3 III 386 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryC SW1 Colourless liquid with a pungent odour. Flashpoint: 29°C o.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2527
2528 ISOBUTYL ISOBUTYRATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid with a fruity odour. Flashpoint: 37°C c.c. Explosive limits: 0.96% to 7.59%. Immiscible with water. 2528
2529 ISOBUTYRIC ACID 3 8 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-C CategoryA Colourless liquid with a pungent odour. Flashpoint: 55°C c.c. Explosive limits: 2% to 9.2%. Miscible with water. Causes burns to skin and eyes. Irritating to skin, eyes and mucous membranes. 2529
2531 METHACRYLIC ACID, STABILIZED 8 II 386 1 L E2 P001 IBC02 T7 TP2 TP18 TP30 F-A, S-B CategoryC SW1 SW2 SGG1 SG36 SG49 Colourless, combustible liquid with a specific odour. Miscible with water. Polymerizes readily above its melting point (15°C), thereby generating heat and possible risk of explosion; should therefore be properly stabilized. Cooling below melting point (15°C) followed by subsequent reheating can release uninhibited monomer that readily polymerizes. Decomposes when heated, evolving toxic gases. Causes burns to skin, eyes and mucous membranes. 2531
2533 METHYL TRICHLOROACETATE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2533
2534 METHYLCHLOROSILANE 2.3 2.1/8 0 E0 P200 F-D, S-U CategoryD SW2 SG4 SG9 Liquefied, flammable, toxic and corrosive colourless gas with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas. Heavier than air. Boiling point: 9°C. Highly irritating to skin, eyes and mucous membranes. 2534
2535 4-METHYLMORPHOLINE (-METHYLMORPHOLINE) 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C CategoryB SW2 Colourless liquid with an ammonia-like odour. Flashpoint: 13°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2535
2536 METHYLTETRAHYDROFURAN 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless, volatile liquid with an ether-like odour. Flashpoint: −11°C o.c. Immiscible with water. 2536
2538 NITRONAPHTHALENE 4.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-G CategoryA Yellow crystals. Insoluble in water. Harmful if swallowed. 2538
2541 TERPINOLENE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-E CategoryA Colourless to pale amber liquid with a lemon odour. Flashpoint: 37°C c.c. Immiscible with water. 2541
2542 TRIBUTYLAMINE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Colourless, combustible liquid with an amine odour. Immiscible with water. When involved in a fire, evolves toxic gases. Toxic if swallowed, by skin contact or by inhalation. 2542
2545 HAFNIUM POWDER, DRY 4.2 I 0 E0 P404 PP31 F-G, S-M CategoryD H1 SGG15 SG26 Black amorphous powder. Insoluble in water. Liable to ignite spontaneously in air. Forms explosive mixtures with oxidizing substances. 2545
2545 HAFNIUM POWDER, DRY 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-G, S-M CategoryD H1 SGG15 SG26 See entry above. 2545
2545 HAFNIUM POWDER, DRY 4.2 III 223 0 E1 P002 LP02 PP31 L4 IBC08 B4 T1 TP33 F-G, S-M CategoryD H1 SGG15 SG26 See entry above. 2545
2546 TITANIUM POWDER, DRY 4.2 I 0 E0 P404 PP31 F-G, S-M CategoryD H1 SGG7 SGG15 SG26 Grey powder. Liable to ignite spontaneously in air. Forms explosive mixtures with oxidizing substances. 2546
2546 TITANIUM POWDER, DRY 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-G, S-M CategoryD H1 SGG7 SGG15 SG26 See entry above. 2546
2546 TITANIUM POWDER, DRY 4.2 III 223 0 E1 P002 LP02 PP31 L4 IBC08 B4 T1 TP33 F-G, S-M CategoryD H1 SGG7 SGG15 SG26 See entry above. 2546
2547 SODIUM SUPEROXIDE 5.1 I 0 E0 P503 IBC06 B1 F-G, S-Q CategoryD H1 SGG16 SG16 SG26 SG35 SG59 Pale yellow coarse powder or granules. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. 2547
2548 CHLORINE PENTAFLUORIDE 2.3 5.1/8 0 E0 P200 F-C, S-W CategoryD SW2 SG6 SG19 Non-flammable, toxic and corrosive gas. Forms dense, white, corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, a toxic, irritating and corrosive gas apparent as white fumes. Corrosive to glass and to most metals. Powerful oxidizing agent which may cause violent fires with combustible materials. Much heavier than air (4.5). Highly irritating to skin, eyes and mucous membranes. 2548
2552 HEXAFLUOROACETONE HYDRATE, LIQUID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryB SW2 Toxic if swallowed, by skin contact or by inhalation. 2552
2554 METHYLALLYL CHLORIDE 3 II 1 L E2 P001 IBC02 T4 TP1 TP13 F-E, S-D CategoryE SGG10 Colourless to yellowish, volatile liquid with a penetrating odour. Flashpoint: −12°C c.c. Explosive limits: 2.3% to 9.3%. Immiscible with water. When involved in a fire, may evolve highly toxic phosgene gas. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2554
2555 NITROCELLULOSE WITH WATER (not less than 25% water, by mass) 4.1 II 28 394 0 E0 P406 PP31 F-B, S-J CategoryE SG7 SG30 Desensitized explosive. Nitrocellulose may be granular or in flakes, blocks or fibrous form. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. 2555
2556 NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass) 4.1 II 28 394 0 E0 P406 PP31 F-B, S-J CategoryD SW1 H2 SG7 SG30 Nitrocellulose may be granular or in flakes, blocks or fibrous form. In case of leakage, flammable vapours are evolved which, in closed compartments, may form explosive mixtures with air. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Highly explosive when dry. May form extremely sensitive compounds with heavy metals or their salts. 2556
2557 NITROCELLULOSE with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WITH or WITHOUT PIGMENT 4.1 II 241 394 0 E0 P406 PP31 F-B, S-J CategoryD SG7 SG30 Nitrocellulose may be in granular form or in flakes. This product may also contain added pigments. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Burns extremely rapidly with intense heat radiation. The formulation should be prepared so that it remains homogeneous and does not separate during transport. May form extremely sensitive compounds with heavy metals or their salts. 2557
2558 EPIBROMOHYDRIN 6.1 3 I 0 E0 P001 T14 TP2 TP13 F-E, S-D CategoryD SW2 Flammable liquid. Flashpoint: 56°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. 2558
2560 2-METHYLPENTAN−2-OL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 30°C c.c. Partially miscible with water. Irritating to skin, eyes and mucous membranes. 2560
2561 3-METHYL−1-BUTENE 3 I 0 E3 P001 T11 TP2 F-E, S-D CategoryE Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2561
2564 TRICHLOROACETIC ACID SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryB SGG1 SG36 SG49 Colourless, clear solution with a pungent odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2564
2564 TRICHLOROACETIC ACID SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryB SGG1 SG36 SG49 See entry above. 2564
2565 DICYCLOHEXYLAMINE 8 III 5 L E1 P001 LP01 IBC03 - T4 TP1 F-A, S-B CategoryA SG35 Clear, colourless, combustible liquid with a fishy odour which may taint other cargoes. Immiscible with water. Causes burns to skin, eyes and mucous membranes. 2565
2567 SODIUM PENTACHLOROPHENATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA White or light brown powder with a pungent odour. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2567
2570 CADMIUM COMPOUND 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryA Powder or crystals with various colours. May be soluble or insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2570
2570 CADMIUM COMPOUND 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA See entry above. 2570
2570 CADMIUM COMPOUND 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA See entry above. 2570
2571 ALKYLSULPHURIC ACIDS 8 II 1 L E2 P001 IBC02 T8 TP2 TP13 TP28 F-A, S-B CategoryC SW15 SGG1 SG36 SG49 Colourless oily liquids. React with water, evolving heat. Cause burns to skin, eyes and mucous membranes. Highly corrosive to metal. 2571
2572 PHENYLHYDRAZINE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW2 Pale yellow oily liquid. Melting point: 20°C. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2572
2573 THALLIUM CHLORATE 5.1 6.1 II 1 kg E2 P002 IBC06 B21 T3 TP33 F-H, S-Q CategoryA SGG4 SG38 SG49 Colourless crystals. Slightly soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. 2573
2574 TRICRESYL PHOSPHATE with more than 3% isomer 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Colourless liquid. A mixture of isomers. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2574
2576 PHOSPHORUS OXYBROMIDE, MOLTEN 8 II 0 E0 T7 TP3 TP13 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Melting point: 56°C. Reacts violently with water, evolving hydrogen bromide, a toxic and corrosive gas apparent as white fumes. Reacts violently with organic materials (such as wood, cotton, straw), causing fire. When involved in a fire, evolves highly toxic and corrosive gases. In the presence of moisture, highly corrosive to most metals. Vapours and liquid cause burns to skin, eyes and mucous membranes. Shipped molten above its melting point. 2576
2577 PHENYLACETYL CHLORIDE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryC SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves highly toxic fumes. Corrosive to most metals. Vapour irritates eyes and mucous membranes. Liquid is corrosive to skin, eyes and mucous membranes. 2577
2578 PHOSPHORUS TRIOXIDE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SW1 H2 SGG1 SG36 SG49 Colourless crystals or white deliquescent powder. Melting point: 23°C. Reacts with water, evolving heat and at normal temperatures phosphoric acid, but at higher temperatures phosphine, a highly toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2578
2579 PIPERAZINE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SW1 H2 SGG18 SG35 Colourless, deliquescent crystals, turning dark on exposure to light. Soluble in water. Decomposes when heated and when involved in a fire, evolving highly toxic nitrous fumes. The solution in water is a strong base and is highly corrosive. Reacts violently with acids. Irritating to skin, eyes and mucous membranes. 2579
2580 ALUMINIUM BROMIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless to yellowish liquid. Highly corrosive to most metals. Vapour highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membranes. 2580
2581 ALUMINIUM CHLORIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless to yellowish liquid. Highly corrosive to most metals. Vapour highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membranes. 2581
2582 FERRIC CHLORIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG1 SG36 SG49 Colourless to light brown liquid. Highly corrosive to most metals. 2582
2583 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 When involved in a fire, evolve highly toxic gases. Corrosive to most metals, especially in the presence of moisture. Cause burns to skin, eyes and mucous membranes. 2583
2584 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 8 II 1 L E2 P001 IBC02 B20 T8 TP2 TP13 F-A, S-B CategoryB SGG1 SG36 SG49 Liquids usually with a pungent odour. When involved in a fire, evolve highly toxic gases. Highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 2584
2585 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 Crystalline solids. When involved in a fire, evolve highly toxic gases. In the presence of moisture, corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 2585
2586 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryB SGG1 SG36 SG49 Liquids usually with a pungent odour. When involved in a fire, evolve highly toxic gases. Corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 2586
2587 BENZOQUINONE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA Yellow crystals with an irritating and penetrating odour resembling that of chlorine. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2587
2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 I 61 274 0 E5 P002 IBC99 T6 TP33 F-A, S-A CategoryA SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2588
2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SW2 See entry above. 2588
2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SW2 See entry above. 2588
2589 VINYL CHLOROACETATE 6.1 3 II 100 mL E4 P001 IBC02 T7 TP2 F-E, S-D CategoryA Flammable liquid. Flashpoint: 50°C c.c. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2589
2590 ASBESTOS, CHRYSOTILE 9 III 168 5 kg E1 P002 PP37 IBC08 B3 B21 T1 TP33 F-A, S-A CategoryA SW2 H4 SG29 Mineral fibres of varying length. Non-combustible. Inhalation of the dust of asbestos fibres is dangerous and therefore exposure should be avoided at all times. Always prevent the generation of asbestos dust. A safe level of airborne concentration of asbestos fibres may be obtained through effective packing. Cargo spaces or freight containers that have contained any type of raw asbestos should be carefully cleaned before discharging any remaining cargo, loading other cargo or carrying out repair or maintenance work. Whenever possible, cleaning of cargo spaces should be carried out whilst the ship is in a port where proper facilities and equipment, including proper respiratory apparatus and protective clothing, are available. Parts of the body that may have been exposed should be immediately and thoroughly washed. All waste material should be collected in impermeable and sealed bags for safe disposal ashore. If cleaning cannot be carried out at the discharge port, arrangements should be made in advance for cleaning to be carried out at the next port where necessary facilities are available. 2590
2591 XENON, REFRIGERATED LIQUID 2.2 120 mL E1 P203 T75 TP5 F-C, S-V CategoryD Liquefied, inert, colourless and odourless gas. Much heavier than air (4.5). 2591
2599 CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane (REFRIGERANT GAS R 503) 2.2 120 mL E1 P200 F-C, S-V CategoryA Non-flammable, colourless gas with a mild ethereal odour. Much heavier than air (3.2). 2599
2601 CYCLOBUTANE 2.1 0 E0 P200 F-D, S-U CategoryB SW2 Liquefied, flammable, colourless gas. Explosive limits: 1.8% to 10%. Heavier than air (1.9). Boiling point: 13°C. 2601
2602 DICHLORODIFLUORO-METHANE AND DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500) 2.2 120 mL E1 P200 T50 F-C, S-V CategoryA Non-flammable, colourless and odourless gas. Much heavier than air (3.7). 2602
2603 CYCLOHEPTATRIENE 3 6.1 II 1 L E2 P001 IBC02 T7 TP1 TP13 F-E, S-D CategoryE SW2 Colourless to dark yellow liquid with a characteristic odour. Flashpoint: 0°C to 4°C c.c. Immiscible with water. Reacts vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2603
2604 BORON TRIFLUORIDE DIETHYL ETHERATE 8 3 I 0 E0 P001 PP31 T10 TP2 F-E, S-C CategoryD SW2 SGG1 SG36 SG49 Colourless fuming flammable liquid. Flashpoint: 59°C c.c. The flashpoint will be lower when free ether is present. Reacts vigorously with oxidizing substances. Decomposes in contact with water, evolving toxic, corrosive and flammable vapours. Causes burns to skin, eyes and mucous membranes. Inhalation of small quantities of vapour can cause breathing difficulties. 2604
2605 METHOXYMETHYL ISOCYANATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Colourless liquid with a pungent odour. Flashpoint: 13°C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 2605
2606 METHYL ORTHOSILICATE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D CategoryD SW2 Colourless, flammable liquid with an ethereal odour. Immiscible with water. Flashpoint: −18°C to 19°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. May cause blindness. 2606
2607 ACROLEIN DIMER, STABILIZED 3 III 386 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryC SW1 SW2 Colourless liquid with a pungent odour. Flashpoint: 48°C o.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2607
2608 NITROPROPANES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids. Explosive limits: 2.2% to 11%. 1-NITROPROPANE: flashpoint approx. 33°C c.c. 2-NITROPROPANE: flashpoint approx. 28°C c.c. Partially miscible with water. Harmful by inhalation. 2608
2609 TRIALLYL BORATE 6.1 III 5 L E1 P001 LP01 IBC03 - F-A, S-A CategoryA H1 Liquid. Hydrolyses in contact with water, forming allyl alcohol. Toxic if swallowed, by skin contact or by inhalation. 2609
2610 TRIALLYLAMINE 3 8 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-C CategoryA SW2 SG35 Colourless liquid with a fishy odour. Flashpoint: 39°C o.c. Corrosive when in contact with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2610
2611 PROPYLENE CHLOROHYDRIN 6.1 3 II 100 mL E4 P001 IBC02 T7 TP2 TP13 F-E, S-D CategoryA SW1 SW2 H2 Colourless flammable liquid with a mild odour. Flashpoint: 51°C c.c. Miscible with water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by inhalation. 2611
2612 METHYL PROPYL ETHER 3 II 1 L E2 P001 IBC02 B8 T7 TP2 F-E, S-D CategoryE SW2 Colourless, volatile liquid with an ethereal odour. Flashpoint: below −18°C c.c. Lower explosive limit: 2%. Boiling point: 39°C. Partially miscible with water. Narcotic. Irritating to skin, eyes and mucous membranes. 2612
2614 METHALLYL ALCOHOL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid with a pungent odour. Flashpoint: 34°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. 2614
2615 ETHYL PROPYL ETHER 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryE Colourless, volatile liquids. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 9.0%. Miscible with water. Irritating to skin, eyes and mucous membranes. 2615
2616 TRIISOPROPYL BORATE 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquid. Flashpoint: 17°C to 60°C c.c. Reacts with water, evolving flammable vapours. 2616
2616 TRIISOPROPYL BORATE 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA See entry above. 2616
2617 METHYLCYCLOHEXANOLS, flammable 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless, viscous liquid with a menthol-like odour. Flashpoint: 58°C c.c. Partially miscible with water. 2617
2618 VINYLTOLUENES, STABILIZED 3 III 386 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryC SW1 Colourless liquids. Flashpoint: 54°C to 60°C c.c. Explosive limits: 0.9% to 6.1%. Partially miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2618
2619 BENZYLDIMETHYLAMINE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SW1 SW2 SG35 Colourless, flammable liquid with an aromatic odour. Flashpoint: 58°C c.c. Immiscible with water. Harmful if swallowed, by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes. 2619
2620 AMYL BUTYRATES 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquids. Flashpoint: 52°C to 58°C c.c. Partially miscible with water. 2620
2621 ACETYL METHYL CARBINOL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Yellow liquid with a pleasant odour. Flashpoint: 44°C to 52°C c.c. Miscible with water. Reacts vigorously with oxidizing substances. Irritating to skin, eyes and mucous membranes. 2621
2622 GLYCIDALDEHYDE 3 6.1 II 1 L E2 P001 IBC02 B8 T7 TP1 F-E, S-D CategoryA SW2 Colourless liquid with a pungent odour. Flashpoint: 31°C o.c. Miscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. 2622
2623 FIRELIGHTERS, SOLID with flammable liquid 4.1 III 5 kg E1 P002 LP02 PP15 F-A, S-I CategoryA SG35 A porous solid, e.g. cellular urea–formaldehyde resin, compacted wood shavings, etc., impregnated with flammable liquid, usually white spirit or kerosene, and designed to burn in a controlled manner. When heated, evolves flammable vapours. 2623
2624 MAGNESIUM SILICIDE 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-O CategoryB SW5 H1 SG26 White powder or crystals. Reacts with water or steam, evolving hydrogen, a flammable gas. In contact with acids, evolves silane, a spontaneously flammable gas. 2624
2626 CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid 5.1 II 900 1 L E0 P504 PP31 IBC02 F-A, S-Q CategoryD SGG1 SG36 SG38 SG49 Colourless liquid. May decompose, evolving chlorine and oxygen with toxic, corrosive and oxidizing effects. May form explosive mixtures with ammonium compounds, combustible material or powdered metals. Corrosive to most metals. Transport of CHLORIC ACID, AQUEOUS SOLUTION with more than 10% chloric acid is prohibited. 2626
2627 NITRITES, INORGANIC, N.O.S. 5.1 II 274 900 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q CategoryA SGG12 SG38 SG49 SG62 Solids. Solid mixtures with combustible material are readily ignited and may burn fiercely. Solid mixtures with ammonium compounds or cyanides may explode. If heated, may decompose, giving off toxic nitrous fumes. Harmful if swallowed. Transport of AMMONIUM NITRITES and mixtures of an inorganic nitrite with an ammonium salt is prohibited. 2627
2628 POTASSIUM FLUOROACETATE 6.1 I 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryE Solid. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 2628
2629 SODIUM FLUOROACETATE 6.1 I 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryE White powder. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 2629
2630 SELENATES or SELENITES 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryE A wide range of toxic solids. Generally soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 2630
2642 FLUOROACETIC ACID 6.1 I 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A CategoryE SGG1 SG36 SG49 Colourless crystals. Melting point: 33°C. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. 2642
2643 METHYL BROMOACETATE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryD SW2 Colourless to straw-coloured liquid. Slightly miscible with water. Causes tears. Toxic if swallowed, by skin contact or by inhalation. 2643
2644 METHYL IODIDE 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A CategoryD SW1 SW2 H2 SGG10 Colourless liquid. Boiling point: 42°C to 43°C. Slightly miscible with water. When heated, evolves toxic fumes. Highly toxic if swallowed, by skin contact or by inhalation. Has strong narcotic effects. 2644
2645 PHENACYL BROMIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryB SW2 White crystals changing to a greenish colour under the influence of light. Melting point: 50°C. Insoluble in water. Causes tears. Toxic if swallowed, by skin contact or by inhalation. 2645
2646 HEXACHLOROCYCLO-PENTADIENE 6.1 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A CategoryD SW2 SGG10 Pale yellow liquid with a pungent odour. Immiscible with water. Causes tears. Highly toxic if swallowed, by skin contact or by inhalation. 2646
2647 MALONONITRILE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA SW1 H2 Colourless crystals. Melting point: 32°C. Soluble in water. When heated, evolves highly toxic cyanogen fumes. Toxic if swallowed, by skin contact or by dust inhalation. 2647
2648 1,2-DIBROMOBUTAN−3-ONE 6.1 II 100 mL E4 P001 IBC02 F-A, S-A CategoryB SW2 Liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes tears. 2648
2649 1,3-DICHLOROACETONE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryB SW1 SW2 H2 Crystals. Melting point: 45°C. Soluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. Causes tears. 2649
2650 1,1-DICHLORO−1-NITRO-ETHANE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW1 SW2 H2 SG17 Liquid. Immiscible with water. May react vigorously with oxidizing substances. Decomposes when heated, evolving highly toxic fumes (oxides of nitrogen). Toxic if swallowed, by skin contact or by inhalation. 2650
2651 4,4’-DIAMINODIPHENYL-METHANE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA Tan-coloured flakes or lumps. Slightly soluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. 2651
2653 BENZYL IODIDE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryB SW1 SW2 H2 Colourless crystals. Melting point: 24°C. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. Causes tears. 2653
2655 POTASSIUM FLUOROSILICATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SG35 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 2655
2656 QUINOLINE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SW1 H2 Colourless liquid with a pungent odour. Immiscible with water. When heated, evolves highly toxic fumes (of oxides of nitrogen). Toxic if swallowed, by skin contact or by inhalation. 2656
2657 SELENIUM DISULPHIDE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA Bright red-yellow crystals with a faint odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2657
2659 SODIUM CHLOROACETATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2659
2660 NITROTOLUIDINES (MONO) 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA Yellow to orange-red crystalline solids. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2660
2661 HEXACHLOROACETONE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryB SW1 SW2 H2 Colourless to yellowish liquid. Slightly miscible with water. When heated, evolves extremely toxic fumes (phosgene). Causes tears. Toxic if swallowed, by skin contact or by inhalation. 2661
2664 DIBROMOMETHANE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SGG10 Clear, colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2664
2667 BUTYLTOLUENES 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2667
2668 CHLOROACETONITRILE 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-A CategoryD SW1 SW2 H2 SG35 Colourless flammable liquid with a pungent odour. Flashpoint: 56°C c.c. Immiscible with water. Decomposes when heated, evolving highly toxic fumes of cyanides. Reacts with steam and acids, evolving toxic and flammable vapours. Highly toxic if swallowed, by skin contact or by inhalation. 2668
2669 CHLOROCRESOLS SOLUTION 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA SW1 H2 Solutions with a phenol-like odour. Slightly miscible with water. Decompose when heated, evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 2669
2669 CHLOROCRESOLS SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T7 TP2 F-A, S-A CategoryA SW1 H2 See entry above. 2669
2670 CYANURIC CHLORIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SW1 SW2 H2 SGG1 SG36 SG49 Colourless crystals with a pungent odour. Reacts with water, forming toxic and corrosive acids. Decomposes when heated, evolving toxic and corrosive gases. Causes burns to skin, eyes and mucous membranes. 2670
2671 AMINOPYRIDINES (, , ) 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryB SW1 SW2 H2 SGG18 SG35 White powder or crystals. Melting points: 58°C to 64°C. Soluble in water. Reacts violently with acids. Toxic if swallowed, by skin contact or by dust inhalation. 2671
2672 AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15°C in water, with more than 10% but not more than 35% ammonia 8 III 5 L E1 P001 LP01 IBC03 B11 T7 TP2 F-A, S-B CategoryA SW2 SW5 SGG18 SG35 Colourless liquid with a pungent odour. Corrosive to copper, nickel, zinc and tin and their alloys such as brass. Not significantly corrosive to iron and steel. Reacts violently with acids. Liquid and vapour cause burns to skin, eyes and mucous membranes. 2672
2673 2-AMINO−4-CHLOROPHENOL 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A CategoryA Light brown crystals. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2673
2674 SODIUM FLUOROSILICATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SG35 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 2674
2676 STIBINE 2.3 2.1 0 E0 P200 F-D, S-U CategoryD SW2 Flammable, toxic, colourless gas with a foul odour. Decomposes violently in the presence of water. Much heavier than air (4.3). 2676
2677 RUBIDIUM HYDROXIDE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG18 SG22 SG35 Liquid. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 2677
2677 RUBIDIUM HYDROXIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG18 SG22 SG35 See entry above. 2677
2678 RUBIDIUM HYDROXIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG22 SG35 Greyish-white solid, very hygroscopic. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 2678
2679 LITHIUM HYDROXIDE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG18 SG22 SG35 Colourless liquid. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 2679
2679 LITHIUM HYDROXIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP2 F-A, S-B CategoryA SGG18 SG22 SG35 See entry above. 2679
2680 LITHIUM HYDROXIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG35 Colourless crystals. Soluble in water. Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. 2680
2681 CAESIUM HYDROXIDE SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryA SGG18 SG22 SG35 Colourless liquid. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to glass, aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 2681
2681 CAESIUM HYDROXIDE SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B CategoryA SGG18 SG22 SG35 See entry above. 2681
2682 CAESIUM HYDROXIDE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryA SGG18 SG22 SG35 Colourless or yellowish hygroscopic crystals. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to glass, aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. 2682
2683 AMMONIUM SULPHIDE SOLUTION 8 3/6.1 II 1 L E2 P001 IBC01 T7 TP2 TP13 F-E, S-C CategoryB SW1 H2 SGG2 SGG18 SG35 SG68 Yellow liquid with a foul odour (of rotten eggs). When heated, evolves toxic and flammable vapours. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes. 2683
2684 3-DIETHYLAMINO-PROPYLAMINE 3 8 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-C CategoryA SG35 Colourless liquid with a fishy odour. Flashpoint: 59°C o.c. Miscible with water. Irritating to skin, eyes and mucous membranes. 2684
2685 ,-DIETHYLETHYLENE-DIAMINE 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SG35 Colourless, flammable liquid with a fishy odour. Flashpoint: 46°C o.c. Miscible with water. Harmful by skin contact. Irritating to eyes and mucous membranes. 2685
2686 2-DIETHYLAMINOETHANOL 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C CategoryA SG35 Colourless liquid. Miscible with water. Reacts violently with oxidizing substances. Explosive limits: 1.8% to 28%. Flashpoint: 46°C to 60°C c.c. Causes burns to skin, eyes and mucous membranes. 2686
2687 DICYCLOHEXYLAMMONIUM NITRITE 4.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-G CategoryA SGG2 White powder. Insoluble in water. Harmful if swallowed. 2687
2688 1-BROMO−3-CHLOROPROPANE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA SGG10 Colourless liquid. Immiscible with water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by inhalation. 2688
2689 GLYCEROL MONOCHLOROHYDRIN 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2689
2690 ,-BUTYLIMIDAZOLE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A CategoryA Colourless to amber mobile liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2690
2691 PHOSPHORUS PENTABROMIDE 8 II 1 kg E0 P002 IBC08 B4 B21 T3 TP33 F-A, S-B CategoryB SW1 SW2 H2 SGG1 SG36 SG37 SG49 Yellow hygroscopic crystals, evolving fumes in the air which are corrosive and heavier than air. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. Reacts violently with ammonia, bases and many other substances and may cause fire and explosion. Decomposes when heated, evolving corrosive and toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2691
2692 BORON TRIBROMIDE 8 I 0 E0 P602 T20 TP2 TP13 F-A, S-B CategoryC SW1 H2 SGG1 SG36 SG49 Colourless fuming liquid. Reacts violently with water, evolving toxic and corrosive fumes. Decomposes when heated, evolving toxic fumes. In the presence of moisture, highly corrosive to most metals. Liquid and vapour cause severe burns to skin, eyes and mucous membranes. 2692
2693 BISULPHITES, AQUEOUS SOLUTION, N.O.S. 8 III 274 5 L E1 P001 LP01 IBC03 - T7 TP1 TP28 F-A, S-B CategoryA SW2 SG35 Liquid with a pungent odour. Reacts with acids, evolving sulphur dioxide, a toxic gas. Causes burns to skin, eyes and mucous membranes. 2693
2698 TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% maleic anhydride 8 III 29 169 939 973 5 kg E1 P002 LP02 PP14 IBC08 B3 T1 TP33 F-A, S-B CategoryA SGG1 SG36 SG49 White crystalline powders. React with water, evolving heat and forming tetrahydrophthalic acid. Cause burns to skin, eyes and mucous membranes. When heated, evolve acrid fumes which are irritating to skin, eyes and mucous membranes. 2698
2699 TRIFLUOROACETIC ACID 8 I 0 E0 P001 T10 TP2 F-A, S-B CategoryB SW1 SW2 H2 SGG1 SG36 SG49 Colourless, fuming, hygroscopic liquid with a pungent odour. Miscible with water. When heated to decomposition or in contact with acids, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapours are highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membranes. 2699
2705 1-PENTOL 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B CategoryB SG20 SG21 Colourless liquid with a perceptible odour. May react in contact with acids and alkalis. Causes burns to skin, eyes and mucous membranes. 2705
2707 DIMETHYLDIOXANES 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D CategoryB Colourless liquids with a pungent odour. Partially miscible with water. React vigorously with oxidizing substances. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2707
2707 DIMETHYLDIOXANES 3 III 223 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA See entry above. 2707
2709 BUTYLBENZENES 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-D CategoryA Colourless liquids with an unpleasant odour. Flashpoint: 34°C to 60°C c.c. Explosive limits: 0.7% to 6.9%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2709
2710 DIPROPYL KETONE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D CategoryA Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. 2710
2713 ACRIDINE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA Small colourless to yellowish crystals or needles. Sublimes at 100°C. Practically insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 2713
2714 ZINC RESINATE 4.1 III 5 kg E1 P002 IBC06 T1 TP33 F-A, S-I CategoryA SGG7 Powder or clear amber lumps. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. 2714
2715 ALUMINIUM RESINATE 4.1 III 5 kg E1 P002 IBC06 T1 TP33 F-A, S-I CategoryA Cream to brown coloured mass. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. 2715
2716 1,4-BUTYNEDIOL 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA SG35 SG36 SG55 White crystals. Melting point: 58°C. Soluble in water. Forms explosive mixtures with mercury salts, acids, alkaline compounds and halides. Toxic if swallowed, by skin contact or by inhalation. 2716
2717 CAMPHOR, synthetic 4.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-I CategoryA Colourless or white crystals, granules or easily broken masses with a penetrating, pungent and aromatic odour. Slightly soluble in water. When heated, evolves flammable and explosive vapours. Harmful if swallowed. 2717
2719 BARIUM BROMATE 5.1 6.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q CategoryA SGG3 SG38 SG49 White crystals or powder. Slightly soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. 2719
2720 CHROMIUM NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q CategoryA Purple crystals. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. 2720
2721 COPPER CHLORATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q CategoryA SGG4 SG38 SG49 Blue-green deliquescent crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. 2721
2722 LITHIUM NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q CategoryA Colourless deliquescent crystals. Soluble in water. Mixtures with combustible material are readily ignited and burn fiercely. Harmful if swallowed. 2722
2723 MAGNESIUM CHLORATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q CategoryA SGG4 SG38 SG49 White deliquescent crystals or powder. Soluble in water. Melting point: 35°C. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. The cargoes should be protected from moisture prior to and after loading. If weather is inclement, hatches should be closed. 2723
2724 MANGANESE NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q CategoryA Pale pink deliquescent crystals. Soluble in water. Melting point between 26°C and 35°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. 2724
2725 NICKEL NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q CategoryA Green deliquescent crystals. Soluble in water. Melting point: 55°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. 2725
2726 NICKEL NITRITE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q CategoryA SGG12 SG38 SG49 Reddish-yellow crystals. Decomposes if heated, giving off toxic nitrous fumes. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. 2726
2727 THALLIUM NITRATE 6.1 5.1 II 500 g E4 P002 IBC06 B21 T3 TP33 F-A, S-Q CategoryA Colourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. 2727
2728 ZIRCONIUM NITRATE 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q CategoryA White crystals, flakes or powder. Soluble in water. Solutions in water are slightly corrosive. Harmful if swallowed. 2728
2729 HEXACHLOROBENZENE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A CategoryA White needle-like crystals. Insoluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. 2729
2730 NITROANISOLES, LIQUID 6.1 III 279 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Light reddish or amber liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2730
2732 NITROBROMOBENZENES, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A CategoryA Colourless to pale yellow liquids. Melting point of 1-BROMO−3-NITROBENZENE: 17°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2732
2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 3 8 I 274 0 E0 P001 T14 TP1 TP27 F-E, S-C Category D SW2 SGG18 SG35 Colourless to yellowish liquids with an unpleasant odour. Some are very volatile. Miscible with water. Corrosive to most metals, especially to copper and its alloys. When involved in a fire, evolve toxic gases. React violently with acids. Harmful by inhalation. Cause burns to skin, eyes and mucous membranes. 2733
2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 3 8 II 274 1 L E2 P001 IBC02 T11 TP1 TP27 F-E, S-C Category B SW2 SGG18 SG35 See entry above. 2733
2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 3 8 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-E, S-C Category A SW2 SGG18 SG35 See entry above. 2733
2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 8 3 I 274 0 E0 P001 T14 TP2 TP7 F-E, S-C Category A SGG18 SG35 Colourless to yellowish flammable liquids or solutions with a pungent odour. Miscible with water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. React violently with acids. Cause burns to skin, eyes and mucous membranes. 2734
2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 8 3 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-E, S-C Category A SGG18 SG35 See entry above. 2734
2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 8 I 274 0 E0 P001 T14 TP2 TP7 F-A, S-B Category A SGG18 SG35 Colourless to yellowish liquids or solutions with a pungent odour. Miscible with or soluble in water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. React violently with acids. Cause burns to skin, eyes and mucous membranes. 2735
2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP1 TP27 F-A, S-B Category A SGG18 SG35 See entry above. 2735
2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B Category A SGG18 SG35 See entry above. 2735
2738 -BUTYLANILINE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SG17 Amber liquid with a perceptible odour. Immiscible with water. May react vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2738
2739 BUTYRIC ANHYDRIDE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SGG1 SG36 SG49 Colourless liquid. Decomposes in water to form butyric acid. 2739
2740 -PROPYL CHLOROFORMATE 6.1 3/8 I 0 E0 P602 T20 TP2 TP13 F-E, S-C Category B SW2 SGG1 SG5 SG8 SG36 SG49 Colourless flammable liquid. Flashpoint: 28°C c.c. Decomposed by water, generating propyl alcohol. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2740
2741 BARIUM HYPOCHLORITE with more than 22% available chlorine 5.1 6.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category B SGG8 SG35 SG38 SG49 SG53 SG60 White powder with pungent odour. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. Dust irritates mucous membranes. Contact with eyes will cause serious injury to the cornea (blindness) if not treated immediately by using copious amounts of water followed by medical attention. 2741
2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 6.1 3/8 II 274 100 mL E4 P001 IBC01 F-E, S-C Category A SW1 SW2 H1 H2 SGG1 SG5 SG8 SG36 SG49 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: cyclohexyl chloroformate: 53°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2742
2743 -BUTYL CHLOROFORMATE 6.1 3/8 II 100 mL E0 P001 T20 TP2 TP13 F-E, S-C Category A SW1 SW2 H1 H2 SGG1 SG5 SG8 SG36 SG49 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: 32°C c.c. to 39°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2743
2744 CYCLOBUTYL CHLOROFORMATE 6.1 3/8 II 100 mL E4 P001 IBC01 T7 TP2 TP13 F-E, S-C Category A SW1 SW2 H1 H2 SGG1 SG5 SG8 SG36 SG49 A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: 38°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2744
2745 CHLOROMETHYL CHLOROFORMATE 6.1 8 II 100 mL E4 P001 IBC02 T7 TP2 TP13 F-A, S-B Category A SW1 SW2 H1 H2 SGG1 SG36 SG49 A wide range of colourless to yellowish liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2745
2746 PHENYL CHLOROFORMATE 6.1 8 II 100 mL E4 P001 IBC02 T7 TP2 TP13 F-A, S-B Category A SW1 SW2 H1 H2 SGG1 SG36 SG49 A wide range of colourless to yellowish liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2746
2747 -BUTYLCYCLOHEXYL CHLOROFORMATE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SW1 H1 H2 Colourless to yellowish liquid. Reacts with water or decomposes if heated, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. 2747
2748 2-ETHYLHEXYL CHLOROFORMATE 6.1 8 II 100 mL E4 P001 IBC02 T7 TP2 TP13 F-A, S-B Category A SW1 SW2 H1 H2 SGG1 SG36 SG49 A wide range of colourless to yellowish liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 2748
2749 TETRAMETHYLSILANE 3 I 0 E0 P001 T14 TP2 F-E, S-D Category D Colourless, volatile liquid. Flashpoint: below −18°C c.c. Boiling point: 27°C. Immiscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. 2749
2750 1,3-DICHLOROPROPANOL−2 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW1 SW2 H2 Colourless, slightly viscous liquid with a chloroform-like odour. Immiscible with water. Decomposes when heated, evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 2750
2751 DIETHYLTHIOPHOSPHORYL CHLORIDE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category D SW1 SW2 H2 SGG1 SG36 SG49 Colourless liquid with a perceptible odour. Reacts slowly with water, forming hydrochloric acid. When involved in a fire, evolves toxic gases (hydrogen chloride and sulphur dioxide). Vapour highly irritating to eyes and mucous membranes. Liquid causes burns to skin, eyes and mucous membranes. 2751
2752 1,2-EPOXY−3-ETHOXYPROPANE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Immiscible with water. Flashpoint: 47°C c.c. Irritating to skin, eyes and mucous membranes. 2752
2753 -ETHYLBENZYLTOLUIDINES, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T7 TP1 F-A, S-A Category A Liquids with a strong odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2753
2754 -ETHYLTOLUIDINES 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Colourless to light amber liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2754
2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2757
2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2757
2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2757
2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2758
2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2758
2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2759
2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2759
2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2759
2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2760
2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2760
2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2761
2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2761
2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2761
2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2762
2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2762
2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2763
2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2763
2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 IBC08 B3 T3 TP33 F-A, S-A Category A SW2 See entry above. 2763
2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2764
2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2764
2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2771
2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2771
2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2771
2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2772
2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2772
2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2775
2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2775
2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2775
2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2776
2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2776
2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 SGG7 SGG11 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2777
2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 SGG7 SGG11 See entry above. 2777
2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 SGG7 SGG11 See entry above. 2777
2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 SGG7 SGG11 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2778
2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 SGG7 SGG11 See entry above. 2778
2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2779
2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2779
2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2779
2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2780
2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2780
2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2781
2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2781
2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2781
2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2782
2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2782
2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2783
2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2783
2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2783
2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2784
2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2784
2785 4-THIAPENTANAL 6.1 III 5 L E1 P001 LP01 PP31 IBC03 T4 TP1 F-A, S-A Category D SW1 SG20 SG21 Colourless liquid with an extremely foul and persistent odour. Miscible with water. Decomposes rapidly in contact with acids and bases. Toxic if swallowed, by skin contact or by inhalation. 2785
2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 2786
2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 2786
2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 2786
2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2787
2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2787
2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 I 43 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category A SW2 A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 2788
2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 II 43 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category A SW2 See entry above. 2788
2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 III 43 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 2788
2789 ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C Category A SGG1 SG36 SG49 Colourless flammable liquid with a pungent odour. When pure, crystallizes below 16°C. Flashpoint: 40°C c.c. (pure product), 60°C c.c. (80% solution). Explosive limits: 4% to 17%. Miscible with water. Corrosive to lead and most other metals. Corrosive to skin, eyes and mucous membranes. 2789
2790 ACETIC ACID SOLUTION, not less than 50% but not more than 80% acid, by mass 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category A SGG1 SG36 SG49 Colourless liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Corrosive to skin, eyes and mucous membranes. 2790
2790 ACETIC ACID SOLUTION, more than 10% and less than 50% acid, by mass 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SGG1 SG36 SG49 See entry above. 2790
2793 FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self-heating 4.2 III 223 931 0 E1 P003 LP02 PP20 L3 IBC08 B4 B6 BK2 F-G, S-J Category A H1 SG26 These cargoes are liable to self-heating and to ignite spontaneously, particularly when in a finely divided form, wet or contaminated with such materials as unsaturated cutting oil, oily rags and other combustible matter. Self-heating or inadequate ventilation may cause dangerous depletion of oxygen in the stowage spaces. Excessive amounts of cast iron borings or organic materials may encourage heating. The swarf should be protected from moisture prior to and after loading. If, during loading, the weather is inclement, hatches should be closed or otherwise protected to keep the material dry. 2793
2794 BATTERIES, WET, FILLED WITH ACID, electric storage 8 295 1 L E0 P801 F-A, S-B Category A SW16 SGG1 SG36 SG49 Metal plates immersed in acid electrolyte in a glass, hard rubber or plastics receptacle. When electrically charged, may cause fire through short-circuiting of terminals. Acid electrolyte is corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Used batteries being transported for disposal or reclamation should be carefully checked prior to shipment to ensure the integrity of each battery and its suitability for transport. 2794
2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage 8 295 401 1 L E0 P801 F-A, S-B Category A SW16 SGG18 SG35 Metal plates immersed in alkaline electrolyte in a glass, hard rubber or plastics receptacle. When electrically charged, may cause fire through short-circuiting of terminals. Alkaline electrolyte is corrosive to aluminium, zinc and tin. Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. Used batteries being transported for disposal or reclamation should be carefully checked prior to shipment to ensure the integrity of each battery and its suitability for transport. 2795
2796 SULPHURIC ACID with not more than 51% acid or BATTERY FLUID, ACID 8 II 1 L E2 P001 IBC02 B20 T8 TP2 F-A, S-B Category B SGG1 SG36 SG49 Colourless liquid, mixture not exceeding 1.405 relative density. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2796
2797 BATTERY FLUID, ALKALI 8 II 1 L E2 P001 IBC02 T7 TP2 TP28 F-A, S-B Category A SGG18 SG22 SG35 Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. 2797
2798 PHENYLPHOSPHORUS DICHLORIDE 8 II 1 L E0 P001 IBC02 T7 TP2 F-A, S-B Category B SW2 SGG1 SG36 SG49 Colourless liquid. Causes burns to skin, eyes and mucous membranes. 2798
2799 PHENYLPHOSPHORUS THIODICHLORIDE 8 II 1 L E0 P001 IBC02 T7 TP2 F-A, S-B Category B SW2 SGG1 SG36 SG49 Colourless liquid which fumes slightly in air. Reacts with water or steam, evolving toxic and flammable vapours. Causes burns to skin, eyes and mucous membranes. 2799
2800 BATTERIES, WET, NON-SPILLABLE, electric storage 8 238 1 L E0 P003 PP16 F-A, S-B Category A Metal plates immersed in gelled alkaline or acid electrolyte in a glass, hard rubber or plastics receptacle of a non-spillable type. When electrically charged, may cause fire through short-circuiting of terminals. Cause burns to skin, eyes and mucous membranes. 2800
2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 8 I 274 0 E0 P001 T14 TP2 TP7 F-A, S-B Category A A wide range of corrosive liquids. Cause burns to skin, eyes and mucous membranes. 2801
2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B Category A See entry above. 2801
2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B Category A See entry above. 2801
2802 COPPER CHLORIDE 8 III 500 g E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG1 SG36 SG49 White to yellow-brown crystals or powder. Partially to fully soluble in water. Corrosive to steel. Causes burns to skin, eyes and mucous membranes. 2802
2803 GALLIUM 8 III 365 5 kg E0 P800 PP41 T1 TP33 F-A, S-B Category B SW1 Silvery-white metallic element that melts at 29°C, becoming a bright, shiny liquid. Insoluble in water. Highly corrosive to aluminium. Harmful if swallowed, by skin contact or by inhalation. Special care should be taken if a leakage occurs when carried in aluminium freight containers. Carriage should be prohibited in hovercraft and other ships constructed from aluminium. 2803
2805 LITHIUM HYDRIDE, FUSED SOLID 4.3 II 500 g E2 P410 PP31 PP40 IBC04 T3 TP33 F-G, S-N Category E H1 SG26 SG35 White, crystalline mass. Reacts with water, moisture or acids, evolving hydrogen which may be ignited by the heat of the reaction. 2805
2806 LITHIUM NITRIDE 4.3 I 0 E0 P403 PP31 IBC04 B1 F-A, S-O Category E Brownish-red crystals or fine, free-flowing powder. Reacts slowly with water to form lithium hydroxide and ammonia. 2806
2807 MAGNETIZED MATERIAL 9 960 Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. 2807
2809 MERCURY 8 6.1 III 365 5 kg E0 P800 F-A, S-B Category B SW2 SGG7 SGG11 SG24 A silvery metallic element occurring in the liquid state at normal temperatures. Relative density: 13.546. Melting point: −39°C . Highly corrosive to aluminium. Toxic if swallowed, by skin contact or by inhalation. Special care should be taken if a leakage occurs during transport, especially when carried in breakable packages and in aluminium freight containers. Carriage should be prohibited in hovercraft and other ships constructed from aluminium. 2809
2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Toxic if swallowed, by skin contact or by inhalation. 2810
2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 2810
2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category A SW2 See entry above. 2810
2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 I 274 0 E5 P002 IBC99 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 2811
2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 2811
2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 III 223 274 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 2811
2812 SODIUM ALUMINATE, SOLID 8 960 Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. 2812
2813 WATER-REACTIVE SOLID, N.O.S. 4.3 I 274 0 E0 P403 PP31 IBC99 T9 TP7 TP33 F-G, S-N Category E SW2 H1 SG26 2813
2813 WATER-REACTIVE SOLID, N.O.S. 4.3 II 274 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category E SW2 H1 SG26 2813
2813 WATER-REACTIVE SOLID, N.O.S. 4.3 III 223 274 1 kg E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category E SW2 H1 SG26 2813
2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS 6.2 318 341 0 E0 P620 BK2 F-A, S-T Category E SW2 H1 H5 SG50 Substances which are dangerous to humans or to humans and animals. 2814
2815 -AMINOETHYLPIPERAZINE 8 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category B SW1 SW2 H2 SG35 SG50 Yellow liquid. Miscible with water. Corrosive to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. 2815
2817 AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION 8 6.1 II 1 L E2 P001 IBC02 B20 T8 TP2 TP13 F-A, S-B Category B SW2 SGG1 SGG2 SG36 SG49 Colourless liquid. Miscible with water. Highly corrosive to most metals and glass. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2817
2817 AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION 8 6.1 III 223 5 L E1 P001 IBC03 T4 TP1 TP13 F-A, S-B Category B SW2 SGG1 SGG2 SG36 SG49 See entry above. 2817
2818 AMMONIUM POLYSULPHIDE SOLUTION 8 6.1 II 1 L E2 P001 IBC02 T7 TP2 TP13 F-A, S-B Category B SW1 SW2 H2 SGG2 SGG18 SG35 Unstable yellowish liquid with a foul odour (of rotten eggs). Miscible with water. Reacts violently with acids. Decomposes in contact with acids, evolving hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2818
2818 AMMONIUM POLYSULPHIDE SOLUTION 8 6.1 III 223 5 L E1 P001 IBC03 T4 TP1 TP13 F-A, S-B Category B SW1 SW2 H2 SGG2 SGG18 SG35 See entry above. 2818
2819 AMYL ACID PHOSPHATE 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SGG1 SG36 SG49 Clear colourless liquid. A mixture of primary and amyl isomers. Immiscible with water. Corrosive to skin, eyes and mucous membranes. 2819
2820 BUTYRIC ACID 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SW1 H2 SGG1 SG36 SG49 Colourless liquid with a penetrating and unpleasant odour. Freezing point: −5°C to −8°C. Miscible with water. Corrosive to most metals. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. 2820
2821 PHENOL SOLUTION 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Yellowish solutions with a perceptible odour. Toxic if swallowed, by skin contact or by inhalation. Rapidly absorbed through the skin. 2821
2821 PHENOL SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A See entry above. 2821
2822 2-CHLOROPYRIDINE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW2 Colourless oily liquid. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2822
2823 CROTONIC ACID, SOLID 8 III 5 kg E1 P002 LP02 IBC08 B3 B21 T1 TP33 F-A, S-B Category A SW1 H2 SGG1 SG36 SG49 White crystalline solid. Soluble in water. Decomposes when heated, evolving toxic fumes. Causes burns to skin, eyes and mucous membranes. 2823
2826 ETHYL CHLOROTHIOFORMATE 8 3 II 0 E0 P001 T7 TP2 F-E, S-C Category A SW2 SGG1 SG36 SG49 Colourless, flammable liquid. Flashpoint: 29°C c.c. Causes burns to skin, eyes and mucous membranes. 2826
2829 CAPROIC ACID 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SGG1 SG36 SG49 Oily, colourless or yellowish liquid. Melting point: −4°C. Partially miscible with water. Corrosive to mild steel. Causes burns to skin, eyes and mucous membranes. 2829
2830 LITHIUM FERROSILICON 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category E SW2 SW5 H1 SG26 Dark, crystalline, metal-like powder or brittle lumps. In contact with moisture, evolves flammable and toxic gases. 2830
2831 1,1,1-TRICHLOROETHANE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SW2 SGG10 Colourless liquid. Immiscible with water. Decomposes when heated, evolving highly toxic fumes (phosgene and hydrogen chloride). Toxic if swallowed, by skin contact or by inhalation. Narcotic in high concentrations. 2831
2834 PHOSPHOROUS ACID 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SW1 SGG1 SG36 SG49 Colourless to yellow deliquescent crystals. Soluble in water. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2834
2835 SODIUM ALUMINIUM HYDRIDE 4.3 II 500 g E0 P410 PP31 PP40 IBC04 T3 TP33 F-G, S-O Category E H1 SG26 SG35 White, crystalline solid. Reacts with water, moisture or acids, evolving hydrogen, which may be ignited by the heat of the reaction. 2835
2837 BISULPHATES, AQUEOUS SOLUTION 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category A Colourless to white liquid. Miscible with water. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2837
2837 BISULPHATES, AQUEOUS SOLUTION 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A See entry above. 2837
2838 VINYL BUTYRATE, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category C SW1 Colourless liquid with a pungent odour. Flashpoint: 12°C c.c. Explosive limits: 1.4% to 8.8%. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2838
2839 ALDOL 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW1 H2 Clear, colourless to yellow viscous liquid. Miscible with water. Decomposes at 85°C, evolving toxic fumes. May react vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2839
2840 BUTYRALDOXIME 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Immiscible with water. Flashpoint: 58°C c.c. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2840
2841 DI--AMYLAMINE 3 6.1 III 5 L E1 P001 IBC03 T4 TP1 F-E, S-D Category A SG35 Colourless liquid with an ammoniacal odour. Flashpoint: 52°C c.c. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2841
2842 NITROETHANE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless, oily liquid. Flashpoint: 28°C c.c. Lower explosive limit: 3.4%. When involved in a fire, evolves nitrous toxic fumes. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. 2842
2844 CALCIUM MANGANESE SILICON 4.3 III 1 kg E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category A SW5 H1 SG26 SG35 In contact with water, evolves hydrogen, a flammable gas. In contact with acid, evolves silane, a spontaneously flammable gas. 2844
2845 PYROPHORIC LIQUID, ORGANIC, N.O.S. 4.2 I 274 0 E0 P400 T22 TP2 TP7 F-G, S-M Category D H1 SG26 SG63 Highly flammable liquids, may ignite spontaneously in moist air. In contact with air, evolve irritating and slightly toxic fumes. 2845
2846 PYROPHORIC SOLID, ORGANIC, N.O.S. 4.2 I 274 0 E0 P404 PP31 F-G, S-M Category D H1 SG26 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. 2846
2849 3-CHLOROPROPANOL−1 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Colourless to light-yellow liquid. Miscible with water. Mildly corrosive to steel. Toxic if swallowed, by skin contact or by inhalation. 2849
2850 PROPYLENE TETRAMER 3 III 5 L E1 P001 LP01 IBC03 T2 TP2 F-E, S-E Category A Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1-dodecene is not marine pollutant. 2850
2851 BORON TRIFLUORIDE DIHYDRATE 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category B SW1 SW2 H2 SGG1 SG36 SG49 Colourless, non-fuming liquid. Boiling range: 58°C to 60°C. Reacts with water, evolving corrosive and toxic fumes. Corrosive to mild steel. Causes burns to skin, eyes and mucous membranes. 2851
2852 DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP24 PP31 F-B, S-J Category D SG7 SG30 Desensitized explosive. Golden-yellow, crystalline leaflets. Explosive and sensitive to shock and heat in the dry state. May form extremely sensitive compounds with heavy metals or their salts. 2852
2853 MAGNESIUM FLUOROSILICATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SG35 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 2853
2854 AMMONIUM FLUOROSILICATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SGG2 SG35 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 2854
2855 ZINC FLUOROSILICATE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SGG7 SG35 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 2855
2856 FLUOROSILICATES, N.O.S. 6.1 III 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SG35 Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. 2856
2857 REFRIGERATING MACHINES containing non-flammable, non-toxic, gases or ammonia solutions (UN 2672) 2.2 119 0 E0 P003 PP32 F-C, S-V Category A 2857
2858 ZIRCONIUM, DRY, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) 4.1 III 921 5 kg E1 P002 LP02 PP100 L3 F-G, S-G Category A H1 SG25 SG26 Hard silvery metal. 2858
2859 AMMONIUM METAVANADATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG2 SG6 SG8 SG10 SG12 White crystalline powder. Slightly soluble in water. May act as an oxidizing substance. Toxic if swallowed, by skin contact or by inhalation. 2859
2861 AMMONIUM POLYVANADATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG2 SG6 SG8 SG10 SG12 Orange powder. Slightly soluble in water. May act as an oxidizing substance. Toxic if swallowed, by skin contact or by inhalation. 2861
2862 VANADIUM PENTOXIDE, non-fused form 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Brownish powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2862
2863 SODIUM AMMONIUM VANADATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SGG2 Orange wet cake (with 10% to 15% water). Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2863
2864 POTASSIUM METAVANADATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A White crystalline powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. 2864
2865 HYDROXYLAMINE SULPHATE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG1 SG35 SG36 SG49 Colourless to white crystalline powder. Soluble in water. May decompose explosively when heated. Causes burns to skin, eyes and mucous membranes. 2865
2869 TITANIUM TRICHLORIDE MIXTURE 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category A SW2 SGG1 SGG7 SG36 SG49 Violet crystalline solid. Reacts in moist air or in water, evolving heat and hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 2869
2869 TITANIUM TRICHLORIDE MIXTURE 8 III 223 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SW2 SGG1 SGG7 SG36 SG49 See entry above. 2869
2870 ALUMINIUM BOROHYDRIDE 4.2 4.3 I 0 E0 P400 T21 TP7 TP33 F-G, S-M Category D H1 SG26 Liquid. Ignites spontaneously in air. Reacts with water or steam to produce heat or hydrogen, which may form explosive mixtures with air. 2870
2870 ALUMINIUM BOROHYDRIDE IN DEVICES 4.2 4.3 0 E0 P002 PP13 F-G, S-M Category D H1 SG26 2870
2871 ANTIMONY POWDER 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Metallic antimony in the form of a fine grey powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2871
2872 DIBROMOCHLOROPROPANES 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SGG10 Colourless liquid with a perceptible odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2872
2872 DIBROMOCHLOROPROPANES 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SGG10 See entry above. 2872
2873 DIBUTYLAMINOETHANOL 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Colourless liquid with a perceptible odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2873
2874 FURFURYL ALCOHOL 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SG17 SG35 Clear, colourless, mobile liquid, becoming brown to dark-red upon exposure to light and air. Miscible with water. Reacts explosively with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. 2874
2875 HEXACHLOROPHENE 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A White, odourless powder or crystals. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2875
2876 RESORCINOL 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A White to pink crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2876
2878 TITANIUM SPONGE GRANULES or TITANIUM SPONGE POWDERS 4.1 III 223 5 kg E1 P002 LP02 PP100 L3 IBC08 B4 T1 TP33 F-G, S-G Category D H1 SGG7 SGG15 SG17 SG25 SG26 Silvery grey granules or dark grey, amorphous powder. May react with carbon dioxide, evolving oxygen. Forms explosive mixtures with oxidizing substances. 2878
2879 SELENIUM OXYCHLORIDE 8 6.1 I 0 E0 P001 T10 TP2 TP13 F-A, S-B Category E SW2 SGG1 SG36 SG49 Colourless, yellowish liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. 2879
2880 CALCIUM HYPOCHLORITE, HYDRATED or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16% water 5.1 II 314 322 1 kg E2 P002 PP85 F-H, S-Q Category D SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 White or yellowish solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. 2880
2880 CALCIUM HYPOCHLORITE, HYDRATED or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16% water 5.1 III 223 314 5 kg E1 P002 PP85 F-H, S-Q Category D SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 See entry above 2880
2881 METAL CATALYST, DRY 4.2 I 274 0 E0 P404 PP31 T21 TP7 TP33 F-G, S-M Category C H1 SGG7 SGG15 SG25 SG26 Liable to ignite spontaneously in air. 2881
2881 METAL CATALYST, DRY 4.2 II 274 0 E0 P410 PP31 IBC06 B21 T3 TP33 F-G, S-M Category C H1 SGG7 SGG15 SG25 SG26 See entry above. 2881
2881 METAL CATALYST, DRY 4.2 III 223 274 0 E1 P002 LP02 PP31 L4 IBC08 B4 T1 TP33 F-G, S-M Category C H1 SGG7 SGG15 SG25 SG26 See entry above. 2881
2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only 6.2 318 341 0 E0 P620 BK2 F-A, S-T Category E SW2 H1 H5 SG50 Substances which are dangerous to animals only. For action to be taken in the event of damage to, or leaking from, a package containing infectious substances, refer to 7.8.3. 2900
2901 BROMINE CHLORIDE 2.3 5.1/8 0 E0 P200 F-C, S-W Category D SW2 SG6 SG19 Reddish-yellow non-flammable, toxic and corrosive gas. When heated to decomposition, emits highly toxic and corrosive fumes of bromine and chlorine. Reacts with water, evolving toxic and corrosive fumes. Powerful oxidizing agent which may cause violent fires with combustible materials. Much heavier than air. Highly irritating to skin, eyes and mucous membranes. 2901
2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2902
2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 2902
2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 2902
2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2903
2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2903
2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 F-E, S-D Category A SW2 See entry above. 2903
2904 CHLOROPHENOLATES, LIQUID or PHENOLATES, LIQUID 8 III 5 L E1 P001 LP01 IBC03 F-A, S-B Category A A wide range of corrosive liquids. Cause burns to skin, eyes and mucous membranes. 2904
2905 CHLOROPHENOLATES, SOLID or PHENOLATES, SOLID 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A A wide range of corrosive solids. Soluble in water. Cause burns to skin, eyes and mucous membranes. 2905
2907 ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose, mannose, starch, or calcium hydrogen phosphate 4.1 II 28 127 0 E0 P406 PP26 PP80 IBC06 B12 B21 F-A, S-J Category E SG7 SG30 Desensitized explosive. Pure isosorbide dinitrate is explosive. May form extremely sensitive compounds with heavy metals or their salts. 2907
2908 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – EMPTY PACKAGING 7 See SP290 290 368 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A See 1.5.1 and 5.1.5.4.2. 2908
2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM 7 See SP290 290 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A See 1.5.1 and 5.1.5.4.2. 2909
2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – LIMITED QUANTITY OF MATERIAL 7 See SP290 290 368 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A See 1.5.1 and 5.1.5.4.2. 2910
2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – INSTRUMENTS or ARTICLES 7 See SP290 290 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A See 1.5.1 and 5.1.5.4.2. 2911
2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 T5 TP4 F-I, S-S Category A SW20 SW21 See 1.5.1. 2912
2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I, SCO-II or SCO-III), non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 T5 TP4 F-I, S-S Category A See 1.5.1. 2913
2915 RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW20 SW21 See 1.5.1. 2915
2916 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 2916
2917 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 2917
2919 RADIOACTIVE MATERIAL TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW13 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 2919
2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 8 3 I 274 0 E0 P001 T14 TP2 TP7 F-E, S-C Category C SW1 SW2 Causes burns to skin, eyes and mucous membranes. 2920
2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 8 3 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-E, S-C Category C SW1 SW2 See entry above. 2920
2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 8 4.1 I 274 0 E0 P002 IBC99 T6 TP33 F-A, S-G Category B SW1 H2 Causes burns to skin, eyes and mucous membranes. 2921
2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 8 4.1 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-G Category B SW1 H2 See entry above. 2921
2922 CORROSIVE LIQUID, TOXIC, N.O.S. 8 6.1 I 274 0 E0 P001 T14 TP2 TP13 TP27 F-A, S-B Category B SW2 Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. 2922
2922 CORROSIVE LIQUID, TOXIC, N.O.S. 8 6.1 II 274 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category B SW2 See entry above. 2922
2922 CORROSIVE LIQUID, TOXIC, N.O.S. 8 6.1 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-A, S-B Category B SW2 See entry above. 2922
2923 CORROSIVE SOLID, TOXIC, N.O.S. 8 6.1 I 274 0 E0 P002 IBC99 T6 TP33 F-A, S-B Category B SW2 Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. 2923
2923 CORROSIVE SOLID, TOXIC, N.O.S. 8 6.1 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category B SW2 See entry above. 2923
2923 CORROSIVE SOLID, TOXIC, N.O.S. 8 6.1 III 223 274 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-B Category B SW2 See entry above. 2923
2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3 8 I 274 0 E0 P001 T14 TP2 F-E, S-C Category E SW2 Causes burns to skin, eyes and mucous membranes. 2924
2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-E, S-C Category B SW2 See entry above. 2924
2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3 8 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-E, S-C Category A SW2 See entry above. 2924
2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 4.1 8 II 274 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-G Category D SW2 Causes burns to skin, eyes and mucous membranes. 2925
2925 FLAMMA align="center">FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 4.1 8 III 223 274 5 kg E1 P002 IBC06 T1 TP33 F-A, S-G Category D SW2 See entry above. 2925
2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 4.1 6.1 II 274 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-G Category B SW2 Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. 2926
2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 4.1 6.1 III 223 274 5 kg E1 P002 IBC06 T1 TP33 F-A, S-G Category B SW2 See entry above. 2926
2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 6.1 8 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-B Category B SW2 Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2927
2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 6.1 8 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-B Category B SW2 See entry above. 2927
2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 6.1 8 I 274 0 E5 P002 IBC99 T6 TP33 F-A, S-B Category B SW2 Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 2928
2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 6.1 8 II 274 500 g E4 P002 IBC06 B21 T3 TP33 F-A, S-B Category B SW2 See entry above. 2928
2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1 3 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Toxic if swallowed, by skin contact or by inhalation. 2929
2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1 3 II 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2929
2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 6.1 4.1 I 274 0 E5 P002 IBC99 T6 TP33 F-A, S-G Category B Toxic if swallowed, by skin contact or by inhalation. 2930
2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 6.1 4.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-G Category B See entry above. 2930
2931 VANADYL SULPHATE 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Blue, crystalline powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 2931
2933 METHYL 2-CHLORO- PROPIONATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid with an ether-like odour. Flashpoint: 32°C c.c. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. 2933
2934 ISOPROPYL 2-CHLORO- PROPIONATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid with a sweetish odour. Flashpoint: 50°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2934
2935 ETHYL 2-CHLOROPROPIONATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid with a pungent odour. Flashpoint: 38°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. 2935
2936 THIOLACTIC ACID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Oily liquid with a foul odour. Melting point: 10°C. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2936
2937 -METHYLBENZYL ALCOHOL, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Colourless liquid. Slightly miscible with water. Melting point: 21°C (pure substance). Toxic if swallowed, by skin contact or by inhalation. 2937
2940 9-PHOSPHABICYCLONONANES (CYCLOOCTADIENE-PHOSPHINES) 4.2 II 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J Category A Colourless, waxy solids. Melting point: 40°C to 60°C. React in contact with materials such as sawdust or other cellulose-based materials, resulting in charring and evolution of toxic fumes. Irritating to skin, eyes and mucous membranes. 2940
2941 FLUOROANILINES 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Liquids. Freezing points: −28°C to −2°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2941
2942 2-TRIFLUOROMETHYLANILINE 6.1 III 5 L E1 P001 LP01 IBC03 - F-A, S-A Category A Liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 2942
2943 TETRAHYDRO-FURFURYLAMINE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless to yellowish liquid with an ammoniacal odour. Flashpoint: 45°C c.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2943
2945 -METHYLBUTYLAMINE 3 8 II 1 L E2 P001 IBC02 T7 TP1 F-E, S-C Category B SW2 SG35 Colourless liquid. Flashpoint: 0°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. 2945
2946 2-AMINO−5-DIETHYLAMINO-PENTANE 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Liquid with an acrid odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2946
2947 ISOPROPYL CHLOROACETATE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid with a pungent odour. Flashpoint: 56°C c.c. Slightly soluble in water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 2947
2948 3-TRIFLUOROMETHYLANILINE 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A SW2 Colourless to yellowish liquid. Melting point: 5°C. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation. 2948
2949 SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization 8 II 1 kg E2 P002 IBC08 B4 B21 T7 TP2 F-A, S-B Category A SGG18 SG35 Colourless needles or yellow flakes. Soluble in water with a foul odour. Melting point: 52°C. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Causes burns to skin, eyes and mucous membranes. 2949
2950 MAGNESIUM GRANULES, COATED, particle size not less than 149 microns 4.3 III 920 1 kg E1 P410 PP100 IBC08 B4 T1 BK2 TP33 F-G, S-O Category A H1 SGG15 SG26 SG35 Coated granules with particle size ranging from 149 to 2,000 microns. In contact with water or acids, evolve hydrogen, a flammable gas. 2950
2956 5--BUTYL−2,4,6-TRINITRO- -XYLENE (MUSK XYLENE) 4.1 III 133 0 E0 P409 F-B, S-G Category D SW1 SW2 SW11 H2 H3 SG1 Insoluble in water. May explode if involved in a fire under confined conditions. Sensitive to strong detonation shock. Harmful if swallowed or by skin contact. 2956
2965 BORON TRIFLUORIDE DIMETHYL ETHERATE 4.3 3/8 I 0 E0 P401 PP31 T10 TP2 TP7 TP13 F-G, S-O Category D SW2 H1 SG5 SG8 SG13 SG25 SG26 Colourless, flammable liquid. Flashpoint: 20°C c.c. but widely variable, depending upon free ether content. Freezing point: −14°C. Decomposes in contact with water, forming dimethyl ether, a flammable gas. Causes burns to skin, eyes and mucous membranes. 2965
2966 THIOGLYCOL 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Colourless liquid with a foul odour. Miscible with water. Decomposes when heated, evolving sulphur dioxide. Toxic if swallowed, by skin contact or by inhalation. 2966
2967 SULPHAMIC ACID 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG1 SG36 SG49 White crystalline powder. Soluble in water. Decomposes when heated, evolving toxic fumes. Causes burns to skin, eyes and mucous membranes. 2967
2968 MANEB, STABILIZED or MANEB PREPARATION, STABILIZED against self-heating 4.3 III 223 946 1 kg E1 P002 PP100 IBC08 B4 T1 TP33 F-G, S-L Category B H1 SG26 SG29 SG35 Yellow powder. May evolve toxic, irritating or flammable fumes when wet, when involved in a fire or in contact with acids. Requires certification from the shipper that the substance is not class 4.2. 2968
2969 CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE 9 II 141 5 kg E2 P002 PP34 IBC08 B4 B21 T3 BK2 TP33 F-A, S-A Category E SW2 SG10 SG18 SG29 Whole beans or meal. The latter is the residue remaining after the oil has been extracted from the seeds. Castor beans contain a powerful allergen which, by inhalation of dust or by skin contact with crushed bean products, can give rise to severe irritation of the skin, eyes and mucous membranes in some persons. They are also toxic by ingestion. When handling these products, wear at least a dust mask and goggles. Avoid unnecessary skin contact. 2969
2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE 7 6.1/8 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category B SW2 SW12 SG17 SG76 SG78 See 1.5.1. 2977
2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE non fissile or fissile-excepted 7 6.1/8 317 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category B SW2 SW12 SG17 SG76 SG78 See 1.5.1. 2978
2983 ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE with not more than 30% ethylene oxide 3 6.1 I 0 E0 P001 T14 TP2 TP7 TP13 F-E, S-D Category E SW1 SW2 Colourless, volatile liquid with an ethereal odour. Flashpoint: below −18°C c.c. Explosive limits: 2.2% to 55%. Boiling point: 23°C to 28°C. Miscible with water. Corrosive to aluminium. Toxic if swallowed, by skin contact or by inhalation. Irritating to eyes and mucous membranes. 2983
2984 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) 5.1 III 65 5 L E1 P504 IBC02 B5 T4 TP1 TP6 TP24 F-H, S-Q Category B SW1 SG16 SG59 SG72 Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, except aluminium. 2984
2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3 8 II 0 E0 P010 T14 TP2 TP7 TP13 TP27 F-E, S-C Category B SW2 SGG1 SG36 SG49 Colourless liquids with a pungent odour. When involved in a fire, evolve toxic gases. React violently with water, evolving hydrogen chloride, an irritating and corrosive gas. In the presence of moisture, highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 2985
2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 8 3 II 0 E0 P010 T14 TP2 TP7 TP13 TP27 F-E, S-C Category C SW2 SGG1 SG36 SG49 Colourless, flammable liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 2986
2987 CHLOROSILANES, CORROSIVE, N.O.S. 8 II 0 E0 P010 T14 TP2 TP7 TP13 TP27 F-A, S-B Category C SW2 SGG1 SG36 SG49 Colourless liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gases. In the presence of moisture, highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. 2987
2988 CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S. 4.3 3/8 I 0 E0 P401 PP31 T14 TP2 TP7 TP13 F-G, S-N Category D SW2 H1 SGG1 SG5 SG8 SG13 SG25 SG26 SG36 SG49 Colourless, very volatile liquids, flammable and corrosive, with a pungent odour. Immiscible with water. React violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Cause burns to skin, eyes and mucous membranes. 2988
2989 LEAD PHOSPHITE, DIBASIC 4.1 II 922 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-G Category B SGG7 SGG9 SG29 Fine white crystals or powder. Insoluble in water. Combustion can be sustained, even in the absence of air. Harmful if swallowed. 2989
2989 LEAD PHOSPHITE, DIBASIC 4.1 III 922 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-G Category B SGG7 SGG9 SG29 See entry above. 2989
2990 LIFE-SAVING APPLIANCES, SELF-INFLATING 9 296 0 E0 P905 F-A, S-V Category A SG18 SG71 These articles may contain: .1 class 2.2 compressed gases; .2 signal devices (class 1) which may include smoke and illumination signal flares; signal devices must be packed in plastic or fibreboard inner packagings; .3 electric storage batteries; .4 first aid kit; or .5 “strike anywhere” matches. 2990
2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2991
2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2991
2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 2991
2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2992
2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 2992
2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 2992
2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2993
2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2993
2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 2993
2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2994
2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 2994
2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 2994
2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 It frequently contains petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2995
2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2995
2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 2995
2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2996
2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 2996
2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 2996
2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 It frequently contains petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2997
2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 2997
2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 2997
2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 See alphabetical index to identify those pesticides which are marine pollutants. Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 2998
2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 2998
2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 2998
3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3005
3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3005
3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 3005
3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3006
3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 3006
3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 3006
3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3009
3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3009
3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3009
3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3010
3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 3010
3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 3010
3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 SGG7 SGG11 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3011
3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 SGG7 SGG11 See entry above. 3011
3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 SGG7 SGG11 See entry above. 3011
3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 SGG7 SGG11 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3012
3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 SGG7 SGG11 See entry above. 3012
3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 SGG7 SGG11 See entry above. 3012
3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3013
3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3013
3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 3013
3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3014
3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 3014
3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 3014
3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3015
3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3015
3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 3015
3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3016
3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 3016
3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 3016
3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3017
3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3017
3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 3017
3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3018
3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 See entry above. 3018
3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 3018
3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3019
3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3019
3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 3019
3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3020
3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3020
3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 3020
3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3021
3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3021
3022 1,2-BUTYLENE OXIDE, STABILIZED 3 II 386 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category C SW1 SG20 SG21 Colourless liquid. Flashpoint: −15°C c.c. Explosive limits: 1.5% to 18.3%. Reacts violently with acids, alkalis and oxidizers. Miscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. 3022
3023 2-METHYL−2-HEPTANETHIOL 6.1 3 I 354 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW2 SG57 Colourless flammable liquid with a foul odour. Flashpoint: 31°C c.c. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. 3023
3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3024
3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3024
3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3025
3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3025
3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-E, S-D Category A SW2 See entry above. 3025
3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3026
3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B SW2 See entry above. 3026
3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category A SW2 See entry above. 3026
3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 3027
3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 3027
3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 3027
3028 BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE, SOLID electric storage 8 III 295 304 5 kg E0 P801 F-A, S-B Category A SGG18 SG35 Series of metal plates immersed in dry potassium hydroxide in a closed receptacle. When electrically charged, may cause fire through short-circuiting of terminals. Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label. Used batteries being transported for disposal or reclamation should be carefully checked prior to shipment to ensure the integrity of each battery and its suitability for transport. React violently with acids. 3028
3048 ALUMINIUM PHOSPHIDE PESTICIDE 6.1 I 153 930 0 E0 P002 PP31 IBC07 B1 T6 TP33 F-A, S-A Category E SW2 SW5 Waxed pellets, adequately stabilized powder, tablets or crystals. Highly toxic if swallowed, by skin contact or by inhalation. 3048
3054 CYCLOHEXYL MERCAPTAN 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A SW2 SG50 SG57 Colourless liquid with a garlic-like odour. Flashpoint: 49°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. 3054
3055 2-(2-AMINOETHOXY)ETHANOL 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SG35 Colourless, slightly viscous liquid with a mild odour. Miscible with water. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. 3055
3056 -HEPTALDEHYDE 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless or pale yellow, oily liquid with a pungent odour. Flashpoint: 35°C to 45°C c.c. Explosive limits: 1.1% to 5.2%. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. 3056
3057 TRIFLUOROACETYL CHLORIDE 2.3 8 0 E0 P200 T50 TP21 F-C, S-U Category D SW2 Liquefied, non-flammable, toxic and corrosive gas. Reacts with water. Corrosive to glass and to most metals, including steel. Heavier than air (1.4 at 20°C). Highly irritating to skin, eyes and mucous membranes. 3057
3064 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin 3 II 28 359 0 E0 P300 F-E, S-D Category E Immiscible with water. Ignites readily. When involved in a fire, evolves toxic nitrous fumes. Not explosive in this state but damage to, or leakage from, a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. 3064
3065 ALCOHOLIC BEVERAGES, with more than 70% alcohol by volume 3 II 5 L E2 P001 PP2 IBC02 T4 TP1 F-E, S-D Category A Aqueous solutions of ethanol produced and supplied as alcoholic beverages. Miscible with water. Flashpoint: −13°C c.c. or greater. 3065
3065 ALCOHOLIC BEVERAGES, with more than 24% but not more than 70% alcohol by volume 3 III 144 145 247 5 L E1 P001 PP2 IBC03 T2 TP1 F-E, S-D Category A Alcoholic beverages containing more than 24% alcohol but not more than 70% by volume, when transported as part of the manufacturing process, may be transported in wooden barrels with a capacity of more than 250 L and not more than 500 L meeting the general requirements of 4.1.1, as appropriate, on the following conditions: .1 the wooden barrels should be checked and tightened before filling; .2 sufficient ullage (not less than 3%) should be left to allow for the expansion of the liquid; .3 the wooden barrels should be transported with the bungholes pointing upwards; .4 the wooden barrels should be transported in containers meeting the requirements of the , 1972 (CSC Convention), as amended. Each wooden barrel should be secured in custom-made cradles and should be wedged by appropriate means to prevent them from being displaced in any way during transport; and .5 when carried on board ships, the containers should be stowed in open cargo spaces or in enclosed cargo spaces complying with the requirements for class 3 flammable liquids with a flashpoint of 23°C c.c. or less in regulation II−2/19 of SOLAS, 74, as amended. 3065
3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) 8 II 163 367 1 L E2 P001 IBC02 T7 TP2 TP28 F-A, S-B Category B SW2 Corrosive content. Causes burns to skin, eyes and mucous membranes. 3066
3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) 8 III 163 223 367 5 L E1 P001 IBC03 T4 TP1 TP29 F-A, S-B Category A SW2 Corrosive content. Causes burns to skin, eyes and mucous membranes. 3066
3070 ETHYLENE OXIDE AND DICHLORODIFLUORO-METHANE MIXTURE with not more than 12.5% ethylene oxide 2.2 392 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas. Much heavier than air. 3070
3071 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 6.1 3 II 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category C SW2 SG57 Colourless to yellow flammable liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 3071
3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment 9 296 0 E0 P905 F-A, S-V Category A SG18 SG71 These articles may contain: .1 class 2.2 compressed gases; .2 signal devices (class 1) which may include smoke and illumination signal flares; signal devices must be packed in plastic or fibreboard inner packagings; .3 electric storage batteries; .4 first aid kit; or .5 “strike anywhere” matches. 3072
3073 VINYLPYRIDINES, STABILIZED 6.1 3/8 II 386 100 mL E4 P001 IBC01 T7 TP2 TP13 F-E, S-C Category C SW1 SW2 SGG18 SG5 SG8 SG35 Colourless to straw-coloured flammable liquids. Flashpoint: 42°C to 51°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. React violently with acids. 3073
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 9 III 274 335 375 966 967 969 5 kg E1 P002 LP02 PP12 IBC08 B3 T1 BK1 BK2 BK3 TP33 F-A, S-F Category A SW23 3077
3078 CERIUM, turnings or gritty powder 4.3 II 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-O Category E H1 SGG15 SG26 SG35 Grey, ductile metal or powder. Decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. 3078
3079 METHACRYLONITRILE, STABILIZED 6.1 3 I 354 386 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW1 SW2 Colourless, mobile liquid with a pungent odour. Flashpoint: 4°C c.c. Explosive limits: 3% to 17%. Partially miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Practice has shown that this substance may leak from packagings that ordinarily are leakproof to other chemicals. 3079
3080 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. 6.1 3 II 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category D SW1 SW2 Flammable liquids or solutions with a pungent odour. Immiscible with or insoluble in water, but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 3080
3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 9 III 274 335 375 966 967 969 5 L E1 P001 LP01 PP1 IBC03 T4 TP1 TP29 F-A, S-F Category A 3082
3083 PERCHLORYL FLUORIDE 2.3 5.1 0 E0 P200 F-C, S-W Category D SW2 Non-flammable, toxic, colourless gas with a characteristic sweet odour. Strong oxidizing agent; may cause fire in contact with organic materials. Reacts with water or moist air to produce toxic and corrosive fumes. Mixtures with oils or combustible materials may explode. Much heavier than air (3.6). Irritating to skin, eyes and mucous membranes. 3083
3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 8 5.1 I 274 0 E0 P002 T6 TP33 F-A, S-Q Category C Causes burns to skin, eyes and mucous membranes. 3084
3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 8 5.1 II 274 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-Q Category C See entry above. 3084
3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 8 I 274 0 E0 P503 F-A, S-Q Category D H1 SG38 SG49 SG60 Causes burns to skin, eyes and mucous membranes. Particular care in handling should be exercised if packages have become wetted. 3085
3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 8 II 274 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-Q Category B H1 SG38 SG49 SG60 See entry above. 3085
3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 8 III 223 274 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-Q Category B H1 SG38 SG49 SG60 See entry above. 3085
3086 TOXIC SOLID, OXIDIZING, N.O.S. 6.1 5.1 I 274 0 E5 P002 T6 TP33 F-A, S-Q Category C Toxic if swallowed, by skin contact or by inhalation. 3086
3086 TOXIC SOLID, OXIDIZING, N.O.S. 6.1 5.1 II 274 500 g E4 P002 IBC06 B21 T3 TP33 F-A, S-Q Category C See entry above. 3086
3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 6.1 I 274 900 0 E0 P503 F-A, S-Q Category D SG38 SG49 SG60 Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. 3087
3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 6.1 II 274 900 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-Q Category B SG38 SG49 SG60 See entry above. 3087
3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 6.1 III 223 274 900 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-Q Category B SG38 SG49 SG60 See entry above. 3087
3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 4.2 II 274 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J Category C Liable to self-heating or spontaneous combustion. 3088
3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 4.2 III 223 274 0 E1 P002 LP02 PP31 IBC08 B3 T1 TP33 F-A, S-J Category C See entry above. 3088
3089 METAL POWDER, FLAMMABLE, N.O.S. 4.1 II 1 kg E2 P002 PP100 IBC08 B4 B21 T3 TP33 F-G, S-G Category B H1 SGG7 SGG15 SG17 SG25 SG26 3089
3089 METAL POWDER, FLAMMABLE, N.O.S. 4.1 III 223 5 kg E1 P002 PP100 IBC08 B4 B21 T1 TP33 F-G, S-G Category A H1 SGG7 SGG15 SG17 SG25 SG26 3089
3090 LITHIUM METAL BATTERIES (including lithium alloy batteries) 9 188 230 310 377 384 387 0 E0 P903 P908 P909 P910 P911 LP903 LP904 LP905 LP906 F-A, S-I Category A SW19 Electrical batteries containing lithium metal may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. 3090
3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) 9 188 230 310 360 376 377 384 387 390 0 E0 P903 P908 P909 P910 P911 LP903 LP904 LP905 LP906 F-A, S-I Category A SW19 Electrical batteries containing lithium metal may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. 3091
3092 1-METHOXY−2-PROPANOL 3 III 5 L E1 P001 LP01 IBC03 T2 TP1 F-E, S-D Category A Colourless liquid. Flashpoint: 29°C to 35°C c.c. Explosive limits: 1.7% to 11.5%. Miscible with water. Reacts with strong oxidizing substances. Irritating to skin, eyes and mucous membranes. 3092
3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 8 5.1 I 274 0 E0 P001 F-A, S-Q Category C Causes burns to skin, eyes and mucous membranes. 3093
3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 8 5.1 II 274 1 L E2 P001 IBC02 F-A, S-Q Category C See entry above. 3093
3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. 8 4.3 I 274 0 E0 P001 F-G, S-L Category D H1 SG26 Causes burns to skin, eyes and mucous membranes. 3094
3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. 8 4.3 II 274 500 mL E2 P001 F-G, S-L Category D H1 SG26 See entry above. 3094
3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. 8 4.2 I 274 0 E0 P002 T6 TP33 F-A, S-N Category D Causes burns to skin, eyes and mucous membranes. 3095
3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. 8 4.2 II 274 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-N Category D See entry above. 3095
3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. 8 4.3 I 274 0 E0 P002 T6 TP33 F-G, S-L Category D H1 SG26 Causes burns to skin, eyes and mucous membranes. 3096
3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. 8 4.3 II 274 1 kg E2 P002 PP100 IBC06 B21 T3 TP33 F-G, S-L Category D H1 SG26 See entry above. 3096
3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. 4.1 5.1 II 274 976 0 E0 P099 F-A, S-Q 3097
3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. 4.1 5.1 III 274 976 0 E0 P099 T1 TP33 F-A, S-Q 3097
3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 8 I 274 0 E0 P502 F-A, S-Q Category D H1 SG38 SG49 SG60 Causes burns to skin, eyes and mucous membranes. Particular care in handling should be exercised if packages have become wetted. 3098
3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 8 II 274 1 L E2 P504 IBC01 F-A, S-Q Category B H1 SG38 SG49 SG60 See entry above. 3098
3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 8 III 223 274 5 L E1 P504 IBC02 F-A, S-Q Category B H1 SG38 SG49 SG60 See entry above. 3098
3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 6.1 I 274 0 E0 P502 F-A, S-Q Category D SG38 SG49 SG60 Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. 3099
3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 6.1 II 274 1 L E2 P504 IBC01 F-A, S-Q Category B SG38 SG49 SG60 See entry above. 3099
3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 6.1 III 223 274 5 L E1 P504 IBC02 F-A, S-Q Category B SG38 SG49 SG60 See entry above. 3099
3100 OXIDIZING SOLID, SELF-HEATING, N.O.S. 5.1 4.2 I 274 976 0 E0 P099 F-A, S-Q 3100
3100 OXIDIZING SOLID, SELF-HEATING, N.O.S. 5.1 4.2 II 274 976 0 E0 P099 F-A, S-Q 3100
3101 ORGANIC PEROXIDE TYPE B, LIQUID 5.2 See SP181 122 181 195 274 25 mL E0 P520 F-J, S-R Category D SW1 SG1 SG35 SG36 SG72 May explode at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3101
3102 ORGANIC PEROXIDE TYPE B, SOLID 5.2 See SP181 122 181 195 274 100 g E0 P520 F-J, S-R Category D SW1 SG1 SG35 SG36 SG72 May explode at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Addition of water to disuccinic acid peroxide will decrease its thermal stability. May evolve irritant or toxic fumes. 3102
3103 ORGANIC PEROXIDE TYPE C, LIQUID 5.2 122 195 274 25 mL E0 P520 F-J, S-R Category D SW1 SG35 SG36 SG72 May decompose violently at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for -butyl hydroperoxide. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3103
3104 ORGANIC PEROXIDE TYPE C, SOLID 5.2 122 195 274 100 g E0 P520 F-J, S-R Category D SW1 SG35 SG36 SG72 May decompose violently at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3104
3105 ORGANIC PEROXIDE TYPE D, LIQUID 5.2 122 274 125 mL E0 P520 F-J, S-R Category D SW1 SG35 SG36 SG72 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for acetylacetone peroxide, -butyl hydroperoxide and peroxyacetic acid, Type D, stabilized. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3105
3106 ORGANIC PEROXIDE TYPE D, SOLID 5.2 122 274 500 g E0 P520 F-J, S-R Category D SW1 SG35 SG36 SG72 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water except for 3-chloroperoxybenzoic acid. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3106
3107 ORGANIC PEROXIDE TYPE E, LIQUID 5.2 122 274 125 mL E0 P520 F-J, S-R Category D SW1 SG35 SG36 SG72 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for -amyl hydroperoxide, and -butyl hydroperoxide and peroxyacetic acid, Type E, stabilized. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3107
3108 ORGANIC PEROXIDE TYPE E, SOLID 5.2 122 274 500 g E0 P520 F-J, S-R Category D SW1 SG35 SG36 SG72 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3108
3109 ORGANIC PEROXIDE TYPE F, LIQUID 5.2 122 274 125 mL E0 P520 IBC520 T23 F-J, S-R Category D SW1 SG35 SG36 SG72 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for -butyl hydroperoxide; dibenzoyl peroxide; dilauroyl peroxide and peroxyacetic acid, Type F, stabilized. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3109
3110 ORGANIC PEROXIDE TYPE F, SOLID 5.2 122 274 500 g E0 P520 IBC520 T23 TP33 F-J, S-R Category D SW1 SG35 SG36 SG72 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. 3110
3111 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED 5.2 See SP181 122 181 195 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG1 SG35 SG36 SG72 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3111
3112 ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED 5.2 See SP181 122 181 195 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG1 SG35 SG36 SG72 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3112
3113 ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED 5.2 122 195 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 May decompose violently at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3113
3114 ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED 5.2 122 195 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 May decompose violently at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3114
3115 ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 5.2 122 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3115
3116 ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED 5.2 122 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water except for diperoxyazelaic acid. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3116
3117 ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED 5.2 122 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3117
3118 ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED 5.2 122 274 923 0 E0 P520 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water except for di-(2-ethylhexyl) peroxydicarbonate. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3118
3119 ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED 5.2 122 274 923 0 E0 P520 IBC520 T23 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water except for di-(4--butylcyclohexyl) peroxydicarbonate, dicetyl peroxydicarbonate and dimyristyl peroxydicarbonate. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3119
3120 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED 5.2 122 274 923 0 E0 P520 IBC520 T23 TP33 F-F, S-R Category D SW1 SW3 SG35 SG36 SG72 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in the table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. 3120
3121 OXIDIZING SOLID, WATER-REACTIVE, N.O.S. 5.1 4.3 I 274 976 0 E0 P099 F-G, S-L H1 SG26 3121
3121 OXIDIZING SOLID, WATER-REACTIVE, N.O.S. 5.1 4.3 II 274 976 0 E0 P099 F-G, S-L H1 SG26 3121
3122 TOXIC LIQUID, OXIDIZING, N.O.S. 6.1 5.1 I 274 315 0 E0 P001 F-A, S-Q Category C Toxic if swallowed, by skin contact or by inhalation. 3122
3122 TOXIC LIQUID, OXIDIZING, N.O.S. 6.1 5.1 II 274 100 mL E4 P001 IBC02 F-A, S-Q Category C See entry above. 3122
3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. 6.1 4.3 I 274 315 0 E0 P099 F-G, S-N Category D SW2 H1 SG26 Toxic if swallowed, by skin contact or by inhalation. 3123
3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. 6.1 4.3 II 274 100 mL E4 P001 IBC02 F-G, S-N Category D SW2 H1 SG26 See entry above. 3123
3124 TOXIC SOLID, SELF-HEATING, N.O.S. 6.1 4.2 I 274 0 E5 P002 T6 TP33 F-A, S-J Category D SW2 Highly toxic if swallowed, by skin contact or by inhalation. 3124
3124 TOXIC SOLID, SELF-HEATING, N.O.S. 6.1 4.2 II 274 0 E4 P002 IBC06 B21 T3 TP33 F-A, S-J Category D SW2 See entry above. 3124
3125 TOXIC SOLID, WATER-REACTIVE, N.O.S. 6.1 4.3 I 274 0 E5 P099 T6 TP33 F-G, S-N Category D SW2 H1 SG26 Toxic if swallowed, by skin contact or by inhalation. 3125
3125 TOXIC SOLID, WATER-REACTIVE, N.O.S. 6.1 4.3 II 274 500 g E4 P002 PP100 IBC06 B21 T3 TP33 F-G, S-N Category D SW2 H1 SG26 See entry above. 3125
3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 4.2 8 II 274 0 E2 P410 IBC05 B21 T3 TP33 F-A, S-J Category C 3126
3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 4.2 8 III 223 274 0 E1 P002 IBC08 B3 T1 TP33 F-A, S-J Category C 3126
3127 SELF-HEATING SOLID, OXIDIZING, N.O.S. 4.2 5.1 II 274 976 0 E0 P099 T3 TP33 F-A, S-J 3127
3127 SELF-HEATING SOLID, OXIDIZING, N.O.S. 4.2 5.1 III 223 274 976 0 E0 P099 T1 TP33 F-A, S-J 3127
3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4.2 6.1 II 274 0 E2 P410 IBC05 B21 T3 TP33 F-A, S-J Category C 3128
3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4.2 6.1 III 223 274 0 E1 P002 IBC08 B3 T1 TP33 F-A, S-J Category C 3128
3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 8 I 274 0 E0 P402 T14 TP2 TP7 TP13 F-G, S-N Category D H1 SG26 3129
3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 8 II 274 0 E0 P402 IBC01 T11 TP2 TP7 F-G, S-N Category D SW31 H1 SG26 3129
3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 8 III 223 274 0 E1 P001 IBC02 T7 TP2 TP7 F-G, S-N Category D SW31 H1 SG26 3129
3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 6.1 I 274 0 E0 P402 F-G, S-N Category D H1 SG26 3130
3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 6.1 II 274 0 E0 P402 IBC01 F-G, S-N Category D SW31 H1 SG26 3130
3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 6.1 III 223 274 0 E1 P001 IBC02 F-G, S-N Category D SW31 H1 SG26 3130
3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 8 I 274 0 E0 P403 PP31 T9 TP7 TP33 F-G, S-L Category D H1 SG26 3131
3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 8 II 274 0 E2 P410 PP31 PP40 IBC06 B21 T3 TP33 F-G, S-L Category E SW5 H1 SG26 3131
3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 8 III 223 274 0 E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-L Category E SW5 H1 SG26 3131
3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 4.3 4.1 I 274 0 E0 P403 PP31 IBC99 F-G, S-N Category D H1 SG26 3132
3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 4.3 4.1 II 274 0 E2 P410 PP31 PP40 IBC04 T3 TP33 F-G, S-N Category E SW5 H1 SG26 3132
3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 4.3 4.1 III 223 274 0 E1 P410 PP31 IBC06 T1 TP33 F-G, S-N Category E SW5 H1 SG26 3132
3133 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 4.3 5.1 II 274 976 0 E0 P099 F-G, S-L H1 SG26 3133
3133 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 4.3 5.1 III 223 274 976 0 E0 P099 F-G, S-L H1 SG26 3133
3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 6.1 I 274 0 E0 P403 PP31 F-G, S-N Category D H1 SG26 3134
3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 6.1 II 274 500 g E2 P410 PP31 PP40 IBC05 B21 T3 TP33 F-G, S-N Category E SW5 H1 SG26 3134
3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 6.1 III 223 274 1 kg E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category E SW5 H1 SG26 3134
3135 WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. 4.3 4.2 I 274 0 E0 P403 PP31 F-G, S-N Category D H1 SG26 3135
3135 WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. 4.3 4.2 II 274 0 E2 P410 PP31 IBC05 B21 T3 TP33 F-G, S-N Category E SW5 H1 SG26 3135
3135 WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. 4.3 4.2 III 223 274 0 E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category E SW5 H1 SG26 3135
3136 TRIFLUOROMETHANE, REFRIGERATED LIQUID 2.2 120 mL E1 P203 T75 TP5 F-C, S-V Category D Liquefied, non-flammable gas. Much heavier than air (2.4). 3136
3137 OXIDIZING SOLID, FLAMMABLE, N.O.S. 5.1 4.1 I 274 976 0 E0 P099 F-G, S-Q H1 SG25 SG26 3137
3138 ETHYLENE, ACETYLENE AND PROPYLENE MIXTURE, REFRIGERATED LIQUID containing at least 71.5% ethylene, with not more than 22.5% acetylene and not more than 6% propylene 2.1 0 E0 P203 T75 TP5 F-D, S-U Category D SW2 SG46 Liquefied, flammable, colourless mixture of gases with a garlic odour. Explosive limits: 2.7% to 36%. Lighter than air (0.96). 3138
3139 OXIDIZING LIQUID, N.O.S. 5.1 I 274 0 E0 P502 F-A, S-Q Category D SG38 SG49 SG60 3139
3139 OXIDIZING LIQUID, N.O.S. 5.1 II 274 1 L E2 P504 IBC02 F-A, S-Q Category B SG38 SG49 SG60 3139
3139 OXIDIZING LIQUID, N.O.S. 5.1 III 223 274 5 L E1 P504 IBC02 F-A, S-Q Category B SG38 SG49 SG60 3139
3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOIDS SALTS, LIQUID, N.O.S. 6.1 I 43 274 0 E5 P001 F-A, S-A Category A A wide range of toxic liquids, generally of vegetable origin. Toxic if swallowed, by skin contact or by inhalation. 3140
3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOIDS SALTS, LIQUID, N.O.S. 6.1 II 43 274 100 mL E4 P001 IBC02 F-A, S-A Category A See entry above. 3140
3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOIDS SALTS, LIQUID, N.O.S. 6.1 III 43 223 274 5 L E1 P001 LP01 IBC03 F-A, S-A Category A See entry above. 3140
3141 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. 6.1 III 45 274 5 L E1 P001 LP01 IBC03 F-A, S-A Category A A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 3141
3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 I 274 0 E5 P001 F-A, S-A Category A SW2 A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 3142
3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 F-A, S-A Category A SW2 See entry above. 3142
3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 F-A, S-A Category A SW2 See entry above. 3142
3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 3143
3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A See entry above. 3143
3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 3143
3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 6.1 I 43 274 0 E5 P001 F-A, S-A Category B SW2 A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 3144
3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 6.1 II 43 274 100 mL E4 P001 IBC02 F-A, S-A Category B SW2 See entry above. 3144
3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 6.1 III 43 223 274 5 L E1 P001 LP01 IBC03 F-A, S-A Category B SW2 See entry above. 3144
3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C–C homologues) 8 I 0 E0 P001 T14 TP2 F-A, S-B Category B A wide range of colourless to pale straw-coloured liquids with penetrating odours (sometimes camphor-like). Liquids slightly miscible with water. Cause burns to skin, eyes and mucous membranes. 3145
3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C–C homologues) 8 II 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B Category B See entry above. 3145
3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C–C homologues) 8 III 223 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B Category A See entry above. 3145
3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 I 43 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B SW2 A wide variety of toxic solids. Toxic if swallowed, by skin contact or by inhalation. 3146
3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 II 43 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 3146
3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 III 43 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 3146
3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 8 I 274 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B Category A A wide range of corrosive solids or pastes. Cause burns to skin, eyes and mucous membranes. 3147
3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 8 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category A See entry above. 3147
3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 8 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A See entry above. 3147
3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 I 274 0 E0 P402 PP31 T13 TP2 TP7 F-G, S-N Category D SW2 SW31 H1 SG26 3148
3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 II 274 500 mL E2 P402 PP31 IBC01 T7 TP2 TP7 F-G, S-N Category D SW2 SW31 H1 SG26 3148
3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 III 223 274 1 L E1 P001 PP31 IBC02 T7 TP2 TP7 F-G, S-N Category D SW2 SW31 H1 SG26 3148
3149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED 5.1 8 II 196 1 L E2 P504 PP10 IBC02 B5 T7 TP2 TP6 TP24 F-H, S-Q Category D SW1 SGG16 SG16 SG59 SG72 Colourless liquid. Carried as an aqueous solution. Slowly decomposes, evolving oxygen; the rate of decomposition increases on contact with most metals. In contact with combustible material, may cause fire. Causes burns to skin, eyes and mucous membranes. Even though stabilized, these solutions may evolve oxygen. 3149
3150 DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device 2.1 0 E0 P003 F-D, S-U Category B SW2 Various small devices used for cosmetic and other purposes, and their refills. 3150
3151 POLYHALOGENATED BIPHENYLS, LIQUID or HALOGENATED MONOMETHYL-DIPHENYLMETHANES, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID 9 II 203 305 1 L E2 P906 IBC02 F-A, S-A Category A SG50 Viscous liquids with a perceptible odour. Harmful by ingestion or by skin contact. This entry also covers articles, such as transformers and condensers, containing free liquid polyhalogenated biphenyls or polyhalogenated terphenyls. 3151
3152 POLYHALOGENATED BIPHENYLS, SOLID or HALOGENATED MONOMETHYL-DIPHENYLMETHANES, SOLID or POLYHALOGENATED TERPHENYLS, SOLID 9 II 203 305 958 1 kg E2 P906 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SG50 Solid with a perceptible odour. Melting point of solids varies from 2°C to 164°C. Harmful by ingestion or by skin contact. This entry also covers articles, such as rags, cotton waste, clothing or sawdust, containing polyhalogenated biphenyls or polyhalogenated terphenyls where no free visible liquid is present. 3152
3153 PERFLUORO(METHYL VINYL ETHER) 2.1 0 E0 P200 T50 F-D, S-U Category E SW2 Explosive limits: 7% to 73%. Much heavier than air (4.8). Boiling point: −27°C. 3153
3154 PERFLUORO(ETHYL VINYL ETHER) 2.1 0 E0 P200 F-D, S-U Category E SW2 Explosive limits: 7% to 73%. Much heavier than air (6.4). Boiling point: 12°C. 3154
3155 PENTACHLOROPHENOL 6.1 II 43 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Toxic if swallowed, by skin contact or by dust inhalation. 3155
3156 COMPRESSED GAS, OXIDIZING, N.O.S. 2.2 5.1 274 0 E0 P200 F-C, S-W Category D 3156
3157 LIQUEFIED GAS, OXIDIZING, N.O.S. 2.2 5.1 274 0 E0 P200 F-C, S-W Category D 3157
3158 GAS, REFRIGERATED LIQUID, N.O.S. 2.2 274 120 mL E1 P203 T75 TP5 F-C, S-V Category D 3158
3159 1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134a) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Non-flammable gas with a mild ether-like odour. Much heavier than air (3.5). 3159
3160 LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 2.1 274 0 E0 P200 F-D, S-U Category D SW2 3160
3161 LIQUEFIED GAS, FLAMMABLE, N.O.S. 2.1 274 0 E0 P200 T50 F-D, S-U Category D SW2 3161
3162 LIQUEFIED GAS, TOXIC, N.O.S. 2.3 274 0 E0 P200 F-C, S-U Category D SW2 3162
3163 LIQUEFIED GAS, N.O.S. 2.2 274 392 120 mL E1 P200 T50 F-C, S-V Category A 3163
3164 ARTICLES, PRESSURIZED, PNEUMATIC or HYDRAULIC (containing non-flammable gas) 2.2 283 371 120 mL E0 P003 PP32 F-C, S-V Category A Articles containing non-flammable, non-toxic gas necessary for their operation. 3164
3165 AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) (M86 fuel) 3 6.1/8 0 E0 P301 F-E, S-C Category D SW2 SG5 SG8 SG13 The mixture is miscible with water and may react dangerously with oxidizing substances. The mixture is highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3165
3166 VEHICLE, FLAMMABLE GAS POWERED or VEHICLE, FLAMMABLE LIQUID POWERED or VEHICLE, FUEL CELL, FLAMMABLE GAS POWERED or VEHICLE, FUEL CELL, FLAMMABLE LIQUID POWERED 9 356 388 961 962 Category A Types of articles transported under this entry include, but are not limited to motor vehicles, hybrid vehicles, fuel cell powered vehicles, motorcycles and boats. F-D, S-U for gases or F-E, S-E for liquids. 3166
3167 GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid 2.1 209 0 E0 P201 F-D, S-U Category D 3167
3168 GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid 2.3 2.1 209 0 E0 P201 F-D, S-U Category D 3168
3169 GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid 2.3 209 0 E0 P201 F-C, S-U Category D 3169
3170 ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS 4.3 II 244 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 BK2 TP33 F-G, S-P Category B SW5 H1 SGG15 SG26 Grey powder or lumps with some metallic inclusions. Contact with water may cause heating with possible evolution of flammable and toxic gases such as hydrogen and ammonia. This entry includes e.g. aluminium dross, aluminium skimmings, spent cathodes, spent potliner and aluminium salt slags. 3170
3170 ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS 4.3 III 223 244 1 kg E1 P002 PP31 IBC08 B4 T1 BK2 TP33 F-G, S-P Category B SW5 H1 SGG15 SG26 See entry above. 3170
3171 BATTERY-POWERED VEHICLE or BATTERY-POWERED EQUIPMENT 9 388 961 962 971 F-A, S-I Category A This entry applies to vehicles and equipment powered by wet batteries, metallic sodium batteries or sodium alloy batteries with the batteries installed. 3171
3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 6.1 I 210 274 0 E5 P001 F-A, S-A Category B Toxins from plant, animal or bacterial sources which contain infectious substances or toxins that are contained in infectious substances should be classified in class 6.2. Toxic if swallowed, by skin contact or by inhalation. 3172
3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 6.1 II 210 274 100 mL E4 P001 IBC02 F-A, S-A Category B See entry above. 3172
3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 6.1 III 210 223 274 5 L E1 P001 LP01 IBC03 F-A, S-A Category A See entry above. 3172
3174 TITANIUM DISULPHIDE 4.2 III 0 E1 P002 LP02 PP31 IBC08 B3 T1 TP33 F-A, S-J Category A SGG7 Yellow or grey powder with an unpleasant odour. In contact with water slowly evolves hydrogen sulphide gas. 3174
3175 SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. 4.1 II 216 274 1 kg E2 P002 PP9 IBC06 B21 T3 BK2 TP33 F-A, S-I Category B Mixtures of non-dangerous solids (such as soil, sand, production materials, etc.) and flammable liquids. 3175
3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4.1 II 274 0 E0 - T3 TP3 TP26 F-A, S-H Category C Shipped molten above its melting point. 3176
3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4.1 III 223 274 0 E0 T1 TP3 TP26 F-A, S-H Category C See entry above. 3176
3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 4.1 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-G Category B 3178
3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 4.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-G Category B 3178
3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1 6.1 II 274 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-G Category B SW2 Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. 3179
3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1 6.1 III 223 274 5 kg E1 P002 IBC06 T1 TP33 F-A, S-G Category B SW2 See entry above. 3179
3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 4.1 8 II 274 1 kg E2 P002 IBC06 B21 T3 TP33 F-A, S-G Category D SW2 Causes burns to skin, eyes and mucous membranes. 3180
3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 4.1 8 III 223 274 5 kg E1 P002 IBC06 T1 TP33 F-A, S-G Category D SW2 See entry above. 3180
3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 4.1 II 274 1 kg E2 P002 PP31 IBC08 B4 B21 T3 TP33 F-A, S-I Category B SW2 SGG7 Decomposes in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. 3181
3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 4.1 III 223 274 5 kg E1 P002 LP02 PP31 IBC08 B3 T1 TP33 F-A, S-I Category B SW2 SGG7 See entry above. 3181
3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 4.1 II 274 1 kg E2 P410 PP31 PP40 IBC04 T3 TP33 F-A, S-G Category E 3182
3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 4.1 III 223 274 5 kg E1 P002 PP31 IBC04 T1 TP33 F-A, S-G Category E 3182
3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.2 II 274 0 E2 P001 PP31 IBC02 F-A, S-J Category C 3183
3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.2 III 223 274 0 E1 P001 PP31 IBC02 F-A, S-J Category C 3183
3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 4.2 6.1 II 274 0 E2 P402 PP31 IBC02 F-A, S-J Category C 3184
3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 4.2 6.1 III 223 274 0 E1 P001 PP31 IBC02 F-A, S-J Category C 3184
3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 4.2 8 II 274 0 E2 P402 PP31 IBC02 F-A, S-J Category C 3185
3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 4.2 8 III 223 274 0 E1 P001 PP31 IBC02 F-A, S-J Category C 3185
3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4.2 II 274 0 E2 P001 PP31 IBC02 F-A, S-J Category C 3186
3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4.2 III 223 274 0 E1 P001 PP31 IBC02 F-A, S-J Category C 3186
3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 4.2 6.1 II 274 0 E2 P402 PP31 IBC02 F-A, S-J Category C 3187
3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 4.2 6.1 III 223 274 0 E1 P001 PP31 IBC02 F-A, S-J Category C 3187
3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 4.2 8 II 274 0 E2 P402 PP31 IBC02 F-A, S-J Category C 3188
3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 4.2 8 III 223 274 0 E1 P001 PP31 IBC02 F-A, S-J Category C 3188
3189 METAL POWDER, SELF-HEATING, N.O.S. 4.2 II 274 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-G, S-J Category C H1 SGG7 SGG15 SG26 Forms explosive mixtures with oxidizing substances. 3189
3189 METAL POWDER, SELF-HEATING, N.O.S. 4.2 III 223 274 0 E1 P002 LP02 PP31 L4 IBC08 B4 T1 TP33 F-G, S-J Category C H1 SGG7 SGG15 SG26 See entry above. 3189
3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 4.2 II 274 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J Category C Liable to self-heating or spontaneous combustion. 3190
3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 4.2 III 223 274 0 E1 P002 LP02 PP31 IBC08 B3 T1 TP33 F-A, S-J Category C See entry above. 3190
3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 6.1 II 274 0 E2 P410 IBC05 B21 T3 TP33 F-A, S-J Category C 3191
3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 6.1 III 223 274 0 E1 P002 IBC08 B3 T1 TP33 F-A, S-J Category C 3191
3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 4.2 8 II 274 0 E2 P410 IBC05 B21 T3 TP33 F-A, S-J Category C 3192
3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 4.2 8 III 274 0 E1 P002 IBC08 B3 T1 TP33 F-A, S-J Category C 3192
3194 PYROPHORIC LIQUID, INORGANIC, N.O.S. 4.2 I 274 0 E0 P400 F-G, S-M Category D H1 SG26 SG63 Highly flammable liquids, may ignite spontaneously in moist air. In contact with air, evolve irritating and slightly toxic fumes. 3194
3200 PYROPHORIC SOLID, INORGANIC, N.O.S. 4.2 I 274 0 E0 P404 PP31 T21 TP7 TP33 F-G, S-M Category D H1 SG26 Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. 3200
3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 4.2 II 183 274 0 E2 P410 PP31 IBC06 B21 T3 TP33 F-A, S-J Category B Free-flowing hygroscopic powders. Irritating to skin, eyes and mucous membranes. 3205
3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 4.2 III 183 223 274 0 E1 P002 LP02 PP31 IBC08 B3 T1 TP33 F-A, S-J Category B Free-flowing hygroscopic powders. Irritating to skin, eyes and mucous membranes. 3205
3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. 4.2 8 II 182 274 0 E2 P410 PP31 IBC05 B21 T3 TP33 F-A, S-J Category B SGG18 SG35 Free-flowing hygroscopic powder. Cause burns to skin, eyes and mucous membranes. 3206
3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. 4.2 8 III 182 223 274 0 E1 P002 PP31 IBC08 B3 T1 TP33 F-A, S-J Category B SGG18 SG35 See entry above. 3206
3208 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 I 274 0 E0 P403 PP31 IBC99 F-G, S-N Category E SW2 H1 SG26 3208
3208 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 II 274 500 g E2 P410 PP31 PP40 IBC07 B4 B21 T3 TP33 F-G, S-N Category E SW2 H1 SG26 3208
3208 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 III 223 274 1 kg E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category E SW2 H1 SG26 3208
3209 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. 4.3 4.2 I 274 0 E0 P403 PP31 F-G, S-N Category E SW2 H1 SG26 3209
3209 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. 4.3 4.2 II 274 0 E0 P410 PP31 PP40 IBC05 B21 T3 TP33 F-G, S-N Category E SW2 H1 SG26 3209
3209 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. 4.3 4.2 III 223 274 0 E1 P410 PP31 IBC08 B4 T1 TP33 F-G, S-N Category E SW2 H1 SG26 3209
3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 II 274 351 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category B SG38 SG49 SG62 When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium chlorate, aqueous solution is prohibited. 3210
3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 III 223 274 351 5 L E1 P504 IBC02 T4 TP1 F-H, S-Q Category B SG38 SG49 SG62 See entry above. 3210
3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category B SGG13 SG38 SG49 SG62 When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 3211
3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 III 223 5 L E1 P504 IBC02 T4 TP1 F-H, S-Q Category B SGG13 SG38 SG49 SG62 See entry above. 3211
3212 HYPOCHLORITES, INORGANIC, N.O.S. 5.1 II 274 349 900 903 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-H, S-Q Category D SW1 SW17 SGG8 SG35 SG38 SG49 SG53 SG60 Solids. Critical ambient temperature of decomposition may be as low as 60°C. May cause fire in contact with organic material or ammonium compounds. React with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. Transport of ammonium hypochlorite and mixtures of a hypochlorite with an ammonium salt is prohibited. 3212
3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 II 274 350 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category B SGG3 SG38 SG49 SG62 When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium bromate, aqueous solution is prohibited. 3213
3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 III 223 274 350 5 L E1 P504 IBC02 T4 TP1 F-H, S-Q Category B SGG3 SG38 SG49 SG62 See entry above. 3213
3214 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 II 274 353 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category D SGG14 SG38 SG49 SG60 SG62 When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium permanganate, aqueous solution is prohibited. 3214
3215 PERSULPHATES, INORGANIC, N.O.S. 5.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-Q Category A SG40 SG49 Solids. Solid mixtures with combustible material are sensitive to friction and are liable to ignite. React fiercely with cyanides when heated or by friction. May form explosive mixture with powdered metals or ammonium compounds. 3215
3216 PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 III 5 L E1 P504 IBC02 T4 TP1 TP29 F-A, S-Q Category A SG38 SG49 SG62 When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 3216
3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 II 270 1 L E2 P504 IBC02 T4 TP1 F-A, S-Q Category B SG38 SG49 SG62 When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 3218
3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 III 223 270 5 L E1 P504 IBC02 T4 TP1 F-A, S-Q Category B SG38 SG49 SG62 See entry above. 3218
3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 II 274 900 1 L E2 P504 IBC01 T4 TP1 F-A, S-Q Category B SGG12 SG38 SG49 SG62 When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium nitrites, aqueous solution is prohibited. 3219
3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 III 223 274 900 5 L E1 P504 IBC02 T4 TP1 F-A, S-Q Category B SGG12 SG38 SG49 SG62 See entry above. 3219
3220 PENTAFLUOROETHANE (REFRIGERANT GAS R 125) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable gas with a mild ether-like odour. Much heavier than air (4.2). 3220
3221 SELF-REACTIVE LIQUID TYPE B 4.1 See SP181 181 274 25 mL E0 P520 PP21 F-J, S-G Category D SW1 SG1 SG35 SG36 May explode at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3221
3222 SELF-REACTIVE SOLID TYPE B 4.1 See SP181 181 274 100 g E0 P520 PP21 F-J, S-G Category D SW1 SG1 SG35 SG36 May explode at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3222
3223 SELF-REACTIVE LIQUID TYPE C 4.1 274 25 mL E0 P520 PP21 PP94 PP95 F-J, S-G Category D SW1 SG35 SG36 May decompose violently at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3223
3224 SELF-REACTIVE SOLID TYPE C 4.1 274 100 g E0 P520 PP21 PP94 PP95 F-J, S-G Category D SW1 SG35 SG36 May decompose violently at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3224
3225 SELF-REACTIVE LIQUID TYPE D 4.1 274 125 mL E0 P520 F-J, S-G Category D SW1 SG35 SG36 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3225
3226 SELF-REACTIVE SOLID TYPE D 4.1 274 500 g E0 P520 F-J, S-G Category D SW1 SG35 SG36 Decomposes at elevated temperatures or in a fire. Burns vigorously. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Insoluble in water except: 4-(BENZYL(ETHYL)AMINO)−3-ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE 3-CHLORO−4-DIETHYLAMINOBENZENEDIAZONIUM ZINC CHLORIDE 4-DIPROPYLAMINOBENZENEDIAZONIUM ZINC CHLORIDE SODIUM 2-DIAZO−1-NAPHTHOL−4-SULPHONATE SODIUM 2-DIAZO−1-NAPHTHOL−5-SULPHONATE 3226
3227 SELF-REACTIVE LIQUID TYPE E 4.1 274 125 mL E0 P520 F-J, S-G Category D SW1 SG35 SG36 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3227
3228 SELF-REACTIVE SOLID TYPE E 4.1 274 500 g E0 P520 F-J, S-G Category D SW1 SG35 SG36 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3228
3229 SELF-REACTIVE LIQUID TYPE F 4.1 274 125 mL E0 P520 IBC99 T23 F-J, S-G Category D SW1 SG35 SG36 Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3229
3230 SELF-REACTIVE SOLID TYPE F 4.1 274 500 g E0 P520 IBC99 T23 F-J, S-G Category D SW1 SG35 SG36 Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3230
3231 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED 4.1 See SP181 181 194 274 923 0 E0 P520 PP21 F-F, S-K Category D SW1 SW3 SG1 SG35 SG36 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. 3231
3232 SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED 4.1 See SP181 181 194 274 923 0 E0 P520 PP21 F-F, S-K Category D SW1 SW3 SG1 SG35 SG36 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. 3232
3233 SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 PP21 F-F, S-K Category D SW1 SW3 SG35 SG36 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. 3233
3234 SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 PP21 F-F, S-K Category D SW1 SW3 SG35 SG36 May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water except: 3-METHYL−4-(PYRROLIDIN−1-YL)BENZENEDIAZONIUM TETRAFLUOROBORATE TETRAMINEPALLADIUM(II) NITRATE Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. 3234
3235 SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 F-F, S-K Category D SW1 SW3 SG35 SG36 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3235
3236 SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 F-F, S-K Category D SW1 SW3 SG35 SG36 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Soluble in water except: AZODICARBONAMIDE FORMULATION TYPE D 2,2’-AZODI(2,4-DIMETHYL−4-METHOXYVALERONITRILE) 2,2’-AZODI(2,4-DIMETHYLVALERONITRILE) 2,2’-AZODI(2-METHYLBUTYRONITRILE) -FORMYL−2-(NITROMETHYLENE)−1,3-PERHYDROTHIAZINE 4-NITROSOPHENOL Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. 3236
3237 SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 F-F, S-K Category D SW1 SW3 SG35 SG36 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. 3237
3238 SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 F-F, S-K Category D SW1 SW3 SG35 SG36 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. 3238
3239 SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 T23 F-F, S-K Category D SW1 SW3 SG35 SG36 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature must be checked regularly. 3239
3240 SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED 4.1 194 274 923 0 E0 P520 T23 F-F, S-K Category D SW1 SW3 SG35 SG36 Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature must be checked regularly. 3240
3241 2-BROMO−2-NITROPROPANE−1,3-DIOL 4.1 III 5 kg E1 P520 PP22 IBC08 B3 F-J, S-G Category C SW1 SW2 H2 H3 White crystals. Soluble in water. Decomposes when heated, evolving toxic gases. Sensitive to strong detonation shock. This substance shall be packed in accordance with packing method OP6 (see applicable packing instruction). 3241
3242 AZODICARBONAMIDE 4.1 II 215 500 g E0 P409 T3 TP33 F-J, S-G Category D SG17 SG35 SG36 Yellow or orange powder. Insoluble in water. Heat may cause exothermic decomposition, producing carbon monoxide (a toxic and flammable gas) and nitrogen. May explode if involved in a fire under confined conditions. Addition of activators (e.g. zinc compounds) may result in a decrease of thermal stability and/or a change in explosive properties. 3242
3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. 6.1 II 217 274 500 g E4 P002 PP9 IBC02 T3 BK2 TP33 F-A, S-A Category B SW2 Mixtures of non-dangerous solids (such as soil, sand, production materials, etc.) and toxic liquids. Toxic if swallowed, by skin contact or by inhalation. 3243
3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. 8 II 218 274 1 kg E2 P002 PP9 IBC05 T3 BK2 TP33 F-A, S-B Category B SW2 Mixtures of non-dangerous solids (such as soil, sand, production materials, etc.) and corrosive liquids. Cause burns to skin, eyes and mucous membranes. 3244
3245 GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED ORGANISMS 9 219 0 E0 P904 IBC99 F-A, S-T SW7 SG50 3245
3246 METHANESULPHONYL CHLORIDE 6.1 8 I 354 0 E0 P602 T20 TP2 TP13 F-A, S-B Category D SW2 SGG1 SG36 SG49 Pale yellow liquid. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3246
3247 SODIUM PEROXOBORATE, ANHYDROUS 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-Q Category A SW1 H1 Yellowish, odourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. 3247
3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 6.1 II 220 221 1 L E2 P001 F-E, S-D Category B SW2 Toxic if swallowed, by skin contact or by inhalation. 3248
3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 6.1 III 220 221 223 5 L E1 P001 F-E, S-D Category A See entry above. 3248
3249 MEDICINE, SOLID, TOXIC, N.O.S. 6.1 II 221 500 g E4 P002 T3 TP33 F-A, S-A Category C SW2 Toxic if swallowed, by skin contact or by dust inhalation. 3249
3249 MEDICINE, SOLID, TOXIC, N.O.S. 6.1 III 221 223 5 kg E1 P002 LP02 T1 TP33 F-A, S-A Category C SW2 See entry above. 3249
3250 CHLOROACETIC ACID, MOLTEN 6.1 8 II 0 E0 T7 TP3 TP28 F-A, S-B Category C SW2 SGG1 SG36 SG49 Molten liquid. Melting point may be as low as 50°C. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3250
3251 ISOSORBIDE−5-MONONITRATE 4.1 III 226 5 kg E0 P409 F-F, S-G Category D SW1 SW2 H2 H3 May explode if involved in a fire under confined conditions. Sensitive to strong detonation shock. 3251
3252 DIFLUOROMETHANE (REFRIGERANT GAS R 32) 2.1 0 E0 P200 T50 F-D, S-U Category D SW2 Flammable colourless gas. Heavier than air (1.8). 3252
3253 DISODIUM TRIOXOSILICATE 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG18 SG35 Colourless hygroscopic solid. Dangerous reaction with oxidizers. In the presence of moisture, reacts with aluminium, zinc, tin and their compounds, evolving hydrogen, a flammable gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 3253
3254 TRIBUTYLPHOSPHANE 4.2 I 0 E0 P400 T21 TP2 TP7 F-A, S-M Category D SG44 Colourless yellowish liquid. Insoluble in water. Strong garlic odour (phosphine). Liable to heat and ignite spontaneously in air. If involved in a fire, evolves phosphine, a flammable and highly toxic gas. Reacts violently with oxidizing substances (peroxides, halogens, nitric oxides and carbon tetrachloride). Irritating to mucous membranes. 3254
3255 -BUTYL HYPOCHLORITE 4.2 8 I 976 0 E0 P099 F-A, S-M Category D SGG8 Volatile flammable slightly yellow liquid with a pungent odour. Immiscible with water. Boiling point: 77°C to 79°C. Flashpoint between −15°C and −10°C. Exposure to light causes immediate dangerous decomposition. Causes burns to skin, eyes and mucous membranes. 3255
3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60°C, at or above its flashpoint 3 III 274 0 E0 P099 IBC01 T3 TP3 TP29 F-E, S-D Category A 3256
3257 ELEVATED TEMPERATURE LIQUID, N.O.S. at or above 100°C and below its flashpoint (including molten metals, molten salts, etc.) 9 III 232 274 0 E0 P099 IBC01 T3 TP3 TP29 F-A, S-P Category A SW5 Any liquid which is transported at or above 100°C but below its flashpoint. May cause fire if in contact with combustible material due to extreme temperature. 3257
3258 ELEVATED TEMPERATURE SOLID, N.O.S. at or above 240°C 9 III 232 274 0 E0 P099 F-A, S-P Category A SW5 Any solid which is transported at or above 240°C. May cause fire if in contact with combustible material due to extreme temperature. 3258
3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 8 I 274 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B Category A SGG18 SG35 Colourless to yellowish solids with a pungent odour. Miscible with or soluble in water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. Cause burns to skin, eyes and mucous membranes. React violently with acids. 3259
3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 8 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category A SGG18 SG35 See entry above. 3259
3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 8 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG18 SG35 See entry above. 3259
3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 I 274 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B Category B SGG1 SG36 SG49 Causes burns to skin, eyes and mucous membranes. 3260
3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category B SGG1 SG36 SG49 See entry above. 3260
3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG1 SG36 SG49 See entry above. 3260
3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 8 I 274 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B Category B SGG1 SG36 SG49 Causes burns to skin, eyes and mucous membranes. 3261
3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 8 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category B SGG1 SG36 SG49 See entry above. 3261
3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 8 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG1 SG36 SG49 See entry above. 3261
3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 I 274 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B Category B SGG18 SG35 Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. 3262
3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category B SGG18 SG35 See entry above. 3262
3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG18 SG35 See entry above. 3262
3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 I 274 0 E0 P002 IBC07 B1 T6 TP33 F-A, S-B Category B SGG18 SG35 Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. 3263
3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 II 274 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category B SGG18 SG35 See entry above. 3263
3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG18 SG35 See entry above. 3263
3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 I 274 0 E0 P001 T14 TP2 TP7 F-A, S-B Category B SW2 SGG1 SG36 SG49 Causes burns to skin, eyes and mucous membranes. 3264
3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B Category B SW2 SGG1 SG36 SG49 See entry above. 3264
3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B Category A SW2 SGG1 SG36 SG49 See entry above. 3264
3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 I 274 0 E0 P001 T14 TP2 TP7 F-A, S-B Category B SW2 SGG1 SG36 SG49 Causes burns to skin, eyes and mucous membranes. 3265
3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B Category B SW2 SGG1 SG36 SG49 See entry above. 3265
3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B Category A SW2 SGG1 SG36 SG49 See entry above. 3265
3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 I 274 0 E0 P001 T14 TP2 TP7 F-A, S-B Category B SW2 SGG18 SG35 Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. 3266
3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B Category B SW2 SGG18 SG35 See entry above. 3266
3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B Category A SW2 SGG18 SG35 See entry above. 3266
3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 I 274 0 E0 P001 T14 TP2 TP7 F-A, S-B Category B SW2 SGG18 SG35 Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. 3267
3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 II 274 1 L E2 P001 IBC02 T11 TP2 TP7 F-A, S-B Category B SW2 SGG18 SG35 See entry above. 3267
3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-B Category A SW2 SGG18 SG35 See entry above. 3267
3268 SAFETY DEVICES, electrically initiated 9 280 289 0 E0 P902 LP902 F-B, S-X Category A 3268
3269 POLYESTER RESIN KIT, liquid base material 3 II 236 340 5 L See SP340 P302 F-E, S-D Category B Polyester resin kits consist of two components: a base material (flammable liquid) and an activator (organic peroxide), each separately packed in an inner packaging. 3269
3269 POLYESTER RESIN KIT, liquid base material 3 III 236 340 5 L See SP340 P302 F-E, S-D Category A See entry above. 3269
3270 NITROCELLULOSE MEMBRANE FILTERS with not more than 12.6% nitrogen, by dry mass 4.1 II 237 286 403 1 kg E2 P411 F-A, S-I Category D Filters may be small round pieces or large sheets. When involved in a fire, evolve toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Burn rapidly with intense heat radiation. 3270
3271 ETHERS, N.O.S. 3 II 274 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-D Category B 3271
3271 ETHERS, N.O.S. 3 III 223 274 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D Category A 3271
3272 ESTERS, N.O.S. 3 II 274 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-D Category B 3272
3272 ESTERS, N.O.S. 3 III 223 274 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D Category A 3272
3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3 6.1 I 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category E SW2 SG35 Liquids evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. 3273
3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3 6.1 II 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 SG35 See entry above. 3273
3274 ALCOHOLATES SOLUTION, N.O.S. in alcohol 3 8 II 274 1 L E2 P001 IBC02 F-E, S-C Category B SGG18 SG35 Colourless solution. Reacts violently with water. Causes burns to skin, eyes and mucous membranes. 3274
3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 6.1 3 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 SG35 Flammable liquids, evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 3275
3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 6.1 3 II 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 SG35 See entry above. 3275
3276 NITRILES, LIQUID, TOXIC, N.O.S. 6.1 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SG35 Liquids, evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. 3276
3276 NITRILES, LIQUID, TOXIC, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B SG35 See entry above. 3276
3276 NITRILES, LIQUID, TOXIC, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category A SG35 See entry above. 3276
3277 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 6.1 8 II 274 100 mL E4 P001 IBC02 T8 TP2 TP13 TP28 F-A, S-B Category A SW1 SW2 H1 H2 SGG1 SG36 SG49 React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 3277
3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 I 43 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3278
3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 II 43 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B See entry above. 3278
3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 III 43 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category A See entry above. 3278
3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 6.1 3 I 43 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 A wide variety of toxic flammable liquids. Toxic if swallowed, by skin contact or by inhalation. 3279
3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 6.1 3 II 43 274 100 mL E4 P001 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3279
3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 6.1 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3280
3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B See entry above. 3280
3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category A See entry above. 3280
3281 METAL CARBONYLS, LIQUID, N.O.S. 6.1 I 274 315 0 E5 P601 T14 TP2 TP13 TP27 F-A, S-A Category D SW2 A range of metal carbonyls which, when heated, can give off carbon monoxide, a toxic gas. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 3281
3281 METAL CARBONYLS, LIQUID, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B SW2 A range of metal carbonyls which, when heated, can give off carbon monoxide, a toxic gas. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. 3281
3281 METAL CARBONYLS, LIQUID, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category B SW2 See entry above. 3281
3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 I 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3282
3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B See entry above. 3282
3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category A See entry above. 3282
3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3283
3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3283
3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3283
3284 TELLURIUM COMPOUND, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3284
3284 TELLURIUM COMPOUND, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3284
3284 TELLURIUM COMPOUND, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3284
3285 VANADIUM COMPOUND, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3285
3285 VANADIUM COMPOUND, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3285
3285 VANADIUM COMPOUND, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3285
3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. 3 6.1/8 I 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-C Category E SW2 SG5 SG8 Flammable, toxic, corrosive liquid. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3286
3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. 3 6.1/8 II 274 1 L E2 P001 IBC99 T11 TP2 TP13 TP27 F-E, S-C Category B SW2 SG5 SG8 See entry above. 3286
3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Toxic if swallowed, by skin contact or by inhalation. 3287
3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B SW2 See entry above. 3287
3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 III 223 274 5 L E1 P001 LP01 IBC03 T7 TP1 TP28 F-A, S-A Category A SW2 See entry above. 3287
3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 I 274 0 E5 P002 IBC99 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3288
3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3288
3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3288
3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 6.1 8 I 274 315 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-B Category B SW2 Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3289
3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 6.1 8 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-B Category B SW2 See entry above. 3289
3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1 8 I 274 0 E5 P002 IBC99 T6 TP33 F-A, S-B Category B SW2 Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3290
3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1 8 II 274 500 g E4 P002 IBC06 B21 T3 TP33 F-A, S-B Category B SW2 See entry above. 3290
3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. 6.2 0 E0 P621 LP621 IBC620 BK2 F-A, S-T SW28 Derived from the medical treatment of animals, humans or from bio-research. 3291
3292 BATTERIES, CONTAINING METALLIC SODIUM OR SODIUM ALLOY or CELLS, CONTAINING METALLIC SODIUM OR SODIUM ALLOY 4.3 239 401 0 E0 P408 F-G, S-P Category A H1 SG26 Series of hermetically sealed metal cells containing sodium, electrically connected and secured within a metal casing. “Cold” batteries (batteries containing elemental sodium only in the solid state) are electrically inert. Batteries are activated by heating to between 300°C and 350°C before operating to produce electricity. Activated batteries (i.e. “hot” batteries containing liquid elemental sodium) may cause fire through short-circuit of the terminals. Batteries or cells should not be offered for transport at a temperature such that liquid elemental sodium is present in the battery or cell unless approved, and under conditions of transport established by the competent authority. 3292
3293 HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SGG18 SG35 Colourless liquid. Reacts violently with acids. Toxic if swallowed, by skin contact or by inhalation. 3293
3294 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide 6.1 3 I 900 0 E0 P601 T14 TP2 TP13 F-E, S-D Category D SW2 Flammable solution, evolving extremely toxic flammable vapours. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Transport of HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with more than 45% hydrogen cyanide is prohibited. 3294
3295 HYDROCARBONS, LIQUID, N.O.S. 3 I 500 mL E3 P001 T11 TP1 TP8 TP28 F-E, S-D Category E Immiscible with water. 3295
3295 HYDROCARBONS, LIQUID, N.O.S. 3 II 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-D Category B See entry above. 3295
3295 HYDROCARBONS, LIQUID, N.O.S. 3 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D Category A See entry above. 3295
3296 HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) 2.2 120 mL E1 P200 T50 F-C, S-V Category A Non-flammable compressed gas. Heavier than air (1.4). 3296
3297 ETHYLENE OXIDE AND CHLOROTETRAFLUORO-ETHANE MIXTURE with not more than 8.8% ethylene oxide 2.2 392 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable, colourless gas with an ether-like odour. Much heavier than air. 3297
3298 ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide 2.2 392 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable, colourless gas with an ether-like odour. Much heavier than air. 3298
3299 ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide 2.2 392 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable, colourless gas with an ether-like odour. Much heavier than air. 3299
3300 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide 2.3 2.1 0 E0 P200 F-D, S-U Category D SW2 Liquefied, flammable, toxic colourless gas with an ether-like odour. Heavier than air (1.5). 3300
3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. 8 4.2 I 274 0 E0 P001 F-A, S-J Category D Causes burns to skin, eyes and mucous membranes. 3301
3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. 8 4.2 II 274 0 E2 P001 F-A, S-J Category D See entry above. 3301
3302 2-DIMETHYLAMINOETHYL ACRYLATE, STABILIZED 6.1 II 386 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category D SW1 Colourless to light yellow liquid. Acrid odour. Miscible with water. Causes tears. Stabilized with hydroquinone derivatives. Hydrolyses in water to give off acrylic acid and dimethylaminoethanol. Toxic if swallowed, by skin contact or by inhalation. 3302
3303 COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. 2.3 5.1 274 0 E0 P200 F-C, S-W Category D SW2 3303
3304 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 2.3 8 274 0 E0 P200 F-C, S-U Category D SW2 3304
3305 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2.3 2.1/8 274 0 E0 P200 F-D, S-U Category D SW2 SG4 SG9 3305
3306 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2.3 5.1/8 274 0 E0 P200 F-C, S-W Category D SW2 SG6 SG19 3306
3307 LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. 2.3 5.1 274 0 E0 P200 F-C, S-W Category D SW2 3307
3308 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 2.3 8 274 0 E0 P200 F-C, S-U Category D SW2 3308
3309 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2.3 2.1/8 274 0 E0 P200 F-D, S-U Category D SW2 SG4 SG9 3309
3310 LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2.3 5.1/8 274 0 E0 P200 F-C, S-W Category D SW2 SG6 SG19 3310
3311 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 2.2 5.1 274 0 E0 P203 T75 TP5 TP22 F-C, S-W Category D 3311
3312 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 2.1 274 0 E0 P203 T75 TP5 F-D, S-U Category D SW2 3312
3313 ORGANIC PIGMENTS, SELF-HEATING 4.2 II 0 E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-J Category C Self-heating coloured powder or granules. Odourless. Liable to self-heating or spontaneous combustion. 3313
3313 ORGANIC PIGMENTS, SELF-HEATING 4.2 III 223 0 E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-J Category C See entry above. 3313
3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form, evolving flammable vapour 9 III 207 965 5 kg E1 P002 PP14 IBC08 B3 B6 F-A, S-I Category E SW1 SW6 SG5 SG14 A moulding material consisting predominantly of polystyrene, poly(methyl methacrylate) or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predominantly pentane. During storage, a small proportion of this pentane is released to the atmosphere; this proportion increases at elevated temperatures. 3314
3315 CHEMICAL SAMPLE, TOXIC 6.1 I 250 0 E0 P099 F-A, S-A Category D SW2 This entry may only be used for samples of chemicals taken for analysis in connection with the implementation of the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction. The transport of substances under this entry shall be in accordance with the chain of custody and security procedures specified by the Organization for the Prohibition of Chemical Weapons. The chemical sample may only be transported providing prior approval has been granted by the competent authority or the Director General of the Organization for the Prohibition of Chemical Weapons. During transport, the packaging shall be accompanied by a copy of the document of approval for transport, showing the quantity limitations and the packing requirements. 3315
3316 CHEMICAL KIT or FIRST AID KIT 9 251 340 See SP251 See SP340 P901 F-A, S-P Category A 3316
3317 2-AMINO−4,6-DINITROPHENOL, WETTED with not less than 20% water, by mass 4.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category D SG7 SG30 Desensitized explosive. Red crystals. Insoluble in water. Explosive in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Harmful if swallowed or by skin contact. 3317
3318 AMMONIA SOLUTION, relative density less than 0.880 at 15°C in water, with more than 50% ammonia 2.3 8 23 0 E0 P200 T50 F-C, S-U Category D SW2 SGG18 SG35 SG46 Highly concentrated solution in water of a non-flammable, toxic and corrosive gas with a pungent odour. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. Reacts violently with acids. Highly irritating to skin, eyes and mucous membranes. Suffocating in low concentrations. 3318
3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass 4.1 II 28 272 274 0 E0 P099 F-B, S-J Category E Desensitized explosive with lactose, glucose or cellulose. White solid. Soluble in water. When involved in a fire, the nitroglycerin may accumulate and may produce an explosion. Contact with water may dissolve the desensitizer (lactose or glucose), causing migration and accumulation of the nitroglycerin, which may explode. Nitroglycerin is more dense than water. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Inhalation of vapours may cause headaches, dizziness and fainting. 3319
3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION with not more than 12% sodium borohydride and not more than 40% sodium hydroxide, by mass 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category A SGG18 SG35 Off-white clear liquid with a slight hydrocarbon odour. Reacts violently with acids. In contact with acids or if diluted with large amount of water, evolves hydrogen gas and heat. Causes burns to skin, eyes and mucous membranes. 3320
3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION with not more than 12% sodium borohydride and not more than 40% sodium hydroxide, by mass 8 III 223 5 L E1 P001 LP01 IBC03 T4 TP2 F-A, S-B Category A SGG18 SG35 See entry above. 3320
3321 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 T5 TP4 F-I, S-S Category A SW20 SW21 See 1.5.1. 3321
3322 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 T5 TP4 F-I, S-S Category A SW21 See 1.5.1. 3322
3323 RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted 7 See SP172 172 317 325 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 3323
3324 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 SW20 SW21 See 1.5.1. 3324
3325 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 SW21 See 1.5.1. 3325
3326 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. 3326
3327 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 SW20 SW21 See 1.5.1. 3327
3328 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 3328
3329 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 3329
3330 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 3330
3331 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE 7 See SP172 172 326 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW13 See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. 3331
3332 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissile-excepted 7 See SP172 172 317 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A See 1.5.1. 3332
3333 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE 7 See SP172 172 0 E0 See 4.1.9 See 4.1.9 See 4.1.9 See 4.1.9 F-I, S-S Category A SW12 See 1.5.1. 3333
3334 AVIATION REGULATED LIQUID, N.O.S. 9 960 Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. 3334
3335 AVIATION REGULATED SOLID, N.O.S. 9 960 Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. 3335
3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. 3 I 274 0 E0 P001 T11 TP2 F-E, S-D Category E SG50 SG57 Colourless to yellow liquids with a garlic odour. Immiscible with water. 3336
3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. 3 II 274 1 L E2 P001 IBC02 T7 TP1 TP8 TP28 F-E, S-D Category B SG50 SG57 See entry above. 3336
3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. 3 III 223 274 5 L E1 P001 LP01 IBC03 T4 TP1 TP29 F-E, S-D Category B SG50 SG57 See entry above. 3336
3337 REFRIGERANT GAS R 404A 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.06). Very high exposures may cause anaesthetic effects and asphyxiation. 3337
3338 REFRIGERANT GAS R 407A 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.17). Very high exposures may cause anaesthetic effects and asphyxiation. 3338
3339 REFRIGERANT GAS R 407B 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.19). Very high exposures may cause anaesthetic effects and asphyxiation. 3339
3340 REFRIGERANT GAS R 407 C 2.2 120 mL E1 P200 T50 F-C, S-V Category A Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.16). Very high exposures may cause anaesthetic effects and asphyxiation. 3340
3341 THIOUREA DIOXIDE 4.2 II 0 E2 P002 PP31 IBC06 B21 T3 TP33 F-A, S-J Category D White to yellow-white crystalline powder. Virtually odourless. Strong reducing agent. Violent exothermic decomposition above 100°C with emission of large amounts of sulphur oxides, ammonia, carbon monoxide, carbon dioxide, nitrogen oxides and hydrogen sulphide. Extended exposure to temperatures above 50°C and moisture may cause visible decomposition. Dust irritating to skin, eyes and mucous membranes. 3341
3341 THIOUREA DIOXIDE 4.2 III 223 0 E1 P002 LP02 PP31 IBC08 B3 T1 TP33 F-A, S-J Category D See entry above. 3341
3342 XANTHATES 4.2 II 0 E2 P002 PP31 IBC06 B21 T3 TP33 F-A, S-J Category D SW2 Hygroscopic yellow powder with an unpleasant odour. On contact with moisture, evolves highly flammable vapours such as carbon disulphide (UN 1131, which has a flashpoint of −30°C c.c. and a very low ignition temperature of 100°C). When confined, can cause an explosion due to the wide explosive limits of the vapours. Finely divided dust forms explosive mixtures in air. Care should be taken when opening cargo transport units in case carbon disulphide vapours are present. 3342
3342 XANTHATES 4.2 III 223 0 E1 P002 LP02 PP31 IBC08 B3 T1 TP33 F-A, S-J Category D SW2 See entry above. 3342
3343 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass 3 28 274 278 0 E0 P099 F-E, S-Y Category D 3343
3344 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass 4.1 II 28 272 274 0 E0 P406 PP26 PP80 F-B, S-J Category E 3344
3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 3345
3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 3345
3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B21 T1 TP33 F-A, S-A Category A SW2 See entry above. 3345
3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Pesticides frequently containing petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3346
3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3346
3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3347
3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3347
3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 3347
3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3348
3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B SW2 See entry above. 3348
3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3348
3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 I 61 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category A SW2 Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. 3349
3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 II 61 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 See entry above. 3349
3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 III 61 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SW2 See entry above. 3349
3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 I 61 274 0 E0 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3350
3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3 6.1 II 61 274 1 L E2 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3350
3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-E, S-D Category B SW2 They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3351
3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP13 TP27 F-E, S-D Category B SW2 See entry above. 3351
3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C 6.1 3 III 61 223 274 5 L E1 P001 IBC03 T7 TP2 TP28 F-E, S-D Category A SW2 See entry above. 3351
3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 I 61 274 0 E5 P001 T14 TP2 TP13 TP27 F-A, S-A Category B SW2 Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. 3352
3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 II 61 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B SW2 See entry above. 3352
3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 III 61 223 274 5 L E1 P001 LP01 IBC03 T7 TP2 TP28 F-A, S-A Category A SW2 See entry above. 3352
3354 INSECTICIDE GAS, FLAMMABLE, N.O.S. 2.1 274 0 E0 P200 F-D, S-U Category D Flammable mixtures of insecticides with liquefied gases. 3354
3355 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 2.1 274 0 E0 P200 F-D, S-U Category D SW2 Toxic, flammable mixtures of insecticides with liquefied gases. 3355
3356 OXYGEN GENERATOR, CHEMICAL 5.1 284 0 E0 P500 F-H, S-Q Category D Oxygen generators, chemical are devices containing chemicals which, upon activation, release oxygen as a product of chemical reaction. Chemical oxygen generators are used for the generation of oxygen for respiratory support, e.g. in aircraft, submarines, spacecraft, bomb shelters and breathing apparatus. Oxidizing salts such as chlorates and perchlorates of lithium, sodium and potassium, which are used in chemical oxygen generators, evolve oxygen when heated. These salts are mixed (compounded) with a fuel, usually iron powder, to form a chlorate candle, which produces oxygen by continuous reaction. The fuel is used to generate heat by oxidation. Once the reaction begins, oxygen is released from the hot salt by thermal decomposition (a thermal shield is used around the generator). A portion of the oxygen reacts with the fuel to produce more heat, which produces more oxygen, and so on. Initiation of the reaction can be achieved by a percussion device, friction device or electric wire. 3356
3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass 3 II 28 274 288 0 E0 P099 F-E, S-Y Category D 3357
3358 REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas 2.1 291 0 E0 P003 PP32 F-D, S-U Category D 3358
3359 FUMIGATED CARGO TRANSPORT UNIT 9 302 0 E0 F-A, S-D Category B SW2 A ‘FUMIGATED CARGO TRANSPORT UNIT’ is a closed cargo transport unit containing goods or materials that either are or have been fumigated within the unit. The fumigant gases used are either poisonous or asphyxiant. The gases are usually evolved from solid or liquid preparations distributed within the unit. See also 5.5.2. 3359
3360 FIBRES, VEGETABLE, DRY 4.1 29 123 299 973 0 E0 P003 PP19 F-A, S-I Category A Ignite readily. Consignments of cotton, dry having a density not less than 360 kg/m, flax, dry having a density not less than 400 kg/m, sisal, dry having a density not less than 360 kg/m (ISO Standard 8115 (1986)) and tampico fibre, dry having a density not less than 360 kg/m³ are not subject to the provisions of this Code when carried in closed cargo transport units. 3360
3361 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 6.1 8 II 274 0 E0 P010 T14 TP2 TP7 TP13 TP27 F-A, S-B Category C SW2 SGG1 SG36 SG49 Colourless to yellow liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 3361
3362 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 6.1 3/8 II 274 0 E0 P010 T14 TP2 TP7 TP13 TP27 F-E, S-C Category C SW2 SGG1 SG5 SG8 SG36 SG49 Colourless to yellow flammable liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 3362
3363 DANGEROUS GOODS IN ARTICLES or DANGEROUS GOODS IN MACHINERY or DANGEROUS GOODS IN APPARATUS 9 301 See SP301 E0 P907 F-A, S-P Category A Types of articles transported under this entry contain only limited quantities of dangerous goods. 3363
3364 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP24 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 3364
3365 TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP24 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Explosive and sensitive to shock and heat in the dry state. Reacts violently with heavy metals and their salts. 3365
3366 TRINITROTOLUENE (TNT), WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP24 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Reacts violently with heavy metals and their salts. 3366
3367 TRINITROBENZENE, WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP24 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of odourless yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Harmful if swallowed or by skin contact. Reacts violently with heavy metals and their salts. 3367
3368 TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP24 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Harmful if swallowed or by skin contact. Reacts violently with heavy metals and their salts. 3368
3369 SODIUM DINITRO--CRESOLATE, WETTED with not less than 10% water, by mass 4.1 6.1 I 28 0 E0 P406 PP24 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Substance in pure form consists of yellow powder. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. Toxic if swallowed, by skin contact or by inhalation. 3369
3370 UREA NITRATE, WETTED with not less than 10% water, by mass 4.1 I 28 0 E0 P406 PP31 PP78 F-B, S-J Category E SG7 SG30 Desensitized explosive. May form extremely sensitive compounds with heavy metals or their salts. Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. 3370
3371 2-METHYLBUTANAL 3 II 1 L E2 P001 IBC02 T4 TP1 F-E, S-D Category B Colourless liquid. Flashpoint: −3.5°C. Explosive limits: 1.3 to 13.9%. Slightly miscible with water. 3371
3373 BIOLOGICAL SUBSTANCE, CATEGORY B 6.2 319 341 0 E0 P650 T1 BK2 TP1 F-A, S-T Category C SW2 SW18 Substances which are known or are reasonably expected to contain pathogens, transported in a form that, when exposure to it occurs, are not capable of causing permanent disability, life-threatening or fatal disease to humans or animals. Human or animal specimens for which there is minimal likelihood that pathogens are present are not subject to the provisions of this Code (see 2.6.3.2.3.6). Other exemptions are stated in 2.6.3.2.3. 3373
3374 ACETYLENE, SOLVENT FREE 2.1 0 E0 P200 F-D, S-U Category D SW1 SW2 SG46 Flammable gas with slight odour. Explosive limits: 2.1 to 80%. Lighter than air (0.907). Acetylene without solvent. Rough handling and exposure to local heating should be avoided, since these conditions may result in delayed explosion. Empty cylinders should be carried with the same precautions as filled cylinders. 3374
3375 AMMONIUM NITRATE EMULSION or SUSPENSION or GEL, intermediate for blasting explosives 5.1 II 309 0 E2 P505 IBC02 B16 T1 TP1 TP9 TP17 TP32 F-H, S-Q Category D SW1 SGG2 SG16 SG42 SG45 SG47 SG48 SG51 SG56 SG58 SG59 SG61 Non-sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. Substances shall satisfactorily pass test series 8 of the , part I, section 18 and be approved by the competent authority. 3375
3376 4-NITROPHENYLHYDRAZINE, with not less than 30% water, by mass 4.1 I 28 0 E0 P406 PP26 PP31 F-B, S-J Category E SG7 SG30 Desensitized explosive. Dark orange solid. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. 3376
3377 SODIUM PERBORATE MONOHYDRATE 5.1 III 967 5 kg E1 P002 LP02 IBC08 B3 T1 BK2 BK3 TP33 F-A, S-Q Category A SW1 SW23 H1 SGG16 SG59 White crystals or powder. Partially soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Risk of decomposition when exposed to continuous heat (exothermic decomposition ≥ 60°C). When involved in a fire or exposed to high temperatures, it may decompose, yielding oxygen and steam. Harmful if swallowed. 3377
3378 SODIUM CARBONATE PEROXYHYDRATE 5.1 II 1 kg E2 P002 IBC08 B4 B21 T3 BK2 TP33 F-A, S-Q Category A SW1 H1 SGG16 SG59 White crystals or powder. Soluble in water. Mixtures with combustible material are readily ignited. Decomposes in contact with water and acids, forming hydrogen peroxide. Risk of decomposition when exposed to continuous heat (exothermic decomposition ≥ 60°C). When involved in a fire or exposed to high temperatures, it may decompose, yielding oxygen and steam. Irritating to eyes, skin and mucous membranes. Harmful if swallowed. 3378
3378 SODIUM CARBONATE PEROXYHYDRATE 5.1 III 967 5 kg E1 P002 LP02 IBC08 B21 T1 BK2 BK3 TP33 F-A, S-Q Category A SW1 SW23 H1 SGG16 SG59 See entry above. 3378
3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. 3 I 274 311 0 E0 P099 F-E, S-Y Category D SG30 Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. 3379
3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. 4.1 I 274 311 394 0 E0 P099 F-B, S-J Category D SG7 SG30 Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. 3380
3381 TOXIC BY INHALATION LIQUID, N.O.S. with an LC lower than or equal to 200 mL/m and saturated vapour concentration greater than or equal to 500 LC 6.1 I 274 0 E0 P601 T22 TP2 TP13 F-A, S-A Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. 3381
3382 TOXIC BY INHALATION LIQUID, N.O.S. with an LC lower than or equal to 1000 m L/m and saturated vapour concentration greater than or equal to 10 LC 6.1 I 274 0 E0 P602 T20 TP2 TP13 F-A, S-A Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. 3382
3383 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC lower than or equal to 200 mL/m and saturated vapour concentration greater than or equal to 500 LC 6.1 3 I 274 0 E0 P601 T22 TP2 TP13 F-E, S-D Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable. Highly toxic if swallowed, by skin contact or by inhalation. 3383
3384 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC lower than or equal to 1000 mL/m and saturated vapour concentration greater than or equal to 10 LC 6.1 3 I 274 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable. Highly toxic if swallowed, by skin contact or by inhalation. 3384
3385 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC lower than or equal to 200 mL/m and saturated vapour concentration greater than or equal to 500 LC 6.1 4.3 I 274 0 E0 P601 T22 TP2 TP13 F-G, S-N Category D SW2 H1 SG26 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive. Highly toxic if swallowed, by skin contact or by inhalation. 3385
3 386 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC lower than or equal to 1000 mL/m and saturated vapour concentration greater than or equal to 10 LC 6.1 4.3 I 274 0 E0 P602 T20 TP2 TP13 F-G, S-N Category D SW2 H1 SG26 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive. Highly toxic if swallowed, by skin contact or by inhalation. 3 386
3387 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC lower than or equal to 200 mL/m and saturated vapour concentration greater than or equal to 500 LC 6.1 5.1 I 274 0 E0 P601 T22 TP2 TP13 F-A, S-Q Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being an oxidizer. Highly toxic if swallowed, by skin contact or by inhalation. 3387
3388 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC lower than or equal to 1000 mL/m and saturated vapour concentration greater than or equal to 10 LC 6.1 5.1 I 274 0 E0 P602 T20 TP2 TP13 F-A, S-Q Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being an oxidizer. Highly toxic if swallowed, by skin contact or by inhalation. 3388
3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC lower than or equal to 200 mL/m and saturated vapour concentration greater than or equal to 500 LC 6.1 8 I 274 0 E0 P601 T22 TP2 TP13 F-A, S-B Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being corrosive. Highly toxic if swallowed, by skin contact or by inhalation. 3389
3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC lower than or equal to 1000 mL/m and saturated vapour concentration greater than or equal to 10 LC 6.1 8 I 274 0 E0 P602 T20 TP2 TP13 F-A, S-B Category D SW2 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being corrosive. Highly toxic if swallowed, by skin contact or by inhalation. 3390
3391 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC 4.2 I 274 0 E0 P404 PP86 T21 TP7 TP33 TP36 F-G, S-M Category D H1 SG26 SG72 Liable to ignite spontaneously in air. If shaken, may produce sparks. 3391
3392 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC 4.2 I 274 0 E0 P400 PP86 T21 TP2 TP7 TP36 F-G, S-M Category D H1 SG26 SG63 SG72 Highly flammable liquid. Liable to ignite spontaneously in air. In contact with air, evolve irritating and slightly toxic fumes. 3392
3393 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER-REACTIVE 4.2 4.3 I 274 0 E0 P404 PP86 T21 TP7 TP33 TP36 TP41 F-G, S-M Category D H1 SG26 SG35 SG72 Liable to ignite spontaneously in air. If shaken, may produce sparks. React violently with moisture, water and acids, evolving flammable gas. 3393
3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE 4.2 4.3 I 274 0 E0 P400 PP86 T21 TP2 TP7 TP36 TP41 F-G, S-M Category D H1 SG26 SG35 SG63 SG72 Highly flammable liquid. Liable to ignite spontaneously in air. In contact with air, evolve irritating and slightly toxic fumes. React violently with moisture, water and acids, evolving flammable gas. 3394
3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE 4.3 I 274 0 E0 P403 PP31 T9 TP7 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 Reacts violently with moisture, water and acids, evolving flammable gas. 3395
3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE 4.3 II 274 500 g E2 P410 PP31 IBC04 T3 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3395
3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE 4.3 III 223 274 1 kg E1 P410 PP31 IBC06 T1 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3395
3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE 4.3 4.1 I 274 0 E0 P403 PP31 T9 TP7 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 Flammable solid. Reacts violently with moisture, water and acids, evolving flammable gas. 3396
3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE 4.3 4.1 II 274 500 g E2 P410 PP31 IBC04 T3 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3396
3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE 4.3 4.1 III 223 274 1 kg E1 P410 PP31 IBC06 T1 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3396
3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING 4.3 4.2 I 274 0 E0 P403 PP31 T9 TP7 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 Liable to self-heating or spontaneous combustion. Reacts violently with moisture, water and acids, evolving flammable gas. 3397
3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING 4.3 4.2 II 274 500 g E2 P410 PP31 IBC04 T3 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3397
3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING 4.3 4.2 III 223 274 1 kg E1 P410 PP31 IBC06 T1 TP33 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3397
3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE 4.3 I 274 0 E0 P402 PP31 T13 TP2 TP7 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 Reacts violently with moisture, water and acids, evolving flammable gas. 3398
3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE 4.3 II 274 500 mL E2 P001 PP31 IBC01 T7 TP2 TP7 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 Reacts violently with moisture, water and acids, evolving flammable gas. 3398
3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE 4.3 III 223 274 1 L E1 P001 PP31 IBC02 T7 TP2 TP7 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3398
3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE 4.3 3 I 274 0 E0 P402 PP31 T13 TP2 TP7 TP36 TP41 F-G, S-N Category D SW2 H1 SG26 SG35 SG72 Flammable liquid. Reacts violently with moisture, water and acids, evolving flammable gas. 3399
3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE 4.3 3 II 274 500 mL E2 P001 PP31 IBC01 T7 TP2 TP7 TP36 TP41 F-G, S-N Category D SW2 H1 SG26 SG35 SG72 See entry above. 3399
3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE 4.3 3 III 223 274 1 L E1 P001 PP31 IBC02 T7 TP2 TP7 TP36 TP41 F-G, S-N Category E SW2 H1 SG26 SG35 SG72 See entry above. 3399
3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING 4.2 II 274 500 g E2 P410 IBC06 T3 TP33 TP36 F-A, S-J Category C SG72 Liable to self-heating or spontaneous combustion. 3400
3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING 4.2 III 223 274 1 kg E1 P002 IBC08 T1 TP33 TP36 F-A, S-J Category C SG72 See entry above. 3400
3401 ALKALI METAL AMALGAM, SOLID 4.3 I 182 0 E0 P403 PP31 T9 TP7 TP33 F-G, S-N Category D H1 SGG7 SGG11 SG26 SG35 Silvery solid, consisting of metal alloyed with mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. 3401
3402 ALKALINE EARTH METAL AMALGAM, SOLID 4.3 I 183 0 E0 P403 PP31 T9 TP7 TP33 F-G, S-N Category D H1 SGG7 SGG11 SG26 SG35 Consists of metal alloyed with mercury. Contains 2% to 10% alkaline earth metals and may contain up to 98% mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. 3402
3403 POTASSIUM METAL ALLOYS, SOLID 4.3 I 0 E0 P403 PP31 T9 TP7 TP33 F-G, S-L Category D H1 SG26 SG35 Soft, silvery metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 3403
3404 POTASSIUM SODIUM ALLOYS, SOLID 4.3 I 0 E0 P403 PP31 T9 TP7 TP33 F-G, S-L Category D H1 SG26 SG35 Soft, silvery metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. 3404
3405 BARIUM CHLORATE SOLUTION 5.1 6.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category A SGG4 SG38 SG49 SG62 Colourless aqueous solution. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by inhalation. Leakage and subsequent evaporation of the water from the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion, .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 3405
3405 BARIUM CHLORATE SOLUTION 5.1 6.1 III 223 5 L E1 P001 IBC02 T4 TP1 F-H, S-Q Category A SGG4 SG38 SG49 SG62 See entry above. 3405
3406 BARIUM PERCHLORATE SOLUTION 5.1 6.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category A SGG13 SG38 SG49 SG62 Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by inhalation. Leakage and subsequent evaporation of the water from the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion, .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 3406
3406 BARIUM PERCHLORATE SOLUTION 5.1 6.1 III 223 5 L E1 P001 IBC02 T4 TP1 F-H, S-Q Category A SGG13 SG38 SG49 SG62 See entry above. 3406
3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION 5.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category A SGG4 SG38 SG49 SG62 Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water from the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion, .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. 3407
3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION 5.1 III 223 5 L E1 P504 IBC02 T4 TP1 F-H, S-Q Category A SGG4 SG38 SG49 SG62 See entry above. 3407
3408 LEAD PERCHLORATE SOLUTION 5.1 6.1 II 1 L E2 P504 IBC02 T4 TP1 F-H, S-Q Category A SGG7 SGG9 SGG13 SG38 SG49 Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. 3408
3408 LEAD PERCHLORATE SOLUTION 5.1 6.1 III 223 5 L E1 P001 IBC02 T4 TP1 F-H, S-Q Category A SGG7 SGG9 SGG13 SG38 SG49 See entry above. 3408
3409 CHLORONITROBENZENES, LIQUID 6.1 II 279 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Yellow liquid. Toxic if swallowed, by skin contact or by inhalation. 3409
3410 4-CHLORO--TOLUIDINE HYDROCHLORIDE SOLUTION 6.1 III 223 5 L E1 P001 IBC03 T4 TP1 F-A, S-A Category A Toxic if swallowed, by skin contact or by inhalation. 3410
3411 -NAPHTHYLAMINE SOLUTION 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A Toxic if swallowed, by skin contact or by inhalation. 3411
3411 -NAPHTHYLAMINE SOLUTION 6.1 III 223 5 L E1 P001 IBC02 T7 TP2 F-A, S-A Category A See entry above. 3411
3412 FORMIC ACID with not less than 10% but not more than 85% acid by mass 8 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category A SW2 SGG1 SG36 SG49 Colourless liquid with a pungent odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 3412
3412 FORMIC ACID with not less than 5% but less than 10% acid by mass 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SW2 SGG1 SG36 SG49 See entry above. 3412
3413 POTASSIUM CYANIDE SOLUTION 6.1 I 0 E5 P001 PP31 T14 TP2 TP13 F-A, S-A Category B SGG6 SG35 Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. 3413
3413 POTASSIUM CYANIDE SOLUTION 6.1 II 100 mL E4 P001 PP31 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SGG6 SG35 Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. 3413
3413 POTASSIUM CYANIDE SOLUTION 6.1 III 223 5 L E1 P001 LP01 PP31 IBC03 T7 TP2 TP13 TP28 F-A, S-A Category A SGG6 SG35 See entry above. 3413
3414 SODIUM CYANIDE SOLUTION 6.1 I 0 E5 P001 PP31 T14 TP2 TP13 F-A, S-A Category B SGG6 SG35 Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. 3414
3414 SODIUM CYANIDE SOLUTION 6.1 II 100 mL E4 P001 PP31 IBC02 T11 TP2 TP13 TP27 F-A, S-A Category B SGG6 SG35 See entry above. 3414
3414 SODIUM CYANIDE SOLUTION 6.1 III 223 5 L E1 P001 LP01 PP31 IBC03 T7 TP2 TP13 TP28 F-A, S-A Category A SGG6 SG35 See entry above. 3414
3415 SODIUM FLUORIDE SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SG35 Colourless liquid. Reacts with acids, evolving hydrogen fluoride, a toxic, irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. 3415
3416 CHLOROACETOPHENONE, LIQUID 6.1 II 0 E0 P001 IBC02 T7 TP2 TP13 F-A, S-A Category D SW1 SW2 H2 Liquid evolving irritating vapour (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. 3416
3417 XYLYL BROMIDE, SOLID 6.1 II 0 E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-G Category D SW2 Crystals or powder, evolving irritating vapour (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. 3417
3418 2,4-TOLUYLENEDIAMINE SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Toxic if swallowed, by skin contact or by inhalation. 3418
3419 BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category A SGG1 SG36 SG49 White crystalline solid. Melting point: 23°C. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 3419
3420 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category A SGG1 SG36 SG49 White crystalline solid. Melting point: 28°C. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 3420
3421 POTASSIUM HYDROGEN DIFLUORIDE SOLUTION 8 6.1 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category A SW1 SW2 SGG1 SG35 SG36 SG49 Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3421
3421 POTASSIUM HYDROGEN DIFLUORIDE SOLUTION 8 6.1 III 223 5 L E1 P001 IBC03 T4 TP1 F-A, S-B Category A SW1 SW2 SGG1 SG35 SG36 SG49 See entry above. 3421
3422 POTASSIUM FLUORIDE SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SG35 Decomposed by acids, evolving hydrogen fluoride, an irritating and corrosive gas. Toxic if swallowed, by skin contact or by inhalation. 3422
3423 TETRAMETHYLAMMONIUM HYDROXIDE, SOLID 6.1 8 I 279 409 0 E5 P002 IBC99 T6 TP33 F-A, S-B Category A SGG2 SGG18 SG35 Very soluble in water with a strong ammonia-like odour. Highly toxic if swallowed, by skin contact or by dust inhalation. When heated emits toxic fumes of nitrogen and ammonia. Corrosive to metals and tissue. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 3423
3424 AMMONIUM DINITRO--CRESOLATE SOLUTION 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category B SGG2 SG15 SG16 SG30 SG63 The commercial product is a 50% suspension in water. May support combustion and burn without oxygen. When involved in a fire, evolves toxic fumes. Forms extremely sensitive explosive compounds with lead, silver or other heavy metals and their compounds. Toxic if swallowed, by skin contact or by inhalation. 3424
3424 AMMONIUM DINITRO--CRESOLATE SOLUTION 6.1 III 223 5 L E1 P001 IBC02 T7 TP2 F-A, S-A Category A SGG2 SG15 SG16 SG30 SG63 See entry above. 3424
3425 BROMOACETIC ACID, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category A SGG1 SG36 SG49 Colourless, deliquescent crystals. Melting point: 51°C. Corrosive to most metals. Harmful if swallowed. Causes burns to eyes and skin. 3425
3426 ACRYLAMIDE SOLUTION 6.1 III 223 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A SW1 H2 Toxic if swallowed, by skin contact or by inhalation. 3426
3427 CHLOROBENZYL CHLORIDES, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Colourless crystalline solid. Melting point: 29°C. Immiscible with or insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 3427
3428 3-CHLORO−4-METHYLPHENYL ISOCYANATE, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B SW2 Colourless solid with a pungent odour. Melting point: 23°C. Insoluble in water. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. 3428
3429 CHLOROTOLUIDINES, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Brown liquid. Toxic if swallowed, by skin contact or by inhalation. 3429
3430 XYLENOLS, LIQUID 6.1 II 100 mL E4 P001 IBC02 T7 TP2 F-A, S-A Category A The commercial products are liquids with a pungent tar odour. Toxic if swallowed, by skin contact or by inhalation. 3430
3431 NITROBENZOTRIFLUORIDES, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 Low melting point (31°C to 32°C) solids with an aromatic odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 3431
3432 POLYCHLORINATED BIPHENYLS, SOLID 9 II 305 958 1 kg E2 P906 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SG50 Solids with perceptible odour. Insoluble in water. Harmful by ingestion or by skin contact. If spilled, can be a persistent hazard to the environment. This entry also covers articles, such as rags, cotton waste, clothing or sawdust, containing polychlorinated biphenyls where no free visible liquid is present. 3432
3434 NITROCRESOLS, LIQUID 6.1 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-A Category A Slightly miscible in water. Toxic if swallowed, by skin contact or by inhalation. 3434
3436 HEXAFLUOROACETONE HYDRATE, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B SW2 This entry covers solid hydrate and hexafluoroacetone. Melting point of the pure substance: 23°C. Toxic if swallowed, by skin contact or by inhalation. 3436
3437 CHLOROCRESOLS, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW1 H2 White or pink crystals with a phenol-like odour. Melting point: 45°C to 68°C. Slightly soluble in water. Decomposes when heated, evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. 3437
3438 -METHYLBENZYL ALCOHOL, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Slightly soluble in water. Melting point: 21°C (pure substance). Toxic if swallowed, by skin contact or by inhalation. 3438
3439 NITRILES, SOLID, TOXIC, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B SG35 Solid, evolving toxic vapours. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 3439
3439 NITRILES, SOLID, TOXIC, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B SG35 See entry above. 3439
3439 NITRILES, SOLID, TOXIC, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SG35 See entry above. 3439
3440 SELENIUM COMPOUND, LIQUID, N.O.S. 6.1 I 274 0 E5 P001 T14 TP2 TP7 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3440
3440 SELENIUM COMPOUND, LIQUID, N.O.S. 6.1 II 274 100 mL E4 P001 IBC02 T11 TP2 TP7 F-A, S-A Category B See entry above. 3440
3440 SELENIUM COMPOUND, LIQUID, N.O.S. 6.1 III 223 274 5 L E1 P001 IBC03 T7 TP1 TP28 F-A, S-A Category A See entry above. 3440
3441 CHLORODINITROBENZENES, SOLID 6.1 II 279 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SG15 Crystals. Melting point: 27°C to 53°C. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 3441
3442 DICHLOROANILINES, SOLID 6.1 II 279 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SW2 Solid with a penetrating odour. Liquid mixtures of various isomers of dichloroanilines, some of which in the pure state may be solid, with a melting point varying from 24°C to 72°C. Toxic if swallowed, by skin contact or by inhalation. 3442
3443 DINITROBENZENES, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A SG15 May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. 3443
3444 NICOTINE HYDROCHLORIDE, SOLID 6.1 II 43 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Deliquescent crystals or solids or pastes. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 3444
3445 NICOTINE SULPHATE, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Solid or paste. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. 3445
3446 NITROTOLUENES, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Yellow solid. Melting point: -NITROTOLUENE: 52°C to 54°C. Toxic if swallowed, by skin contact or by inhalation. 3446
3447 NITROXYLENES, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Yellow solid. Melting points: 4-NITRO−2-XYLENE: 29°C to 31°C, 5-NITRO−3-XYLENE: 72°C to 74°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 3447
3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 I 274 0 E0 P002 PP31 T6 TP33 F-A, S-A Category D SW2 “Tear gas substance” is a generic term for substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. Toxic if swallowed, by skin contact or by inhalation. 3448
3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 II 274 0 E0 P002 PP31 IBC08 B4 B21 T3 TP33 F-A, S-A Category D SW2 See entry above. 3448
3449 BROMOBENZYL CYANIDES, SOLID 6.1 I 138 0 E5 P002 PP31 T6 TP33 F-A, S-A Category D SW1 SW2 H2 SGG6 SG35 Volatile, yellow crystals evolving irritating vapours (“Tear Gas”). Melting point: -BROMOBENZYL CYANIDE 25°C. Highly toxic if swallowed, by skin contact or by inhalation. 3449
3450 DIPHENYLCHLOROARSINE, SOLID 6.1 I 0 E0 P002 PP31 IBC07 B1 T6 TP33 F-A, S-A Category D SW2 When pure, volatile, colourless crystals evolving an irritating vapour (“Tear Gas”). Melting point: 41°C. Highly toxic if swallowed, by skin contact or by inhalation. 3450
3451 TOLUIDINES, SOLID 6.1 II 279 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A -TOLUIDINE is solid in pure form, with a melting point of approximately 45°C. Toxic if swallowed, by skin contact or by inhalation. 3451
3452 XYLIDINES, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A 3,4-Dimethylaniline is a solid, which has a melting point of 47°C. Toxic if swallowed, by skin contact or by dust inhalation. 3452
3453 PHOSPHORIC ACID, SOLID 8 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-B Category A SGG1 SG36 SG49 Very deliquescent, crystalline solid. Melting point: 42°C. Soluble in water. Mildly corrosive to most metals. 3453
3454 DINITROTOLUENES, SOLID 6.1 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category A Yellow crystals or flakes, insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 3454
3455 CRESOLS, SOLID 6.1 8 II 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category B Light yellow solid. Soluble in water. Melting points of CRESOLS: -CRESOL: 30°C, -CRESOL: 35°C. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. 3455
3456 NITROSYLSULPHURIC ACID, SOLID 8 II 1 kg E2 P002 IBC08 B4 B21 T3 TP33 F-A, S-B Category D SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Crystalline solid. Oxidant which may cause fire with organic materials (such as wood, straw, etc.). When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 3456
3457 CHLORONITROTOLUENES, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A SG6 SG8 SG10 SG12 Melting range 20°C to 40°C. Insoluble in water. Oxidizing substance which may explode or burn fiercely when in contact with organic materials. Toxic if swallowed, by skin contact or by inhalation. 3457
3458 NITROANISOLES, SOLID 6.1 III 279 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Light reddish or amber crystals. Melting points: 38°C to 54°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 3458
3459 NITROBROMOBENZENES, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Colourless to pale yellow crystals which may liquefy under transport conditions. Melting points: 1-BROMO−2-NITROBENZENE: 43°C. 1-BROMO−4-NITROBENZENE: 127°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 3459
3460 ETHYLBENZYLTOLUIDINES, SOLID 6.1 III 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A Solid which may liquefy under transport conditions. Strong odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. 3460
3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 6.1 I 210 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B Toxins from plant, animal or bacterial sources which contain infectious substances or toxins that are contained in infectious substances should be classified in class 6.2. Toxic if swallowed, by skin contact or by inhalation. 3462
3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 6.1 II 210 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3462
3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 6.1 III 210 223 274 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3462
3463 PROPIONIC ACID, with not less than 90% acid by mass 8 3 II 1 L E2 P001 IBC02 T7 TP2 F-E, S-C Category A SGG1 SG36 SG49 Colourless flammable liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Burns skin. Vapours irritate mucous membranes. Pure PROPIONIC ACID: flashpoint 50°C c.c. 3463
3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 6.1 I 43 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3464
3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 6.1 II 43 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3464
3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 6.1 III 43 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3464
3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3465
3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3465
3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3465
3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category D SW2 Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. 3466
3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category D SW2 See entry above. 3466
3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category D SW2 See entry above. 3466
3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 6.1 I 274 0 E5 P002 IBC07 B1 T6 TP33 F-A, S-A Category B Toxic if swallowed, by skin contact or by inhalation. 3467
3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 6.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-A Category B See entry above. 3467
3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 6.1 III 223 274 5 kg E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-A Category A See entry above. 3467
3468 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT 2.1 321 356 0 E0 P205 F-D, S-U Category D Article containing flammable odourless gas, which is much lighter than air. 3468
3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) 3 8 I 163 367 0 E0 P001 T11 TP2 TP7 F-E, S-C Category E SW2 Miscibility with water depends upon the composition. Corrosive contents cause burns to skin, eyes and mucous membranes. 3469
3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) 3 8 II 163 367 1 L E2 P001 IBC02 T7 TP2 TP8 TP28 F-E, S-C Category B SW2 See entry above. 3469
3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) 3 8 III 163 223 367 5 L E1 P001 IBC03 T4 TP1 TP29 F-E, S-C Category A SW2 See entry above. 3469
3470 PAINT, CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including paint thinning or reducing compound) 8 3 II 163 367 1 L E2 P001 IBC02 T7 TP2 TP8 TP28 F-E, S-C Category B SW2 Miscibility with water depends upon the composition. Corrosive contents cause burns to skin, eyes and mucous membranes. 3470
3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S. 8 6.1 II 1 L E2 P001 IBC02 T7 TP2 F-A, S-B Category A SW1 SW2 SG35 When involved in a fire or in contact with acids, evolves hydrogen fluoride, an extremely irritating and corrosive gas. Corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3471
3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S. 8 6.1 III 223 5 L E1 P001 IBC03 T4 TP1 F-A, S-B Category A SW1 SW2 SG35 See entry above. 3471
3472 CROTONIC ACID, LIQUID 8 III 5 L E1 P001 LP01 IBC03 T4 TP1 F-A, S-B Category A SW1 H2 SGG1 SG36 SG49 Causes burns to skin, eyes and mucous membranes. 3472
3473 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT containing flammable liquids 3 328 1 L E0 P004 F-E, S-D Category A Fuel cell cartridges containing flammable liquids including methanol or methanol/water solutions. Fuel cell cartridges may also be shipped in, or packed with, equipment. 3473
3474 1-HYDROXYBENZOTRIAZOLE MONOHYDRATE 4.1 I 0 E0 P406 PP48 F-B, S-J Category D SG7 SG30 Desensitized explosive. White to light beige powder. Explosive and sensitive to friction in the dry state. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. 3474
3475 ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10% ethanol 3 II 333 1 L E2 P001 IBC02 T4 TP1 F-E, S-E Category E Colourless, volatile liquids. Miscibility with water depends on the composition. 3475
3476 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing water-reactive substances 4.3 328 334 500 mL or 500 g E0 P004 F-G, S-P Category A H1 SG26 Fuel cell cartridges containing water-reactive substances may also be shipped in, or packed with, equipment. 3476
3477 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing corrosive substances 8 328 334 1 L or 1 kg E0 P004 F-A, S-B Category A Fuel cell cartridges containing corrosive substances may also be shipped in, or packed with, equipment. 3477
3478 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas 2.1 328 338 120 mL E0 P004 F-D, S-U Category B Fuel cell cartridges containing butane or other flammable liquefied gas may also be shipped in, or packed with, equipment. 3478
3479 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride 2.1 328 339 120 mL E0 P004 F-D, S-U Category B Fuel cell cartridges containing hydrogen, butane or other flammable odourless gas, which is much lighter than air, may also be shipped in or packed with equipment. 3479
3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 9 188 230 310 348 376 377 384 387 0 E0 P903 P908 P909 P910 P911 LP903 LP904 LP905 LP906 F-A, S-I Category A SW19 Electrical batteries containing lithium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. 3480
3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) 9 188 230 310 348 360 376 377 384 387 390 0 E0 P903 P908 P909 P910 P911 LP903 LP904 LP905 LP906 F-A, S-I Category A SW19 Electrical batteries containing lithium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. 3481
3482 ALKALI METAL DISPERSION, FLAMMABLE or ALKALINE EARTH METAL DISPERSION, FLAMMABLE 4.3 3 I 182 183 0 E0 P402 PP31 T13 TP2 TP7 TP42 F-G, S-N Category D H1 SG26 SG35 Finely divided alkali or alkaline earth metal suspended in a flammable liquid. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. 3482
3483 MOTOR FUEL ANTI-KNOCK MIXTURE, FLAMMABLE 6.1 3 I 0 E0 P602 T14 TP2 TP13 F-E, S-D Category D SW1 SW2 SGG7 SGG9 Volatile flammable liquids evolving toxic vapour. Mixture of tetraethyllead or tetramethyllead with ethylene dibromide and ethylene dichloride. Insoluble in water. Highly toxic if swallowed, by skin contact or by inhalation. 3483
3484 HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE with more than 37% hydrazine, by mass 8 3 6.1 I 0 E0 P001 T10 TP2 TP13 F-E, S-C Category D SW2 SGG18 SG5 SG8 SG35 Colourless flammable liquid. Powerful reducing agent, burns readily. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. 3484
3485 CALCIUM HYPOCHLORITE, DRY, CORROSIVE or CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) 5.1 8 II 314 1 kg E2 P002 PP85 F-H, S-Q Category D SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 White or yellowish corrosive solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 3485
3486 CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 10% but not more than 39% available chlorine 5.1 8 III 314 5 kg E1 P002 PP85 F-H, S-Q Category D SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 White or yellowish corrosive solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 3486
3487 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water 5.1 8 II 314 322 1 kg E2 P002 PP85 F-H, S-Q Category D SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 White or yellowish corrosive solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. 3487
3487 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water 5.1 8 III 223 314 5 kg E1 P002 PP85 F-H, S-Q Category D SW1 SW11 SGG8 SG35 SG38 SG49 SG53 SG60 See entry above. 3487
3488 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC lower than or equal to 200 mL/m and saturated vapour concentration greater than or equal to 500 LC 6.1 3 8 I 274 0 E0 P601 T22 TP2 TP13 F-E, S-D Category D SW2 SG5 SG8 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable and corrosive. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3488
3489 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC lower than or equal to 1000 mL/m and saturated vapour concentration greater than or equal to 10 LC 6.1 3 8 I 274 0 E0 P602 T20 TP2 TP13 F-E, S-D Category D SW2 SG5 SG8 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable and corrosive. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. 3489
3490 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC lower than or equal to 200 mL/m and saturated vapour concentration greater than or equal to 500 LC 6.1 4.3 3 I 274 0 E0 P601 T22 TP2 TP13 F-G, S-N Category D SW2 H1 SG5 SG13 SG25 SG26 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. 3490
3491 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC lower than or equal to 1000 mL/m and saturated vapour concentration greater than or equal to 10 LC 6.1 4.3 3 I 274 0 E0 P602 T20 TP2 TP13 F-G, S-N Category D SW2 H1 SG5 SG13 SG25 SG26 A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. 3491
3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3 6.1 I 343 0 E0 P001 T14 TP2 TP13 F-E, S-E Category D SW2 Immiscible with water. Evolves hydrogen sulphide, which is a flammable, toxic gas with a foul odour, heavier than air (1.2). Toxic if swallowed, by skin contact or by inhalation. 3494
3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3 6.1 II 343 1 L E2 P001 IBC02 T7 TP2 F-E, S-E Category D SW2 See entry above. 3494
3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3 6.1 III 343 5 L E1 P001 IBC03 T4 TP1 F-E, S-E Category C SW2 See entry above. 3494
3495 IODINE 8 6.1 III 279 5 kg E1 P002 IBC08 B3 T1 TP33 F-A, S-B Category B SW2 SG37 Bluish-black solid with a metallic lustre and a pungent odour. Melting point: 114°C. Below its melting point, may evolve vapours which are irritating to skin, eyes and mucous membranes. Slightly soluble in water but soluble in most organic solvents. Corrosive to most metals. 3495
3496 BATTERIES, NICKEL-METAL HYDRIDE 9 117 963 0 E0 See SP963 IBC08 F-A, S-I Category A SW1 Nickel-metal hydride cells or batteries packed with or contained in equipment and nickel-metal hydride button cells are not subject to the provisions of this Code. 3496
3497 KRILL MEAL 4.2 II 300 0 E2 P410 IBC06 B21 T3 TP33 F-A, S-J Category B SW27 SG65 Pink to red meal derived from Krill which is a shrimp-like marine organism. Medium odour, which may affect other sensitive cargo. Liable to self-heating. Naturally rich in anti-oxidants, which lessen the risk of spontaneous heating. 3497
3497 KRILL MEAL 4.2 III 223 300 0 E1 P002 LP02 IBC08 B3 T1 TP33 F-A, S-J Category A See entry above. 3497
3498 IODINE MONOCHLORIDE, LIQUID 8 II 1 L E0 P001 IBC02 T7 TP2 F-A, S-B Category D SW2 SGG1 SG6 SG16 SG17 SG19 SG36 SG49 Red Liquid. Reacts violently with water, evolving irritating and corrosive gases apparent as white fumes. Powerful oxidant: may cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. 3498
3499 CAPACITOR, ELECTRIC DOUBLE LAYER (with an energy storage capacity greater than 0.3 Wh) 9 361 0 E0 P003 F-A, S-I Category A Articles intended to store energy containing a non-dangerous activated carbon and an electrolyte. Electric double layer capacitors installed in equipment may be transported in a charged state. 3499
3500 CHEMICAL UNDER PRESSURE, N.O.S. 2.2 274 362 0 E0 P206 PP97 T50 TP4 TP40 F-C, S-V Category B Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3500
3501 CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. 2.1 274 362 0 E0 P206 PP89 T50 TP4 TP40 F-D, S-U Category D SW2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3501
3502 CHEMICAL UNDER PRESSURE, TOXIC, N.O.S. 2.2 6.1 274 362 0 E0 P206 PP89 T50 TP4 TP40 F-C, S-V Category D SW2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3502
3503 CHEMICAL UNDER PRESSURE, CORROSIVE, N.O.S. 2.2 8 274 362 0 E0 P206 PP89 T50 TP4 TP40 F-C, S-V Category D SW2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3503
3504 CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. 2.1 6.1 274 362 0 E0 P206 PP89 T50 TP4 TP40 F-D, S-U Category D SW2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3504
3505 CHEMICAL UNDER PRESSURE, FLAMMABLE, CORROSIVE, N.O.S. 2.1 8 274 362 0 E0 P206 PP89 T50 TP4 TP40 F-D, S-U Category D SW2 Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. 3505
3506 MERCURY CONTAINED IN MANUFACTURED ARTICLES 8 6.1 366 5 kg E0 P003 PP90 F-A, S-B Category B SW2 SG24 Mercury (UN 2809) is highly corrosive to aluminium. Carriage should be prohibited in hovercraft and other ships constructed with aluminium. 3506
3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, less than 0.1 kg per package, non-fissile or fissile-excepted 6.1 7/8 I 317 369 0 E0 P603 F-I, S-S Category A SW12 SG77 See 1.5.1. 3507
3508 CAPACITOR, ASYMMETRIC (with an energy storage capacity greater than 0.3Wh) 9 372 0 E0 P003 F-A, S-I Category A Articles intended to store energy containing positive and negative electrodes comprised of different materials and an electrolyte. Asymetric capacitors may be transported in a charged state. 3508
3509 PACKAGINGS, DISCARDED, EMPTY, UNCLEANED 9 968 0 E0 This entry shall not be used for sea transport. Discarded packaging shall meet the requirements of 4.1.1.11. Discarded packaging means packagings, large packagings or intermediate bulk containers (IBC), or parts thereof, which have contained dangerous goods, other than radioactive material, which are transported for disposal, recycling or recovery of their material, other than reconditioning, repair, routine maintenance, remanufacturing or reuse, and which have been emptied to the extent that only residues of dangerous goods adhering to the packaging parts are present. 3509
3510 ADSORBED GAS, FLAMMABLE, N.O.S. 2.1 274 0 E0 P208 F-D, S-U Category D SW2 3510
3511 ADSORBED GAS, N.O.S. 2.2 274 0 E0 P208 F-C, S-V Category A 3511
3512 ADSORBED GAS, TOXIC, N.O.S. 2.3 274 0 E0 P208 F-C, S-U Category D SW2 3512
3513 ADSORBED GAS, OXIDIZING, N.O.S. 2.2 5.1 274 0 E0 P208 F-C, S-W Category D 3513
3514 ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S. 2.3 2.1 274 0 E0 P208 F-D, S-U Category D SW2 3514
3515 ADSORBED GAS, TOXIC, OXIDIZING, N.O.S. 2.3 5.1 274 0 E0 P208 F-C, S-W Category D SW2 3515
3516 ADSORBED GAS, TOXIC, CORROSIVE, N.O.S. 2.3 8 274 379 0 E0 P208 F-C, S-U Category D SW2 3516
3517 ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2.3 2.1 8 274 0 E0 P208 F-D, S-U Category D SW2 SG4 SG9 3517
3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2.3 5.1 8 274 0 E0 P208 F-C, S-W Category D SW2 SG6 SG19 3518
3519 BORON TRIFLUORIDE, ADSORBED 2.3 8 0 E0 P208 F-C, S-U Category D SW2 Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass and most metals. Much heavier than air (2.35). Highly irritating to skin, eyes and mucous membranes. 3519
3520 CHLORINE, ADSORBED 2.3 5.1/8 0 E0 P208 F-C, S-W Category D SW2 SG6 SG19 Non-flammable, toxic and corrosive yellow gas with a pungent odour. Corrosive to glass and to most metals. Much heavier than air (2.4). Highly irritating to skin, eyes and mucous membranes. Powerful oxidant which may cause fire. 3520
3521 SILICON TETRAFLUORIDE, ADSORBED 2.3 8 0 E0 P208 F-C, S-U Category D SW2 Non-flammable, toxic and corrosive gas with a pungent odour. Corrosive to metals. In moist air, produces hydrogen fluoride. Much heavier than air (3.6). Highly irritating to skin, eyes and mucous membranes. 3521
3522 ARSINE, ADSORBED 2.3 2.1 0 E0 P208 F-D, S-U Category D SW2 Flammable, toxic, colourless gas with a garlic odour. Explosive limits: 3.9% to 77.8%. Much heavier than air (2.8). 3522
3523 GERMANE, ADSORBED 2.3 2.1 0 E0 P208 F-D, S-U Category D SW2 Flammable, toxic, colourless gas with a pungent odour. Much heavier than air (2.6). 3523
3524 PHOSPHORUS PENTAFLUORIDE, ADSORBED 2.3 8 0 E0 P208 F-C, S-U Category D SW2 Non-flammable, toxic and corrosive gas with an irritating odour. Reacts with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (4.3). Highly irritating to skin, eyes and mucous membranes. 3524
3525 PHOSPHINE, ADSORBED 2.3 2.1 0 E0 P208 F-D, S-U Category D SW2 Flammable, toxic, colourless gas with a garlic odour. Ignites spontaneously in air. Heavier than air (1.2). Irritating to skin, eyes and mucous membranes. 3525
3526 HYDROGEN SELENIDE, ADSORBED 2.3 2.1 0 E0 P208 F-D, S-U Category D SW2 Flammable, toxic, colourless gas with a disagreeable odour. Much heavier than air (2.8). Highly irritating to skin, eyes and mucous membranes. 3526
3527 POLYESTER RESIN KIT, solid base material 4.1 II 236 340 5 kg See SP340 P412 F-A, S-G Category B Polyester resin kits consist of two components: a base material (flammable solid) and an activator (organic peroxide), each separately packed in an inner packaging. 3527
3527 POLYESTER RESIN KIT, solid base material 4.1 III 236 340 5 kg See SP340 P412 F-A, S-G Category B See entry above. 3527
3528 ENGINE, INTERNAL COMBUSTION, FLAMMABLE LIQUID POWERED or ENGINE, FUEL CELL, FLAMMABLE LIQUID POWERED or MACHINERY, INTERNAL COMBUSTION, FLAMMABLE LIQUID POWERED or MACHINERY, FUEL CELL, FLAMMABLE LIQUID POWERED 3 363 972 0 E0 P005 F-E, S-E Category E SW29 Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems or fuel cells (e.g. combustion engines, generators, compressors, turbines, heating units, etc.). 3528
3529 ENGINE, INTERNAL COMBUSTION, FLAMMABLE GAS POWERED or ENGINE, FUEL CELL, FLAMMABLE GAS POWERED or MACHINERY, INTERNAL COMBUSTION, FLAMMABLE GAS POWERED or MACHINERY, FUEL CELL, FLAMMABLE GAS POWERED 2.1 356 363 972 0 E0 P005 F-D, S-U Category E Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems or fuel cells (e.g. combustion engines, generators, compressors, turbines, heating units, etc.). 3529
3530 ENGINE, INTERNAL COMBUSTION or MACHINERY, INTERNAL COMBUSTION 9 363 972 0 E0 P005 F-A, S-F Category A Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems (e.g. combustion engines, generators, compressors, turbines, heating units, etc.). 3530
3531 POLYMERIZING SUBSTANCE, SOLID, STABILIZED, N.O.S. 4.1 III 274 386 0 E0 P002 PP92 IBC07 B18 T7 TP4 TP6 TP33 F-J, S-G Category D SW1 SG35 SG36 Polymerizes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. 3531
3532 POLYMERIZING SUBSTANCE, LIQUID, STABILIZED, N.O.S. 4.1 III 274 386 0 E0 P001 PP93 IBC03 B19 T7 TP4 TP6 F-J, S-G Category D SW1 SG35 SG36 Polymerizes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. 3532
3533 POLYMERIZING SUBSTANCE, SOLID, TEMPERATURE CONTROLLED, N.O.S. 4.1 III 274 386 0 E0 P002 PP92 IBC07 B18 T7 TP4 TP6 TP33 F-F, S-K Category D SW1 SW3 SG35 SG36 Polymerizes at temperatures higher than the self-accelerating polymerization temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. Control and emergency temperatures can be found in the transport document as required in 5.4.1.5.5. The temperature must be checked regularly. 3533
3534 POLYMERIZING SUBSTANCE, LIQUID, TEMPERATURE CONTROLLED, N.O.S. 4.1 III 274 386 0 E0 P001 PP93 IBC03 B19 T7 TP4 TP6 F-F, S-K Category D SW1 SW3 SG35 SG36 Polymerizes at temperatures higher than the self-accelerating polymerization temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. Control and emergency temperatures can be found in the transport document as required in 5.4.1.5.5. The temperature must be checked regularly. 3534
3535 TOXIC SOLID, FLAMMABLE, INORGANIC, N.O.S. 6.1 4.1 I 274 0 E5 P002 IBC99 T6 TP33 F-A, S-G Category B Toxic if swallowed, by skin contact or by dust inhalation. 3535
3535 TOXIC SOLID, FLAMMABLE, INORGANIC, N.O.S. 6.1 4.1 II 274 500 g E4 P002 IBC08 B4 B21 T3 TP33 F-A, S-G Category B See entry above. 3535
3536 LITHIUM BATTERIES INSTALLED IN CARGO TRANSPORT UNIT lithium ion batteries or lithium metal batteries 9 389 0 E0 F-A, S-I Category D SW1 SW2 Cargo transport unit containing lithium metal or lithium ion batteries which is designed to serve as mobile power supply unit. 3536
3537 ARTICLES CONTAINING FLAMMABLE GAS, N.O.S. 2.1 See 2.0.6.6 274 310 391 0 E0 P006 LP03 F-D, S-U Category D SW2 3537
3538 ARTICLES CONTAINING NON-FLAMMABLE, NON-TOXIC GAS, N.O.S. 2.2 See 2.0.6.6 274 310 391 396 0 E0 P006 LP03 F-C, S-V Category A 3538
3539 ARTICLES CONTAINING TOXIC GAS, N.O.S. 2.3 See 2.0.6.6 274 391 0 E0 F-C, S-U 3539
3540 ARTICLES CONTAINING FLAMMABLE LIQUID, N.O.S. 3 See 2.0.6.6 274 310 391 0 E0 P006 LP03 F-E, S-D Category B 3540
3541 ARTICLES CONTAINING FLAMMABLE SOLID, N.O.S. 4.1 See 2.0.6.6 274 310 391 0 E0 P006 LP03 F-A, S-G Category B 3541
3542 ARTICLES CONTAINING A SUBSTANCE LIABLE TO SPONTANEOUS COMBUSTION, N.O.S. 4.2 See 2.0.6.6 274 391 0 E0 * * F-G, S-M for pyrophoric substances, F-A, S-J for self-heating substances 3542
3543 ARTICLES CONTAINING A SUBSTANCE WHICH IN CONTACT WITH WATER EMITS FLAMMABLE GASES, N.O.S. 4.3 See 2.0.6.6 274 391 0 E0 F-G, S-N 3543
3544 ARTICLES CONTAINING OXIDIZING SUBSTANCE, N.O.S. 5.1 See 2.0.6.6 274 391 0 E0 F-A, S-Q 3544
3545 ARTICLES CONTAINING ORGANIC PEROXIDE, N.O.S. 5.2 See 2.0.6.6 274 391 0 E0 F-J, S-R 3545
3546 ARTICLES CONTAINING TOXIC SUBSTANCE, N.O.S. 6.1 See 2.0.6.6 274 310 391 0 E0 P006 LP03 F-A, S-A Category B SW2 * Toxic if swallowed, by skin contact or by dust inhalation. * When competent authority approval is required by SP391, the stowage and handling will be specified by the competent authority. 3546
3547 ARTICLES CONTAINING CORROSIVE SUBSTANCE, N.O.S. 8 See 2.0.6.6 274 310 391 0 E0 P006 LP03 F-A, S-B Category B SW2 Causes burns to skin, eyes and mucous membranes. 3547
3548 ARTICLES CONTAINING MISCELLANEOUS DANGEROUS GOODS, N.O.S. 9 See 2.0.6.6 274 310 391 0 E0 P006 LP03 F-A, S-P Category A 3548
3549 MEDICAL WASTE, CATEGORY A, AFFECTING HUMANS, solid or MEDICAL WASTE, CATEGORY A, AFFECTING ANIMALS only, solid 6.2 395 975 0 E0 P622 LP622 F-A, S-T Category E SW2 H1 H5 SG50 Waste containing substances which are dangerous to humans and/or animals. 3549
3550 COBALT DIHYDROXIDE POWDER, containing not less than 10% respirable particles 6.1 I 0 E5 P002 IBC07 B1 B40 T6 TP33 F-A, S-A Category D SW2 Pink odourless powder. Toxic by dust inhalation. 3550
3551 SODIUM ION BATTERIES with organic electrolyte 9 188 230 310 348 376 377 384 400 401 0 E0 P903 P908 P909 P910 P911 LP903 LP904 LP905 LP906 F-A, S-I Category A SW19 Electrical batteries containing sodium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. 3551
3552 SODIUM ION BATTERIES CONTAINED IN EQUIPMENT or SODIUM ION BATTERIES PACKED WITH EQUIPMENT, with organic electrolyte 9 188 230 310 348 376 377 384 400 401 0 E0 P903 P908 P909 P910 P911 LP903 LP904 LP905 LP906 F-A, S-I Category A SW19 Electrical batteries containing sodium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. 3552
3553 DISILANE 2.1 0 E0 P200 F-D, S-U Category D SW2 SG43 SG46 Gas that is extremely flammable and spontaneously ignites in air (pyrophoric). Repulsive odour. Slowly decomposes with water. Irritant to mucous membranes and is an asphyxiant. Boiling point −14.3°C. Lighter than air (0.675). 3553
3554 GALLIUM CONTAINED IN MANUFACTURED ARTICLES 8 366 5 kg E0 P003 PP90 F-A, S-B Category B SW1 Gallium (UN 2803) is highly corrosive to aluminium. Carriage should be prohibited in hovercraft and other ships constructed from aluminium. 3554
3555 TRIFLUOROMETHYL-TETRAZOLE-SODIUM SALT IN ACETONE, with not less than 68% acetone, by mass 3 II 28 0 E0 P303 PP26 F-E, S-Y Category D SW1 SW11 H2 H3 SG30 Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. 3555
3556 VEHICLE, LITHIUM ION BATTERY POWERED 9 384 388 405 961 962 0 E0 P912 F-A, S-I Category A This entry applies to vehicles powered by lithium ion batteries with the batteries installed, such as electrically-powered cars, lawn tractors, wheelchairs and other mobility aids. 3556
3557 VEHICLE, LITHIUM METAL BATTERY POWERED 9 384 388 405 961 962 0 E0 P912 F-A, S-I Category A This entry applies to vehicles powered by lithium metal batteries with the batteries installed, such as electrically-powered cars, lawn tractors, wheelchairs and other mobility aids. 3557
3558 VEHICLE, SODIUM ION BATTERY POWERED 9 384 388 404 405 961 962 977 0 E0 P912 F-A, S-I Category A This entry applies to vehicles powered by sodium ion batteries with the batteries installed, such as electrically-powered cars, lawn tractors, wheelchairs and other mobility aids. 3558
3559 FIRE SUPPRESSANT DISPERSING DEVICES 9 407 0 E0 P902 F-B, S-X Category A Articles which contain a pyrotechnic substance, which are intended to disperse a fire extinguishing agent (or aerosol) when activated, and which do not contain any other dangerous goods. 3559
3560 TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with not less than 25% tetramethylammonium hydroxide 6.1 8 I 279 408 409 0 E5 P001 T14 TP2 F-A, S-B Category D SW2 SGG2 SGG18 SG35 Colourless liquid with a strong ammonia-like odour that is miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Corrosive to metal. When heated emits toxic fumes of nitrogen oxides and ammonia. Causes burns to skin, eyes, and mucous membranes. Reacts violently with acids. 3560