|
UN No. |
Proper shipping name (PSN) |
Class or division
|
Subsidiary hazard(s) |
Packing group
|
Special provisions
|
Limited and excepted quantity provisions |
Packing |
IBC |
|
Portable tanks and bulk containers |
EmS |
Stowage and handling |
Segregation |
Properties and observations |
UN No. |
|
| Limited quantities |
Excepted quantities |
Instructions |
Provisions |
Instructions |
Provisions |
|
|
Tank instructions |
Provisions |
|
|
(1) |
(2) 3.1.2
|
(3) 2.0
|
(4) 2.0
|
(5) 2.0.1.3 |
(6) 3.3
|
(7a) 3.4
|
(7b) 3.5
|
(8) 4.1.4
|
(9) 4.1.4 |
(10) 4.1.4
|
(11) 4.1.4 |
|
(12) |
(13) 4.2.5
4.3
|
(14) 4.2.5
|
(15) 5.4.3.4
7.8
|
(16a) 7.1
7.3–7.7
|
(16b) 7.2–7.7
|
(17) |
(18) |
|
|
0004
|
AMMONIUM PICRATE dry or wetted with less than 10% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SGG2
SG27
SG31
|
Substance. |
0004 |
|
|
0005
|
CARTRIDGES FOR WEAPONS with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0005 |
|
|
0006
|
CARTRIDGES FOR WEAPONS with bursting charge |
1.1E
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0006 |
|
|
0007
|
CARTRIDGES FOR WEAPONS with bursting charge |
1.2 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0007 |
|
|
0009
|
AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge |
1.2G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0009 |
|
|
0010
|
AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge |
1.3G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0010 |
|
|
0012
|
CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS |
1.4S
|
– |
– |
364
|
5 kg |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0012 |
|
|
0014
|
CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK or CARTRIDGES FOR TOOLS, BLANK |
1.4S
|
– |
– |
364
|
5 kg |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0014 |
|
|
0015
|
AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge |
1.2G
|
See SP204
|
– |
204
|
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0015 |
|
|
0016
|
AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge |
1.3G
|
See SP204
|
– |
204
|
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0016 |
|
|
0018
|
AMMUNITION, TEAR- PRODUCING with burster, expelling charge or propelling charge |
1.2G
|
6.1/8
|
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 03
SW1
|
SG2
|
See glossary of terms in appendix B. |
0018 |
|
|
0019
|
AMMUNITION, TEAR-PRODUCING with burster, expelling charge or propelling charge |
1.3G
|
6.1/8
|
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 03
SW1
|
SG3
|
See glossary of terms in appendix B. |
0019 |
|
|
0020
|
AMMUNITION, TOXIC with burster, expelling charge or propelling charge |
1.2 K
|
6.1
|
– |
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0020 |
|
|
0021
|
AMMUNITION, TOXIC with burster, expelling charge or propelling charge |
1.3 K
|
6.1
|
– |
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0021 |
|
|
0027
|
BLACK POWDER (GUNPOWDER) granular, or as a meal |
1.1D
|
– |
– |
– |
0 |
E0 |
P113
|
PP50 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0027 |
|
|
0028
|
BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS |
1.1D
|
– |
– |
– |
0 |
E0 |
P113
|
PP51 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0028 |
|
|
0029
|
DETONATORS, NON-ELECTRIC for blasting |
1.1B
|
– |
– |
– |
0 |
E0 |
P131
|
PP68 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0029 |
|
|
0030
|
DETONATORS, ELECTRIC for blasting |
1.1B
|
– |
– |
399
|
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0030 |
|
|
0033
|
BOMBS with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0033 |
|
|
0034
|
BOMBS with bursting charge |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0034 |
|
|
0035
|
BOMBS with bursting charge |
1.2D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0035 |
|
|
0037
|
BOMBS, PHOTO-FLASH |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0037 |
|
|
0038
|
BOMBS, PHOTO-FLASH |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0038 |
|
|
0039
|
BOMBS, PHOTO-FLASH |
1.2G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0039 |
|
|
0042
|
BOOSTERS without detonator |
1.1D
|
– |
– |
– |
0 |
E0 |
P132 (a) or (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0042 |
|
|
0043
|
BURSTERS explosive |
1.1D
|
– |
– |
– |
0 |
E0 |
P133
|
PP69 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0043 |
|
|
0044
|
PRIMERS, CAP TYPE |
1.4S
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0044 |
|
|
0048
|
CHARGES, DEMOLITION |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0048 |
|
|
0049
|
CARTRIDGES, FLASH |
1.1G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0049 |
|
|
0050
|
CARTRIDGES, FLASH |
1.3G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0050 |
|
|
0054
|
CARTRIDGES, SIGNAL |
1.3G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0054 |
|
|
0055
|
CASES, CARTRIDGE, EMPTY, WITH PRIMER |
1.4S
|
– |
– |
364
|
5 kg |
E0 |
P136
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0055 |
|
|
0056
|
CHARGES, DEPTH |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0056 |
|
|
0059
|
CHARGES, SHAPED, without detonator |
1.1D
|
– |
– |
– |
0 |
E0 |
P137
|
PP70 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0059 |
|
|
0060
|
CHARGES, SUPPLEMENTARY, EXPLOSIVE |
1.1D
|
– |
– |
– |
0 |
E0 |
P132 (a) or (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0060 |
|
|
0065
|
CORD, DETONATING, flexible |
1.1D
|
– |
– |
– |
0 |
E0 |
P139
|
PP71 PP72 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0065 |
|
|
0066
|
CORD, IGNITER |
1.4G
|
– |
– |
– |
0 |
E0 |
P140
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0066 |
|
|
0070
|
CUTTERS, CABLE, EXPLOSIVE |
1.4S
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0070 |
|
|
0072
|
CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass |
1.1D
|
– |
– |
266
|
0 |
E0 |
P112 (a)
|
PP45 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Mass detonating explosive which becomes more sensitive if the wetting agent is lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0072 |
|
|
0073
|
DETONATORS FOR AMMUNITION |
1.1B
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0073 |
|
|
0074
|
DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass |
1.1A
|
– |
– |
266
|
0 |
E0 |
P110 (a) or (b)
|
PP42 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0074 |
|
|
0075
|
DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer, by mass |
1.1D
|
– |
– |
266
|
0 |
E0 |
P115
|
PP53 PP54 PP57 PP58 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0075 |
|
|
0076
|
DINITROPHENOL, dry or wetted with less than 15% water, by mass |
1.1D
|
6.1
P
|
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 04
SW1
|
SG31
|
Substance. |
0076 |
|
|
0077
|
DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass |
1.3 C
|
6.1
P
|
– |
– |
0 |
E0 |
P114 (a) or (b)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 04
SW1
|
SG31
|
Substance. |
0077 |
|
|
0078
|
DINITRORESORCINOL, dry or wetted with less than 15% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0078 |
|
|
0079
|
HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0079 |
|
|
0081
|
EXPLOSIVE, BLASTING, TYPE A |
1.1D
|
– |
– |
– |
0 |
E0 |
P116
|
PP63 PP66 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG34
|
Substance. See glossary of terms in appendix B. |
0081 |
|
|
0082
|
EXPLOSIVE, BLASTING, TYPE B |
1.1D
|
– |
– |
– |
0 |
E0 |
P116
|
PP61 PP62 |
IBC100
|
B9 |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG34
|
Substance. See glossary of terms in appendix B. |
0082 |
|
|
0083
|
EXPLOSIVE, BLASTING, TYPE C |
1.1D
|
– |
– |
267
|
0 |
E0 |
P116
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG28
|
Substance. See glossary of terms in appendix B. |
0083 |
|
|
0084
|
EXPLOSIVE, BLASTING, TYPE D |
1.1D
|
– |
– |
– |
0 |
E0 |
P116
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. See glossary of terms in appendix B. |
0084 |
|
|
0092
|
FLARES, SURFACE |
1.3G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0092 |
|
|
0093
|
FLARES, AERIAL |
1.3G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0093 |
|
|
0094
|
FLASH POWDER |
1.1G
|
– |
– |
– |
0 |
E0 |
P113
|
PP49 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0094 |
|
|
0099
|
FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells |
1.1D
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0099 |
|
|
0101
|
FUSE, NON-DETONATING |
1.3G
|
– |
– |
– |
0 |
E0 |
P140
|
PP74 PP75 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0101 |
|
|
0102
|
CORD (FUSE), DETONATING, metal-clad |
1.2D
|
– |
– |
– |
0 |
E0 |
P139
|
PP71 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0102 |
|
|
0103
|
FUSE, IGNITER tubular, metal-clad |
1.4G
|
– |
– |
– |
0 |
E0 |
P140
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0103 |
|
|
0104
|
CORD (FUSE), DETONATING, MILD EFFECT, metal-clad |
1.4D
|
– |
– |
– |
0 |
E0 |
P139
|
PP71 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0104 |
|
|
0105
|
FUSE, SAFETY |
1.4S
|
– |
– |
– |
0 |
E0 |
P140
|
PP73 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0105 |
|
|
0106
|
FUZES, DETONATING |
1.1B
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0106 |
|
|
0107
|
FUZES, DETONATING |
1.2B
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0107 |
|
|
0110
|
GRENADES, PRACTICE, hand or rifle |
1.4S
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0110 |
|
|
0113
|
GUANYL NITROSAMINO-GUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass |
1.1A
|
– |
– |
266
|
0 |
E0 |
P110 (a) or (b)
|
PP42 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0113 |
|
|
0114
|
GUANYL NITROSAMINO-GUANYLTETRAZENE (TETRAZENE), WETTED with not less than 30% water, or mixture of alcohol and water, by mass |
1.1A
|
– |
– |
266
|
0 |
E0 |
P110 (a) or (b)
|
PP42 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0114 |
|
|
0118
|
HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mixtures of mass detonating explosives. |
0118 |
|
|
0121
|
IGNITERS |
1.1G
|
– |
– |
– |
0 |
E0 |
P142
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0121 |
|
|
0124
|
JET PERFORATING GUNS, CHARGED, oil well, without detonator |
1.1D
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
SW30
|
– |
See glossary of terms in appendix B. |
0124 |
|
|
0129
|
LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass |
1.1A
|
– |
– |
266
|
0 |
E0 |
P110 (a) or (b)
|
PP42 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
SGG7
SGG9
SGG17
|
Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0129 |
|
|
0130
|
LEAD STYPHNATE (LEAD TRINITRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass |
1.1A
|
– |
– |
266
|
0 |
E0 |
P110 (a) or (b)
|
PP42 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
SGG7
SGG9
|
Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0130 |
|
|
0131
|
LIGHTERS, FUSE |
1.4S
|
– |
– |
– |
0 |
E0 |
P142
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0131 |
|
|
0132
|
DEFLAGRATING METAL SALTS OF AROMATIC NITRO-DERIVATIVES, N.O.S. |
1.3 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0132 |
|
|
0133
|
MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass |
1.1D
|
– |
– |
266
|
0 |
E0 |
P112 (a)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0133 |
|
|
0135
|
MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass |
1.1A
|
– |
– |
266
|
0 |
E0 |
P110 (a) or (b)
|
PP42 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
SGG7
SGG11
|
Sensitive substance used in detonators which will become extremely sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0135 |
|
|
0136
|
MINES with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0136 |
|
|
0137
|
MINES with bursting charge |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0137 |
|
|
0138
|
MINES with bursting charge |
1.2D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0138 |
|
|
0143
|
NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer, by mass |
1.1D
|
See SP271
|
– |
266
271
272
|
0 |
E0 |
P115
|
PP53 PP54 PP57 PP58 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 04
SW1
|
– |
Substance. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0143 |
|
|
0144
|
NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin |
1.1D
|
– |
– |
358
|
0 |
E0 |
P115
|
PP45 PP55 PP56 PP59 PP60 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0144 |
|
|
0146
|
NITROSTARCH, dry or wetted, with less than 20% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0146 |
|
|
0147
|
NITRO UREA |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0147 |
|
|
0150
|
PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), WETTED with not less than 25% water, by mass or PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), DESENSITIZED with not less than 15% phlegmatizer, by mass |
1.1D
|
– |
– |
266
|
0 |
E0 |
P112 (a) or (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive which will become more sensitive if it loses its wetting or desensitizing agent. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0150 |
|
|
0151
|
PENTOLITE, dry or wetted with less than 15% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mixtures of mass detonating explosive substances. |
0151 |
|
|
0153
|
TRINITROANILINE (PICRAMIDE) |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0153 |
|
|
0154
|
TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0154 |
|
|
0155
|
TRINITROCHLOROBENZENE (PICRYL CHLORIDE) |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0155 |
|
|
0159
|
POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass |
1.3 C
|
– |
– |
266
|
0 |
E0 |
P111
|
PP43 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance consisting of nitrocellulose impregnated with not more than 60% of nitroglycerin or other liquid organic nitrates or a mixture of these. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0159 |
|
|
0160
|
POWDER, SMOKELESS |
1.1 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
PP50 PP52 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substances based on nitrocellulose used as propellant. Sensitive to sparks, friction, pressure and electrostatic discharge. |
0160 |
|
|
0161
|
POWDER, SMOKELESS |
1.3 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
PP50 PP52 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substances based on nitrocellulose used as propellant. Sensitive to sparks, friction, pressure and electrostatic discharge. |
0161 |
|
|
0167
|
PROJECTILES with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0167 |
|
|
0168
|
PROJECTILES with bursting charge |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0168 |
|
|
0169
|
PROJECTILES with bursting charge |
1.2D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0169 |
|
|
0171
|
AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge |
1.2G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0171 |
|
|
0173
|
RELEASE DEVICES, EXPLOSIVE |
1.4S
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0173 |
|
|
0174
|
RIVETS, EXPLOSIVE |
1.4S
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0174 |
|
|
0180
|
ROCKETS with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0180 |
|
|
0181
|
ROCKETS with bursting charge |
1.1E
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0181 |
|
|
0182
|
ROCKETS with bursting charge |
1.2E
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0182 |
|
|
0183
|
ROCKETS with inert head |
1.3 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0183 |
|
|
0186
|
ROCKET MOTORS |
1.3 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0186 |
|
|
0190
|
SAMPLES, EXPLOSIVE, other than initiating explosive |
1
|
– |
– |
16
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
Substance or article. Division and compatibility group as classified by the competent authority. |
0190 |
|
|
0191
|
SIGNAL DEVICES, HAND |
1.4G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0191 |
|
|
0192
|
SIGNALS, RAILWAY TRACK, EXPLOSIVE |
1.1G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0192 |
|
|
0193
|
SIGNALS, RAILWAY TRACK, EXPLOSIVE |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0193 |
|
|
0194
|
SIGNALS, DISTRESS, ship |
1.1G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0194 |
|
|
0195
|
SIGNALS, DISTRESS, ship |
1.3G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0195 |
|
|
0196
|
SIGNALS, SMOKE |
1.1G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0196 |
|
|
0197
|
SIGNALS, SMOKE |
1.4G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0197 |
|
|
0204
|
SOUNDING DEVICES, EXPLOSIVE |
1.2 F
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0204 |
|
|
0207
|
TETRANITROANILINE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0207 |
|
|
0208
|
TRINITROPHENYLMETHYL-NITRAMINE (TETRYL) |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive. |
0208 |
|
|
0209
|
TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
PP46 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Tritonal is a substance consisting of trinitrotoluene (TNT) mixed with aluminium. |
0209 |
|
|
0212
|
TRACERS FOR AMMUNITION |
1.3 G
|
– |
– |
– |
0 |
E0 |
P133
|
PP69 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0212 |
|
|
0213
|
TRINITROANISOLE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0213 |
|
|
0214
|
TRINITROBENZENE, dry or wetted with less than 30% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0214 |
|
|
0215
|
TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0215 |
|
|
0216
|
TRINITRO-m-CRESOL |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0216 |
|
|
0217
|
TRINITRONAPHTHALENE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
–
|
Substance. |
0217 |
|
|
0218
|
TRINITROPHENETOLE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
–
|
Substance. |
0218 |
|
|
0219
|
TRINITRORESORCINOL (STYPHNIC ACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0219 |
|
|
0220
|
UREA NITRATE, dry or wetted with less than 20% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0220 |
|
|
0221
|
WARHEADS, TORPEDO with bursting charge |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0221 |
|
|
0222
|
AMMONIUM NITRATE |
1.1D
|
– |
– |
370
|
0 |
E0 |
P112 (b) or (c)
|
PP47 |
IBC100
|
B2 B3 B17 |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SGG2
SG27
|
Substance. |
0222 |
|
|
0224
|
BARIUM AZIDE, dry or wetted with less than 50% water, by mass |
1.1A
|
6.1
|
– |
– |
0 |
E0 |
P110 (a) or (b)
|
PP42 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 05
SW1
|
SGG17
|
Sensitive substance used in detonators, which becomes extremely sensitive if the wetting agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0224 |
|
|
0225
|
BOOSTERS WITH DETONATOR |
1.1B
|
– |
– |
– |
0 |
E0 |
P133
|
PP69 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0225 |
|
|
0226
|
CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15% water, by mass |
1.1D
|
– |
– |
266
|
0 |
E0 |
P112 (a)
|
PP45 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agent is lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0226 |
|
|
0234
|
SODIUM DINITRO-o-CRESOLATE, dry or wetted with less than 15% water, by mass |
1.3 C
|
6.1
P
|
– |
– |
0 |
E0 |
P114 (a) or (b)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 04
SW1
|
SG31
|
Substance. |
0234 |
|
|
0235
|
SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass |
1.3 C
|
– |
– |
– |
0 |
E0 |
P114 (a) or (b)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0235 |
|
|
0236
|
ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass |
1.3 C
|
– |
– |
– |
0 |
E0 |
P114 (a) or (b)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0236 |
|
|
0237
|
CHARGES, SHAPED, FLEXIBLE, LINEAR |
1.4D
|
– |
– |
– |
0 |
E0 |
P138
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0237 |
|
|
0238
|
ROCKETS, LINE-THROWING |
1.2 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0238 |
|
|
0240
|
ROCKETS, LINE-THROWING |
1.3 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0240 |
|
|
0241
|
EXPLOSIVE, BLASTING, TYPE E |
1.1D
|
– |
– |
– |
0 |
E0 |
P116
|
PP61 PP62 |
IBC100
|
B10 |
|
– |
– |
– |
F-B, S-X
|
Category 04
SW1
|
SG34
|
See glossary of terms in appendix B. |
0241 |
|
|
0242
|
CHARGES, PROPELLING, FOR CANNON |
1.3 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0242 |
|
|
0243
|
AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge |
1.2 H
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0243 |
|
|
0244
|
AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge |
1.3 H
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0244 |
|
|
0245
|
AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge |
1.2 H
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0245 |
|
|
0246
|
AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge |
1.3 H
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0246 |
|
|
0247
|
AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge |
1.3 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0247 |
|
|
0248
|
CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge |
1.2 L
|
4.3
|
– |
274
|
0 |
E0 |
P144
|
PP77 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0248 |
|
|
0249
|
CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge |
1.3 L
|
4.3
|
– |
274
|
0 |
E0 |
P144
|
PP77 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0249 |
|
|
0250
|
ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge |
1.3 L
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0250 |
|
|
0254
|
AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge |
1.3 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0254 |
|
|
0255
|
DETONATORS, ELECTRIC for blasting |
1.4B
|
– |
– |
399
|
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0255 |
|
|
0257
|
FUZES, DETONATING |
1.4B
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0257 |
|
|
0266
|
OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mixtures of mass detonating explosives. |
0266 |
|
|
0267
|
DETONATORS, NON-ELECTRIC for blasting |
1.4B
|
– |
– |
– |
0 |
E0 |
P131
|
PP68 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0267 |
|
|
0268
|
BOOSTERS WITH DETONATOR |
1.2B
|
– |
– |
– |
0 |
E0 |
P133
|
PP69 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0268 |
|
|
0271
|
CHARGES, PROPELLING |
1.1 C
|
– |
– |
– |
0 |
E0 |
P143
|
PP76 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0271 |
|
|
0272
|
CHARGES, PROPELLING |
1.3 C
|
– |
– |
– |
0 |
E0 |
P143
|
PP76 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0272 |
|
|
0275
|
CARTRIDGES, POWER DEVICE |
1.3 C
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0275 |
|
|
0276
|
CARTRIDGES, POWER DEVICE |
1.4 C
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0276 |
|
|
0277
|
CARTRIDGES, OIL WELL |
1.3 C
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0277 |
|
|
0278
|
CARTRIDGES, OIL WELL |
1.4 C
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0278 |
|
|
0279
|
CHARGES, PROPELLING, FOR CANNON |
1.1 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0279 |
|
|
0280
|
ROCKET MOTORS |
1.1 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0280 |
|
|
0281
|
ROCKET MOTORS |
1.2 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0281 |
|
|
0282
|
NITROGUANIDINE (PICRITE), dry or wetted with less than 20% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0282 |
|
|
0283
|
BOOSTERS without detonator |
1.2D
|
– |
– |
– |
0 |
E0 |
P132 (a) or (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0283 |
|
|
0284
|
GRENADES, hand or rifle, with bursting charge |
1.1D
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0284 |
|
|
0285
|
GRENADES, hand or rifle, with bursting charge |
1.2D
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0285 |
|
|
0286
|
WARHEADS, ROCKET with bursting charge |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0286 |
|
|
0287
|
WARHEADS, ROCKET with bursting charge |
1.2D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
|
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0287 |
|
|
0288
|
CHARGES, SHAPED, FLEXIBLE, LINEAR |
1.1D
|
– |
– |
– |
0 |
E0 |
P138
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0288 |
|
|
0289
|
CORD, DETONATING, flexible |
1.4D
|
– |
– |
– |
0 |
E0 |
P139
|
PP71 PP72 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0289 |
|
|
0290
|
CORD (FUSE), DETONATING, metal-clad |
1.1D
|
– |
– |
– |
0 |
E0 |
P139
|
PP71 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0290 |
|
|
0291
|
BOMBS with bursting charge |
1.2 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0291 |
|
|
0292
|
GRENADES, hand or rifle, with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0292 |
|
|
0293
|
GRENADES, hand or rifle, with bursting charge |
1.2 F
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0293 |
|
|
0294
|
MINES with bursting charge |
1.2 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0294 |
|
|
0295
|
ROCKETS with bursting charge |
1.2 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0295 |
|
|
0296
|
SOUNDING DEVICES, EXPLOSIVE |
1.1 F
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0296 |
|
|
0297
|
AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge |
1.4 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0297 |
|
|
0299
|
BOMBS, PHOTO-FLASH |
1.3 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0299 |
|
|
0300
|
AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge |
1.4 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0300 |
|
|
0301
|
AMMUNITION, TEAR- PRODUCING with burster, expelling charge or propelling charge |
1.4 G
|
6.1/8
|
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-Z
|
Category 02
SW1
|
SG74
|
See glossary of terms in appendix B. |
0301 |
|
|
0303
|
AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge |
1.4G
|
See SP204
|
– |
204
|
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0303 |
|
|
0305
|
FLASH POWDER |
1.3 G
|
– |
– |
– |
0 |
E0 |
P113
|
PP49 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0305 |
|
|
0306
|
TRACERS FOR AMMUNITION |
1.4 G
|
– |
– |
– |
0 |
E0 |
P133
|
PP69 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0306 |
|
|
0312
|
CARTRIDGES, SIGNAL |
1.4 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0312 |
|
|
0313
|
SIGNALS, SMOKE |
1.2 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0313 |
|
|
0314
|
IGNITERS |
1.2 G
|
– |
– |
– |
0 |
E0 |
P142
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0314 |
|
|
0315
|
IGNITERS |
1.3 G
|
– |
– |
– |
0 |
E0 |
P142
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0315 |
|
|
0316
|
FUZES, IGNITING |
1.3 G
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0316 |
|
|
0317
|
FUZES, IGNITING |
1.4 G
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0317 |
|
|
0318
|
GRENADES, PRACTICE, hand or rifle |
1.3 G
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0318 |
|
|
0319
|
PRIMERS, TUBULAR |
1.3 G
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0319 |
|
|
0320
|
PRIMERS, TUBULAR |
1.4 G
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0320 |
|
|
0321
|
CARTRIDGES FOR WEAPONS with bursting charge |
1.2E
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0321 |
|
|
0322
|
ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge |
1.2 L
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0322 |
|
|
0323
|
CARTRIDGES, POWER DEVICE |
1.4S
|
– |
– |
347
|
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0323 |
|
|
0324
|
PROJECTILES with bursting charge |
1.2 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0324 |
|
|
0325
|
IGNITERS |
1.4 G
|
– |
– |
– |
0 |
E0 |
P142
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0325 |
|
|
0326
|
CARTRIDGES FOR WEAPONS, BLANK |
1.1 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0326 |
|
|
0327
|
CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK |
1.3 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0327 |
|
|
0328
|
CARTRIDGES FOR WEAPONS, INERT PROJECTILE |
1.2 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0328 |
|
|
0329
|
TORPEDOES with bursting charge |
1.1E
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0329 |
|
|
0330
|
TORPEDOES with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0330 |
|
| △ |
0331
|
EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B) |
1.5D
|
– |
– |
– |
0 |
E0 |
P116
|
PP61 PP62 PP64 |
IBC100
|
– |
|
– |
T1
|
TP17 TP32
|
F-B, S-Y
|
Category 03
SW1
|
SG34
|
See glossary of terms in appendix B. |
0331 |
△ |
|
0332
|
EXPLOSIVE, BLASTING, TYPE E (AGENT, BLASTING, TYPE E) |
1.5D
|
– |
– |
– |
0 |
E0 |
P116
|
PP61 PP62 |
IBC100
|
– |
|
– |
T1
|
TP1 TP17 TP32
|
F-B, S-Y
|
Category 03
SW1
|
SG34
|
See glossary of terms in appendix B. |
0332 |
|
|
0333
|
FIREWORKS |
1.1 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0333 |
|
|
0334
|
FIREWORKS |
1.2 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0334 |
|
|
0335
|
FIREWORKS |
1.3 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0335 |
|
|
0336
|
FIREWORKS |
1.4 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0336 |
|
|
0337
|
FIREWORKS |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0337 |
|
|
0338
|
CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK |
1.4 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0338 |
|
|
0339
|
CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS |
1.4 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0339 |
|
|
0340
|
NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass |
1.1D
|
– |
– |
393
|
0 |
E0 |
P112 (c) or (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0340 |
|
|
0341
|
NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass |
1.1D
|
– |
– |
393
|
0 |
E0 |
P112 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0341 |
|
|
0342
|
NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass |
1.3 C
|
– |
– |
105
393
|
0 |
E0 |
P114 (a)
|
PP43 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0342 |
|
|
0343
|
NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass |
1.3 C
|
– |
– |
105
393
|
0 |
E0 |
P111
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0343 |
|
|
0344
|
PROJECTILES with bursting charge |
1.4D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0344 |
|
|
0345
|
PROJECTILES, inert with tracer |
1.4S
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0345 |
|
|
0346
|
PROJECTILES with burster or expelling charge |
1.2D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0346 |
|
|
0347
|
PROJECTILES with burster or expelling charge |
1.4D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0347 |
|
|
0348
|
CARTRIDGES FOR WEAPONS with bursting charge |
1.4 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0348 |
|
|
0349
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.4S
|
– |
– |
178
274
347
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
– |
0349 |
|
|
0350
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.4B
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
– |
0350 |
|
|
0351
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.4 C
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
– |
0351 |
|
|
0352
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.4D
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
– |
0352 |
|
|
0353
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.4 G
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
– |
0353 |
|
|
0354
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.1 L
|
See SP943
|
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
– |
0354 |
|
|
0355
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.2 L
|
See SP943
|
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
– |
0355 |
|
|
0356
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.3 L
|
See SP943
|
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
– |
0356 |
|
|
0357
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.1 L
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
– |
0357 |
|
|
0358
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.2 L
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
– |
0358 |
|
|
0359
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.3 L
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
– |
0359 |
|
|
0360
|
DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting |
1.1B
|
– |
– |
– |
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0360 |
|
|
0361
|
DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting |
1.4B
|
– |
– |
– |
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0361 |
|
|
0362
|
AMMUNITION, PRACTICE |
1.4 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0362 |
|
|
0363
|
AMMUNITION, PROOF |
1.4 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0363 |
|
|
0364
|
DETONATORS FOR AMMUNITION |
1.2B
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0364 |
|
|
0365
|
DETONATORS FOR AMMUNITION |
1.4B
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0365 |
|
|
0366
|
DETONATORS FOR AMMUNITION |
1.4S
|
– |
– |
347
|
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0366 |
|
|
0367
|
FUZES, DETONATING |
1.4S
|
– |
– |
347
|
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0367 |
|
|
0368
|
FUZES, IGNITING |
1.4S
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0368 |
|
|
0369
|
WARHEADS, ROCKET with bursting charge |
1.1 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0369 |
|
|
0370
|
WARHEADS, ROCKET with burster or expelling charge |
1.4D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0370 |
|
|
0371
|
WARHEADS, ROCKET with burster or expelling charge |
1.4 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0371 |
|
|
0372
|
GRENADES, PRACTICE, hand or rifle |
1.2 G
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0372 |
|
|
0373
|
SIGNAL DEVICES, HAND |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0373 |
|
|
0374
|
SOUNDING DEVICES, EXPLOSIVE |
1.1D
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0374 |
|
|
0375
|
SOUNDING DEVICES, EXPLOSIVE |
1.2D
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0375 |
|
|
0376
|
PRIMERS, TUBULAR |
1.4S
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0376 |
|
|
0377
|
PRIMERS, CAP TYPE |
1.1B
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0377 |
|
|
0378
|
PRIMERS, CAP TYPE |
1.4B
|
– |
– |
– |
0 |
E0 |
P133
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0378 |
|
|
0379
|
CASES, CARTRIDGE, EMPTY, WITH PRIMER |
1.4 C
|
– |
– |
– |
0 |
E0 |
P136
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0379 |
|
|
0380
|
ARTICLES, PYROPHORIC |
1.2 L
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0380 |
|
|
0381
|
CARTRIDGES, POWER DEVICE |
1.2 C
|
– |
– |
– |
0 |
E0 |
P134
LP102
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0381 |
|
|
0382
|
COMPONENTS, EXPLOSIVE TRAIN, N.O.S. |
1.2B
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0382 |
|
|
0383
|
COMPONENTS, EXPLOSIVE TRAIN, N.O.S. |
1.4B
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0383 |
|
|
0384
|
COMPONENTS, EXPLOSIVE TRAIN, N.O.S. |
1.4S
|
– |
– |
178
274
347
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0384 |
|
|
0385
|
5-NITROBENZOTRIAZOL |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0385 |
|
|
0386 |
TRINITROBENZENESULPHONIC ACID |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. |
0386 |
|
|
0387
|
TRINITROFLUORENONE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0387 |
|
|
0388
|
TRINITROTOLUENE (TNT) AND TRINITROBENZENE MIXTURE or TRINITROTOLUENE (TNT) AND HEXANITROSTILBENE MIXTURE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0388 |
|
|
0389
|
TRINITROTOLUENE (TNT) MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0389 |
|
|
0390
|
TRITONAL |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Tritonal is a substance consisting of trinitrotoluene (TNT) mixed with aluminium. |
0390 |
|
|
0391
|
CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN) MIXTURE, WETTED with not less than 15% water, by mass or CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN) MIXTURE, DESENSITIZED with not less than 10% phlegmatizer, by mass |
1.1D
|
– |
– |
266
|
0 |
E0 |
P112 (c) or (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be transported, unless specifically authorized by the competent authority. |
0391 |
|
|
0392
|
HEXANITROSTILBENE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive. |
0392 |
|
|
0393
|
HEXOTONAL |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive. |
0393 |
|
|
0394
|
TRINITRORESORCINOL (STYPHNIC ACID), WETTED with not less than 20% water, or mixture of alcohol and water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a)
|
PP26 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SG31
|
Substance. Mass detonating explosive. |
0394 |
|
|
0395
|
ROCKET MOTORS, LIQUID FUELLED |
1.2 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0395 |
|
|
0396
|
ROCKET MOTORS, LIQUID FUELLED |
1.3 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0396 |
|
|
0397
|
ROCKETS, LIQUID FUELLED with bursting charge |
1.1 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0397 |
|
|
0398
|
ROCKETS, LIQUID FUELLED with bursting charge |
1.2 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0398 |
|
|
0399
|
BOMBS WITH FLAMMABLE LIQUID with bursting charge |
1.1 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0399 |
|
|
0400
|
BOMBS WITH FLAMMABLE LIQUID with bursting charge |
1.2 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0400 |
|
|
0401
|
DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (a), (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0401 |
|
|
0402
|
AMMONIUM PERCHLORATE |
1.1D
|
– |
– |
152
|
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
SGG2
SG27
|
Substance. |
0402 |
|
|
0403
|
FLARES, AERIAL |
1.4 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0403 |
|
|
0404
|
FLARES, AERIAL |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0404 |
|
|
0405
|
CARTRIDGES, SIGNAL |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0405 |
|
|
0406
|
DINITROSOBENZENE |
1.3 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0406 |
|
|
0407
|
TETRAZOL−1-ACETIC ACID |
1.4 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 02
SW1
|
– |
Substance. |
0407 |
|
|
0408
|
FUZES, DETONATING with protective features |
1.1D
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0408 |
|
|
0409
|
FUZES, DETONATING with protective features |
1.2D
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0409 |
|
|
0410
|
FUZES, DETONATING with protective features |
1.4D
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0410 |
|
|
0411
|
PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with not less than 7% wax, by mass |
1.1D
|
– |
– |
131
|
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0411 |
|
|
0412
|
CARTRIDGES FOR WEAPONS with bursting charge |
1.4E
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0412 |
|
|
0413
|
CARTRIDGES FOR WEAPONS, BLANK |
1.2 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0413 |
|
|
0414
|
CHARGES, PROPELLING, FOR CANNON |
1.2 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0414 |
|
|
0415
|
CHARGES, PROPELLING |
1.2 C
|
– |
– |
– |
0 |
E0 |
P143
|
PP76 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0415 |
|
|
0417
|
CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS |
1.3 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0417 |
|
|
0418
|
FLARES, SURFACE |
1.1 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0418 |
|
|
0419
|
FLARES, SURFACE |
1.2 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0419 |
|
|
0420
|
FLARES, AERIAL |
1.1 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0420 |
|
|
0421
|
FLARES, AERIAL |
1.2 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0421 |
|
|
0424
|
PROJECTILES, inert with tracer |
1.3 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0424 |
|
|
0425
|
PROJECTILES, inert with tracer |
1.4 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0425 |
|
|
0426
|
PROJECTILES with burster or expelling charge |
1.2 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0426 |
|
|
0427
|
PROJECTILES with burster or expelling charge |
1.4 F
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0427 |
|
|
0428
|
ARTICLES, PYROTECHNIC for technical purposes |
1.1 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0428 |
|
|
0429
|
ARTICLES, PYROTECHNIC for technical purposes |
1.2 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0429 |
|
|
0430
|
ARTICLES, PYROTECHNIC for technical purposes |
1.3 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0430 |
|
|
0431
|
ARTICLES, PYROTECHNIC for technical purposes |
1.4 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0431 |
|
|
0432
|
ARTICLES, PYROTECHNIC for technical purposes |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0432 |
|
|
0433
|
POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass |
1.1 C
|
– |
– |
266
|
0 |
E0 |
P111
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0433 |
|
|
0434
|
PROJECTILES with burster or expelling charge |
1.2 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0434 |
|
|
0435
|
PROJECTILES with burster or expelling charge |
1.4 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0435 |
|
|
0436
|
ROCKETS with expelling charge |
1.2 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0436 |
|
|
0437
|
ROCKETS with expelling charge |
1.3 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0437 |
|
|
0438
|
ROCKETS with expelling charge |
1.4 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0438 |
|
|
0439
|
CHARGES, SHAPED, without detonator |
1.2D
|
– |
– |
– |
0 |
E0 |
P137
|
PP70 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0439 |
|
|
0440
|
CHARGES, SHAPED, without detonator |
1.4D
|
– |
– |
– |
0 |
E0 |
P137
|
PP70 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0440 |
|
|
0441
|
CHARGES, SHAPED, without detonator |
1.4S
|
– |
– |
347
|
0 |
E0 |
P137
|
PP70 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0441 |
|
|
0442
|
CHARGES, EXPLOSIVE, COMMERCIAL without detonator |
1.1D
|
– |
– |
– |
0 |
E0 |
P137
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0442 |
|
|
0443
|
CHARGES, EXPLOSIVE, COMMERCIAL without detonator |
1.2D
|
– |
– |
– |
0 |
E0 |
P137
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0443 |
|
|
0444
|
CHARGES, EXPLOSIVE, COMMERCIAL without detonator |
1.4D
|
– |
– |
– |
0 |
E0 |
P137
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0444 |
|
|
0445
|
CHARGES, EXPLOSIVE, COMMERCIAL without detonator |
1.4S
|
– |
– |
347
|
0 |
E0 |
P137
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0445 |
|
|
0446
|
CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER |
1.4 C
|
– |
– |
– |
0 |
E0 |
P136
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0446 |
|
|
0447
|
CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER |
1.3 C
|
– |
– |
– |
0 |
E0 |
P136
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0447 |
|
|
0448
|
5-MERCAPTOTETRAZOL−1-ACETIC ACID |
1.4 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 02
SW1
|
– |
Substance. |
0448 |
|
|
0449
|
TORPEDOES, LIQUID FUELLED with or without bursting charge |
1.1 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0449 |
|
|
0450
|
TORPEDOES, LIQUID FUELLED with inert head |
1.3 J
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
SG67
|
See glossary of terms in appendix B. |
0450 |
|
|
0451
|
TORPEDOES with bursting charge |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0451 |
|
|
0452
|
GRENADES, PRACTICE, hand or rifle |
1.4 G
|
– |
– |
– |
0 |
E0 |
P141
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0452 |
|
|
0453
|
ROCKETS, LINE-THROWING |
1.4 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0453 |
|
|
0454
|
IGNITERS |
1.4S
|
– |
– |
– |
0 |
E0 |
P142
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0454 |
|
|
0455
|
DETONATORS, NON-ELECTRIC for blasting |
1.4S
|
– |
– |
347
|
0 |
E0 |
P131
|
PP68 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0455 |
|
|
0456
|
DETONATORS, ELECTRIC for blasting |
1.4S
|
– |
– |
347
399
|
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0456 |
|
|
0457
|
CHARGES, BURSTING, PLASTICS BONDED |
1.1D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0457 |
|
|
0458
|
CHARGES, BURSTING, PLASTICS BONDED |
1.2D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0458 |
|
|
0459
|
CHARGES, BURSTING, PLASTICS BONDED |
1.4D
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0459 |
|
|
0460
|
CHARGES, BURSTING, PLASTICS BONDED |
1.4S
|
– |
– |
347
|
0 |
E0 |
P130
LP101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0460 |
|
|
0461
|
COMPONENTS, EXPLOSIVE TRAIN, N.O.S. |
1.1B
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0461 |
|
|
0462
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.1 C
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0462 |
|
|
0463
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.1D
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0463 |
|
|
0464
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.1E
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0464 |
|
|
0465
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.1 F
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0465 |
|
|
0466
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.2 C
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0466 |
|
|
0467
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.2D
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0467 |
|
|
0468
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.2E
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0468 |
|
|
0469
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.2 F
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0469 |
|
|
0470
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.3 C
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0470 |
|
|
0471
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.4E
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0471 |
|
|
0472
|
ARTICLES, EXPLOSIVE, N.O.S. |
1.4 F
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
– |
0472 |
|
|
0473
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.1A
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 05
SW1
|
– |
– |
0473 |
|
|
0474
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.1 C
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
– |
0474 |
|
|
0475
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.1D
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
– |
0475 |
|
|
0476
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.1 G
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 03
SW1
|
– |
– |
0476 |
|
|
0477
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.3 C
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
– |
0477 |
|
|
0478
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.3 G
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 03
SW1
|
– |
– |
0478 |
|
|
0479
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.4 C
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 02
SW1
|
– |
– |
0479 |
|
|
0480
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.4D
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 02
SW1
|
– |
– |
0480 |
|
|
0481
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.4S
|
– |
– |
178
274
347
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 01
SW1
|
– |
– |
0481 |
|
|
0482
|
SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S. |
1.5D
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 03
SW1
|
– |
– |
0482 |
|
|
0483
|
CYCLOTRIMETHYLENE-TRINITRAMINE (CYCLONITE; HEXOGEN; RDX), DESENSITIZED |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. |
0483 |
|
|
0484
|
CYCLOTETRAMETHYLENE-TETRANITRAMINE (HMX; OCTOGEN), DESENSITIZED |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mass detonating explosive which will become more sensitive if the wetting or desensitizing agents are lost. |
0484 |
|
|
0485
|
SUBSTANCES, EXPLOSIVE, N.O.S. |
1.4 G
|
– |
– |
178
274
|
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 02
SW1
|
– |
– |
0485 |
|
|
0486
|
ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) |
1.6 N
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0486 |
|
|
0487
|
SIGNALS, SMOKE |
1.3 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0487 |
|
|
0488
|
AMMUNITION, PRACTICE |
1.3 G
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0488 |
|
|
0489
|
DINITROGLYCOLURIL (DINGU) |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0489 |
|
|
0490
|
NITROTRIAZOLONE (NTO) |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0490 |
|
|
0491
|
CHARGES, PROPELLING |
1.4 C
|
– |
– |
– |
0 |
E0 |
P143
|
PP76 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0491 |
|
|
0492
|
SIGNALS, RAILWAY TRACK, EXPLOSIVE |
1.3 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0492 |
|
|
0493
|
SIGNALS, RAILWAY TRACK, EXPLOSIVE |
1.4 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0493 |
|
|
0494
|
JET PERFORATING GUNS, CHARGED, oil well, without detonator |
1.4D
|
– |
– |
– |
0 |
E0 |
P101
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
SW30
|
– |
See glossary of terms in appendix B. |
0494 |
|
|
0495
|
PROPELLANT, LIQUID |
1.3 C
|
– |
– |
224
|
0 |
E0 |
P115
|
PP53 PP54 PP57 PP58 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0495 |
|
|
0496
|
OCTONAL |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (b) or (c)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. Mixtures of mass detonating explosives. |
0496 |
|
|
0497
|
PROPELLANT, LIQUID |
1.1 C
|
– |
– |
224
|
0 |
E0 |
P115
|
PP53 PP54 PP57 PP58 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0497 |
|
|
0498
|
PROPELLANT, SOLID |
1.1 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0498 |
|
|
0499
|
PROPELLANT, SOLID |
1.3 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
See glossary of terms in appendix B. |
0499 |
|
|
0500
|
DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting |
1.4S
|
– |
– |
347
|
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0500 |
|
|
0501
|
PROPELLANT, SOLID |
1.4 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
– |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0501 |
|
|
0502
|
ROCKETS with inert head |
1.2 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 03
SW1
|
– |
See glossary of terms in appendix B. |
0502 |
|
|
0503
|
SAFETY DEVICES, PYROTECHNIC |
1.4 G
|
– |
– |
235
289
|
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0503 |
|
|
0504
|
1 H-TETRAZOLE |
1.1D
|
– |
– |
– |
0 |
E0 |
P112 (c)
|
PP48 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0504 |
|
|
0505
|
SIGNALS, DISTRESS, ship |
1.4 G
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0505 |
|
|
0506
|
SIGNALS, DISTRESS, ship |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0506 |
|
|
0507
|
SIGNALS, SMOKE |
1.4S
|
– |
– |
– |
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0507 |
|
|
0508
|
1-HYDROXYBENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass |
1.3 C
|
– |
– |
– |
0 |
E0 |
P114 (b)
|
PP48 PP50 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 04
SW1
|
– |
Substance. |
0508 |
|
|
0509
|
POWDER, SMOKELESS |
1.4 C
|
– |
– |
– |
0 |
E0 |
P114(b)
|
PP48 |
– |
– |
|
– |
– |
– |
F-B, S-Y
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0509 |
|
|
0510
|
ROCKET MOTORS |
1.4 C
|
– |
– |
– |
0 |
E0 |
P130
LP101
|
PP67 L1 |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 02
SW1
|
– |
See glossary of terms in appendix B. |
0510 |
|
|
0511
|
DETONATORS, ELECTRONIC programmable for blasting |
1.1B
|
– |
– |
399
|
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0511 |
|
|
0512
|
DETONATORS, ELECTRONIC programmable for blasting |
1.4B
|
– |
– |
399
|
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 05
SW1
|
– |
See glossary of terms in appendix B. |
0512 |
|
|
0513
|
DETONATORS, ELECTRONIC programmable for blasting |
1.4S
|
– |
– |
347
399
|
0 |
E0 |
P131
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0513 |
|
| ■ |
0514
|
FIRE SUPPRESSANT DISPERSING DEVICES |
1.4S
|
– |
– |
407
|
0 |
E0 |
P135
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category 01
SW1
|
– |
See glossary of terms in appendix B. |
0514 |
■ |
|
1001
|
ACETYLENE, DISSOLVED |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW1
SW2
|
SG46
|
Flammable gas with slight odour. Explosive limits: 2.1% to 80%. Lighter than air (0.907). Rough handling and exposure to local heating should be avoided, since these conditions may result in delayed explosion. Empty cylinders should be carried with the same precautions as filled cylinders. |
1001 |
|
|
1002
|
AIR, COMPRESSED |
2.2
|
– |
– |
392
397
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Non-flammable gas. |
1002 |
|
|
1003
|
AIR, REFRIGERATED LIQUID |
2.2
|
5.1
|
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5 TP22
|
F-C, S-W
|
Category D
|
– |
Liquefied, non-flammable gas. Strong oxidizing agent. Mixtures of liquid air with combustible materials or oils may explode. May ignite organic materials. |
1003 |
|
|
1005
|
AMMONIA, ANHYDROUS |
2.3
|
8
P
|
– |
23
379
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-U
|
Category D
SW2
|
SGG18
SG35
SG46
|
Liquefied, non-flammable, toxic and corrosive gas with a pungent odour. Lighter than air (0.6). Suffocating in low concentrations. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. Reacts violently with acids. Highly irritating to skin, eyes and mucous membranes. |
1005 |
|
| △ |
1006
|
ARGON, COMPRESSED |
2.2
|
– |
– |
378
392
406
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Inert gas. Heavier than air (1.4). |
1006 |
△ |
|
1008
|
BORON TRIFLUORIDE |
2.3
|
8
|
– |
373
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass and most metals. Much heavier than air (2.35). Highly irritating to skin, eyes and mucous membranes. |
1008 |
|
|
1009
|
BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas with a slight odour. Much heavier than air (5.2). |
1009 |
|
| △ |
1010
|
BUTADIENES, STABILIZED or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, containing more than 20% butadienes |
2.1
|
– |
– |
386
402
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW1
SW2
|
– |
Liquefied, flammable gas with an unpleasant odour. Explosive limits: 2% to 12%. Heavier than air (1.84). |
1010 |
△ |
|
1011
|
BUTANE |
2.1
|
– |
– |
392
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category E
SW2
|
– |
Flammable hydrocarbon gas. Explosive limits: 1.8% to 8.4%. Heavier than air (2.11). |
1011 |
|
|
1012
|
BUTYLENE |
2.1
|
– |
– |
398
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category E
SW2
|
– |
Flammable hydrocarbon gas. Explosive limits: 1.6% to 10%. Heavier than air (2.0). |
1012 |
|
| △ |
1013
|
CARBON DIOXIDE |
2.2
|
– |
– |
378
392
406
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas. Heavier than air (1.5). Cannot remain in the liquid state above 31°C. |
1013 |
△ |
|
1016
|
CARBON MONOXIDE, COMPRESSED |
2.3
|
2.1
|
– |
974
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable, toxic, odourless gas. Explosive limits: 12% to 75%. Slightly lighter than air (0.97). |
1016 |
|
|
1017
|
CHLORINE |
2.3
|
5.1/8
P
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
TP19
|
F-C, S-U
|
Category D
SW2
|
SG6
SG19
|
Non-flammable, toxic and corrosive yellow gas with a pungent odour. Corrosive to glass and to most metals. Much heavier than air (2.4). Highly irritating to skin, eyes and mucous membranes. Powerful oxidant which may cause fire. |
1017 |
|
|
1018
|
CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (3.0). |
1018 |
|
|
1020
|
CHLOROPENTAFLUORO-ETHANE (REFRIGERANT GAS R 115) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas. Much heavier than air (5.4). |
1020 |
|
|
1021
|
1-CHLORO−1,2,2,2-TETRA-FLUOROETHANE (REFRIGERANT GAS R 124) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas. Much heavier than air (4.7). |
1021 |
|
|
1022
|
CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas. Much heavier than air (3.6). Cannot remain in the liquid state above 29°C. |
1022 |
|
|
1023
|
COAL GAS, COMPRESSED |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable, toxic gas. Explosive limits: 4.5% to 40%. Much lighter than air (0.4 to 0.6). |
1023 |
|
|
1026
|
CYANOGEN |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Liquefied, flammable, toxic gas with a pungent odour. Explosive limits: 6.6% to 43%. Heavier than air (1.9). |
1026 |
|
|
1027
|
CYCLOPROPANE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category E
SW2
|
– |
Flammable hydrocarbon gas. Heavier than air. |
1027 |
|
|
1028
|
DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas. Much heavier than air (4.2). |
1028 |
|
|
1029
|
DICHLOROFLUOROMETHANE (REFRIGERANT GAS R 21) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (3.6). Boiling point: 9°C. |
1029 |
|
|
1030
|
1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW2
|
– |
Flammable gas. Explosive limits: 5% to 17%. Much heavier than air (2.3). |
1030 |
|
|
1032
|
DIMETHYLAMINE, ANHYDROUS |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category D
SW2
|
SG35
|
Liquefied, flammable gas with an ammonia-like odour. Heavier than air (1.6). Boiling point: 7°C. Suffocating in low concentrations. |
1032 |
|
|
1033
|
DIMETHYL ETHER |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW2
|
– |
Flammable gas with a chloroform-like odour. Heavier than air (1.6). |
1033 |
|
|
1035
|
ETHANE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category E
SW2
|
– |
Flammable gas. Explosive limits: 3% to 16%. Slightly heavier than air (1.05). |
1035 |
|
|
1036
|
ETHYLAMINE |
2.1
|
– |
– |
912
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category D
SW2
|
SG35
|
Liquefied, flammable gas with an ammonia-like odour. Explosive limits: 3.5% to 14%. Heavier than air (1.6). Boiling point: 17°C. |
1036 |
|
|
1037
|
ETHYL CHLORIDE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 3.5% to 15%. Much heavier than air (2.2). Boiling point: 13°C. |
1037 |
|
|
1038
|
ETHYLENE, REFRIGERATED LIQUID |
2.1
|
– |
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-D, S-U
|
Category D
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 3% to 34%. Lighter than air (0.98). |
1038 |
|
|
1039
|
ETHYL METHYL ETHER |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category B
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 2% to 10%. Much heavier than air (2.1). Boiling point: 11°C. |
1039 |
|
|
1040
|
ETHYLENE OXIDE or ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50°C |
2.3
|
2.1
|
– |
342
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
TP20 TP90
|
F-D, S-U
|
Category D
SW2
|
– |
Liquefied, flammable, toxic gases with an ether-like odour. Heavier than air (1.5). Boiling point: 11°C. |
1040 |
|
|
1041
|
ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW2
|
– |
Liquefied, flammable gas with an ether-like odour. Heavier than air (1.5). |
1041 |
|
|
1043
|
FERTILIZER AMMONIATING SOLUTION with free ammonia |
2.2
|
– |
– |
– |
120 mL |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category E
SW2
|
– |
Non-flammable aqueous solution of ammonium nitrate, calcium nitrate, urea and their mixtures containing ammonia gas. Emits toxic vapours of ammonia. |
1043 |
|
|
1044
|
FIRE EXTINGUISHERS with compressed or liquefied gas |
2.2
|
– |
– |
225
|
120 mL |
E0 |
P003
|
PP91 |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Fire extinguishers, containing compressed or liquefied gases under pressure above 175 kPa for expelling fire-extinguishing contents. |
1044 |
|
|
1045
|
FLUORINE, COMPRESSED |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
Non-flammable, toxic and corrosive pale yellowish gas with a pungent odour. Powerful oxidant which may cause fire. Reacts with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Will explode when mixed with hydrogen. Heavier than air (1.3). Highly irritating to skin, eyes and mucous membranes. |
1045 |
|
| △ |
1046
|
HELIUM, COMPRESSED |
2.2
|
– |
– |
378
392
406
974
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Inert gas. Much lighter than air (0.14). |
1046 |
△ |
|
1048
|
HYDROGEN BROMIDE, ANHYDROUS |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic and corrosive gas with a pungent odour. Highly corrosive in the presence of water. Much heavier than air (3.6). Highly irritating to the skin, eyes and mucous membranes. |
1048 |
|
|
1049
|
HYDROGEN, COMPRESSED |
2.1
|
– |
– |
392
974
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category E
SW2
|
SG46
|
Flammable, odourless gas. Explosive limits: 4% to 75%. Much lighter than air (0.07). |
1049 |
|
|
1050
|
HYDROGEN CHLORIDE, ANHYDROUS |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic and corrosive colourless gas with a pungent odour. Highly corrosive in the presence of water. Heavier than air (1.3). Highly irritating to skin, eyes and mucous membranes. |
1050 |
|
|
1051
|
HYDROGEN CYANIDE, STABILIZED containing less than 3% water |
6.1
|
3
P
|
I |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category D
SW1
SW2
|
– |
Very volatile, colourless flammable liquid, evolving extremely toxic flammable vapours. Boiling point: 26°C. Flashpoint: −18°C c.c. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1051 |
|
|
1052
|
HYDROGEN FLUORIDE, ANHYDROUS |
8
|
6.1
|
I |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T10
|
TP2
|
F-C, S-U
|
Category D
SW2
|
SGG1
SG36
SG49
|
Colourless, fuming and highly volatile liquid with an irritating and pungent odour. Highly corrosive to metals and glass in the presence of moisture. Boiling point: 20°C. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. |
1052 |
|
|
1053
|
HYDROGEN SULPHIDE |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.2). |
1053 |
|
|
1055
|
ISOBUTYLENE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category E
SW2
|
– |
Flammable hydrocarbon gas. Explosive limits: 1.8% to 8.8%. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air (1.94). |
1055 |
|
|
1056
|
KRYPTON, COMPRESSED |
2.2
|
– |
– |
378
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Inert gas. Much heavier than air (2.9). |
1056 |
|
|
1057
|
LIGHTERS or LIGHTER REFILLS containing flammable gas |
2.1
|
– |
– |
201
|
0 |
E0 |
P002
|
PP84 |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category B
SW2
|
– |
Lighters or lighter refills containing butane or other flammable gas. |
1057 |
|
|
1058
|
LIQUEFIED GASES non-flammable, charged with nitrogen, carbon dioxide or air |
2.2
|
– |
– |
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Non-flammable gases or mixtures of such gases which are used for filling receptacles from which the contents are to be dispersed under pressure. Vapour may be heavier than air. |
1058 |
|
|
1060
|
METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW1
SW2
|
– |
Flammable gas. Explosive limits: 3% to 11%. Heavier than air (1.4). |
1060 |
|
|
1061
|
METHYLAMINE, ANHYDROUS |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW2
|
SG35
|
Liquefied, flammable gas with an ammonia-like odour. Heavier than air (1.09). |
1061 |
|
|
1062
|
METHYL BROMIDE with not more than 2.0% chloropicrin |
2.3
|
– |
– |
23
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-U
|
Category D
SW2
|
– |
Liquefied, toxic gas with a chloroform-like odour. Much heavier than air (3.3). Boiling point: 4.5°C. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. |
1062 |
|
|
1063
|
METHYL CHLORIDE (REFRIGERANT GAS R 40) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category D
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 8% to 20%. Heavier than air (1.8). |
1063 |
|
|
1064
|
METHYL MERCAPTAN |
2.3
|
2.1
P
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category D
SW2
|
– |
Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.7). Boiling point: 6°C. |
1064 |
|
|
1065
|
NEON, COMPRESSED |
2.2
|
– |
– |
378
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Inert gas. Lighter than air (0.7). |
1065 |
|
| △ |
1066
|
NITROGEN, COMPRESSED |
2.2
|
– |
– |
378
392
406
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Non-flammable, odourless gas. Lighter than air (0.97). |
1066 |
△ |
|
1067
|
DINITROGEN TETROXIDE (NITROGEN DIOXIDE) |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
TP21
|
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
Liquefied, non-flammable, toxic and corrosive gas which gives off brown vapour with a pungent odour. Strong oxidizing agent. Boiling point: 21°C. Highly irritating to skin, eyes and mucous membranes. Toxic by inhalation, with delayed effect, similar to phosgene. |
1067 |
|
|
1069
|
NITROSYL CHLORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic yellow gas with an irritating odour. Corrosive to steel. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. |
1069 |
|
|
1070
|
NITROUS OXIDE |
2.2
|
5.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category A
SW2
|
– |
Non-flammable gas. Strong oxidizing agent. Heavier than air (1.5). |
1070 |
|
|
1071
|
OIL GAS, COMPRESSED |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable, toxic gas. A mixture of hydrocarbons and carbon monoxide. |
1071 |
|
|
1072
|
OXYGEN, COMPRESSED |
2.2
|
5.1
|
– |
355
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category A
|
– |
Non-flammable, odourless gas. Strong oxidizing agent. Heavier than air (1.1). |
1072 |
|
|
1073
|
OXYGEN, REFRIGERATED LIQUID |
2.2
|
5.1
|
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5 TP22
|
F-C, S-W
|
Category D
|
– |
Liquefied, non-flammable gas. Strong oxidizing agent. Mixtures of liquid oxygen with acetylene or oils may explode. |
1073 |
|
|
1075
|
PETROLEUM GASES, LIQUEFIED |
2.1
|
– |
– |
392
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category E
SW2
|
– |
Flammable hydrocarbon gases or mixtures obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air. |
1075 |
|
|
1076
|
PHOSGENE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Liquefied, non-flammable, toxic and corrosive gas with a foul odour. Corrosive in the presence of water. Much heavier than air (3.5). Boiling point: 8°C. Highly irritating to skin, eyes and mucous membranes. This gas is particularly dangerous in that it may be inhaled without immediate effect but can cause severe damage and death after a few hours’ delay. |
1076 |
|
|
1077
|
PROPYLENE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category E
SW2
|
– |
Flammable hydrocarbon gas. Explosive limits: 2% to 11.1%. Heavier than air (1.5). |
1077 |
|
|
1078
|
REFRIGERANT GAS, N.O.S. |
2.2
|
– |
– |
274
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Different chlorofluorohydrocarbons or other non-flammable, non-toxic gases considered as refrigerant agents. |
1078 |
|
|
1079
|
SULPHUR DIOXIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
TP19
|
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic and corrosive gas with a pungent odour. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. |
1079 |
|
|
1080
|
SULPHUR HEXAFLUORIDE |
2.2
|
– |
– |
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, odourless gas. Much heavier than air (5.1). |
1080 |
|
|
1081
|
TETRAFLUOROETHYLENE, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category E
SW1
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 11% to 60%. Much heavier than air (3.5). Irritating to skin, eyes and mucous membranes. |
1081 |
|
|
1082
|
TRIFLUOROCHLORO-ETHYLENE, STABILIZED (REFRIGERANT GAS R 1113) |
2.3
|
2.1
|
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category D
SW1
SW2
|
– |
Flammable, toxic, odourless gas. Explosive limits: 8.4% to 38.7%. Much heavier than air (4.0). |
1082 |
|
|
1083
|
TRIMETHYLAMINE, ANHYDROUS |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW2
|
SG35
|
Liquefied, flammable gas with a fishy odour. Explosive limits: 2% to 12%. Much heavier than air (2.1). Boiling point: 3°C. |
1083 |
|
|
1085
|
VINYL BROMIDE, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW1
SW2
|
– |
Liquefied, flammable gas. Much heavier than air (3.7). Boiling point: 16°C. |
1085 |
|
|
1086
|
VINYL CHLORIDE, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW1
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 4% to 31%. Much heavier than air (2.2). |
1086 |
|
|
1087
|
VINYL METHYL ETHER, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category B
SW1
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 2.6% to 39%. Heavier than air (2.0). Boiling point: 6°C. |
1087 |
|
|
1088
|
ACETAL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category E
|
– |
Colourless, volatile liquid with an agreeable odour. Flashpoint: below −18°C c.c. Explosive limits: 1.6% to 10.4%. Miscible with water. |
1088 |
|
|
1089
|
ACETALDEHYDE |
3
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-D
|
Category E
|
– |
Colourless liquid with a pungent, fruity odour. Flashpoint: −27°C c.c. Explosive limits: 4% to 57%. Boiling point: 21°C. Miscible with water. Harmful if swallowed or by inhalation. |
1089 |
|
|
1090
|
ACETONE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category E
|
– |
Colourless, clear liquid, with a characteristic mint-like odour. Flashpoint: −20°C to −18°C c.c. Explosive limits: 2.5% to 13%. Miscible with water. |
1090 |
|
|
1091
|
ACETONE OILS |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
Light yellow to brownish, oily liquids. Flashpoint: −4°C to 8°C c.c. Immiscible with water. |
1091 |
|
|
1092
|
ACROLEIN, STABILIZED |
6.1
|
3
P
|
I |
354
386
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP7 TP13
|
F-E, S-D
|
Category D
SW1
SW2
|
– |
Colourless or yellow liquid with a most irritating odour. Flashpoint: −26°C c.c. Explosive limits: 2.8% to 31%. Boiling point: 52°C. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1092 |
|
|
1093
|
ACRYLONITRILE, STABILIZED |
3
|
6.1
|
I |
386
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
Category D
SW1
SW2
|
– |
Colourless, mobile liquid with a mild pungent odour. Flashpoint: −5°C c.c. Explosive limits: 3% to 17%. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Practice has shown that this substance may leak from packagings that ordinarily are leakproof to other chemicals. |
1093 |
|
|
1098
|
ALLYL ALCOHOL |
6.1
|
3
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
– |
Colourless liquid with a pungent mustard-like odour. Flashpoint: 21°C c.c. Explosive limits: 2.5% to 18%. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1098 |
|
|
1099
|
ALLYL BROMIDE |
3
|
6.1
P
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
Category B
SW2
|
SGG10
|
Colourless to light yellow liquid with an irritating odour. Flashpoint: −1°C c.c. Explosive limits: 4.4% to 7.3%. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1099 |
|
|
1100
|
ALLYL CHLORIDE |
3
|
6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
Category E
SW2
|
SGG10
|
Colourless liquid with an unpleasant pungent odour. Flashpoint: −29°C c.c. Explosive limits: 3.3% to 11.1%. Boiling point: 44°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1100 |
|
|
1104
|
AMYL ACETATES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquids with a pear- or banana-like odour. normal-AMYL ACETATE: flashpoint 25°C c.c. secondary-AMYL ACETATE: flashpoint 32°C c.c. Immiscible with water. |
1104 |
|
|
1105
|
PENTANOLS |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
Category B
|
– |
Colourless liquids with a strong odour. Immiscible with water. tertiary-AMYL ALCOHOL: flashpoint 19°C to 21°C c.c. |
1105 |
|
|
1105
|
PENTANOLS |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. Explosive limits: 1.2% to 10.5%. |
1105 |
|
|
1106
|
AMYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
|
SG35
|
Colourless, clear liquids. Explosive limits: 2.2% to 22%. normal-AMYLAMINE (1-PENTYLAMINE): flashpoint 4°C c.c. tertiary-AMYLAMINE (3-PENTYLAMINE): flashpoint 2°C c.c. Miscible with water. Harmful by inhalation. Cause burns to skin, eyes and mucous membranes. |
1106 |
|
|
1106
|
AMYLAMINE |
3
|
8
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
Category A
|
SG35
|
See entry above. However, irritating to skin, eyes and mucous membranes. |
1106 |
|
|
1107
|
AMYL CHLORIDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
SGG10
|
Colourless or light brown liquids with an aromatic odour. n-AMYL CHLORIDE: flashpoint 11°C. Explosive limits: normal-AMYL CHLORIDE 1.4% to 8.6%. Immiscible with water. |
1107 |
|
|
1108
|
1-PENTENE (n-AMYLENE) |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category E
|
– |
Colourless, volatile liquid with a disagreeable odour. Flashpoint: −20°C c.c. Explosive limits: 1.4% to 8.7%. Boiling point: 30°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. |
1108 |
|
|
1109
|
AMYL FORMATES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquids with a pleasant odour. normal-AMYL FORMATE: flashpoint 27°C c.c. ISOAMYL FORMATE: flashpoint 26°C c.c. Explosive limits: 1.7% to 10%. Immiscible with water. |
1109 |
|
|
1110
|
n-AMYL METHYL KETONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. |
1110 |
|
|
1111
|
AMYL MERCAPTAN |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
SG50
SG57
|
Colourless to yellow liquids with an extremely disagreeable garlic-like odour. tertiary-AMYL MERCAPTAN: flashpoint −7°C c.c. normal-AMYL MERCAPTAN: flashpoint 19°C c.c. ISOAMYL MERCAPTAN: flashpoint 18°C c.c. Immiscible with water. These substances may leak from packagings that ordinarily are leakproof to other chemicals. |
1111 |
|
|
1112
|
AMYL NITRATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
SW2
|
– |
Colourless liquids with an ether-like odour. normal-AMYL NITRATE: flashpoint 48°C c.c. ISOAMYL NITRATE: flashpoint 52°C c.c. Immiscible with water. Harmful by inhalation. |
1112 |
|
|
1113
|
AMYL NITRITE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category E
SW2
|
– |
Yellowish, transparent, volatile liquid with a fragrant fruity odour. Flashpoint of the pure ISOAMYL NITRITE: −20°C c.c. Flashpoint of pure normal-AMYL NITRITE: 10°C c.c. Decomposes on exposure to air, light or water, evolving toxic nitrous fumes which are orange in colour. Immiscible with water. Harmful by inhalation. |
1113 |
|
|
1114
|
BENZENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
SW2
|
– |
Colourless liquid with a characteristic odour. Flashpoint: −11°C c.c. Explosive limits: 1.4% to 8%. Freezing point 5°C; flashes below its freezing point. Immiscible with water. Narcotic. Exposure to this substance may produce serious chronic effects of a toxic nature. |
1114 |
|
|
1120
|
BUTANOLS |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
Category B
|
– |
Colourless liquids with a disagreeable odour. Explosive limits: normal-BUTANOL 1.4% to 11.2%. secondary-BUTANOL 1.7% to 9.8%. tertiary-BUTANOL 2.4% to 8%. tertiary-BUTANOL solidifies at about 25°C. normal-BUTANOL is immiscible with water. secondary-BUTANOL is immiscible with water. tertiary-BUTANOL is miscible with water. Irritating to skin, eyes and mucous membranes. |
1120 |
|
|
1120
|
BUTANOLS |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1120 |
|
|
1123
|
BUTYL ACETATES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquids with a pineapple-like odour. Immiscible with water. normal-BUTYL ACETATE: flashpoint 27°C c.c. Explosive limits: 1.5% to 15%. |
1123 |
|
|
1123
|
BUTYL ACETATES |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1123 |
|
|
1125
|
n-BUTYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
SW2
|
SG35
|
Flashpoint: −9°C c.c. Explosive limits: 1.7% to 10%. Colourless, volatile liquid with an ammonia-like odour. Miscible with water. Causes burns to skin, eyes and mucous membranes. |
1125 |
|
|
1126
|
1-BROMOBUTANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
SW2
|
SGG10
|
Colourless to pale straw-coloured, clear liquid. Flashpoint: 13°C c.c. Explosive limits: 2.6% to 6.6%. Immiscible with water. Narcotic. |
1126 |
|
|
1127
|
CHLOROBUTANES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
SGG10
|
Colourless liquids. tertiary-BUTYL CHLORIDE: flashpoint −30°C c.c., boiling point 51°C. Immiscible with water. |
1127 |
|
|
1128
|
n-BUTYL FORMATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: 18°C c.c. Explosive limits: 1.6% to 8.3%. Immiscible with water. |
1128 |
|
|
1129
|
BUTYRALDEHYDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with a characteristic pungent odour. Flashpoint: −7°C c.c. Explosive limits: 1.4% to 12.5%. Immiscible with water. |
1129 |
|
|
1130
|
CAMPHOR OIL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
Category A
|
– |
Colourless oil with a characteristic odour. Flashpoint: 47°C c.c. Immiscible with water. |
1130 |
|
|
1131
|
CARBON DISULPHIDE |
3
|
6.1
|
I |
– |
0 |
E0 |
P001
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP7 TP13
|
F-E, S-D
|
Category D
SW2
|
SG63
|
Colourless or faintly yellow, clear liquid, almost odourless when pure; the commercial substance has a strong disagreeable odour. Flashpoint: −30°C c.c. Explosive limits: 1% to 60%. Boiling point: 46°C. Ignition temperature: 100°C. Immiscible with water. Vapours are heavier than air, will travel a considerable distance to a source of ignition and will flash back. Vapours may be ignited by contact with an ordinary light bulb or a warm steam pipe. Toxic if swallowed, by skin contact or by inhalation. |
1131 |
|
|
1133
|
ADHESIVES containing flammable liquid |
3
|
– |
I |
– |
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8 TP27
|
F-E, S-D
|
Category E
|
– |
Adhesives are solutions of gums, resins, etc., usually volatile due to the solvents. Miscibility with water depends upon their composition. |
1133 |
|
|
1133
|
ADHESIVES containing flammable liquid |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
PP1 |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
See entry above. |
1133 |
|
|
1133
|
ADHESIVES containing flammable liquid |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
PP1 |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1133 |
|
|
1134
|
CHLOROBENZENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
SGG10
|
Colourless liquid with an almond-like odour. Flashpoint: 29°C c.c. Explosive limits: 1.3% to 11%. Immiscible with water. |
1134 |
|
|
1135
|
ETHYLENE CHLOROHYDRIN |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
– |
Colourless flammable liquid with a faint, ethereal odour. Flashpoint: 60°C o.c. Explosive limits: 4.9% to 15.9%. Miscible with water. When involved in a fire, evolves extremely toxic (phosgene) and corrosive (hydrogen chloride) fumes. Highly toxic if swallowed, by skin contact or by inhalation. |
1135 |
|
|
1136
|
COAL TAR DISTILLATES, FLAMMABLE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-E
|
Category B
|
– |
Immiscible with water. May form extremely sensitive compounds with heavy metals or their salts. |
1136 |
|
|
1136
|
COAL TAR DISTILLATES, FLAMMABLE |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-E
|
Category A
|
– |
See entry above. |
1136 |
|
|
1139
|
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under-coating, drum or barrel lining) |
3
|
– |
I |
– |
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8 TP27
|
F-E, S-E
|
Category E
|
– |
Miscibility with water depends upon the composition. |
1139 |
|
|
1139
|
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under-coating, drum or barrel lining) |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-E
|
Category B
|
– |
See entry above. |
1139 |
|
|
1139
|
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under-coating, drum or barrel lining) |
3
|
– |
III |
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
Category A
|
– |
See entry above. |
1139 |
|
|
1143
|
CROTONALDEHYDE or CROTONALDEHYDE, STABILIZED |
6.1
|
3
P
|
I |
324
354
386
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW1
SW2
|
– |
Colourless, mobile liquid with a pungent odour. Turns to pale yellow in contact with light and air. Miscible with water. Flashpoint: 13°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. May cause lung damage. |
1143 |
|
|
1144
|
CROTONYLENE |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category E
|
– |
Colourless liquid. Flashpoint: −53°C c.c. Lower explosive limit: 1.4%. Boiling point: 27°C. Immiscible with water. |
1144 |
|
|
1145
|
CYCLOHEXANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category E
|
– |
Colourless, mobile liquid with a sweet aromatic odour. Flashpoint: −18°C c.c. Explosive limits: 1.2% to 8.4%. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. |
1145 |
|
|
1146
|
CYCLOPENTANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
Category E
|
– |
Colourless liquid with a pungent odour. Flashpoint: below −18°C c.c. Explosive limits: 1.4% to 8%. Boiling point: 49°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. |
1146 |
|
|
1147
|
DECAHYDRONAPHTHALENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquids with an aromatic odour. Flashpoint: 52°C to 57°C c.c. Explosive limits: 0.7% to 4.9%. Immiscible with water. Harmful by inhalation. |
1147 |
|
|
1148
|
DIACETONE ALCOHOL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Explosive limits: 1.4% to 8%. Miscible with water. |
1148 |
|
|
1148
|
DIACETONE ALCOHOL |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1148 |
|
|
1149
|
DIBUTYL ETHERS |
3
|
– |
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquids with a mild ether-like odour. Explosive limits: 0.9% to 8.5%. Immiscible with water. normal-DIBUTYL ETHER: flashpoint 25°C c.c. |
1149 |
|
|
1150
|
1,2-DICHLOROETHYLENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category B
|
SGG10
|
Colourless liquid with a chloroform-like odour. Flashpoint: 6°C c.c. Explosive limits: 5.6% to 16%. Immiscible with water. Boiling range: 48°C to 61°C. |
1150 |
|
|
1152
|
DICHLOROPENTANES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
SGG10
|
Light yellow liquids. 1,5-DICHLOROPENTANE: flashpoint 26°C c.c. Immiscible with water. |
1152 |
|
|
1153
|
ETHYLENE GLYCOL DIETHYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with an ether-like odour. Flashpoint: 35°C c.c. Immiscible with water. |
1153 |
|
|
1153
|
ETHYLENE GLYCOL DIETHYL ETHER |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1153 |
|
|
1154
|
DIETHYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category E
SW2
|
SG35
|
Colourless liquid with an ammonia-like odour. Flashpoint: −39°C c.c. Explosive limits: 1.7% to 10.1%. Boiling point: 55°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. Higher concentrations cause dangerous lung irritation. |
1154 |
|
|
1155
|
DIETHYL ETHER (ETHYL ETHER) |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category E
SW2
|
– |
Colourless, volatile and mobile liquid with a pleasant aromatic odour. Flashpoint: −40°C c.c. Explosive limits: 1.7% to 48%. Boiling point: 34°C. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Strongly narcotic. Readily ignited by static electricity. |
1155 |
|
|
1156
|
DIETHYL KETONE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless, mobile liquid. Flashpoint: 13°C c.c. Lower explosive limit: 1.6%. Immiscible with water. |
1156 |
|
|
1157
|
DIISOBUTYL KETONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 49°C c.c. Explosive limits: 0.8% to 7.1%. Immiscible with water. |
1157 |
|
|
1158
|
DIISOPROPYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
|
SG35
|
Colourless, volatile liquid with a fishy odour. Flashpoint: −7°C c.c. Explosive limits: 1.1% to 7.1%. Partially miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. |
1158 |
|
|
1159
|
DIISOPROPYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category E
SW2
|
– |
Colourless liquid with an ether-like odour. Flashpoint: −29°C c.c. Explosive limits: 1.1% to 21%. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Strongly narcotic. Readily ignited by static electricity. |
1159 |
|
|
1160
|
DIMETHYLAMINE, AQUEOUS SOLUTION |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
|
SGG18
SG35
|
Aqueous solution of a flammable gas with an ammonia-like odour. Flashpoint for 60% solution in water: −32°C c.c. Explosive limits: 2.8% to 14.4%. Boiling point for 60% solution in water: 36°C. Flashpoint for 25% solution in water: 0°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
1160 |
|
|
1161
|
DIMETHYL CARBONATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Immiscible with water. Flashpoint: 18°C c.c. |
1161 |
|
|
1162
|
DIMETHYLDICHLOROSILANE |
3
|
8
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
Category B
SW2
|
– |
Colourless liquid with a pungent odour. Flashpoint: −9°C c.c. Explosive limits: 1.4% to 9.5%. Immiscible with water. Reacts with water to form a complex mixture of dimethylsiloxanes and evolves hydrogen chloride, a toxic and corrosive gas. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. |
1162 |
|
|
1163
|
DIMETHYLHYDRAZINE, UNSYMMETRICAL |
6.1
|
3/8
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-C
|
Category D
SW2
|
SGG18
SG5
SG8
SG13
SG35
|
Colourless liquid with an ammonia-like odour. Flashpoint: −18°C c.c. Explosive limits: 2% to 95%. Miscible with water, generating heat. Reacts violently with acids. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. May react dangerously with oxidizing substances. |
1163 |
|
|
1164
|
DIMETHYL SULPHIDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category E
SW2
|
– |
Colourless liquid with a disagreeable odour. Flashpoint: −37°C c.c. Explosive limits: 2.2% to 19.7%. Boiling point: 37°C. Immiscible with water. When involved in a fire, evolves toxic gases. Narcotic in high concentrations. |
1164 |
|
|
1165
|
DIOXANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with an ether-like odour. Flashpoint: 12°C c.c. Explosive limits: 2% to 22%. Miscible with water. Harmful by inhalation. |
1165 |
|
|
1166
|
DIOXOLANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
SW2
|
– |
Colourless liquid. Flashpoint: 2°C c.c. Miscible with water. Harmful by inhalation. |
1166 |
|
|
1167
|
DIVINYL ETHER, STABILIZED |
3
|
– |
I |
386
|
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category E
SW1
SW2
|
– |
Colourless, clear liquid with a characteristic odour. Flashpoint: −30°C c.c. Explosive limits: 1.7% to 27%. Boiling point: 30°C. Immiscible with water. In the presence of oxygen or on long standing or exposure to sunlight, unstable peroxides sometimes form; these may explode spontaneously or when heated. Strongly narcotic. Readily ignited by static electricity. |
1167 |
|
|
1170
|
ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) |
3
|
– |
II |
144
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless, volatile liquids. Pure ETHANOL: flashpoint 13°C c.c. Explosive limits: 3.3% to 19%. Miscible with water. |
1170 |
|
|
1170
|
ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) |
3
|
– |
III |
144
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1170 |
|
|
1171
|
ETHYLENE GLYCOL MONOETHYL ETHER |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 40°C c.c. Explosive limits: 1.7% to 15.6%. Miscible with water. |
1171 |
|
|
1172
|
ETHYLENE GLYCOL MONOETHYL ETHER ACETATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 51°C c.c. Explosive limits: 1.7% to 10.1%. Partially miscible with water. |
1172 |
|
|
1173
|
ETHYL ACETATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with a fragrant odour. Flashpoint: −4°C c.c. Explosive limits: 2.18% to 11.5%. Immiscible with water. |
1173 |
|
|
1175
|
ETHYLBENZENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with an aromatic odour. Flashpoint: 22°C c.c. Explosive limits: 1% to 6.7%. Immiscible with water. |
1175 |
|
|
1176
|
ETHYL BORATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: 11°C c.c. Immiscible with water. |
1176 |
|
|
1177
|
2-ETHYLBUTYL ACETATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 54°C o.c. Immiscible with water. |
1177 |
|
|
1178
|
2-ETHYLBUTYRALDEHYDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: 11°C c.c. Explosive limits: 1.2% to 7.7%. Immiscible with water. |
1178 |
|
|
1179
|
ETHYL BUTYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: −1°C c.c. Immiscible with water. |
1179 |
|
|
1180
|
ETHYL BUTYRATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless, volatile liquid with a pineapple-like odour. Flashpoint: 26°C c.c. Immiscible with water. |
1180 |
|
|
1181
|
ETHYL CHLOROACETATE |
6.1
|
3
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category A
|
– |
Colourless, flammable liquid with a pungent and fruity odour. Flashpoint: 54°C c.c. Immiscible with water. When heated, evolves toxic and corrosive fumes. Toxic if swallowed, by skin contact or by inhalation. |
1181 |
|
|
1182
|
ETHYL CHLOROFORMATE |
6.1
|
3/8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-C
|
Category D
SW2
|
SGG1
SG5
SG8
SG36
SG49
|
Colourless liquid. Flashpoint: 16°C c.c. Reacts and decomposes with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1182 |
|
|
1183
|
ETHYLDICHLOROSILANE |
4.3
|
3/8
|
I |
– |
0 |
E0 |
P401
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP7 TP13
|
F-G, S-O
|
Category D
SW2
H1
|
SGG1
SG5
SG8
SG13
SG25
SG26
SG36
SG49
|
Colourless, very volatile liquid with a pungent odour. Flashpoint: −1°C c.c. Immiscible with water. Reacts violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Causes burns to skin, eyes and mucous membranes. |
1183 |
|
|
1184
|
ETHYLENE DICHLORIDE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
Category B
SW2
|
SGG10
|
Colourless liquid with a chloroform-like odour. Flashpoint: 13°C c.c. Explosive limits: 6.2% to 15.9%. Immiscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. |
1184 |
|
|
1185
|
ETHYLENEIMINE, STABILIZED |
6.1
|
3
|
I |
354
386
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-D
|
Category D
SW1
SW2
|
– |
Colourless oily flammable liquid with a pungent ammonia-like odour. Flashpoint: −13°C c.c. Boiling point: 55°C. Explosive limits: 3.6% to 6.0%. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1185 |
|
|
1188
|
ETHYLENE GLYCOL MONOMETHYL ETHER |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 38°C c.c. Explosive limits: 1.8% to 20%. Miscible with water. |
1188 |
|
|
1189
|
ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with a characteristic odour. Flashpoint: 44°C c.c. Explosive limits: 1.7% to 8.2%. Miscible with water. |
1189 |
|
|
1190
|
ETHYL FORMATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category E
|
– |
Colourless liquid with a pleasant aromatic odour. Flashpoint: −20°C c.c. Explosive limits: 3.5% to 16.5%. Boiling point: 54°C. Immiscible with water. |
1190 |
|
|
1191
|
OCTYL ALDEHYDES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquids with a characteristic odour. Flashpoint: 44°C to 52°C c.c. Explosive limits: 0.9% to 7.2%. Immiscible with water. |
1191 |
|
|
1192
|
ETHYL LACTATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 46°C c.c. Explosive limits: 1.5% to 11.4%. Miscible with water. |
1192 |
|
|
1193
|
ETHYL METHYL KETONE (METHYL ETHYL KETONE) |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: −1°C c.c. Explosive limits: 1.8% to 11.5%. Miscible with water. |
1193 |
|
|
1194
|
ETHYL NITRITE SOLUTION |
3
|
6.1
|
I |
900
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category D
SW2
|
– |
Alcoholic solution of ethyl nitrite. Extremely volatile, with an aromatic, ethereal odour. Explosive limits of the pure product: 3% to 50%. Boiling point of pure product: 17°C. Miscible or partially miscible with water. Decomposes under exposure to air, light, water or heat to evolve toxic nitrous fumes. Toxic if swallowed, by skin contact or by inhalation. Inhalation of ethyl nitrite vapours, even in small quantities, rapidly affects the heart and can be dangerous. Transport of ETHYL NITRITE pure is prohibited. |
1194 |
|
|
1195
|
ETHYL PROPIONATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with a pineapple-like odour. Flashpoint: 12°C c.c. Explosive limits: 1.8% to 11%. Immiscible with water. |
1195 |
|
|
1196
|
ETHYLTRICHLOROSILANE |
3
|
8
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
Category B
SW2
|
– |
Colourless liquid with a pungent odour. Flashpoint: 14°C c.c. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Causes burns to skin and eyes. Irritating to mucous membranes. |
1196 |
|
|
1197
|
EXTRACTS, LIQUID, for flavour or aroma |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
Usually consist of alcoholic solutions. Miscibility with water depends upon the composition. |
1197 |
|
|
1197
|
EXTRACTS, LIQUID, for flavour or aroma |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1197 |
|
|
1198
|
FORMALDEHYDE SOLUTION, FLAMMABLE |
3
|
8
|
III |
– |
5 L |
E0 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
Category A
SW2
|
– |
Colourless liquids with a pungent odour. Flashpoint: 32−60°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. |
1198 |
|
|
1199
|
FURALDEHYDES |
6.1
|
3
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category A
|
– |
Colourless or reddish-brown, mobile liquids with a pungent odour. Miscible with water. Explosive limits for 2-FURALDEHYDE: 2.1% to 19.3%. Flashpoints: 2-FURALDEHYDE 60°C c.c., 3-FURALDEHYDE 48°C c.c. Toxic if swallowed, by skin contact or by inhalation. |
1199 |
|
|
1201
|
FUSEL OIL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless, oily liquid with a disagreeable odour. A mixture consisting of amyl alcohols. Immiscible with water. |
1201 |
|
|
1201
|
FUSEL OIL |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1201 |
|
|
1202
|
GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
Category A
|
– |
Immiscible with water. |
1202 |
|
|
1203
|
MOTOR SPIRIT or GASOLINE or PETROL |
3
|
– |
II |
243
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-E
|
Category E
|
– |
Immiscible with water. |
1203 |
|
| △ |
1204
|
NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin |
3
|
– |
II |
28
|
1 L |
E0 |
P001
|
PP5 |
IBC02
|
– |
|
– |
– |
– |
F-E, S-D
|
Category B
|
– |
Immiscible with water. Ignites readily. When involved in a fire, evolves toxic nitrous fumes. Not explosive in this state but damage to, or leakage from, a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. |
1204 |
△ |
|
1206
|
HEPTANES |
3
|
–
P
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-D
|
Category B
|
– |
Colourless, volatile liquids. Explosive limits: 1.1% to 6.7%. n-HEPTANE: flashpoint −4°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
1206 |
|
|
1207
|
HEXALDEHYDE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with a pungent odour. Flashpoint: 32°C c.c. Immiscible with water. |
1207 |
|
|
1208
|
HEXANES |
3
|
–
P
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-D
|
Category E
|
– |
Colourless, volatile liquids with a faint odour. Explosive limits: 1.1% to 7.5%. n-HEXANE: flashpoint −22°C c.c., boiling point 69°C. NEOHEXANE: flashpoint −48°C c.c., boiling point 50°C. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. |
1208 |
|
|
1210
|
PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable |
3
|
– |
I |
163
367
|
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8
|
F-E, S-D
|
Category E
|
– |
Fluid or viscous liquid containing colouring matter in solution or suspension. Miscibility with water depends upon the solvent. |
1210 |
|
|
1210
|
PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable |
3
|
– |
II |
163
367
|
5 L |
E2 |
P001
|
PP1 |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
See entry above. |
1210 |
|
|
1210
|
PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable |
3
|
– |
III |
163
223
367
955
|
5 L |
E1 |
P001
LP01
|
PP1 |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1210 |
|
|
1212
|
ISOBUTANOL (ISOBUTYL ALCOHOL) |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with a sweet odour. Flashpoint: 28°C c.c. Explosive limits: 1.2% to 10.9%. Partially miscible with water. |
1212 |
|
|
1213
|
ISOBUTYL ACETATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with a pineapple-like odour. Flashpoint: 18°C c.c. Explosive limits: 1.3% to 10.5%. Immiscible with water. |
1213 |
|
|
1214
|
ISOBUTYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
SW2
|
SG35
|
Colourless liquid. Flashpoint: −9°C c.c. Explosive limits: 3.4% to 9%. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
1214 |
|
|
1216
|
ISOOCTENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquids. Immiscible with water. |
1216 |
|
|
1218
|
ISOPRENE, STABILIZED |
3
|
–
P
|
I |
386
|
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category D
SW1
|
– |
Colourless, volatile liquid. Flashpoint: −48°C c.c. Explosive limits: 1.5% to 9.7%. Boiling point: 34°C. Immiscible with water. |
1218 |
|
|
1219
|
ISOPROPANOL (ISOPROPYL ALCOHOL) |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless, mobile liquid. Flashpoint: 12°C c.c. Explosive limits: 2% to 12%. Miscible with water. |
1219 |
|
|
1220
|
ISOPROPYL ACETATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with an aromatic odour. Flashpoint: 11°C c.c. Explosive limits: 1.8% to 7.8%. Immiscible with water. |
1220 |
|
|
1221
|
ISOPROPYLAMINE |
3
|
8
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-C
|
Category E
SW2
|
SG35
|
Colourless, volatile liquid with an ammonia-like odour. Flashpoint: −37°C c.c. Explosive limits: 2.3% to 10.4%. Boiling point: 32°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. |
1221 |
|
|
1222
|
ISOPROPYL NITRATE |
3
|
– |
II |
26
|
1 L |
E2 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category D
|
– |
Colourless liquid. Flashpoint: 12°C c.c. Explosive limits: up to 100%. Immiscible with water. May explode on heating. Harmful by inhalation. |
1222 |
|
|
1223 |
KEROSENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-E
|
Category A
|
– |
Immiscible with water. |
1223 |
|
|
1224
|
KETONES, LIQUID, N.O.S. |
3
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-D
|
Category B
|
– |
– |
1224 |
|
|
1224
|
KETONES, LIQUID, N.O.S. |
3
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
Category A
|
– |
– |
1224 |
|
|
1228
|
MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
II |
274
|
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP27
|
F-E, S-D
|
Category B
SW2
|
SG50
SG57
|
Colourless to yellow liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1228 |
|
|
1228
|
MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-E, S-D
|
Category B
SW2
|
SG50
SG57
|
Colourless to yellow liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1228 |
|
|
1229
|
MESITYL OXIDE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless, oily liquid with a sweet odour. Flashpoint: 32°C c.c. Miscible with water. |
1229 |
|
|
1230
|
METHANOL |
3
|
6.1
|
II |
279
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category B
SW2
|
– |
Colourless, volatile liquid. Flashpoint: 12°C c.c. Explosive limits: 6% to 36.5%. Miscible with water. Toxic if swallowed; may cause blindness. Avoid skin contact. |
1230 |
|
|
1231
|
METHYL ACETATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless, volatile liquid with a fragrant odour. Flashpoint: −10°C c.c. Explosive limits: 3% to 16%. Miscible with water. |
1231 |
|
|
1233
|
METHYLAMYL ACETATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 43°C o.c. Immiscible with water. |
1233 |
|
|
1234
|
METHYLAL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category E
|
– |
Colourless, volatile liquid with a chloroform-like odour. Flashpoint: −28°C c.c. Explosive limits: 3.6% to 12.6%. Boiling point: 42°C. Miscible with water. Irritating to skin, eyes and mucous membranes. |
1234 |
|
|
1235
|
METHYLAMINE, AQUEOUS SOLUTION |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category E
|
SGG18
SG35
SG54
|
Aqueous solution of a flammable gas having an ammonia-like odour. Explosive limits: 5% to 20.7% (pure product). Boiling point: −7°C (pure product). Commercial product is a 40% solution with: boiling point 48°C, flashpoint −13°C c.c. Miscible with water. May react explosively with mercury. Causes burns to skin, eyes and mucous membranes. |
1235 |
|
|
1237
|
METHYL BUTYRATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: 14°C c.c. Immiscible with water. |
1237 |
|
|
1238
|
METHYL CHLOROFORMATE |
6.1
|
3/8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-C
|
Category D
SW2
|
SGG1
SG5
SG8
SG36
SG49
|
Colourless liquid. Flashpoint: 5°C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1238 |
|
|
1239
|
METHYL CHLOROMETHYL ETHER |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
– |
Colourless liquid. Flashpoint: below −18°C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1239 |
|
|
1242
|
METHYLDICHLOROSILANE |
4.3
|
3/8
|
I |
– |
0 |
E0 |
P401
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP7 TP13
|
F-G, S-O
|
Category D
SW2
H1
|
SGG1
SG5
SG8
SG13
SG25
SG26
SG36
SG49
|
Colourless, very volatile liquid with a pungent odour. Flashpoint: −26°C c.c. Explosive limits: 4.5% to 70%. Boiling point: 41°C. Immiscible with water. Reacts violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Causes burns to skin, eyes and mucous membranes. |
1242 |
|
|
1243
|
METHYL FORMATE |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category E
|
– |
Colourless liquid with an agreeable odour. Flashpoint: −32°C c.c. Explosive limits: 5% to 22.7%. Boiling point: 32°C. Miscible with water. |
1243 |
|
|
1244
|
METHYLHYDRAZINE |
6.1
|
3/8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-C
|
Category D
SW2
|
SGG18
SG5
SG8
SG13
SG35
|
Colourless liquid with an ammonia-like odour. Flashpoint: 20°C c.c. Explosive limits: 2.5% to 98%. Miscible with water. Reacts violently with acids. May react dangerously with oxidizing substances. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1244 |
|
|
1245
|
METHYL ISOBUTYL KETONE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with a pleasant odour. Flashpoint: 14°C c.c. Explosive limits: 1.4% to 7.5%. Immiscible with water. |
1245 |
|
|
1246
|
METHYL ISOPROPENYL KETONE, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category C
SW1
|
– |
Colourless liquid with a pleasant odour. Explosive limits: 1.8% to 9%. Immiscible with water. |
1246 |
|
|
1247
|
METHYL METHACRYLATE MONOMER, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category C
SW1
SW2
|
– |
Colourless, volatile liquid. Flashpoint: 8°C c.c. Explosive limits: 1.5% to 11.6%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
1247 |
|
|
1248
|
METHYL PROPIONATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: −2°C c.c. Explosive limits: 2.4% to 13%. Immiscible with water. |
1248 |
|
|
1249
|
METHYL PROPYL KETONE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: 7°C c.c. Explosive limits: 1.5% to 8.2%. Immiscible with water. |
1249 |
|
|
1250
|
METHYLTRICHLOROSILANE |
3
|
8
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
Category B
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Flashpoint: 8°C o.c. Explosive limits: 5.1% to 20%. Immiscible with water. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin and eyes. Irritating to mucous membranes. |
1250 |
|
|
1251
|
METHYL VINYL KETONE, STABILIZED |
6.1
|
3/8
|
I |
354
386
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-C
|
Category D
SW1
SW2
|
SG5
SG8
|
Colourless liquid with a pungent odour. Miscible with water. Explosive limits: 2.1% to 15.6%. Flashpoint: −7°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1251 |
|
|
1259
|
NICKEL CARBONYL |
6.1
|
3
P
|
I |
– |
0 |
E0 |
P601
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category D
SW2
|
SG63
|
Colourless or yellow, volatile, flammable liquid. Flashpoint: below −20°C c.c. Oxidizes in air and explodes at a temperature of 60°C. Lower explosive limit: 2.0%. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1259 |
|
|
1261
|
NITROMETHANE |
3
|
– |
II |
26
|
1 L |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 35°C c.c. Explosive limits: 7.1% to 63%. Miscible with water. Fire and explosion hazard if package is ruptured. |
1261 |
|
|
1262
|
OCTANES |
3
|
–
P
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-E
|
Category B
|
– |
Colourless liquids. Explosive limits: 1% to 6.5%. ISOOCTANE: flashpoint −12°C c.c. n-OCTANE: flashpoint 13°C c.c. Immiscible with water. |
1262 |
|
|
1263
|
PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) |
3
|
– |
I |
163
367
|
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8 TP27
|
F-E, S-E
|
Category E
|
– |
Miscibility with water depends upon the composition. |
1263 |
|
|
1263
|
PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) |
3
|
– |
II |
163
367
|
5 L |
E2 |
P001
|
PP1 |
IBC02
|
– |
|
– |
T4
|
TP1 TP8 TP28
|
F-E, S-E
|
Category B
|
– |
See entry above. |
1263 |
|
|
1263
|
PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) |
3
|
– |
III |
163
223
367
955
|
5 L |
E1 |
P001
LP01
|
PP1 |
IBC03
|
– |
|
– |
T2
|
TP1 TP29
|
F-E, S-E
|
Category A
|
– |
See entry above. |
1263 |
|
|
1264
|
PARALDEHYDE |
3
|
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 27°C c.c. Lower explosive limit: 1.3%. Miscible with water. |
1264 |
|
|
1265
|
PENTANES, liquid |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category E
|
– |
Colourless liquids with a paraffin-like odour. Explosive limits: 1.4% to 8%. ISOPENTANE (2-METHYLBUTANE): boiling point 28°C. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. |
1265 |
|
|
1265
|
PENTANES, liquid |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category E
|
– |
See entry above. normal-PENTANE: boiling point 36°C. |
1265 |
|
|
1266
|
PERFUMERY PRODUCTS with flammable solvents |
3
|
– |
II |
163
|
5 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
Miscibility with water depends upon the composition. |
1266 |
|
|
1266
|
PERFUMERY PRODUCTS with flammable solvents |
3
|
– |
III |
163
223
904
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1266 |
|
|
1267
|
PETROLEUM CRUDE OIL |
3
|
– |
I |
357
|
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8
|
F-E, S-E
|
Category E
|
– |
Immiscible with water. |
1267 |
|
|
1267
|
PETROLEUM CRUDE OIL |
3
|
– |
II |
357
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-E
|
Category B
|
– |
See entry above. |
1267 |
|
|
1267
|
PETROLEUM CRUDE OIL |
3
|
– |
III |
223
357
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
Category A
|
– |
See entry above. |
1267 |
|
|
1268
|
PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. |
3
|
– |
I |
– |
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8
|
F-E, S-E
|
Category E
|
– |
Immiscible with water. |
1268 |
|
|
1268
|
PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-E
|
Category B
|
– |
See entry above. |
1268 |
|
|
1268
|
PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-E
|
Category A
|
– |
See entry above. |
1268 |
|
|
1272
|
PINE OIL |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-E
|
Category A
|
– |
Volatile oils with characteristic odours. Flashpoint: 57°C to 60°C c.c. Immiscible with water. |
1272 |
|
|
1274
|
n-PROPANOL (PROPYL ALCOHOL, NORMAL) |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Explosive limits: 2% to 12%. Flashpoint: 15°C to 23°C c.c. Miscible with water. |
1274 |
|
|
1274
|
n-PROPANOL (PROPYL ALCOHOL, NORMAL) |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. Flashpoint: 23°C to 26°C c.c. |
1274 |
|
|
1275
|
PROPIONALDEHYDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
Category E
|
– |
Colourless liquid with a pungent odour. Flashpoint: below −18°C c.c. Explosive limits: 2.3% to 21%. Boiling point: 49°C. Miscible with water. Irritating to skin, eyes and mucous membranes. |
1275 |
|
|
1276
|
n-PROPYL ACETATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless, clear liquid with a pleasant odour. Flashpoint: 10°C c.c. Explosive limits: 1.8% to 8%. Immiscible with water. |
1276 |
|
|
1277
|
PROPYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category E
SW2
|
SG35
|
Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 2% to 10.4%. Boiling point: 48°C. Miscible with water. Harmful if swallowed. Causes burns to skin, eyes and mucous membranes. |
1277 |
|
|
1278
|
1-CHLOROPROPANE |
3
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category E
|
SGG10
|
Colourless liquid with a chloroform-like odour. Flashpoint: −18°C c.c. Explosive limits: 2.6% to 10.5%. Boiling point: 47°C. Immiscible with water. |
1278 |
|
|
1279
|
1,2-DICHLOROPROPANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
SGG10
|
Colourless liquid. Flashpoint: 15°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin and eyes. |
1279 |
|
|
1280
|
PROPYLENE OXIDE |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-D
|
Category E
SW2
|
– |
Colourless, volatile liquid with an ether-like odour. Flashpoint: below −18°C c.c. Explosive limits: 2% to 22%. Boiling point: 34°C. Partially miscible with water. |
1280 |
|
|
1281
|
PROPYL FORMATES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquids with a pleasant odour. Explosive limits: 2.4% to 7.8%. Miscibility with water depends upon the composition. Irritating to skin, eyes and mucous membranes. |
1281 |
|
|
1282
|
PYRIDINE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-D
|
Category B
SW2
|
– |
Colourless or slightly yellow liquid with a pungent odour. Flashpoint: 17°C c.c. Explosive limits: 1.8% to 12.4%. Miscible with water. Harmful by inhalation. |
1282 |
|
|
1286
|
ROSIN OIL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-E
|
Category B
|
– |
Colourless to brown viscous liquid. Immiscible with water. |
1286 |
|
|
1286
|
ROSIN OIL |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
Category A
|
– |
See entry above. |
1286 |
|
|
1287
|
RUBBER SOLUTION |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
Miscibility with water depends upon the composition. |
1287 |
|
|
1287
|
RUBBER SOLUTION |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1287 |
|
|
1288
|
SHALE OIL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-E
|
Category B
|
– |
Immiscible with water. |
1288 |
|
|
1288
|
SHALE OIL |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
Category A
|
– |
Immiscible with water. |
1288 |
|
|
1289
|
SODIUM METHYLATE SOLUTION in alcohol |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8
|
F-E, S-C
|
Category B
|
SGG18
SG35
|
Reacts violently with water. Causes burns to skin, eyes and mucous membranes. |
1289 |
|
|
1289
|
SODIUM METHYLATE SOLUTION in alcohol |
3
|
8
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
Category A
|
SGG18
SG35
|
See entry above. Irritating to skin, eyes and mucous membranes. |
1289 |
|
|
1292
|
TETRAETHYL SILICATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A. |
– |
Colourless liquid. Flashpoint: 37°C c.c. Explosive limits: 1.3% to 23%. Immiscible with water. |
1292 |
|
|
1293
|
TINCTURES, MEDICINAL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
Miscibility with water depends upon the composition. |
1293 |
|
|
1293
|
TINCTURES, MEDICINAL |
3
|
– |
III |
904
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1293 |
|
|
1294
|
TOLUENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid with a benzene-like odour. Flashpoint: 7°C c.c. Explosive limits: 1.27% to 7%. Immiscible with water. |
1294 |
|
|
1295
|
TRICHLOROSILANE |
4.3
|
3/8
|
I |
– |
0 |
E0 |
P401
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP7 TP13
|
F-G, S-O
|
Category D
SW2
H1
|
SGG1
SG5
SG8
SG13
SG25
SG26
SG36
SG49
SG72
|
Colourless, very volatile, flammable and corrosive liquid. Flashpoint: below −50°C. Explosive limits: 1.2% to 90.5%. Boiling point: 32°C. Reacts with water or steam to produce heat, which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Causes burns to skin, eyes and mucous membranes. |
1295 |
|
|
1296
|
TRIETHYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
SW2
|
SG35
|
Colourless liquid with a strong ammonia-like odour. Flashpoint: −11°C c.c. Explosive limits: 1.2% to 8%. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
1296 |
|
|
1297
|
TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass |
3
|
8
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1
|
F-E, S-C
|
Category D
SW2
|
SG35
SG54
|
Aqueous solution of a flammable gas with an ammonia-like odour. Flashpoint depending on percentage of dissolved gas. May react explosively with mercury. Miscible with water. An aqueous solution of 45% TRIMETHYLAMINE, by mass, has a flashpoint of −45°C c.c. and a boiling point of 30°C (applicable to PG I only). Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. |
1297 |
|
|
1297
|
TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
SW2
|
SG35
SG54
|
See entry above. |
1297 |
|
|
1297
|
TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass |
3
|
8
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category A
SW2
|
SG35
SG54
|
See entry above. Irritating to skin, eyes and mucous membranes. |
1297 |
|
|
1298
|
TRIMETHYLCHLOROSILANE |
3
|
8
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
Category E
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.8% to 6%. Boiling point: 57°C. Immiscible with water. Readily hydrolysed by moisture, evolving hydrogen chloride, a toxic and corrosive gas. Causes burns to skin, eyes and mucous membranes. |
1298 |
|
|
1299
|
TURPENTINE |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-E
|
Category A
|
– |
Colourless liquid. Flashpoint: 35°C c.c. Mixture of resin and volatile oils. Immiscible with water. |
1299 |
|
|
1300
|
TURPENTINE SUBSTITUTE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-E
|
Category B
|
– |
Immiscible with water. |
1300 |
|
|
1300
|
TURPENTINE SUBSTITUTE |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
Category A
|
– |
See entry above. |
1300 |
|
|
1301
|
VINYL ACETATE, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category C
SW1
|
– |
Colourless to light yellow liquid. Flashpoint: −8°C c.c. Explosive limits: 2.6% to 14%. Immiscible with water. |
1301 |
|
|
1302
|
VINYL ETHYL ETHER, STABILIZED |
3
|
– |
I |
386
|
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category D
SW1
|
– |
Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 28%. Boiling point: 33°C. Immiscible with water. Extremely reactive; may polymerize. |
1302 |
|
|
1303
|
VINYLIDENE CHLORIDE, STABILIZED |
3
|
–
P
|
I |
386
|
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T12
|
TP2 TP7
|
F-E, S-D
|
Category D
SW1
SW2
|
SGG10
|
Colourless to straw-coloured, volatile liquid with a sweet odour. Flashpoint: −28°C c.c. Explosive limits: 6.5% to 15.5%. Boiling point: 32°C. Immiscible with water. |
1303 |
|
|
1304
|
VINYL ISOBUTYL ETHER, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category C
SW1
|
– |
Colourless liquid. Flashpoint: −9°C o.c. Immiscible with water. |
1304 |
|
|
1305
|
VINYLTRICHLOROSILANE |
3
|
8
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
Category B
SW2
|
SGG1
SG36
SG49
|
Colourless, pale yellow or pink liquid with a pungent odour. Flashpoint: 11°C c.c. Lower explosive limit: 3%. Readily hydrolysed by moisture, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Immiscible with water. In the presence of moisture, corrosive to most metals. |
1305 |
|
|
1306
|
WOOD PRESERVATIVES, LIQUID |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
Category B
|
– |
Miscibility with water depends upon the composition. Harmful by inhalation. |
1306 |
|
|
1306
|
WOOD PRESERVATIVES, LIQUID |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. |
1306 |
|
|
1307
|
XYLENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquids. Flashpoint: 17°C to 23°C c.c. Explosive limits: 1.1% to 7%. Immiscible with water. |
1307 |
|
|
1307
|
XYLENES |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
See entry above. Flashpoint: 23°C to 30°C c.c. |
1307 |
|
|
1308
|
ZIRCONIUM, SUSPENDED IN A FLAMMABLE LIQUID |
3
|
– |
I |
– |
0 |
E0 |
P001
|
PP33 |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category D
|
– |
Finely divided zirconium metal in a flammable liquid. Immiscible with water. Spillage is liable to self-ignition. |
1308 |
|
|
1308
|
ZIRCONIUM, SUSPENDED IN A FLAMMABLE LIQUID |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
PP33 |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category B
|
– |
See entry above. |
1308 |
|
|
1308
|
ZIRCONIUM, SUSPENDED IN A FLAMMABLE LIQUID |
3
|
– |
III |
223
|
5 L |
E1 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category B
|
– |
See entry above. |
1308 |
|
|
1309
|
ALUMINIUM POWDER, COATED |
4.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP38 PP100 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-G
|
Category A
H1
|
SGG15
SG17
SG25
SG26
SG32
SG35
SG36
SG52
|
If uncoated, it possesses the property of evolving hydrogen gas when in contact with water, especially seawater; if treated with oil or wax, it does not at ordinary temperatures. Reacts readily with acids and caustic alkalis, evolving hydrogen, a flammable gas. Reacts readily with iron oxide, producing a thermite effect. May form explosive mixtures with oxidizing substances. In the event of breakage of receptacles, the scattered powder is readily ignited by sparks or open flame and may give rise to an explosive atmosphere. |
1309 |
|
|
1309
|
ALUMINIUM POWDER, COATED |
4.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
PP11 L3 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-G
|
Category A
H1
|
SGG15
SG17
SG25
SG26
SG32
SG35
SG36
SG52
|
See entry above. |
1309 |
|
|
1310
|
AMMONIUM PICRATE, WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SGG2
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. |
1310 |
|
|
1312
|
BORNEOL |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-I
|
Category A
|
– |
White, translucent lumps. Camphor-like odour. Insoluble in water. Harmful by ingestion. |
1312 |
|
|
1313
|
CALCIUM RESINATE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-I
|
Category A
|
– |
Yellowish-white, amorphous powder or lumps. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. |
1313 |
|
|
1314
|
CALCIUM RESINATE, FUSED |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC04
|
– |
|
– |
T1
|
TP33
|
F-A, S-I
|
Category A
|
– |
Yellowish-white, amorphous powder or lumps. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. |
1314 |
|
|
1318
|
COBALT RESINATE, PRECIPITATED |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-I
|
Category A
|
– |
Dark brownish-black solid. Insoluble in water. Readily combustible; may ignite spontaneously if contaminated with vegetable fibres (such as cotton). Irritating to skin and mucous membranes. |
1318 |
|
|
1320
|
DINITROPHENOL, WETTED with not less than 15% water, by mass |
4.1
|
6.1
P
|
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance when pure consists of yellow crystals. Slightly soluble in water. May form extremely sensitive compounds with heavy metals or their salts. Toxic if swallowed, by skin contact or by inhalation. |
1320 |
|
|
1321
|
DINITROPHENOLATES, WETTED with not less than 15% water, by mass |
4.1
|
6.1
P
|
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosives. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Toxic if swallowed, by skin contact or by inhalation. |
1321 |
|
|
1322
|
DINITRORESORCINOL, WETTED with not less than 15% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Explosive when dry. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. |
1322 |
|
|
1323
|
FERROCERIUM |
4.1
|
– |
II |
249
|
1 kg |
E2 |
P002
|
PP100 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-G
|
Category A
H1
|
SG25
SG26
|
Alloy derived from cerium or mischmetal, with the addition of 10% to 65% iron. Emits sparks when struck. |
1323 |
|
|
1324
|
FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
PP15 |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category D
|
SG7
|
Ignites readily. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. |
1324 |
|
|
1325
|
FLAMMABLE SOLID, ORGANIC, N.O.S. |
4.1
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
|
SG72
|
– |
1325 |
|
|
1325
|
FLAMMABLE SOLID, ORGANIC, N.O.S. |
4.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category B
|
SG72
|
– |
1325 |
|
|
1326
|
-
HAFNIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present)
- (a) mechanically produced, particle size less than 53 microns;
-
(b) chemically produced, particle size less than 840 microns
|
4.1
|
– |
II |
916
|
1 kg |
E2 |
P410
|
PP31 PP40 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category E
|
SGG15
SG17
|
Insoluble in water. Liable to spontaneous combustion when dry. Forms explosive mixtures with oxidizing substances. |
1326 |
|
|
1327
|
HAY, STRAW or BHUSA |
4.1
|
– |
– |
29
281
954
973
|
3 kg |
E0 |
P003
|
PP19 |
IBC08
|
B6 |
|
– |
– |
– |
F-A, S-I
|
Category A
SW10
|
SG23
|
Ignites readily. Liable to spontaneous combustion when wet, damp or contaminated with oil. Refuse for shipment when loose, damp, wet or contaminated with oil. |
1327 |
|
|
1328
|
HEXAMETHYLENETETRAMINE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC08
|
B3
|
|
– |
T1
|
TP33
|
F-A, S-G
|
Category A
|
– |
White, crystalline powder. Soluble in water. |
1328 |
|
|
1330
|
MANGANESE RESINATE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-I
|
Category A
|
– |
Very dark brown solid. Insoluble in water. Liable to spontaneous heating. Irritating to skin, eyes and mucous membranes. |
1330 |
|
|
1331
|
MATCHES, “STRIKE ANYWHERE” |
4.1
|
– |
III |
293
|
5 kg |
E0 |
P407
|
PP27 |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category B
|
– |
Ignite by friction; prepared surface is not required. |
1331 |
|
|
1332
|
METALDEHYDE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category A
|
– |
White crystals, powder or tablets. Insoluble in water. Harmful if swallowed or by dust inhalation. |
1332 |
|
|
1333
|
CERIUM, slabs, ingots or rods |
4.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC08
|
B4 B21 |
|
– |
– |
– |
F-G, S-P
|
Category A
H1
|
SG17
SG25
SG26
|
Contains 94−99% rare earth metals. In contact with water or moist air, evolves hydrogen, a flammable gas. Emits sparks when scratched or struck. |
1333 |
|
|
1334 |
NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED |
4.1
|
–
P
|
III |
948
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-G
|
Category A
SW23
|
– |
Crystalline flakes or powder with a persistent odour. Evolves flammable vapours at, or below, its melting point. |
1334 |
|
|
1336
|
NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. White solid. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. |
1336 |
|
|
1337
|
NITROSTARCH, WETTED with not less than 20% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SG7
SG30
|
Desensitized explosive. Orange powder. Explosive and sensitive to friction in the dry state. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. |
1337 |
|
|
1338 |
PHOSPHORUS, AMORPHOUS |
4.1
|
– |
III |
– |
5 kg |
E1 |
P410
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category A
|
SG17
|
Reddish-brown powder. Insoluble in water. Ignites readily by friction. When involved in a fire, evolves irritating fumes. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. |
1338 |
|
|
1339
|
PHOSPHORUS HEPTASULPHIDE, free from yellow or white phosphorus |
4.1
|
– |
II |
– |
1 kg |
E2 |
P410
|
PP31 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-G, S-G
|
Category B
H1
|
SG17
SG25
SG26
|
Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. |
1339 |
|
|
1340
|
PHOSPHORUS PENTASULPHIDE, free from yellow or white phosphorus |
4.3
|
4.1
|
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category D
H1
|
SG26
|
Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. |
1340 |
|
|
1341
|
PHOSPHORUS SESQUISULPHIDE, free from yellow or white phosphorus |
4.1
|
– |
II |
– |
1 kg |
E2 |
P410
|
PP31 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
|
SG17
|
Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. |
1341 |
|
|
1343
|
PHOSPHORUS TRISULPHIDE, free from yellow or white phosphorus |
4.1
|
– |
II |
– |
1 kg |
E2 |
P410
|
PP31 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-G, S-G
|
Category B
H1
|
SG17
SG25
SG26
|
Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive mixtures with oxidizing substances. Harmful if swallowed or by dust inhalation. |
1343 |
|
|
1344
|
TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. |
1344 |
|
|
1345
|
RUBBER SCRAP or RUBBER SHODDY, powdered or granulated, not exceeding 840 microns and rubber content exceeding 45% |
4.1
|
– |
II |
223
917
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-I
|
Category A
|
– |
Liable to spontaneous heating. |
1345 |
|
|
1346 |
SILICON POWDER, AMORPHOUS |
4.1
|
– |
III |
32
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category A
|
SG17
|
Dark brown, non-metallic powder. Burns in air, when ignited; readily flammable when mixed with oxidizing substances. |
1346 |
|
|
1347
|
SILVER PICRATE, WETTED with not less than 30% water, by mass |
4.1
|
– |
I |
28
900
|
0 |
E0 |
P406
|
PP25 PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SGG7
SG7
SG30
|
Desensitized explosive. Yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. May form extremely sensitive compounds with heavy metals or their salts. Transport of SILVER PICRATE, dry or wetted with less than 30% water, by mass is prohibited. |
1347 |
|
|
1348
|
SODIUM DINITRO-o-CRESOLATE, WETTED with not less than 15% water, by mass |
4.1
|
6.1
P
|
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow powder. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Toxic if swallowed, by skin contact or by inhalation. |
1348 |
|
|
1349
|
SODIUM PICRAMATE, WETTED with not less than 20% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow powder. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Harmful if swallowed or by skin contact. |
1349 |
|
|
1350
|
SULPHUR |
4.1
|
– |
III |
242
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-G
|
Category A
SW1
SW23
|
SG17
|
When involved in a fire, evolves toxic, very irritating and suffocating gas. The dust forms an explosive mixture with air which may be ignited by static electricity. Forms explosive mixtures with oxidizing substances. Corrosive to steel, in particular in the presence of moisture. The provisions of this Code should not apply to sulphur when it is formed to a specific shape (such as prills, granules, pellets, pastilles or flakes). |
1350 |
|
|
1352 |
-
TITANIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present)
- (a) mechanically produced, particle size less than 53 microns;
-
(b) chemically produced, particle size less than 840 microns
|
4.1
|
– |
II |
28
916
|
1 kg |
E2 |
P410
|
PP31 PP40 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category E
|
SGG15
SG17
|
Grey powder. Forms explosive mixtures with oxidizing substances. |
1352 |
|
|
1353
|
FIBRES or FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. |
4.1
|
– |
III |
– |
5 kg |
E1 |
P410
|
– |
IBC08
|
B3 |
|
– |
– |
– |
F-A, S-I
|
Category D
|
– |
Toe board used in the manufacture of boots and shoes. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. |
1353 |
|
|
1354
|
TRINITROBENZENE, WETTED with not less than 30% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. |
1354 |
|
|
1355
|
TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. May form extremely sensitive compounds with heavy metals or their salts. |
1355 |
|
|
1356 |
TRINITROTOLUENE (TNT), WETTED with not less than 30% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. |
1356 |
|
|
1357
|
UREA NITRATE, WETTED with not less than 20% water, by mass |
4.1
|
– |
I |
28
227
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of white crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. |
1357 |
|
|
1358
|
-
ZIRCONIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present)
- (a) mechanically produced, particle size less than 53 microns;
-
(b) chemically produced, particle size less than 840 microns
|
4.1
|
– |
II |
916
|
1 kg |
E2 |
P410
|
PP31 PP40 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-J
|
Category E
H1
|
SGG15
SG17
SG25
SG26
|
Grey powder. Insoluble in water. Liable to spontaneous combustion when dry. Forms explosive mixtures with oxidizing substances. |
1358 |
|
|
1360
|
CALCIUM PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category E
SW2
SW5
H1
|
SG26
SG35
|
Red to brown crystals. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
1360 |
|
| △ |
1361
|
CARBON, animal or vegetable origin |
4.2
|
– |
II |
978
|
0 |
E0 |
P002
|
– |
IBC06
|
– |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category A
SW1
SW27
H2
|
– |
Black material originating from organic sources. Particularly includes carbon blacks of animal or vegetable origin, other non-activated carbon materials and charcoal produced from materials such as bone, bamboo, coconut shell, jute and wood. Liable to heat slowly and ignite spontaneously in air. |
1361 |
△ |
| △ |
1361
|
CARBON, animal or vegetable origin |
4.2
|
– |
III |
978
|
0 |
E0 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category A
SW1
SW27
H2
|
– |
See entry above. |
1361 |
△ |
| △ |
1362
|
CARBON, ACTIVATED |
4.2
|
– |
III |
979
|
0 |
E1 |
P002
|
PP11 PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category A
SW1
SW27
H2
|
– |
Activated porous black carbon materials not including charcoal (see UN 1361). May be in the form of powder, granules, pellets, fibres or felts. If chemically activated, may self-heat, and may ignite spontaneously in air. |
1362 |
△ |
|
1363
|
COPRA |
4.2
|
– |
III |
29
926
973
|
0 |
E0 |
P003
LP02
|
PP20 |
IBC08
|
B3 B6 |
|
– |
BK2
|
– |
F-A, S-J
|
Category A
SW1
SW9
H1
|
– |
Dried kernels of coconuts, with a penetrating rancid odour which may taint other cargoes. |
1363 |
|
|
1364
|
COTTON WASTE, OILY |
4.2
|
– |
III |
29
973
|
0 |
E0 |
P003
LP02
|
PP19 |
IBC08
|
B3 B6 |
|
– |
– |
– |
F-A, S-J
|
Category A
|
SG41
|
Fibres of vegetable origin. |
1364 |
|
|
1365
|
COTTON, WET |
4.2
|
– |
III |
29
973
|
0 |
E0 |
P003
|
PP19 |
IBC08
|
B3 B6 |
|
– |
– |
– |
F-A, S-J
|
Category A
|
– |
Readily combustible, liable to ignite spontaneously according to moisture content. |
1365 |
|
|
1369
|
p-NITROSODIMETHYLANILINE |
4.2
|
– |
II |
927
|
0 |
E2 |
P410
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category D
|
SG29
|
Dark green, crystalline solid, insoluble in water. Ignites spontaneously in air when dry. Harmful if swallowed. |
1369 |
|
|
1372
|
FIBRES, ANIMAL or FIBRES, VEGETABLE burnt, wet or damp |
4.2
|
– |
III |
123
|
0 |
E1 |
P410
|
– |
– |
– |
|
– |
– |
– |
F-A, S-J
|
Category A
|
– |
Liable to ignite spontaneously according to moisture content. |
1372 |
|
|
1373
|
FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil |
4.2
|
– |
III |
– |
0 |
E0 |
P410
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category A
|
– |
Liable to ignite spontaneously according to the oil content. |
1373 |
|
|
1374
|
FISH MEAL, UNSTABILIZED or FISH SCRAP, UNSTABILIZED High hazard. Unrestricted moisture content. Unrestricted fat content in excess of 12%, by mass; unrestricted fat content in excess of 15%, by mass, in the case of anti-oxidant treated fish meal or fish scrap |
4.2
|
– |
II |
300
928
|
0 |
E2 |
P410
|
PP31 PP40 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category B
SW1
SW24
|
SG65
|
Brown to greenish-brown product derived from oily fish. Strong odour which may affect other cargo. Liable to heat and ignite spontaneously. |
1374 |
|
|
1374
|
FISH MEAL, UNSTABILIZED or FISH SCRAP, UNSTABILIZED Not anti-oxidant treated. Moisture content: more than 5% but not more than 12%, by mass. Fat content: not more than 12%, by mass |
4.2
|
– |
III |
29
300
907
928
|
0 |
E1 |
P410
|
PP31 |
IBC08
|
B3 B21 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category A
SW1
SW24
|
– |
See entry above. |
1374 |
|
|
1376
|
IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification |
4.2
|
– |
III |
223
|
0 |
E0 |
P002
LP02
|
PP100 L3 |
IBC08
|
B4 |
|
– |
T1
BK2
|
TP33
|
F-G, S-P
|
Category E
H1
|
SG26
|
Obtained from coal gas purification. Strong odour which may taint other cargo. Liable to heat and ignite spontaneously. May evolve hydrogen sulphide, sulphur dioxide and hydrogen cyanide, which are toxic gases. This substance should have been cooled and weathered for not less than eight weeks before shipment, unless packed in a metal drum. |
1376 |
|
|
1378
|
METAL CATALYST, WETTED with a visible excess of liquid |
4.2
|
– |
II |
274
|
0 |
E0 |
P410
|
PP31 PP39 PP40 |
IBC01
|
– |
|
– |
T3
|
TP33
|
F-H, S-M
|
Category C
|
– |
Liable to ignite spontaneously if dry. |
1378 |
|
|
1379
|
PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) |
4.2
|
– |
III |
– |
0 |
E0 |
P410
|
PP31 |
IBC08
|
B3 |
|
– |
– |
– |
F-A, S-J
|
Category A
|
– |
Liable to ignite spontaneously. The provisions of this Code should not apply to manufactured articles properly aged. |
1379 |
|
|
1380
|
PENTABORANE |
4.2
|
6.1
|
I |
– |
0 |
E0 |
P601
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
Category D
H1
|
SG26
|
Colourless liquid. Boiling point range: 48°C to 63°C. Ignites spontaneously in air. Decomposes in contact with water, evolving hydrogen, a flammable gas. Toxic if swallowed, by skin contact or by inhalation. |
1380 |
|
|
1381
|
PHOSPHORUS, WHITE or YELLOW, DRY or UNDER WATER or IN SOLUTION |
4.2
|
6.1
P
|
I |
– |
0 |
E0 |
P405
|
PP31 |
– |
– |
|
– |
T9
|
TP3 TP31
|
F-A, S-J
|
Category E
|
– |
Ignites spontaneously in air. Melting point: 44°C. Toxic if swallowed, by skin contact or by inhalation. Receptacles are usually filled with substance in the liquid state which subsequently solidifies. A sufficient ullage should be allowed. |
1381 |
|
|
1382
|
POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 PP40 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category A
|
SGG18
SG35
|
Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas. Reacts violently with acids. |
1382 |
|
|
1383
|
PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. |
4.2
|
– |
I |
274
|
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
T21
|
TP7 TP33
|
F-G, S-M
|
Category D
H1
|
SGG15
SG26
|
Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolves hydrogen, a flammable gas. |
1383 |
|
|
1384
|
SODIUM DITHIONITE (SODIUM HYDROSULPHITE) |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category E
H1
|
– |
White or grey crystalline powder. Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. |
1384 |
|
|
1385
|
SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category A
|
SGG18
SG35
|
Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas. Reacts violently with acids. |
1385 |
|
|
1386 |
SEED CAKE, containing vegetable oil (a) mechanically expelled seeds, containing more than 10% oil or more than 20% oil and moisture combined |
4.2
|
– |
III |
29
929
973
|
0 |
E0 |
P003
LP02
|
PP20 |
IBC08
|
B3 B6 |
|
– |
BK2
|
– |
F-A, S-J
|
Category E
SW1
SW25
H1
|
– |
Residue remaining after oil has been expelled mechanically from oil-bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal, etc. May self-heat slowly and, if wet or containing an excessive proportion of unoxidized oil, ignite spontaneously. Before shipment, this cargo should be properly aged. The duration of ageing varies with the oil content. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the cargo space(s) at any time. |
1386 |
|
|
1386 |
SEED CAKE, containing vegetable oil (b) solvent extractions and expelled seeds, containing not more than 10% of oil and when the amount of moisture is higher than 10%, not more than 20% of oil and moisture combined |
4.2
|
– |
III |
29
929
973
|
0 |
E0 |
P003
LP02
|
PP20 |
IBC08
|
B3 B6 |
|
– |
BK2
|
– |
F-A, S-J
|
Category A
SW1
SW25
H1
|
– |
Residue remaining after oil has been extracted by a solvent process or expelled mechanically from oil-bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal, etc. May self-heat slowly and, if wet or containing an excessive proportion of unoxidized oil, ignite spontaneously. The seed cake should be substantially free from flammable solvent. Before shipment, this cargo should be properly aged. The duration of ageing varies with the oil content. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the cargo space(s) at any other time. |
1386 |
|
|
1387
|
WOOL WASTE, WET |
4.2
|
– |
III |
123
|
0 |
E1 |
P410
|
– |
– |
– |
|
– |
– |
– |
F-A, S-J
|
Category A
|
– |
Liable to ignite spontaneously in air according to moisture content. |
1387 |
|
|
1389
|
ALKALI METAL AMALGAM, LIQUID |
4.3
|
– |
I |
182
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SGG7
SGG11
SG26
SG35
|
Silvery liquid, consisting of metal alloyed with mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. |
1389 |
|
|
1390
|
ALKALI METAL AMIDES |
4.3
|
– |
II |
182
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category E
SW2
H1
|
SG26
SG35
|
Small crystals. Decomposes in contact with water or acids, evolving ammonia vapour and producing highly caustic alkaline solutions. |
1390 |
|
| △ |
1391
|
ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION |
4.3
|
– |
I |
182
183
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
T13
|
TP2 TP7 TP42
|
F-G, S-N
|
Category D
H1
|
SG26
SG35
|
Finely divided alkali metal or alkaline earth metal, suspended in a liquid. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. |
1391 |
△ |
|
1392 |
ALKALINE EARTH METAL AMALGAM, LIQUID |
4.3
|
– |
I |
183
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SGG7
SGG11
SG26
SG35
|
Consists of metal alloyed with mercury. Contains 2% to 10% alkaline earth metals and may contain up to 98% mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. |
1392 |
|
|
1393
|
ALKALINE EARTH METAL ALLOY, N.O.S. |
4.3
|
– |
II |
183
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
H1
|
SG26
SG35
|
When containing a substantial proportion of alkaline earth metals, readily decomposed by water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. |
1393 |
|
|
1394
|
ALUMINIUM CARBIDE |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category A
H1
|
SG26
SG35
|
Yellow crystals or powder. In contact with water, rapidly evolves methane, a flammable gas. Reacts violently with acids. |
1394 |
|
|
1395
|
ALUMINIUM FERROSILICON POWDER |
4.3
|
6.1
|
II |
932
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC05
|
B21 |
|
– |
T3
BK2
|
TP33
|
F-G, S-N
|
Category A
SW2
SW5
H1
|
SG26
SG32
SG35
SG36
|
In contact with water, caustic alkalis or acids, evolves hydrogen, a flammable gas. Impurities may, under similar circumstances, produce phosphine and arsine, which are highly toxic gases. |
1395 |
|
|
1396
|
ALUMINIUM POWDER, UNCOATED |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG15
SG26
SG32
SG35
SG36
|
In contact with water, caustic alkalis or acids, evolves hydrogen, a flammable gas. When finely divided aluminium dust is scattered, it is easily ignited by naked lights, causing explosion. May explode when in contact with oxidizing substances. Reacts with liquid halogenated hydrocarbons. |
1396 |
|
|
1396
|
ALUMINIUM POWDER, UNCOATED |
4.3
|
– |
III |
223
|
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG15
SG26
SG32
SG35
SG36
|
See entry above. |
1396 |
|
|
1397
|
ALUMINIUM PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category E
SW2
SW5
H1
|
SG26
SG35
|
Crystals or powder. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
1397 |
|
|
1398
|
ALUMINIUM SILICON POWDER, UNCOATED |
4.3
|
– |
III |
37
223
932
|
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
BK2
|
TP33
|
F-G, S-N
|
Category A
SW2
SW5
H1
|
SGG15
SG26
SG32
SG35
SG36
|
In contact with water, caustic alkalis or acids, generates heat and evolves hydrogen, a flammable gas. May also evolve silanes, which are toxic and may ignite spontaneously. |
1398 |
|
|
1400
|
BARIUM |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category E
H1
|
SG26
SG35
|
Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. Harmful if swallowed or by dust inhalation. |
1400 |
|
|
1401
|
CALCIUM |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category E
H1
|
SG26
SG35
|
Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. |
1401 |
|
|
1402
|
CALCIUM CARBIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
IBC04
|
B1 |
|
– |
– |
– |
F-G, S-N
|
Category B
H1
|
SG26
SG35
|
Solid. In contact with water, rapidly evolves acetylene, a highly flammable gas, which may be ignited by the heat of the reaction. Acetylene forms highly explosive compounds with salts of some heavy metals. Reacts violently with acids. |
1402 |
|
|
1402
|
CALCIUM CARBIDE |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category B
H1
|
SG26
SG26
SG35
|
See entry above. |
1402 |
|
|
1403
|
CALCIUM CYANAMIDE with more than 0.1% calcium carbide |
4.3
|
– |
III |
38
934
|
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category A
H1
|
SG26
SG26
SG35
|
Powder or granules. Contains calcium carbide as an impurity. In contact with water, evolves ammonia and acetylene, which is a highly flammable gas. Reacts vigorously with acids. |
1403 |
|
|
1404
|
CALCIUM HYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
Category E
H1
|
SG26
SG26
SG35
|
Solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
1404 |
|
|
1405
|
CALCIUM SILICIDE |
4.3
|
– |
II |
932
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category B
SW5
H1
|
SG26
SG35
|
In contact with water, evolves hydrogen, a flammable gas. If calcium carbide is present as an impurity, acetylene will also be evolved. In contact with acids, evolves silane, a spontaneously flammable gas. |
1405 |
|
|
1405
|
CALCIUM SILICIDE |
4.3
|
– |
III |
223
932
|
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category B
SW5
H1
|
SG26
SG35
|
See entry above. |
1405 |
|
|
1407
|
CAESIUM |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
IBC04
|
B1 |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SG26
SG35
|
White, ductile, soft metal. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
1407 |
|
|
1408
|
FERROSILICON with 30% or more but less than 90% silicon |
4.3
|
6.1
|
III |
39
223
932
|
1 kg |
E1 |
P003
|
PP20 PP100 |
IBC08
|
B4 B6 |
|
– |
T1
BK2
|
TP33
|
F-G, S-N
|
Category A
SW2
SW5
H1
|
SG26
SG35
SG36
|
In contact with moisture, water, alkalis or acids, may evolve hydrogen, a flammable gas, which may form explosive mixtures with air, and also arsine and phosphine, which are highly toxic gases. These gases are evolved in proportions which, under mechanically ventilated conditions, make the poison hazard by far predominant over the explosion hazard. The rate of gas evolution is greatest from freshly broken surfaces, so is liable to increase whenever the cargo is disturbed, such as during loading. Toxic if swallowed, by skin contact or by vapour inhalation. |
1408 |
|
|
1409
|
METAL HYDRIDES, WATER-REACTIVE, N.O.S. |
4.3
|
– |
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-L
|
Category D
H1
|
SG26
SG35
|
Solids. React with water, moisture or acids, evolving hydrogen, which may be ignited by the heat of the reaction. |
1409 |
|
|
1409
|
METAL HYDRIDES, WATER-REACTIVE, N.O.S. |
4.3
|
– |
II |
274
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-G, S-L
|
Category D
H1
|
SG26
SG35
|
See entry above. |
1409 |
|
|
1410
|
LITHIUM ALUMINIUM HYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
Category E
H1
|
SG26
SG35
|
White powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
1410 |
|
|
1411
|
LITHIUM ALUMINIUM HYDRIDE, ETHEREAL |
4.3
|
3
|
I |
– |
0 |
E0 |
P402
|
– |
– |
– |
|
– |
– |
– |
F-G, S-M
|
Category D
SW2
H1
|
SG26
|
Clear, colourless solution of lithium aluminium hydride in ether. Reacts readily with water, evolving hydrogen, a flammable gas. Evaporates readily to leave a residue which is easily ignited by a spark or friction. |
1411 |
|
|
1413
|
LITHIUM BOROHYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
Category E
H1
|
SG26
SG35
|
Crystalline, hygroscopic solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
1413 |
|
|
1414
|
LITHIUM HYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category E
H1
|
SG26
SG35
|
Solid. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
1414 |
|
|
1415
|
LITHIUM |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
IBC04
|
B1 |
|
– |
T9
|
TP7 TP33
|
F-G, S-N
|
Category E
H1
|
SG26
SG35
|
White, ductile, soft metal. Floats on water. Readily decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. For fire-fighting purposes, dry lithium chloride powder, dry sodium chloride or graphite powder should be carried on board when this substance is transported. |
1415 |
|
|
1417
|
LITHIUM SILICON |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category A
SW5
H1
|
SG26
|
Shiny lumps, crystals or powder, with sharp irritating odour. Reacts readily with water, evolving hydrogen and silane, flammable gases. Enough heat may be generated to ignite the gas mixture in air. |
1417 |
|
|
1418
|
MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER |
4.3
|
4.2
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
Category A
H1
|
SGG15
SG26
SG32
SG35
|
In contact with moisture, water or acids, evolves hydrogen, a flammable gas. Magnesium dust is easily ignited, causing explosion. May explode when in contact with oxidizing substances. For fire-fighting purposes, dry lithium chloride powder, dry sodium chloride or graphite powder should be carried on board when this substance is transported. Reacts with liquid halogenated hydrocarbons. |
1418 |
|
|
1418
|
MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER |
4.3
|
4.2
|
II |
– |
0 |
E2 |
P410
|
PP31 PP40 |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG15
SG26
SG32
SG35
|
See entry above. |
1418 |
|
|
1418
|
MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER |
4.3
|
4.2
|
III |
223
|
0 |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG15
SG26
SG32
SG35
|
See entry above. |
1418 |
|
|
1419
|
MAGNESIUM ALUMINIUM PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category E
SW2
SW5
H1
|
SG26
SG35
|
Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
1419 |
|
|
1420
|
POTASSIUM METAL ALLOYS, LIQUID |
4.3
|
– |
I |
– |
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-L
|
Category D
H1
|
SG26
SG35
|
Soft, silvery metal liquid. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
1420 |
|
|
1421
|
ALKALI METAL ALLOY, LIQUID, N.O.S. |
4.3
|
– |
I |
182
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-L
|
Category D
H1
|
SG26
SG35
|
Flows like mercury at ordinary temperatures. Not volatile. Reacts violently with moisture, water or acids, evolving hydrogen, a flammable gas, and developing considerable heat, which may ignite the gas. |
1421 |
|
|
1422
|
POTASSIUM SODIUM ALLOYS, LIQUID |
4.3
|
– |
I |
– |
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
T9
|
TP3 TP7 TP31
|
F-G, S-L
|
Category D
H1
|
SG26
SG35
|
Soft, silvery metal liquid. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
1422 |
|
|
1423
|
RUBIDIUM |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
IBC04
|
B1 |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SG26
SG35
|
Silvery-white, ductile, soft metal. Melting point: 39°C. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
1423 |
|
|
1426
|
SODIUM BOROHYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
Category E
H1
|
SG26
SG35
|
Crystalline powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
1426 |
|
|
1427
|
SODIUM HYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
Category E
H1
|
SG26
SG35
|
White powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
1427 |
|
|
1428
|
SODIUM |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
IBC04
|
B1 |
|
– |
T9
|
TP7 TP33
|
F-G, S-N
|
Category D
H1
|
SG26
SG35
|
White, ductile, soft metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
1428 |
|
|
1431
|
SODIUM METHYLATE |
4.2
|
8
|
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-L
|
Category B
|
SGG18
SG35
|
White, amorphous, free-flowing, hygroscopic powder. Decomposed by water to form methanol, a flammable liquid, which may be ignited by the heat of the reaction. Causes burns to skin, eyes and mucous membranes. |
1431 |
|
|
1432
|
SODIUM PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category E
SW2
SW5
H1
|
SG26
SG35
|
Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
1432 |
|
|
1433
|
STANNIC PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category E
SW2
SW5
H1
|
SG26
SG35
|
Silver-white solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
1433 |
|
|
1435
|
ZINC ASHES |
4.3
|
– |
III |
223
935
|
1 kg |
E1 |
P002
|
PP100 |
IBC08
|
B4 |
|
– |
T1
BK2
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG7
SGG15
SG26
|
In contact with moisture or water, liable to evolve dangerous gases, including hydrogen, a flammable gas. |
1435 |
|
|
1436
|
ZINC POWDER or ZINC DUST |
4.3
|
4.2
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
Category A
H1
|
SGG7
SGG15
SG26
SG35
SG36
|
In contact with water, alkalis or acids, evolves hydrogen, a flammable gas. Zinc dust is easily ignited, causing explosion. May explode when in contact with oxidizing substances. |
1436 |
|
|
1436
|
ZINC POWDER or ZINC DUST |
4.3
|
4.2
|
II |
– |
0 |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG7
SGG15
SG26
SG35
SG36
|
See entry above. |
1436 |
|
|
1436
|
ZINC POWDER or ZINC DUST |
4.3
|
4.2
|
III |
223
|
0 |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG7
SGG15
SG26
SG35
SG36
|
See entry above. |
1436 |
|
|
1437
|
ZIRCONIUM HYDRIDE |
4.1
|
– |
II |
– |
1 kg |
E2 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category E
|
– |
Black coloured powder. |
1437 |
|
|
1438
|
ALUMINIUM NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
|
TP33
|
F-A, S-Q
|
Category A
|
– |
Colourless or white crystals. Deliquescent. Soluble in water. Slightly corrosive. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1438 |
|
|
1439
|
AMMONIUM DICHROMATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG2
SG35
|
Orange needles. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. May ignite spontaneously in contact with acids. Harmful if swallowed. |
1439 |
|
|
1442
|
AMMONIUM PERCHLORATE |
5.1
|
– |
II |
152
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category E
|
SGG2
SGG13
SG49
SG60
|
White crystals or powder. Soluble in water. When heated, decomposes readily, even with explosion, evolving toxic fumes. Forms highly explosive mixtures with combustible material or powdered metals. These mixtures are sensitive to friction and are liable to ignite. |
1442 |
|
|
1444
|
AMMONIUM PERSULPHATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
SGG2
|
White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. |
1444 |
|
|
1445
|
BARIUM CHLORATE, SOLID |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
Colourless crystals or powder. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. |
1445 |
|
|
1446
|
BARIUM NITRATE |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
|
– |
White crystals. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. |
1446 |
|
|
1447
|
BARIUM PERCHLORATE, SOLID |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
White crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. |
1447 |
|
|
1448
|
BARIUM PERMANGANATE |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category D
|
SGG14
SG38
SG49
SG60
|
Brownish-violet crystals. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. |
1448 |
|
|
1449
|
BARIUM PEROXIDE |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Toxic if swallowed, by skin contact or by dust inhalation. |
1449 |
|
|
1450
|
BROMATES, INORGANIC, N.O.S. |
5.1
|
– |
II |
274
350
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG3
SG38
SG49
|
Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction, and may form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium bromate and mixtures of a bromate with an ammonium salt is prohibited. |
1450 |
|
|
1451
|
CAESIUM NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
– |
White powder. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1451 |
|
|
1452
|
CALCIUM CHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
White to yellowish deliquescent crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1452 |
|
|
1453
|
CALCIUM CHLORITE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG5
SG38
SG49
|
White deliquescent crystals. Soluble in water. Sensitive to heat. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1453 |
|
|
1454
|
CALCIUM NITRATE |
5.1
|
– |
III |
208
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-Q
|
Category A
SW23
|
– |
White deliquescent solid, soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1454 |
|
|
1455
|
CALCIUM PERCHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
White crystals or powder. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1455 |
|
|
1456
|
CALCIUM PERMANGANATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category D
|
SGG14
SG38
SG49
SG60
|
Violet deliquescent crystals. Soluble in water. Occurs in hydrated form. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1456 |
|
|
1457
|
CALCIUM PEROXIDE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
White or yellowish powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or on contact with water or acids, decomposes, evolving oxygen. |
1457 |
|
|
1458
|
CHLORATE AND BORATE MIXTURE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
Solid. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1458 |
|
|
1458
|
CHLORATE AND BORATE MIXTURE |
5.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
See entry above. |
1458 |
|
|
1459
|
CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
Deliquescent solid. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1459 |
|
|
1459
|
CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID |
5.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
See entry above. |
1459 |
|
|
1461
|
CHLORATES, INORGANIC, N.O.S. |
5.1
|
– |
II |
274
351
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium chlorate and mixtures of a chlorate with an ammonium salt is prohibited. |
1461 |
|
|
1462
|
CHLORITES, INORGANIC, N.O.S. |
5.1
|
– |
II |
274
352
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG5
SG38
SG49
|
Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium chlorite and mixtures of a chlorite with an ammonium salt is prohibited. |
1462 |
|
|
1463
|
CHROMIUM TRIOXIDE, ANHYDROUS |
5.1
|
6.1/8
|
II |
– |
1 kg |
E2 |
P002
|
PP31 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
|
SG6
SG16
SG19
|
Dark purplish-red deliquescent crystals. Soluble in water. Mixtures with combustible material may ignite spontaneously and may even explode. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1463 |
|
|
1465
|
DIDYMIUM NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
– |
Hygroscopic solid. Mixture of neodymium nitrate and praseodymium nitrate. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1465 |
|
|
1466
|
FERRIC NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
– |
Violet deliquescent crystals. Soluble in water. Melting point: 47°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive to most metals. Harmful if swallowed. |
1466 |
|
|
1467
|
GUANIDINE NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
SG45
|
White granules. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. NITROGUANIDINE is a different substance. |
1467 |
|
|
1469
|
LEAD NITRATE |
5.1
|
6.1
P
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
|
SGG7
SGG9
|
White crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. |
1469 |
|
|
1470
|
LEAD PERCHLORATE, SOLID |
5.1
|
6.1
P
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG7
SGG9
SGG13
SG38
SG49
|
White crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. |
1470 |
|
|
1471
|
LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
SW1
SW8
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White powder with pungent odour. Soluble in water. Critical ambient temperature of decomposition may be as low as 60°C. May cause fire in contact with organic material or ammonium compounds. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. |
1471 |
|
|
1471
|
LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE |
5.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-H, S-Q
|
Category A
SW1
SW8
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
See entry above. |
1471 |
|
|
1472
|
LITHIUM PEROXIDE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
White powder. Soluble in water. Solution in water is an alkaline corrosive liquid. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. |
1472 |
|
|
1473
|
MAGNESIUM BROMATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG3
SG38
SG49
|
White deliquescent crystals or crystalline powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1473 |
|
|
1474
|
MAGNESIUM NITRATE |
5.1
|
– |
III |
332
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-Q
|
Category A
SW23
|
– |
White deliquescent crystals, soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1474 |
|
|
1475
|
MAGNESIUM PERCHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
White crystals or powder. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1475 |
|
|
1476
|
MAGNESIUM PEROXIDE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Harmful if swallowed. |
1476 |
|
|
1477
|
NITRATES, INORGANIC, N.O.S. |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
|
SG38
SG49
|
Solids. Solid mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1477 |
|
|
1477
|
NITRATES, INORGANIC, N.O.S. |
5.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
SG38
SG49
|
See entry above. |
1477 |
|
|
1479
|
OXIDIZING SOLID, N.O.S. |
5.1
|
– |
I |
274
900
|
0 |
E0 |
P503
|
– |
IBC05
|
B1 |
|
– |
– |
– |
F-A, S-Q
|
Category D
|
SG38
SG49
SG60
SG61
|
– |
1479 |
|
|
1479
|
OXIDIZING SOLID, N.O.S. |
5.1
|
– |
II |
274
900
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
SG61
|
– |
1479 |
|
|
1479
|
OXIDIZING SOLID, N.O.S. |
5.1
|
– |
III |
223
274
900
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
SG61
|
– |
1479 |
|
|
1481
|
PERCHLORATES, INORGANIC, N.O.S. |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1481 |
|
|
1481
|
PERCHLORATES, INORGANIC, N.O.S. |
5.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
See entry above. |
1481 |
|
|
1482
|
PERMANGANATES, INORGANIC, N.O.S. |
5.1
|
– |
II |
274
353
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category D
|
SGG14
SG38
SG49
SG60
|
Solids. React vigorously with sulphuric acid. React fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Transport of ammonium permanganate and mixtures of a permanganate with an ammonium salt is prohibited. |
1482 |
|
|
1482
|
PERMANGANATES, INORGANIC, N.O.S. |
5.1
|
– |
III |
223
274
353
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-H, S-Q
|
Category D
|
SGG14
SG38
SG49
SG60
|
See entry above. |
1482 |
|
|
1483
|
PEROXIDES, INORGANIC, N.O.S. |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. |
1483 |
|
|
1483
|
PEROXIDES, INORGANIC, N.O.S. |
5.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
PP100 L3 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
See entry above. |
1483 |
|
|
1484
|
POTASSIUM BROMATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG3
SG38
SG49
|
White crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible materials, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1484 |
|
|
1485
|
POTASSIUM CHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
White crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1485 |
|
|
1486
|
POTASSIUM NITRATE |
5.1
|
– |
III |
964
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-Q
|
Category A
SW23
|
– |
White crystals or powder. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1486 |
|
|
1487
|
POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
|
SGG12
SG38
SG49
|
Deliquescent solid. Soluble in water. May cause fire in contact with organic material such as wood, cotton or straw. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. May be shipped in the form of fused solid block or lumps. |
1487 |
|
|
1488
|
POTASSIUM NITRITE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
|
SGG12
SG38
SG49
|
White or slightly yellowish deliquescent crystals or sticks. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. |
1488 |
|
|
1489
|
POTASSIUM PERCHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
White crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1489 |
|
|
1490
|
POTASSIUM PERMANGANATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category D
|
SGG14
SG38
SG49
SG60
|
Dark purple crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1490 |
|
|
1491
|
POTASSIUM PEROXIDE |
5.1
|
– |
I |
– |
0 |
E0 |
P503
|
– |
IBC06
|
B1 |
|
– |
– |
– |
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
Yellow powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. |
1491 |
|
|
1492
|
POTASSIUM PERSULPHATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
SG39
SG49
|
White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Reacts fiercely with cyanides when heated or by friction. May form explosive mixture with powdered metals or ammonium compounds. |
1492 |
|
|
1493
|
SILVER NITRATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
|
SGG7
|
Colourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. Irritating to skin and mucous membranes. |
1493 |
|
|
1494
|
SODIUM BROMATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG3
SG38
SG49
|
White deliquescent crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1494 |
|
|
1495
|
SODIUM CHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
BK2
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
Colourless deliquescent crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1495 |
|
|
1496
|
SODIUM CHLORITE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG5
SG38
SG49
|
Colourless deliquescent solid. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1496 |
|
|
1498
|
SODIUM NITRATE |
5.1
|
– |
III |
964
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-Q
|
Category A
SW23
|
– |
Colourless deliquescent solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. This substance in the impure form is known as Chile Saltpetre. |
1498 |
|
|
1499
|
SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE |
5.1
|
– |
III |
964
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-Q
|
Category A
SW23
|
– |
Colourless, hygroscopic solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. Mixture prepared as a fertilizer. |
1499 |
|
|
1500
|
SODIUM NITRITE |
5.1
|
6.1
|
III |
– |
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
SGG12
SG38
SG49
|
Colourless deliquescent solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Decomposes if heated, giving off toxic nitrous fumes and gases supporting combustion. Harmful if swallowed or by dust inhalation. |
1500 |
|
|
1502
|
SODIUM PERCHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
Colourless crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1502 |
|
|
1503
|
SODIUM PERMANGANATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category D
|
SGG14
SG38
SG49
SG60
|
Red crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1503 |
|
|
1504
|
SODIUM PEROXIDE |
5.1
|
– |
I |
– |
0 |
E0 |
P503
|
– |
IBC05
|
B1 |
|
– |
– |
– |
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
Pale yellow coarse powder or granules. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. |
1504 |
|
|
1505
|
SODIUM PERSULPHATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
SG39
SG49
|
Colourless crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Reacts fiercely with cyanides when heated or by friction. May form explosive mixture with powdered metals or ammonium compounds. |
1505 |
|
|
1506
|
STRONTIUM CHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
|
Colourless deliquescent solid, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1506 |
|
|
1507
|
STRONTIUM NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
– |
Colourless solid. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
1507 |
|
|
1508
|
STRONTIUM PERCHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
|
Colourless crystals or powder, soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1508 |
|
|
1509
|
STRONTIUM PEROXIDE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG16
SG16
SG26
SG35
SG59
|
Colourless powder. Particularly if wetted with small quantities of water, a mixture with combustible materials may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. |
1509 |
|
|
1510
|
TETRANITROMETHANE |
6.1
|
5.1
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
SW2
|
SG16
|
Colourless liquid with a pungent odour. Freezing point: 12.5°C. Insoluble in water. Mixtures with combustible material are readily ignited, burn fiercely and may also explode by friction or shock. Highly toxic if swallowed, by skin contact or by inhalation. |
1510 |
|
|
1511
|
UREA HYDROGEN PEROXIDE |
5.1
|
8
|
III |
– |
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
H1
|
– |
White crystals or powder. Soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Irritating to skin, eyes and mucous membranes. |
1511 |
|
|
1512
|
ZINC AMMONIUM NITRITE |
5.1
|
– |
– |
900
|
– |
– |
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
|
Transport is prohibited. |
1512 |
|
|
1513
|
ZINC CHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG4
SGG7
SG38
SG49
|
Colourless or yellowish crystals. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1513 |
|
|
1514
|
ZINC NITRATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category A
|
SGG7
|
Colourless solid. Soluble in water. Melting point: 36°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. |
1514 |
|
|
1515
|
ZINC PERMANGANATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category D
|
SGG7
SGG14
SG38
SG49
SG60
|
Violet-brown or black crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid and hydrogen peroxide. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
1515 |
|
|
1516
|
ZINC PEROXIDE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-Q
|
Category C
H1
|
SGG7
SGG16
SG16
SG26
SG35
SG59
|
White powder. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. |
1516 |
|
|
1517
|
ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SG7
SG30
|
Desensitized explosive. Highly explosive in the dry state or if insufficiently wetted. May react violently in contact with heavy metals or their salts. |
1517 |
|
|
1541
|
ACETONE CYANOHYDRIN, STABILIZED |
6.1
|
–
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
Category D
SW1
SW2
|
SGG6
SG35
SG36
|
Colourless to amber liquid evolving toxic vapour. Miscible with water. Unstable in contact with acids and alkalis, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by inhalation. |
1541 |
|
|
1544
|
ALKALOIDS, SOLID, N.O.S. or ALKALOIDS SALTS, SOLID, N.O.S. |
6.1
|
– |
I |
43
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
|
– |
A wide range of toxic solids, generally of vegetable origin. Toxic if swallowed, by skin contact or by inhalation. |
1544 |
|
|
1544
|
ALKALOIDS, SOLID, N.O.S. or ALKALOIDS SALTS, SOLID, N.O.S. |
6.1
|
– |
II |
43
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
1544 |
|
|
1544
|
ALKALOIDS, SOLID, N.O.S. or ALKALOIDS SALTS, SOLID, N.O.S. |
6.1
|
– |
III |
43
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
1544 |
|
|
1545
|
ALLYL ISOTHIOCYANATE, STABILIZED |
6.1
|
3
|
II |
386
|
100 mL |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category D
SW1
SW2
|
– |
Colourless liquid evolving toxic vapour which is irritating and causes tears. Flashpoint: 46°C c.c. Toxic if swallowed, by skin contact or by inhalation. |
1545 |
|
|
1546
|
AMMONIUM ARSENATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG2
SG36
|
White powder or crystals. Soluble in water. Reacts with alkalis, evolving ammonia gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1546 |
|
|
1547
|
ANILINE |
6.1
|
–
P
|
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW2
|
SG35
|
Colourless, oily, volatile liquid. Reacts with acids. Toxic if swallowed, by skin contact or by inhalation. |
1547 |
|
|
1548
|
ANILINE HYDROCHLORIDE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
White, crystalline solid. Soluble in water. Decomposes to aniline in contact with alkalis. Toxic if swallowed, by skin contact or by inhalation. |
1548 |
|
|
1549
|
ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. |
6.1
|
– |
III |
45
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. |
1549 |
|
|
1550
|
ANTIMONY LACTATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
White powder or crystals. Toxic if swallowed, by skin contact or by dust inhalation. |
1550 |
|
|
1551
|
ANTIMONY POTASSIUM TARTRATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Colourless crystals or white powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1551 |
|
|
1553
|
ARSENIC ACID, LIQUID |
6.1
|
– |
I |
– |
0 |
E5 |
P001
|
PP31 |
– |
– |
|
– |
T20
|
TP2 TP7 TP13
|
F-A, S-A
|
Category B
|
SG33
|
White, deliquescent crystals which readily become liquid. Melting point: approximately 35°C. Miscible with water. In contact with metals, may evolve arsine, an extremely toxic gas. Highly toxic if swallowed, by skin contact or by inhalation. |
1553 |
|
|
1554
|
ARSENIC ACID, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals with a relatively high melting point. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1554 |
|
|
1555
|
ARSENIC BROMIDE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW1
SW2
H2
|
– |
White, deliquescent crystals. Melting point: approximately 33°C. Decomposed by water, evolving hydrogen bromide, an irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by dust inhalation. |
1555 |
|
|
1556
|
ARSENIC COMPOUND, LIQUID, N.O.S. inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s., and Arsenic sulphides, n.o.s. |
6.1
|
– |
I |
43
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
SG70
|
A wide variety of toxic liquids. In contact with acids, arsenic sulphide evolves hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. |
1556 |
|
|
1556
|
ARSENIC COMPOUND, LIQUID, N.O.S. inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s., and Arsenic sulphides, n.o.s. |
6.1
|
– |
II |
43
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
SG70
|
See entry above. |
1556 |
|
|
1556
|
ARSENIC COMPOUND, LIQUID, N.O.S. inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s., and Arsenic sulphides, n.o.s. |
6.1
|
– |
III |
43
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category B
SW2
|
SG70
|
See entry above. |
1556 |
|
|
1557
|
ARSENIC COMPOUND, SOLID, N.O.S. inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. |
6.1
|
– |
I |
43
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
|
SG70
|
A wide variety of toxic solids. In contact with acids, arsenic sulphide evolves hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1557 |
|
|
1557
|
ARSENIC COMPOUND, SOLID, N.O.S. inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. |
6.1
|
– |
II |
43
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SG70
|
See entry above. |
1557 |
|
|
1557
|
ARSENIC COMPOUND, SOLID, N.O.S. inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. |
6.1
|
– |
III |
43
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SG70
|
See entry above. |
1557 |
|
|
1558
|
ARSENIC |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Silvery, brittle, crystalline solid with the appearance of a metal. Toxic if swallowed, by skin contact or by dust inhalation. |
1558 |
|
|
1559
|
ARSENIC PENTOXIDE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White, deliquescent powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1559 |
|
|
1560
|
ARSENIC TRICHLORIDE |
6.1
|
– |
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
Category B
SW2
|
– |
Colourless, oily liquid. Fumes in moist air, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. Reacts with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1560 |
|
|
1561
|
ARSENIC TRIOXIDE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1561 |
|
|
1562
|
ARSENICAL DUST |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Fine powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1562 |
|
|
1564
|
BARIUM COMPOUND, N.O.S. |
6.1
|
– |
II |
177
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White powder, lumps or crystals. Toxic if swallowed, by skin contact or by inhalation. |
1564 |
|
|
1564
|
BARIUM COMPOUND, N.O.S. |
6.1
|
– |
III |
177
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
1564 |
|
|
1565
|
BARIUM CYANIDE |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
SGG6
SG35
|
White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1565 |
|
|
1566
|
BERYLLIUM COMPOUND, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
A wide range of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. |
1566 |
|
|
1566
|
BERYLLIUM COMPOUND, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
1566 |
|
|
1567
|
BERYLLIUM POWDER |
6.1
|
4.1
|
II |
– |
500 g |
E4 |
P002
|
PP100 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-G
|
Category A
H1
|
SG25
SG26
|
White, metallic powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1567 |
|
|
1569
|
BROMOACETONE |
6.1
|
3
P
|
II |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
– |
When pure, colourless liquid evolving irritating vapour (“Tear Gas”). Flashpoint: approximately 45°C c.c. Toxic if swallowed, by skin contact or by inhalation. |
1569 |
|
|
1570
|
BRUCINE |
6.1
|
– |
I |
43
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals or powder. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1570 |
|
|
1571
|
BARIUM AZIDE, WETTED with not less than 50% water, by mass |
4.1
|
6.1
|
I |
28
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SGG17
SG7
SG30
|
Desensitized explosive. White crystals or powder. Explosive and sensitive to friction in the dry state. Toxic if swallowed, by skin contact or by dust inhalation. May form extremely sensitive compounds with heavy metals or their salts. |
1571 |
|
|
1572
|
CACODYLIC ACID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category E
|
SGG1
SG35
SG36
SG49
|
Colourless crystals or white powder with an offensive odour. Soluble in water. May react with acids, evolving dimethylarsine, an extremely toxic gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1572 |
|
|
1573
|
CALCIUM ARSENATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1573 |
|
|
1574
|
CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1574 |
|
|
1575
|
CALCIUM CYANIDE |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
SGG6
SG35
|
White crystals or powder. Decomposes slowly in water to form a weak hydrogen cyanide solution. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1575 |
|
|
1577
|
CHLORODINITROBENZENES, LIQUID |
6.1
|
–
P
|
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SG15
|
Colourless liquids. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. |
1577 |
|
|
1578
|
CHLORONITROBENZENES, SOLID |
6.1
|
– |
II |
279
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellow crystals. Melting point: approximately 30°C to 80°C. Toxic if swallowed, by skin contact or by dust inhalation. |
1578 |
|
|
1579
|
4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Dry solid or paste. Toxic if swallowed, by skin contact or by dust inhalation. |
1579 |
|
|
1580
|
CHLOROPICRIN |
6.1
|
–
P
|
I |
354
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
– |
Colourless, oily liquid. Highly toxic if swallowed, by skin contact or by inhalation. |
1580 |
|
|
1581
|
CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin |
2.3
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-U
|
Category D
SW1
SW2
|
– |
Extremely volatile liquid evolving highly toxic vapours. Highly toxic by skin contact or by inhalation. Causes burns to skin and eyes; vapour irritating to mucous membranes. |
1581 |
|
|
1582
|
CHLOROPICRIN AND METHYL CHLORIDE MIXTURE |
2.3
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-U
|
Category D
SW1
SW2
|
– |
Extremely volatile liquid evolving highly toxic vapours. Highly toxic by skin contact or by inhalation. Causes burns to skin and eyes; vapour irritating to mucous membranes. |
1582 |
|
|
1583
|
CHLOROPICRIN MIXTURE, N.O.S. |
6.1
|
– |
I |
43
274
315
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category C
SW2
|
– |
A wide range of liquid mixtures. May evolve highly toxic vapour. Toxic if swallowed, by skin contact or by inhalation. |
1583 |
|
|
1583
|
CHLOROPICRIN MIXTURE, N.O.S. |
6.1
|
– |
II |
43
274
|
100 mL |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category C
SW2
|
– |
See entry above. |
1583 |
|
|
1583
|
CHLOROPICRIN MIXTURE, N.O.S. |
6.1
|
– |
III |
43
223
274
|
5 L |
E0 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category C
SW2
|
– |
See entry above. |
1583 |
|
|
1585
|
COPPER ACETOARSENITE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1585 |
|
|
1586
|
COPPER ARSENITE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellowish-green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1586 |
|
|
1587
|
COPPER CYANIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SGG7
SG35
|
Green powder. Slightly soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1587 |
|
|
1588
|
CYANIDES, INORGANIC, SOLID, N.O.S. |
6.1
|
–
P
|
I |
47
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SG35
|
Solids. May be soluble in water. On contact with water, may form a weak hydrogen cyanide solution. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. The provisions of this Code shall not apply to complex ferricyanides and ferrocyanides. |
1588 |
|
|
1588
|
CYANIDES, INORGANIC, SOLID, N.O.S. |
6.1
|
–
P
|
II |
47
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SG35
|
See entry above. |
1588 |
|
|
1588
|
CYANIDES, INORGANIC, SOLID, N.O.S. |
6.1
|
–
P
|
III |
47
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SG35
|
See entry above. |
1588 |
|
|
1589
|
CYANOGEN CHLORIDE, STABILIZED |
2.3
|
8
P
|
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW1
SW2
|
– |
Liquefied, non-flammable, toxic and corrosive gas with an irritating odour. Produces severe tearing of the eyes. On contact with water, reacts violently to give off highly toxic and corrosive fumes. Much heavier than air (2.1). Boiling point: 13°C. Toxic by skin contact or by inhalation. Highly irritating to skin, eyes and mucous membranes. |
1589 |
|
|
1590
|
DICHLOROANILINES, LIQUID |
6.1
|
–
P
|
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW2
|
– |
Colourless liquid with a penetrating odour. Liquid mixtures of various isomers of dichloroanilines, some of which in the pure state may be solid, with a melting point varying from 24°C to 72°C. Toxic if swallowed, by skin contact or by inhalation. |
1590 |
|
|
1591
|
o-DICHLOROBENZENE |
6.1
|
– |
III |
279
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
SGG10
|
Volatile liquid. Melting point: approximately −17°C. Toxic if swallowed, by skin contact or by inhalation. |
1591 |
|
|
1593
|
DICHLOROMETHANE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
B8 |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SGG10
|
Colourless, volatile liquid with heavy vapours. Boiling point: 40°C. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
1593 |
|
|
1594
|
DIETHYL SULPHATE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category C
|
– |
Colourless, oily liquid. Readily hydrolysed by moisture to sulphuric acid, which is a corrosive liquid. Toxic if swallowed, by skin contact or by inhalation. |
1594 |
|
|
1595
|
DIMETHYL SULPHATE |
6.1
|
8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
Category D
SW2
|
SGG1
SG36
SG49
|
Colourless, volatile liquid evolving toxic vapours. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1595 |
|
|
1596
|
DINITROANILINES |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SG15
|
Yellow crystals in pure form. Insoluble in water. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. |
1596 |
|
|
1597
|
DINITROBENZENES, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SG15
|
Yellow solutions. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. |
1597 |
|
|
1597
|
DINITROBENZENES, LIQUID |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SG15
|
See entry above. |
1597 |
|
|
1598
|
DINITRO-o-CRESOL |
6.1
|
–
P
|
II |
43
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellow crystals or crystallized mass. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1598 |
|
|
1599
|
DINITROPHENOL SOLUTION |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SG30
|
Substance when pure consists of yellow crystals. Slightly soluble in water. May form extremely sensitive compounds with heavy metals or their salts. Toxic if swallowed, by skin contact or by inhalation. |
1599 |
|
|
1599
|
DINITROPHENOL SOLUTION |
6.1
|
–
P
|
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
SG30
|
See entry above. |
1599 |
|
|
1600
|
DINITROTOLUENES, MOLTEN |
6.1
|
–
P
|
II |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T7
|
TP3
|
F-A, S-A
|
Category C
|
– |
Molten liquid. This entry covers the 2,3-, 2,4-, 2,5-, 2,6-, 3,4- and 3,5-isomers having melting points between 52°C and 93°C. Toxic if swallowed, by skin contact or by inhalation. |
1600 |
|
|
1601
|
DISINFECTANT, SOLID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. |
1601 |
|
|
1601
|
DISINFECTANT, SOLID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
1601 |
|
|
1601
|
DISINFECTANT, SOLID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
1601 |
|
|
1602
|
DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. |
1602 |
|
|
1602
|
DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
See entry above. |
1602 |
|
|
1602
|
DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
See entry above. |
1602 |
|
|
1603
|
ETHYL BROMOACETATE |
6.1
|
3
|
II |
– |
100 mL |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category D
SW2
|
– |
Colourless, flammable liquid evolving irritating vapour (“Tear Gas”). Flashpoint: 58°C c.c. Toxic if swallowed, by skin contact or by inhalation. |
1603 |
|
|
1604
|
ETHYLENEDIAMINE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
Category A
SW2
|
SGG18
SG35
|
Volatile, colourless, hygroscopic flammable liquid with an ammonia-like odour. Flashpoint: 34°C c.c. Miscible with water. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
1604 |
|
|
1605
|
ETHYLENE DIBROMIDE |
6.1
|
– |
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
SGG10
|
Colourless, volatile liquid. Highly toxic if swallowed, by skin contact or by inhalation. |
1605 |
|
|
1606
|
FERRIC ARSENATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Green crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1606 |
|
|
1607
|
FERRIC ARSENITE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Brown or yellow powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1607 |
|
|
1608
|
FERROUS ARSENATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Green powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1608 |
|
|
1611
|
HEXAETHYL TETRAPHOSPHATE |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category E
SW2
|
– |
Yellow liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1611 |
|
|
1612
|
HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE |
2.3
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
1612 |
|
|
1613
|
HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with not more than 20% hydrogen cyanide |
6.1
|
–
P
|
I |
900
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
– |
Colourless liquid evolving extremely toxic vapour with a bitter almond odour. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Transport of HYDROCYANIC ACID, AQUEOUS SOLUTION with more than 20% hydrogen cyanide and of HYDROGEN CYANIDE, AQUEOUS SOLUTION with more than 20% hydrogen cyanide is prohibited. |
1613 |
|
|
1614
|
HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material |
6.1
|
–
P
|
I |
386
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-A, S-U
|
Category D
SW1
SW2
|
– |
Very volatile, colourless liquid, evolving extremely toxic flammable vapours, absorbed in a porous inert material. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
1614 |
|
|
1616
|
LEAD ACETATE |
6.1
|
–
P
|
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG9
|
White crystals, or brown or grey lumps. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
1616 |
|
|
1617
|
LEAD ARSENATES |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG9
|
White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1617 |
|
|
1618
|
LEAD ARSENITES |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG9
|
White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1618 |
|
|
1620
|
LEAD CYANIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SGG7
SGG9
SG35
|
White powder. Slightly soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1620 |
|
|
1621
|
LONDON PURPLE |
6.1
|
–
P
|
II |
43
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Mixture of arsenic trioxide, lime and ferric oxide, used as an insecticide. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1621 |
|
|
1622
|
MAGNESIUM ARSENATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1622 |
|
|
1623
|
MERCURIC ARSENATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Yellow crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1623 |
|
|
1624
|
MERCURIC CHLORIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1624 |
|
|
1625
|
MERCURIC NITRATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White, deliquescent crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1625 |
|
|
1626
|
MERCURIC POTASSIUM CYANIDE |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SGG7
SGG11
SG35
|
Colourless crystals. Soluble in water. Reacts with acids, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1626 |
|
|
1627
|
MERCUROUS NITRATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1627 |
|
|
1629
|
MERCURY ACETATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1629 |
|
|
1630
|
MERCURY AMMONIUM CHLORIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG2
SGG7
SGG11
|
White crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1630 |
|
|
1631
|
MERCURY BENZOATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White crystals. Toxic if swallowed, by skin contact or by dust inhalation. |
1631 |
|
|
1634
|
MERCURY BROMIDES |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1634 |
|
|
1636
|
MERCURY CYANIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SGG7
SGG11
SG35
|
White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1636 |
|
|
1637
|
MERCURY GLUCONATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Solid. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1637 |
|
|
1638
|
MERCURY IODIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Red crystals or powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1638 |
|
|
1639
|
MERCURY NUCLEATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Brown powder containing about 20% mercury. Toxic if swallowed, by skin contact or by dust inhalation. |
1639 |
|
|
1640
|
MERCURY OLEATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Yellow oily paste. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
1640 |
|
|
1641
|
MERCURY OXIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Orange powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1641 |
|
|
1642
|
MERCURY OXYCYANIDE, DESENSITIZED |
6.1
|
–
P
|
II |
900
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SGG7
SGG11
SG15
SG35
|
White crystals or powder. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. May explode if involved in a fire. Toxic if swallowed, by skin contact or by dust inhalation. Should be sufficiently phlegmatized (mercury oxycyanide–mercury cyanide mixtures containing not less than 65% by mass of mercury cyanide can be regarded as adequately phlegmatized). Transport of MERCURY OXYCYANIDE pure is prohibited. |
1642 |
|
|
1643
|
MERCURY POTASSIUM IODIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
Yellow, deliquescent crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1643 |
|
|
1644
|
MERCURY SALICYLATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1644 |
|
|
1645
|
MERCURY SULPHATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White crystals or powder. Decomposes in water, forming sulphuric acid. Toxic if swallowed, by skin contact or by dust inhalation. |
1645 |
|
|
1646
|
MERCURY THIOCYANATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SGG11
|
White powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1646 |
|
|
1647
|
METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID |
6.1
|
–
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
SGG10
|
Solutions of methyl bromide gas, evolving toxic vapour. Methyl bromide has a boiling point of approximately 4°C. Highly toxic if swallowed, by skin contact or by inhalation. |
1647 |
|
|
1648
|
ACETONITRILE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category B
SW2
|
– |
Colourless, volatile liquid. Flashpoint: 2°C c.c. Explosive limits: 3% to 16%. Miscible with water. When involved in a fire, evolves toxic cyanide fumes. Harmful if swallowed, by skin contact or by inhalation. |
1648 |
|
|
1649
|
MOTOR FUEL ANTI-KNOCK MIXTURE |
6.1
|
–
P
|
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
Category D
SW1
SW2
|
SGG7
SGG9
|
Volatile liquids evolving toxic vapour. Mixture of tetraethyllead or tetramethyllead with ethylene dibromide and ethylene dichloride. Insoluble in water. Highly toxic if swallowed, by skin contact or by inhalation. |
1649 |
|
|
1650
|
beta-NAPHTHYLAMINE, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals. Toxic if swallowed, by skin contact or by inhalation. |
1650 |
|
|
1651
|
NAPHTHYLTHIOUREA |
6.1
|
– |
II |
43
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1651 |
|
|
1652
|
NAPHTHYLUREA |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1652 |
|
|
1653
|
NICKEL CYANIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SGG7
SG35
|
Green crystals or powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1653 |
|
|
1654
|
NICOTINE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
Thick colourless oil, turning brown on exposure to air. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1654 |
|
|
1655
|
NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. |
6.1
|
– |
I |
43
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
A wide variety of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. |
1655 |
|
|
1655
|
NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. |
6.1
|
– |
II |
43
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
1655 |
|
|
1655
|
NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. |
6.1
|
– |
III |
43
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
1655 |
|
|
1656
|
NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION |
6.1
|
– |
II |
43
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1656 |
|
|
1656
|
NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION |
6.1
|
– |
III |
43
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
See entry above. |
1656 |
|
|
1657
|
NICOTINE SALICYLATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1657 |
|
|
1658
|
NICOTINE SULPHATE SOLUTION |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1658 |
|
|
1658
|
NICOTINE SULPHATE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
See entry above. |
1658 |
|
|
1659
|
NICOTINE TARTRATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1659 |
|
|
1660
|
NITRIC OXIDE, COMPRESSED |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
Non-flammable, toxic and corrosive gas. Strong oxidizing agent. On contact with air, gives off brown fumes which are toxic by inhalation, with delayed effect similar to phosgene. Heavier than air (1.04). Highly irritating to skin, eyes and mucous membranes. |
1660 |
|
|
1661
|
NITROANILINES (o-, m-, p-) |
6.1
|
– |
II |
279
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellow crystals. Toxic if swallowed, by skin contact or by dust inhalation. ortho-NITROANILINES may be carried in the molten state. |
1661 |
|
|
1662
|
NITROBENZENE |
6.1
|
– |
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW2
|
– |
Oily liquid, evolving toxic vapour. Melting point: approximately 6°C. Toxic if swallowed, by skin contact or by inhalation. |
1662 |
|
|
1663
|
NITROPHENOLS (o-, m-, p-) |
6.1
|
– |
III |
279
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellow crystals. Some isomers may have a melting point as low as 44°C. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. |
1663 |
|
|
1664
|
NITROTOLUENES, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Yellow liquids. Melting points: ortho-NITROTOLUENE: −4°C, meta-NITROTOLUENE: 15°C. Toxic if swallowed, by skin contact or by inhalation. |
1664 |
|
|
1665
|
NITROXYLENES, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Yellow liquids. Melting points: 2-NITRO−3-XYLENE: 14°C to 16°C, 3-NITRO−2-XYLENE: 7°C to 9°C, 4-NITRO−3-XYLENE: 2°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
1665 |
|
|
1669
|
PENTACHLOROETHANE |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW2
|
SGG10
|
Colourless liquid. Toxic if swallowed, by skin contact or by inhalation. |
1669 |
|
|
1670
|
PERCHLOROMETHYL MERCAPTAN |
6.1
|
–
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
– |
Yellow, oily, volatile liquid evolving irritating vapour (“Tear Gas”). Slowly decomposes in contact with water, producing hydrochloric acid. Reacts with iron or steel, evolving carbon tetrachloride. Corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. |
1670 |
|
|
1671
|
PHENOL, SOLID |
6.1
|
– |
II |
279
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Colourless or white crystals or crystallized mass. Melting point: 43°C (pure product). Soluble in water. Toxic if swallowed, by skin contact or by vapour inhalation. Rapidly absorbed through the skin. |
1671 |
|
|
1672
|
PHENYLCARBYLAMINE CHLORIDE |
6.1
|
– |
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
– |
Pale yellow, oily liquid with an irritating unpleasant odour. Highly toxic if swallowed, by skin contact or by inhalation. |
1672 |
|
|
1673
|
PHENYLENEDIAMINES (o-, m-, p-) |
6.1
|
– |
III |
279
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. |
1673 |
|
|
1674
|
PHENYLMERCURIC ACETATE |
6.1
|
–
P
|
II |
43
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
|
Toxic if swallowed, by skin contact or by dust inhalation. |
1674 |
|
|
1677
|
POTASSIUM ARSENATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Colourless crystals or white powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1677 |
|
|
1678
|
POTASSIUM ARSENITE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1678 |
|
|
1679
|
POTASSIUM CUPROCYANIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG6
SG35
|
White crystals or powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1679 |
|
|
1680
|
POTASSIUM CYANIDE, SOLID |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
SGG6
SG35
|
White, deliquescent crystals or lumps. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1680 |
|
|
1683 |
SILVER ARSENITE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
|
Yellow powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1683 |
|
|
1684 |
SILVER CYANIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
SW2
|
SGG6
SGG7
SG35
|
White powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust inhalation. |
1684 |
|
|
1685 |
SODIUM ARSENATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Colourless crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1685 |
|
|
1686 |
SODIUM ARSENITE, AQUEOUS SOLUTION |
6.1
|
– |
II |
43
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Colourless. Toxic if swallowed, by skin contact or by inhalation. |
1686 |
|
|
1686 |
SODIUM ARSENITE, AQUEOUS SOLUTION |
6.1
|
– |
III |
43
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
See entry above. |
1686 |
|
|
1687 |
SODIUM AZIDE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
– |
– |
F-A, S-A
|
CategoryA
|
SGG17
SG15
SG30
SG35
|
Colourless crystals. May react vigorously with acids to form hydrazoic acid, which is an explosive. May form extremely sensitive compounds with heavy metals or their salts. May explode if involved in a fire. Toxic if swallowed, by skin contact or by dust inhalation. |
1687 |
|
|
1688 |
SODIUM CACODYLATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
SG35
|
White, deliquescent solid with a foul odour. Reacts with acids, evolving dimethylarsine, an extremely toxic gas. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1688 |
|
|
1689 |
SODIUM CYANIDE, SOLID |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryB
|
SGG6
SG35
|
White, deliquescent crystals or lumps. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1689 |
|
|
1690 |
SODIUM FLUORIDE, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SG35
|
White crystals or powder. React with acids, evolving hydrogen fluoride, a toxic, irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. |
1690 |
|
|
1691 |
STRONTIUM ARSENITE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1691 |
|
|
1692 |
STRYCHNINE or STRYCHNINE SALTS |
6.1
|
–
P
|
I |
43
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White crystals or powder. Strychnine is slightly soluble; the salts are soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1692 |
|
|
1693 |
TEAR GAS SUBSTANCE, LIQUID, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E0 |
P001
|
PP31 |
– |
– |
|
– |
– |
– |
F-A, S-A
|
CategoryD
SW2
|
– |
“Tear gas substance” is a generic term for substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. Toxic if swallowed, by skin contact or by inhalation. |
1693 |
|
|
1693 |
TEAR GAS SUBSTANCE, LIQUID, N.O.S. |
6.1
|
– |
II |
274
|
0 |
E0 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
CategoryD
SW2
|
– |
See entry above. |
1693 |
|
|
1694 |
BROMOBENZYL CYANIDES, LIQUID |
6.1
|
– |
I |
138
|
0 |
E0 |
P001
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW1
SW2
H2
|
SGG6
SG35
|
Volatile liquids evolving irritating vapour (“Tear Gas”). Melting points: ortho-BROMOBENZYL CYANIDE 1°C. Highly toxic if swallowed, by skin contact or by inhalation. |
1694 |
|
|
1695 |
CHLOROACETONE, STABILIZED |
6.1
|
3/8
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-C
|
CategoryD
SW2
|
SG5
SG8
|
Flammable, corrosive, colourless liquid, evolving irritating vapour (“Tear Gas”). Miscible with water. Flashpoint: 25°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. |
1695 |
|
|
1697 |
CHLOROACETOPHENONE, SOLID |
6.1
|
– |
II |
– |
0 |
E0 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryD
SW1
SW2
H2
|
– |
White crystals evolving irritating vapour (“Tear Gas”). Melting point may be as low as 20°C. Toxic if swallowed, by skin contact or by inhalation. |
1697 |
|
|
1698 |
DIPHENYLAMINE CHLOROARSINE |
6.1
|
–
P
|
I |
– |
0 |
E0 |
P002
|
PP31 |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryD
SW2
|
– |
Volatile, yellow crystals evolving irritating vapour (“Tear Gas”). Highly toxic if swallowed, by skin contact or by inhalation. |
1698 |
|
|
1699 |
DIPHENYLCHLOROARSINE, LIQUID |
6.1
|
–
P
|
I |
– |
0 |
E0 |
P001
|
PP31 |
– |
– |
|
– |
– |
– |
F-A, S-A
|
CategoryD
SW2
|
– |
When pure, colourless liquid. The commercial product may be a dark brown liquid. Volatile liquid evolving an irritating vapour (“Tear Gas”). Highly toxic if swallowed, by skin contact or by inhalation. |
1699 |
|
|
1700 |
TEAR GAS CANDLES |
6.1
|
4.1
|
– |
– |
0 |
E0 |
P600
|
– |
– |
– |
|
– |
– |
– |
F-A, S-G
|
CategoryD
SW2
|
– |
Devices containing tear-producing substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. |
1700 |
|
|
1701 |
XYLYL BROMIDE, LIQUID |
6.1
|
– |
II |
– |
0 |
E0 |
P001
|
PP31 |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW2
|
SGG10
|
Colourless liquid, evolving irritating vapour (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. |
1701 |
|
|
1702 |
1,1,2,2-TETRACHLOROETHANE |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW2
|
SGG10
|
Colourless liquid with a chloroform-like odour. Toxic if swallowed, by skin contact or by inhalation. |
1702 |
|
|
1704 |
TETRAETHYL DITHIOPYROPHOSPHATE |
6.1
|
–
P
|
II |
43
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryD
SW2
|
– |
Colourless liquid. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. |
1704 |
|
|
1707 |
THALLIUM COMPOUND, N.O.S. |
6.1
|
–
P
|
II |
43
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1707 |
|
|
1708 |
TOLUIDINES, LIQUID |
6.1
|
–
P
|
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Colourless liquids. Toxic if swallowed, by skin contact or by inhalation. |
1708 |
|
|
1709 |
2,4-TOLUYLENEDIAMINE, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
1709 |
|
|
1710 |
TRICHLOROETHYLENE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
SW2
|
SGG10
|
Colourless liquid with a chloroform-like odour. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
1710 |
|
|
1711 |
XYLIDINES, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
1711 |
|
|
1712 |
ZINC ARSENATE, ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
|
Crystalline solid. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1712 |
|
|
1713 |
ZINC CYANIDE |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG6
SGG7
SG35
|
White crystals or powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. |
1713 |
|
|
1714 |
ZINC PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
CategoryE
SW2
SW5
H1
|
SGG7
SG26
SG35
|
Grey crystals or powder. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. |
1714 |
|
|
1715 |
ACETIC ANHYDRIDE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquid with an irritating odour. Flashpoint: 54°C c.c. Immiscible with water. In the presence of moisture, corrosive to most metals. Vapour irritates mucous membranes. |
1715 |
|
|
1716 |
ACETYL BROMIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1716 |
|
|
1717 |
ACETYL CHLORIDE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-E, S-C
|
CategoryB
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Flashpoint: 5°C c.c. Boiling point: 51°C. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1717 |
|
|
1718 |
BUTYL ACID PHOSPHATE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Yellow liquid. Insoluble in water. Mildly corrosive to most metals. |
1718 |
|
|
1719 |
CAUSTIC ALKALI LIQUID, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
Corrosive to aluminium, zinc and tin. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. |
1719 |
|
|
1719 |
CAUSTIC ALKALI LIQUID, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
See entry above. |
1719 |
|
|
1722 |
ALLYL CHLOROFORMATE |
6.1
|
3/8
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-C
|
CategoryD
SW2
|
SGG1
SG5
SG8
SG36
SG49
|
Colourless, flammable liquid, extremely irritating odour, causes tears. Flashpoint: 31°C c.c. When involved in a fire, evolves toxic gases. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1722 |
|
|
1723 |
ALLYL IODIDE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-C
|
CategoryB
SW2
|
SGG1
SGG10
SG36
SG49
|
Yellow liquid with an irritating odour. Flashpoint: 5°C c.c. Immiscible with water. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1723 |
|
|
1724 |
ALLYLTRICHLOROSILANE, STABILIZED |
8
|
3
|
II |
386
|
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
CategoryC
SW1
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquid with a pungent odour. Flashpoint: 35°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1724 |
|
|
1725 |
ALUMINIUM BROMIDE, ANHYDROUS |
8
|
– |
II |
937
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
White to yellowish hygroscopic crystals. Forms corrosive vapours in moist air. Reacts violently with water, evolving heat and hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly irritating to skin, eyes and mucous membranes. The solid hydrated form of this substance is not subject to the provisions of this Code. |
1725 |
|
|
1726 |
ALUMINIUM CHLORIDE, ANHYDROUS |
8
|
– |
II |
937
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
White to yellowish hygroscopic crystals. Forms corrosive vapours in moist air. Reacts violently with water, evolving heat and hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly irritating to skin, eyes and mucous membranes. The solid hydrated form of this substance is not subject to the provisions of this Code. |
1726 |
|
|
1727 |
AMMONIUM HYDROGENDIFLUORIDE, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW1
SW2
|
SGG1
SGG2
SG35
SG36
SG49
|
White deliquescent crystals. Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin and mucous membranes. |
1727 |
|
|
1728 |
AMYLTRICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1728 |
|
|
1729 |
ANISOYL CHLORIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Crystalline powder. Melting point: 22°C. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1729 |
|
|
1730 |
ANTIMONY PENTACHLORIDE, LIQUID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Yellow, oily liquid with an offensive odour. May solidify by absorption of moisture. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1730 |
|
|
1731 |
ANTIMONY PENTACHLORIDE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Yellow liquid with an offensive odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1731 |
|
|
1731 |
ANTIMONY PENTACHLORIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
See entry above. |
1731 |
|
|
1732 |
ANTIMONY PENTAFLUORIDE |
8
|
6.1
|
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG6
SG8
SG10
SG12
SG36
SG49
|
Colourless liquid with a pungent odour. When anhydrous, mildly corrosive to glass, other siliceous materials and most metals. Reacts violently with water, evolving hydrogen fluoride, an irritating gas, highly corrosive to glass and other siliceous materials and most metals. Powerful oxidant, may cause fire in contact with readily flammable organic substances. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin and mucous membranes. |
1732 |
|
|
1733 |
ANTIMONY TRICHLORIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Reacts slowly with water, evolving hydrogen chloride, an irritating and corrosive gas. In the presence of moisture, corrosive to most metals. |
1733 |
|
|
1736 |
BENZOYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid, very irritating odour, causes tears. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1736 |
|
|
1737 |
BENZYL BROMIDE |
6.1
|
8
|
II |
– |
0 |
E4 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
H1
|
SGG1
SGG10
SG36
SG49
|
Colourless liquid with a pungent odour, causes tears. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1737 |
|
|
1738 |
BENZYL CHLORIDE |
6.1
|
8
|
II |
– |
0 |
E4 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
H1
|
SGG1
SGG10
SG36
SG49
|
Colourless liquid with a pungent odour. Causes tears. Immiscible with water, but hydrolyses slowly in contact with it. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by vapour inhalation. Causes burns to skin, eyes and mucous membranes. |
1738 |
|
|
1739 |
BENZYL CHLOROFORMATE |
8
|
–
P
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with an irritating odour. Reacts with water. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1739 |
|
|
1740 |
HYDROGENDIFLUORIDES, SOLID, N.O.S. |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW1
SW2
|
SGG1
SG35
SG36
SG49
|
Crystalline solids. Decomposed by heat or acid, evolving hydrogen fluoride, an extremely irritating and corrosive gas. In the presence of moisture, corrosive to glass, other siliceous materials and most metals. Cause burns to skin, eyes and mucous membranes. |
1740 |
|
|
1740 |
HYDROGENDIFLUORIDES, SOLID, N.O.S. |
8
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
SW1
SW2
|
SGG1
SG35
SG36
SG49
|
See entry above. |
1740 |
|
|
1741 |
BORON TRICHLORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW1
SW2
|
– |
Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Much heavier than air (2.35). Highly irritating to skin, eyes and mucous membranes. |
1741 |
|
|
1742 |
BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1742 |
|
|
1743 |
BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID |
8
|
– |
II |
– |
500 mL |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1743 |
|
|
1744 |
BROMINE or BROMINE SOLUTION |
8
|
6.1
|
I |
– |
0 |
E0 |
P804
|
– |
– |
– |
|
– |
T22
|
TP2 TP10 TP13
|
F-A, S-B
|
CategoryD
SW1
SW2
H2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Very dark brown, heavy liquid with an extremely irritating odour. Density: 3.1 (pure product). Boiling point: 59°C. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Solutions have the same properties to a lesser degree, depending on concentration. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1744 |
|
|
1745 |
BROMINE PENTAFLUORIDE |
5.1
|
6.1/8
|
I |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW1
SW2
|
SGG1
SG6
SG16
SG19
SG36
SG49
|
Colourless, heavy liquid with an extremely irritating odour. Boiling point: 40°C. Powerful oxidant; may cause fire in contact with organic material such as wood, cotton or straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely corrosive gas apparent as white fumes. In contact with acids or acid fumes, evolves highly toxic fumes of bromine, fluorine and their compounds. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1745 |
|
|
1746 |
BROMINE TRIFLUORIDE |
5.1
|
6.1/8
|
I |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW1
SW2
|
SGG1
SG6
SG16
SG19
SG36
SG49
|
Colourless, heavy liquid with an extremely irritating odour. Powerful oxidant; may cause fire in contact with organic material such as wood, cotton or straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely corrosive gas apparent as white fumes. In contact with acids or acid fumes, evolves highly toxic fumes of bromine, fluorine and their compounds. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1746 |
|
|
1747 |
BUTYLTRICHLOROSILANE |
8
|
3
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquid with a pungent odour. Flashpoint: 52°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1747 |
|
|
1748 |
CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) |
5.1
|
–
P
|
II |
314
|
1 kg |
E2 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
CategoryD
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White or yellowish solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. |
1748 |
|
|
1748 |
CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) |
5.1
|
–
P
|
III |
316
|
5 kg |
E1 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
CategoryD
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
See entry above. |
1748 |
|
|
1749 |
CHLORINE TRIFLUORIDE |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
CategoryD
SW2
|
SG6
SG19
|
Non-flammable, toxic and corrosive gas. Forms dense, white, corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. Corrosive to glass and to most metals. Powerful oxidizing agent which may cause fires with combustible materials. Much heavier than air. Highly irritating to skin, eyes and mucous membranes. |
1749 |
|
|
1750 |
CHLOROACETIC ACID SOLUTION |
6.1
|
8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1750 |
|
|
1751 |
CHLOROACETIC ACID, SOLID |
6.1
|
8
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless, very deliquescent crystals. Melting point may be as low as 50°C. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by dust inhalation. Causes burns to skin, eyes and mucous membranes. |
1751 |
|
|
1752 |
CHLOROACETYL CHLORIDE |
6.1
|
8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless liquid, with extremely irritating odour, causing tears. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1752 |
|
|
1753 |
CHLOROPHENYL-TRICHLOROSILANE |
8
|
–
P
|
II |
– |
0 |
E2 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Irritating to skin, eyes and mucous membranes. |
1753 |
|
|
1754 |
CHLOROSULPHONIC ACID (with or without sulphur trioxide) |
8
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T20
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1754 |
|
|
1755 |
CHROMIC ACID SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG6
SG8
SG10
SG12
SG36
SG49
|
Orange liquid. Powerful oxidant. May cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1755 |
|
|
1755 |
CHROMIC ACID SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG6
SG8
SG10
SG12
SG36
SG49
|
See entry above. |
1755 |
|
|
1756 |
CHROMIC FLUORIDE, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG35
SG36
SG49
|
Green or violet crystals. Slightly soluble in water. Reacts with acids, evolving hydrogen fluoride, an extremely irritating and corrosive gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1756 |
|
|
1757 |
CHROMIC FLUORIDE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Green liquid. Reacts with acids, evolving hydrogen fluoride, an extremely irritating and corrosive gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1757 |
|
|
1757 |
CHROMIC FLUORIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
See entry above. |
1757 |
|
|
1758 |
CHROMIUM OXYCHLORIDE |
8
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Dark red liquid. Reacts violently with water, evolving hydrogen chloride and chlorine, both highly irritating and corrosive gases apparent as white fumes. Oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1758 |
|
|
1759 |
CORROSIVE SOLID, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
CategoryB
|
– |
Causes burns to skin, eyes and mucous membranes. |
1759 |
|
|
1759 |
CORROSIVE SOLID, N.O.S. |
8
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
– |
See entry above. |
1759 |
|
|
1759 |
CORROSIVE SOLID, N.O.S. |
8
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
– |
See entry above. |
1759 |
|
|
1760 |
CORROSIVE LIQUID, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-B
|
CategoryB
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. |
1760 |
|
|
1760 |
CORROSIVE LIQUID, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
CategoryB
SW2
|
– |
See entry above. |
1760 |
|
|
1760 |
CORROSIVE LIQUID, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
CategoryA
SW2
|
– |
See entry above. |
1760 |
|
|
1761 |
CUPRIETHYLENEDIAMINE SOLUTION |
8
|
6.1
P
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SG35
|
Dark purple liquid with an ammonia-like odour. Corrosive to copper, aluminium, zinc and tin. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1761 |
|
|
1761 |
CUPRIETHYLENEDIAMINE SOLUTION |
8
|
6.1
P
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
CategoryA
|
SG35
|
See entry above. |
1761 |
|
|
1762 |
CYCLOHEXENYLTRICHLORO-SILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1762 |
|
|
1763 |
CYCLOHEXYLTRICHLORO-SILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1763 |
|
|
1764 |
DICHLOROACETIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless liquid. Melting point: −4°C. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1764 |
|
|
1765 |
DICHLOROACETYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with an extremely irritating odour, causing tears. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1765 |
|
|
1766 |
DICHLOROPHENYL-TRICHLOROSILANE |
8
|
–
P
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Irritating to skin, eyes and mucous membranes. |
1766 |
|
|
1767 |
DIETHYLDICHLOROSILANE |
8
|
3
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquid with a pungent odour. Flashpoint: 25°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1767 |
|
|
1768 |
DIFLUOROPHOSPHORIC ACID, ANHYDROUS |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. In the presence of moisture, highly corrosive to glass and other siliceous materials. Harmful if swallowed. |
1768 |
|
|
1769 |
DIPHENYLDICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1769 |
|
|
1770 |
DIPHENYLMETHYL BROMIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Solid with an irritating odour. Causes tears. Melting point: 45°C. In the presence of moisture, corrosive to most metals. Vapour irritates mucous membranes. |
1770 |
|
|
1771 |
DODECYLTRICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1771 |
|
|
1773 |
FERRIC CHLORIDE, ANHYDROUS |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Brown solid. In the presence of moisture, highly corrosive to most metals. The provisions of this Code should not apply to the solid hydrated form. |
1773 |
|
|
1774 |
FIRE EXTINGUISHER CHARGES, corrosive liquid |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
PP4 |
– |
– |
|
– |
– |
– |
F-A, S-B
|
CategoryA
|
– |
Usually, diluted sulphuric acid in small glass receptacles. |
1774 |
|
|
1775 |
FLUOROBORIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless, clear liquid. Corrosive to most metals. May cause severe burns to skin, eyes and mucous membranes if containing free hydrofluoric acid. |
1775 |
|
|
1776 |
FLUOROPHOSPHORIC ACID, ANHYDROUS |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless liquid. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. |
1776 |
|
|
1777 |
FLUOROSULPHONIC ACID |
8
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen fluoride, an extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes severe burns to skin, eyes and mucous membranes. |
1777 |
|
|
1778 |
FLUOROSILICIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless liquid. Highly corrosive to most metals. May cause severe burns to skin, eyes and mucous membranes if containing free hydrofluoric acid. |
1778 |
|
|
1779 |
FORMIC ACID with more than 85% acid, by mass |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
Colourless flammable liquid with a pungent odour. Pure FORMIC ACID: flashpoint 42°C c.c. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1779 |
|
|
1780 |
FUMARYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Yellow liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1780 |
|
|
1781 |
HEXADECYLTRICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1781 |
|
|
1782 |
HEXAFLUOROPHOSPHORIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless liquid. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. Harmful if swallowed. |
1782 |
|
|
1783 |
HEXAMETHYLENEDIAMINE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SG35
|
Colourless liquid. Causes burns to skin, eyes and mucous membranes. |
1783 |
|
|
1783 |
HEXAMETHYLENEDIAMINE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SG35
|
See entry above. |
1783 |
|
|
1784 |
HEXYLTRICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1784 |
|
|
1786 |
HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE |
8
|
6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless syrupy liquid with a pungent odour. Mixture consists of between 70% and 80% by mass of acids and contains not less than 25% by mass of hydrofluoric acid. Reacts violently with water, developing heat. Highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin and mucous membranes. |
1786 |
|
|
1787 |
HYDRIODIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
Colourless liquid. An aqueous solution of the gas hydrogen iodide. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1787 |
|
|
1787 |
HYDRIODIC ACID |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
See entry above. |
1787 |
|
|
1788 |
HYDROBROMIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
Colourless liquid. An aqueous solution of the gas hydrogen bromide. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1788 |
|
|
1788 |
HYDROBROMIC ACID |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
See entry above. |
1788 |
|
|
1789 |
HYDROCHLORIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
Colourless liquid. An aqueous solution of the gas hydrogen chloride. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1789 |
|
|
1789 |
HYDROCHLORIC ACID |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
See entry above. |
1789 |
|
|
1790 |
HYDROFLUORIC ACID, with more than 60% hydrogen fluoride |
8
|
6.1
|
I |
– |
0 |
E0 |
P802
|
PP79 PP81 |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW1
SW2
H2
|
SGG1
SG36
SG49
|
Colourless liquid with an irritating odour. Highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Both the liquid and its fumes cause severe burns to skin, eyes and mucous membranes. |
1790 |
|
|
1790 |
HYDROFLUORIC ACID, with not more than 60% hydrogen fluoride |
8
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
PP81 |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryD
SW1
SW2
H2
|
SGG1
SG36
SG49
|
See entry above. |
1790 |
|
|
1791 |
HYPOCHLORITE SOLUTION |
8
|
–
P
|
II |
274
900
|
1 L |
E2 |
P001
|
PP10 |
IBC02
|
B5 |
|
– |
T7
|
TP2 TP24
|
F-A, S-B
|
CategoryB
|
SGG8
SG20
|
Liquid with chlorine odour. In contact with acids, evolves very irritating and corrosive gases. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1791 |
|
|
1791 |
HYPOCHLORITE SOLUTION |
8
|
–
P
|
III |
223
274
900
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2 TP24
|
F-A, S-B
|
CategoryB
|
SGG8
SG20
|
Liquid with chlorine odour. In contact with acids, evolves very irritating and corrosive gases. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1791 |
|
|
1792 |
IODINE MONOCHLORIDE, SOLID |
8
|
– |
II |
– |
1 kg |
E0 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Red, brown or black crystals. Reacts violently with water, evolving irritating and corrosive gases apparent as white fumes. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1792 |
|
|
1793 |
ISOPROPYL ACID PHOSPHATE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Oily liquid. Mildly corrosive to most metals. |
1793 |
|
|
1794 |
LEAD SULPHATE with more than 3% free acid |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SGG7
SGG9
SG36
SG49
|
May be dry solid or slurry. Corrosive to most metals. Harmful if swallowed. |
1794 |
|
|
1796 |
NITRATING ACID MIXTURE with more than 50% nitric acid |
8
|
5.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-Q
|
CategoryD
SW2
|
SGG1
SG16
SG36
SG49
|
Mixture of concentrated nitric and sulphuric acids. Oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, developing highly toxic gas (brown fumes). Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1796 |
|
|
1796 |
NITRATING ACID MIXTURE with not more than 50% nitric acid |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
See entry above. |
1796 |
|
|
1798 |
NITROHYDROCHLORIC ACID |
8
|
– |
I |
– |
0 |
E0 |
P802
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Yellow liquid; a mixture of nitric acid and hydrochloric acid, usually in the proportion of 1:3. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, evolving suffocating and highly toxic gases. Highly corrosive to all metals. Causes severe burns to skin, eyes and mucous membranes. |
1798 |
|
|
1799 |
NONYLTRICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1799 |
|
|
1800 |
OCTADECYLTRICHLORO- SILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1800 |
|
|
1801 |
OCTYLTRICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1801 |
|
|
1802 |
PERCHLORIC ACID with not more than 50% acid, by mass |
8
|
5.1
|
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-H, S-Q
|
CategoryC
|
SGG1
SG16
SG36
SG49
|
Colourless liquid. Oxidant. Highly corrosive to most metals. |
1802 |
|
|
1803 |
PHENOLSULPHONIC ACID, LIQUID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW15
|
SGG1
SG36
SG49
|
Yellow, oily liquid. Corrosive to most metals. |
1803 |
|
|
1804 |
PHENYLTRICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1804 |
|
|
1805 |
PHOSPHORIC ACID, SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Miscible in water. Mildly corrosive to most metals. |
1805 |
|
|
1806 |
PHOSPHORUS PENTACHLORIDE |
8
|
– |
II |
– |
1 kg |
E0 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG6
SG8
SG10
SG12
SG36
SG49
|
Colourless, crystalline powder. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. |
1806 |
|
|
1807 |
PHOSPHORUS PENTOXIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Crystalline powder, very deliquescent. Reacts violently with water and organic materials such as wood, cotton or straw, generating heat. In the presence of moisture, mildly corrosive to most metals. |
1807 |
|
|
1808 |
PHOSPHORUS TRIBROMIDE |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1808 |
|
|
1809 |
PHOSPHORUS TRICHLORIDE |
6.1
|
8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1809 |
|
|
1810 |
PHOSPHORUS OXYCHLORIDE |
6.1
|
8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Highly toxic if swallowed, by skin contact or by inhalation. |
1810 |
|
|
1811 |
POTASSIUM HYDROGEN DIFLUORIDE, SOLID |
8
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW1
SW2
|
SGG1
SG35
SG36
SG49
|
White crystalline solid. Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1811 |
|
|
1812 |
POTASSIUM FLUORIDE, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SG35
|
White, deliquescent crystals or powder. Decomposed by acids, evolving hydrogen fluoride, an irritating and corrosive gas. Toxic if swallowed, by skin contact or by inhalation. |
1812 |
|
|
1813 |
POTASSIUM HYDROXIDE, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
White pellets, flakes, lumps or solid blocks, deliquescent. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
1813 |
|
|
1814 |
POTASSIUM HYDROXIDE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
1814 |
|
|
1814 |
POTASSIUM HYDROXIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
See entry above. |
1814 |
|
|
1815 |
PROPIONYL CHLORIDE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Flashpoint: 12°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1815 |
|
|
1816 |
PROPYLTRICHLOROSILANE |
8
|
3
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-E, S-C
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquid, with a pungent odour. Flashpoint: 38°C c.c. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1816 |
|
|
1817 |
PYROSULPHURYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1817 |
|
|
1818 |
SILICON TETRACHLORIDE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
SG72
|
Colourless, extremely mobile liquid with a suffocating odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1818 |
|
|
1819 |
SODIUM ALUMINATE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
1819 |
|
|
1819 |
SODIUM ALUMINATE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
See entry above. |
1819 |
|
|
1823 |
SODIUM HYDROXIDE, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
White pellets, flakes, lumps or solid blocks, deliquescent. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
1823 |
|
|
1824 |
SODIUM HYDROXIDE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Colourless liquid. Corrosive to aluminium, zinc and tin. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
1824 |
|
|
1824 |
SODIUM HYDROXIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
See entry above. |
1824 |
|
|
1825 |
SODIUM MONOXIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Deliquescent crystalline solid. Reacts violently with water and acids, generating heat. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
1825 |
|
|
1826 |
NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid |
8
|
5.1
|
I |
113
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-Q
|
CategoryD
SW2
|
SGG1
SG16
SG36
SG49
|
Usually a mixture of acids which has been used for nitration processes. Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. Prohibited for shipment unless the mixture is (1) chemically stable; and (2) certified as containing no explosive impurities. |
1826 |
|
|
1826 |
NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid |
8
|
– |
II |
113
|
1 L |
E0 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
See entry above. |
1826 |
|
|
1827 |
STANNIC CHLORIDE, ANHYDROUS |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
Colourless liquid. In the presence of water, corrosive to most metals. Vapour irritates mucous membranes. |
1827 |
|
|
1828 |
SULPHUR CHLORIDES |
8
|
– |
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Red liquids with a suffocating odour. React violently with water, evolving hydrogen chloride and sulphur dioxide, irritating and corrosive gases. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1828 |
|
|
1829 |
SULPHUR TRIOXIDE, STABILIZED |
8
|
– |
I |
386
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T20
|
TP4 TP13 TP25 TP26
|
F-A, S-B
|
CategoryC
SW1
SW2
|
SGG1
SG36
SG49
|
Very deliquescent solid. Melting point may be as low as 17°C. Reacts violently with water, generating heat. May cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1829 |
|
|
1830 |
SULPHURIC ACID with more than 51% acid |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryC
SW15
|
SGG1
SG36
SG49
|
Colourless, oily liquid, mixture over 1.41 up to 1.84 relative density. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1830 |
|
|
1831 |
SULPHURIC ACID, FUMING |
8
|
6.1
|
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
CategoryC
SW2
SW15
|
SGG1
SG36
SG49
|
Colourless, oily liquid, may be partly crystallized. Solution of varying quantities of sulphur trioxide in sulphuric acid. Reacts violently with water and organic material, generating heat. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. |
1831 |
|
|
1832 |
SULPHURIC ACID, SPENT |
8
|
– |
II |
113
|
1 L |
E0 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryC
SW15
|
SGG1
SG36
SG49
|
Sulphuric acid, usually of high concentration, which has been used for chemical processes. Highly corrosive to most metals. |
1832 |
|
|
1833 |
SULPHUROUS ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryB
SW2
|
SGG1
SG36
SG49
|
Solution of sulphur dioxide in water, with a suffocating odour. Corrosive to most metals. Vapour irritates mucous membranes. |
1833 |
|
|
1834 |
SULPHURYL CHLORIDE |
6.1
|
8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Boiling point: 69°C. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. Highly toxic if swallowed, by skin contact or by inhalation. |
1834 |
|
| △ |
1835 |
TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with more than 2.5% but less than 25% tetramethylammonium hydroxide |
8
|
6.1
|
II |
279
408
409
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG2
SGG18
SG35
|
Colourless liquid with a strong ammonia-like odour that is miscible with water. Corrosive to metal. When heated emits toxic fumes of nitrogen oxides and ammonia. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes, and mucous membranes. Reacts violently with acids. |
1835 |
△ |
| △ |
1835 |
TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with not more than 2.5% tetramethylammonium hydroxide |
8
|
– |
III |
223
408
409
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG2
SGG18
SG35
|
See entry above. |
1835 |
△ |
|
1836 |
THIONYL CHLORIDE |
8
|
– |
I |
– |
0 |
E0 |
P802
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Yellow or red liquid. Boiling point: 79°C. Reacts violently with water, evolving hydrogen chloride and sulphur dioxide, irritating and corrosive gases. In the presence of moisture, highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1836 |
|
|
1837 |
THIOPHOSPHORYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1837 |
|
|
1838 |
TITANIUM TETRACHLORIDE |
6.1
|
8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SGG7
SG36
SG49
|
Colourless liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1838 |
|
|
1839 |
TRICHLOROACETIC ACID, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless, deliquescent crystals. Melting point of the pure substance: 58°C. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1839 |
|
|
1840 |
ZINC CHLORIDE SOLUTION |
8
|
–
P
|
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SGG7
SG36
SG49
|
Colourless liquid. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1840 |
|
|
1841 |
ACETALDEHYDE AMMONIA |
9
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 B6 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SG29
|
White crystalline solid. Soluble in water. When heated, decomposes into ammonia and acetaldehyde. |
1841 |
|
|
1843 |
AMMONIUM DINITRO-o-CRESOLATE, SOLID |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryB
|
SGG2
SG15
SG16
SG30
SG63
|
May support combustion and burn without oxygen. When involved in a fire, evolves toxic fumes. Forms extremely sensitive explosive compounds with lead, silver or other heavy metals and their compounds. Toxic if swallowed, by skin contact or by inhalation. |
1843 |
|
|
1845 |
CARBON DIOXIDE, SOLID (DRY ICE) |
9
|
– |
– |
– |
0 |
E0 |
P003
|
PP18 |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryC
SW2
|
– |
Non-flammable gas in a white solid form. Slowly evolves vapours which are heavier than air (1.5). Inhalation of vapours may lead to unconsciousness. Can cause severe burns when in contact with the skin. |
1845 |
|
|
1846 |
CARBON TETRACHLORIDE |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW2
|
SGG10
|
Colourless, volatile liquid with a heavy anaesthetic vapour. Non-flammable; when involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
1846 |
|
|
1847 |
POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Crystalline solid. Melting point: 60°C. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1847 |
|
|
1848 |
PROPIONIC ACID with not less than 10% and less than 90% acid, by mass |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Burns skin. Vapours irritate mucous membranes. |
1848 |
|
|
1849 |
SODIUM SULPHIDE, HYDRATED with not less than 30% water |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Yellow-pink or white deliquescent crystals, flakes or lumps. Melting point: 50°C. Soluble in water. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1849 |
|
|
1851 |
MEDICINE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
II |
221
|
100 mL |
E4 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
CategoryC
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
1851 |
|
|
1851 |
MEDICINE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
III |
221
223
|
5 L |
E1 |
P001
LP01
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
CategoryC
SW2
|
– |
See entry above. |
1851 |
|
|
1854 |
BARIUM ALLOYS, PYROPHORIC |
4.2
|
– |
I |
– |
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
T21
|
TP7 TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. |
1854 |
|
|
1855 |
CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC |
4.2
|
– |
I |
– |
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
CategoryD
H1
|
SG26
|
Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. |
1855 |
|
|
1856 |
RAGS, OILY |
4.2
|
– |
– |
29
123
973
|
0 |
E0 |
P003
|
PP19 |
IBC08
|
B3 B6 |
|
– |
– |
– |
F-A, S-J
|
CategoryA
|
– |
Liable to ignite spontaneously in air according to oil content. |
1856 |
|
|
1857 |
TEXTILE WASTE, WET |
4.2
|
– |
III |
123
|
0 |
E1 |
P410
|
– |
– |
– |
|
– |
– |
– |
F-A, S-J
|
CategoryA
|
– |
Liable to ignite spontaneously in air according to moisture content. |
1857 |
|
|
1858 |
HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Non-flammable gas. Much heavier than air (5.2). |
1858 |
|
|
1859 |
SILICON TETRAFLUORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic and corrosive gas with a pungent odour. Corrosive to metals. In moist air, produces hydrogen fluoride. Much heavier than air (3.6). Highly irritating to skin, eyes and mucous membranes. |
1859 |
|
|
1860 |
VINYL FLUORIDE, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW1
SW2
|
– |
Flammable gas. Explosive limits: 2.9% to 29%. Heavier than air (1.6). |
1860 |
|
|
1862 |
ETHYL CROTONATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid with a pungent odour. Flashpoint: 2°C c.c. Immiscible with water. |
1862 |
|
|
1863 |
FUEL, AVIATION, TURBINE ENGINE |
3
|
– |
I |
– |
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8 TP28
|
F-E, S-E
|
CategoryE
|
– |
Boiling range: −14°C upwards. Immiscible with water. |
1863 |
|
|
1863 |
FUEL, AVIATION, TURBINE ENGINE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-E
|
CategoryB
|
– |
Immiscible with water. |
1863 |
|
|
1863 |
FUEL, AVIATION, TURBINE ENGINE |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
CategoryA
|
– |
See entry above. |
1863 |
|
|
1865 |
n-PROPYL NITRATE |
3
|
– |
II |
26
|
1 L |
E2 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
CategoryD
|
SG6
SG8
SG10
SG12
|
White to straw-coloured liquid with an ether-like odour. Flashpoint: 20°C c.c. Explosive limits: 2% to 100%. Immiscible with water. Oxidizing material. May explode on heating. Harmful if swallowed or by inhalation. |
1865 |
|
|
1866 |
RESIN SOLUTION, flammable |
3
|
– |
I |
– |
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8 TP28
|
F-E, S-E
|
CategoryE
|
– |
Miscibility with water depends upon the composition. |
1866 |
|
|
1866 |
RESIN SOLUTION, flammable |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
PP1 |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-E
|
CategoryB
|
– |
See entry above. |
1866 |
|
|
1866 |
RESIN SOLUTION, flammable |
3
|
– |
III |
223
955
|
5 L |
E1 |
P001
LP01
|
PP1 |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
CategoryA
|
– |
See entry above. |
1866 |
|
|
1868 |
DECABORANE |
4.1
|
6.1
|
II |
– |
1 kg |
E0 |
P002
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
CategoryA
|
SG17
|
Colourless crystals. Slightly soluble in water. Vapours may form explosive mixture in air. Forms explosive and extremely sensitive mixtures with oxidizing substances. Toxic if swallowed, by skin contact or by dust inhalation. |
1868 |
|
|
1869 |
MAGNESIUM or MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons |
4.1
|
– |
III |
59
920
|
5 kg |
E1 |
P002
LP02
|
PP100 L3 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-G
|
CategoryA
H1
|
SG17
SG25
SG26
SG32
SG35
SG36
SG52
|
Silvery white metal. Burns with an intense white light and heat. In contact with water, especially seawater, may evolve hydrogen, a flammable gas. Reacts readily with acids and caustic alkali, evolving hydrogen. Reacts readily with iron oxide, producing a thermite effect. Forms explosive mixtures with oxidizing substances. |
1869 |
|
|
1870 |
POTASSIUM BOROHYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
CategoryE
H1
|
SG26
SG35
|
White, crystalline powder. In contact with water, acids or moisture evolves hydrogen, which may be ignited by the heat of the reaction. |
1870 |
|
|
1871 |
TITANIUM HYDRIDE |
4.1
|
– |
II |
– |
1 kg |
E2 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-A, S-G
|
CategoryE
|
– |
Dark grey powder or crystals. |
1871 |
|
|
1872 |
LEAD DIOXIDE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
CategoryA
|
SGG7
SGG9
|
Brown powder or crystals. Insoluble in water. Harmful if swallowed. |
1872 |
|
|
1873 |
PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass |
5.1
|
8
|
I |
900
|
0 |
E0 |
P502
|
PP28 |
– |
– |
|
– |
T10
|
TP1
|
F-A, S-Q
|
CategoryD
|
SGG1
SG16
SG36
SG49
|
Colourless liquid. Mixtures with combustible material may ignite spontaneously and, when involved in a fire, by shock or by friction, may cause an explosion. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Transport of PERCHLORIC ACID with more than 72% acid, by mass, is prohibited. |
1873 |
|
|
1884 |
BARIUM OXIDE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White solid. Evolves heat in contact with water. Toxic if swallowed, by skin contact or by dust inhalation. |
1884 |
|
|
1885 |
BENZIDINE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White, crystalline solid. Toxic if swallowed, by skin contact or by inhalation. |
1885 |
|
|
1886 |
BENZYLIDENE CHLORIDE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryD
SW2
|
– |
Colourless liquid evolving vapour which is irritating to eyes and skin (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. |
1886 |
|
|
1887 |
BROMOCHLOROMETHANE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SGG10
|
Clear, colourless, volatile liquid with a chloroform-like odour. Immiscible with water. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
1887 |
|
|
1888 |
CHLOROFORM |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW2
|
SGG10
|
Colourless, volatile liquid. Boiling point: 61°C. Non-flammable. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. Anaesthetic. |
1888 |
|
|
1889 |
CYANOGEN BROMIDE |
6.1
|
8
P
|
I |
– |
0 |
E0 |
P002
|
PP31 |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-B
|
CategoryD
SW2
|
SGG6
SG35
|
Colourless crystals evolving toxic vapour which is irritating and causes tears. Melting point: approximately 52°C. Boiling point: approximately 62°C. In contact with water evolves hydrogen bromide and hydrogen cyanide, which are highly toxic, flammable and corrosive gases. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
1889 |
|
|
1891 |
ETHYL BROMIDE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP2 TP13
|
F-E, S-D
|
CategoryB
SW2
SW5
|
SGG10
|
Colourless volatile liquid evolving irritating vapour with a narcotic effect. Flashpoint −20°C c.c. Boiling point: 38°C. Vapour can be ignited by an electric spark or similar sources of ignition. Toxic if swallowed, by skin contact or by inhalation. |
1891 |
|
|
1892 |
ETHYLDICHLOROARSINE |
6.1
|
–
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW2
|
– |
Colourless liquid evolving irritating vapour (“Tear Gas”). Highly toxic if swallowed, by skin contact or by inhalation. |
1892 |
|
|
1894 |
PHENYLMERCURIC HYDROXIDE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
White crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
1894 |
|
|
1895 |
PHENYLMERCURIC NITRATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
White crystals or powder. Toxic if swallowed, by skin contact or by inhalation. |
1895 |
|
|
1897 |
TETRACHLOROETHYLENE |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
SW2
|
SGG10
|
Colourless liquid with an ethereal odour. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
1897 |
|
|
1898 |
ACETYL IODIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Reacts violently with water, evolving hydrogen iodide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
1898 |
|
|
1902 |
DIISOOCTYL ACID PHOSPHATE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Oily liquid. Mildly corrosive to most metals. |
1902 |
|
|
1903 |
DISINFECTANT, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
CategoryB
|
– |
A wide variety of corrosive liquids. Cause burns to skin, eyes and mucous membranes. |
1903 |
|
|
1903 |
DISINFECTANT, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-B
|
CategoryB
|
– |
See entry above. |
1903 |
|
|
1903 |
DISINFECTANT, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-B
|
CategoryA
|
– |
See entry above. |
1903 |
|
|
1905 |
SELENIC ACID |
8
|
– |
I |
– |
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
White, very deliquescent crystalline solid. Melting point: 50°C. Soluble in water. Reacts violently with organic materials such as wood, cotton or straw. In the presence of moisture, corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
1905 |
|
|
1906 |
SLUDGE ACID |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T8
|
TP2 TP28
|
F-A, S-B
|
CategoryC
SW15
|
SGG1
SG36
SG49
|
Waste or spent sulphuric acid, usually a by-product of refining petroleum oils or crude benzenes. Highly corrosive to most metals. |
1906 |
|
|
1907 |
SODA LIME with more than 4% sodium hydroxide |
8
|
– |
III |
62 |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Deliquescent, granulated mixture of sodium hydroxide and calcium hydroxide. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
1907 |
|
|
1908 |
CHLORITE SOLUTION |
8
|
– |
II |
274
352
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP24
|
F-A, S-B
|
CategoryB
|
SGG5
SG6
SG8
SG10
SG12
SG20
|
Colourless liquid. In contact with acids, evolves very irritating and corrosive gases. Oxidizing solution. May cause fire in contact with organic materials such as wood, cotton or straw. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1908 |
|
|
1908 |
CHLORITE SOLUTION |
8
|
– |
III |
223
274
352
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2 TP24
|
F-A, S-B
|
CategoryB
|
SGG5
SG6
SG8
SG10
SG12
SG20
|
See entry above. |
1908 |
|
|
1910 |
CALCIUM OXIDE |
8
|
– |
– |
960
|
– |
– |
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
– |
Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. |
1910 |
|
|
1911 |
DIBORANE |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
SG46
|
Liquefied, flammable, toxic, colourless gas with an unpleasant odour. Explosive limits: 0.9% to 98%. Lighter than air (0.95). May decompose above −18°C with the formation of hydrogen and boron hydrides. Autoignition temperature: 90°C. Toxic by inhalation; forms boric acid and water by hydrolysis within the lungs. |
1911 |
|
|
1912 |
METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE |
2.1
|
– |
– |
228
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
CategoryD
SW2
|
– |
Solution of the flammable gas methyl chloride, UN No. 1063, in the liquid methylene chloride. |
1912 |
|
|
1913 |
NEON, REFRIGERATED LIQUID |
2.2
|
– |
– |
– |
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
CategoryD
|
– |
Liquefied, inert gas. Lighter than air (0.7). |
1913 |
|
|
1914 |
BUTYL PROPIONATES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids. Flashpoint: 32°C c.c. Immiscible with water. |
1914 |
|
|
1915 |
CYCLOHEXANONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 38°C to 44°C c.c. Explosive limits: 1.1% to 9.4%. Immiscible with water. |
1915 |
|
|
1916 |
2,2’-DICHLORODIETHYL ETHER |
6.1
|
3
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
CategoryA
|
– |
Colourless flammable liquid. Flashpoint: 55°C c.c. Immiscible with water, but reacts with it, forming corrosive and toxic fumes. Toxic if swallowed, by skin contact or by inhalation. |
1916 |
|
|
1917
|
ETHYL ACRYLATE, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP13
|
F-E, S-D
|
CategoryC
SW1
SW2
|
– |
Colourless liquid with a pungent odour. Flashpoint: 16°C c.c. Explosive limits: 1.8% to 14%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
1917 |
|
|
1918 |
ISOPROPYLBENZENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
CategoryA
|
– |
Colourless liquid with a chloroform-like odour. Flashpoint: 31°C c.c. Explosive limits: 0.9% to 6.5%. Immiscible with water. |
1918 |
|
|
1919 |
METHYL ACRYLATE, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP13
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless, volatile liquid with a pungent odour. Flashpoint: −3°C c.c. Explosive limits: 1.2% to 25%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
1919 |
|
|
1920 |
NONANES |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-E
|
CategoryA
|
– |
Colourless liquids. Explosive limits: 0.8% to 2.9%. normal-NONANE: flashpoint 31°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
1920 |
|
|
1921 |
PROPYLENEIMINE, STABILIZED |
3
|
6.1
|
I |
386
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW1
SW2
|
– |
Colourless liquid with an ammoniacal odour. Flashpoint: −4°C o.c. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin and eyes. |
1921 |
|
|
1922 |
PYRROLIDINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
SW2
|
SGG18
SG35
|
Colourless to pale yellow liquid with an ammoniacal odour. Reacts violently with acids. Flashpoint: 3°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. |
1922 |
|
|
1923 |
CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
CategoryE
H1
|
– |
Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. |
1923 |
|
|
1928 |
METHYLMAGNESIUM BROMIDE IN ETHYL ETHER |
4.3
|
3
|
I |
– |
0 |
E0 |
P402
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
CategoryD
H1
|
SG26
|
Colourless, yellowish liquid. Decomposes violently in contact with water. Spillage will ignite spontaneously. |
1928 |
|
|
1929 |
POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE) |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
CategoryE
H1
|
– |
Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. |
1929 |
|
|
1931 |
ZINC DITHIONITE (ZINC HYDROSULPHITE) |
9
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
CategoryA
H1
|
SGG7
SG11
SG20
|
White, amorphous solid material. Soluble in water. Liable to heat on contact with moisture and heating results in evolution of sulphur dioxide, an intensely irritating gas. Also evolves sulphur dioxide on contact with acids. |
1931 |
|
|
1932 |
ZIRCONIUM SCRAP |
4.2
|
– |
III |
223
|
0 |
E0 |
P002
LP02
|
PP31 L4 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-L
|
CategoryD
H1
|
SG26
|
Particle size larger than 840 microns. Readily flammable; may ignite spontaneously in air. In contact with water, may evolve hydrogen, a flammable gas. |
1932 |
|
|
1935 |
CYANIDE SOLUTION, N.O.S. |
6.1
|
–
P
|
I |
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
CategoryB
SW2
|
SGG6
SG35
|
Liquid evolving toxic vapour. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. |
1935 |
|
|
1935 |
CYANIDE SOLUTION, N.O.S. |
6.1
|
–
P
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
CategoryA
SW2
|
SGG6
SG35
|
See entry above. |
1935 |
|
|
1935 |
CYANIDE SOLUTION, N.O.S. |
6.1
|
–
P
|
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP13 TP28
|
F-A, S-A
|
CategoryA
SW2
|
SGG6
SG35
|
See entry above. |
1935 |
|
|
1938 |
BROMOACETIC ACID SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
Corrosive to most metals. Harmful if swallowed. Causes burns to eyes and skin. |
1938 |
|
|
1938 |
BROMOACETIC ACID SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
See entry above. |
1938 |
|
|
1939 |
PHOSPHORUS OXYBROMIDE |
8
|
– |
II |
– |
1 kg |
E0 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryC
SW1
SW2
H2
|
SGG1
SG36
SG49
|
Colourless crystals. Melting point: 56°C. Reacts violently with water, evolving hydrogen bromide, a toxic and corrosive gas apparent as white fumes. Reacts violently with organic materials (such as wood, cotton, straw), causing fire. Decomposes when heated, evolving toxic and corrosive gases. When involved in a fire, evolves toxic and corrosive gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
1939 |
|
|
1940 |
THIOGLYCOLIC ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless liquid with a strong, very unpleasant odour. Corrosive to most metals. Harmful if swallowed. |
1940 |
|
|
1941 |
DIBROMODIFLUOROMETHANE |
9
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-A, S-A
|
CategoryA
SW1
|
– |
Colourless, heavy liquid. Boiling point: 24°C. Immiscible with water. When involved in a fire, may evolve toxic fumes. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
1941 |
|
|
1942 |
AMMONIUM NITRATE with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance |
5.1
|
– |
III |
900
952
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-H, S-Q
|
CategoryC
SW1
SW14
SW23
|
SGG2
SG16
SG42
SG45
SG47
SG48
SG51
SG56
SG58
SG59
SG61
|
Crystals, granules or prills. Soluble in water. Supporter of combustion. A major fire aboard a ship carrying this substance may involve a risk of explosion in the event of contamination (e.g. by fuel oil) or strong confinement. An adjacent detonation may also involve the risk of explosion. If heated strongly, decomposes, giving off toxic gases and gases which support combustion. Transport of AMMONIUM NITRATE liable to self-heating sufficient to initiate decomposition is prohibited. |
1942 |
|
|
1944 |
MATCHES, SAFETY (book, card or strike on box) |
4.1
|
– |
III |
293
294
|
5 kg |
E1 |
P407
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
CategoryA
|
– |
Intended to be ignited on a specially prepared surface. |
1944 |
|
|
1945 |
MATCHES, WAX ‘VESTA’ |
4.1
|
– |
III |
293
294
|
5 kg |
E1 |
P407
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
CategoryB
|
– |
Ignite by friction; a prepared surface may be required. |
1945 |
|
|
1950 |
AEROSOLS |
2
|
– See SP63
|
– |
63
190
277
327
344
381
959
|
See SP277
|
E0 |
P207
LP200
|
PP87 L2 |
– |
– |
|
– |
– |
– |
F-D, S-U
|
– SW1 SW22 |
SG69
|
– |
1950 |
|
|
1951 |
ARGON, REFRIGERATED LIQUID |
2.2
|
– |
– |
– |
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
CategoryD
|
– |
Liquefied, inert gas. Heavier than air (1.4). |
1951 |
|
|
1952 |
ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide |
2.2
|
– |
– |
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable gas with an ether-like odour. Explosive limits: 31% to 52%. Heavier than air (1.5). |
1952 |
|
|
1953 |
COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. |
2.3
|
2.1
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
– |
1953 |
|
|
1954 |
COMPRESSED GAS, FLAMMABLE, N.O.S. |
2.1
|
– |
– |
274
392
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
– |
1954 |
|
|
1955 |
COMPRESSED GAS, TOXIC, N.O.S. |
2.3
|
– |
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
– |
1955 |
|
|
1956 |
COMPRESSED GAS, N.O.S. |
2.2
|
– |
– |
274
378
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
– |
1956 |
|
|
1957 |
DEUTERIUM, COMPRESSED |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable, odourless gas. Much lighter than air (0.14). |
1957 |
|
|
1958 |
1,2-DICHLORO−1,1,2,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 114) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable gas with a chloroform-like odour. Much heavier than air (5.9). Boiling point: 4°C. |
1958 |
|
|
1959 |
1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable gas. Explosive limits: 2.3% to 25%. Much heavier than air (2.2). |
1959 |
|
|
1961 |
ETHANE, REFRIGERATED LIQUID |
2.1
|
– |
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-D, S-U
|
CategoryD
SW2
|
– |
Liquefied, flammable gas with a faint odour. Explosive limits: 3% to 16%. Slightly heavier than air (1.05). |
1961 |
|
|
1962 |
ETHYLENE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable gas. Explosive limits: 3% to 34%. Slightly lighter than air (0.98). |
1962 |
|
|
1963 |
HELIUM, REFRIGERATED LIQUID |
2.2
|
– |
– |
– |
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5 TP34
|
F-C, S-V
|
CategoryD
|
– |
Liquefied, inert gas. Much lighter than air (0.14). |
1963 |
|
|
1964 |
HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. |
2.1
|
– |
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable hydrocarbon gas mixture obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air. |
1964 |
|
|
1965
|
HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. |
2.1
|
– |
– |
274
392
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Liquefied flammable hydrocarbon gas obtained from natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air. |
1965 |
|
|
1966 |
HYDROGEN, REFRIGERATED LIQUID |
2.1
|
– |
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5 TP34
|
F-D, S-U
|
CategoryD
SW2
|
SG46
|
Liquefied, flammable, odourless gas. Explosive limits: 4% to 75%. Much lighter than air (0.07). |
1966 |
|
|
1967 |
INSECTICIDE GAS, TOXIC, N.O.S. |
2.3
|
– |
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Toxic mixtures of insecticides with liquefied gases. These mixtures may be flammable. |
1967 |
|
|
1968 |
INSECTICIDE GAS, N.O.S. |
2.2
|
– |
– |
274
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Non-flammable and non-toxic mixtures of insecticides with liquefied gases. |
1968 |
|
|
1969 |
ISOBUTANE |
2.1
|
– |
– |
392
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable hydrocarbon. Heavier than air. |
1969 |
|
|
1970 |
KRYPTON, REFRIGERATED LIQUID |
2.2
|
– |
– |
– |
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
CategoryD
|
– |
Liquefied, inert gas. Much heavier than air (2.9). |
1970 |
|
|
1971 |
METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content |
2.1
|
– |
– |
392
974
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable gas. Explosive limits: 5% to 16%. Lighter than air (methane 0.55). |
1971 |
|
|
1972 |
METHANE, REFRIGERATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID with high methane content |
2.1
|
– |
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-D, S-U
|
CategoryD
SW2
|
– |
Liquefied, flammable gas. Explosive limits: 5% to 16%. Lighter than air (methane 0.55). |
1972 |
|
|
1973 |
CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUORO-ETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable gas. Much heavier than air (4.2.) |
1973 |
|
|
1974 |
CHLORODIFLUOROBROMO-METHANE (REFRIGERANT GAS R 12B1) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable gas. Much heavier than air (5.7). |
1974 |
|
|
1975 |
NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
CategoryD
SW2
|
SG6
SG19
|
Non-flammable, toxic and corrosive, brown gas mixtures of varying composition with a pungent odour. Strong oxidizing agent. Heavier than air. Highly irritating to skin, eyes and mucous membranes. Toxic by inhalation, with delayed effect similar to phosgene. |
1975 |
|
|
1976 |
OCTAFLUOROCYCLOBUTANE (REFRIGERANT GAS RC 318) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable gas. Much heavier than air (7.0). |
1976 |
|
|
1977 |
NITROGEN, REFRIGERATED LIQUID |
2.2
|
– |
– |
345
346
|
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
CategoryD
|
– |
Liquefied, non-flammable, odourless gas. Lighter than air (0.97). Arrangements for the containment of the liquid nitrogen and fittings in use should be appropriate to the potential danger to the structure of the freight container or ship from the effect of misuse or accidental spillage. |
1977 |
|
|
1978 |
PROPANE |
2.1
|
– |
– |
392
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable hydrocarbon gas. Explosive limits: 2.3% to 9.5%. Heavier than air (1.56). |
1978 |
|
|
1982 |
TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Non-flammable gas. Much heavier than air (3.1). |
1982 |
|
|
1983 |
1-CHLORO−2,2,2-TRIFLUORO-ETHANE (REFRIGERANT GAS R 133a) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable gas. Much heavier than air (4.1). Boiling point: 7°C. |
1983 |
|
|
1984 |
TRIFLUOROMETHANE (REFRIGERANT GAS R 23) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable gas. Much heavier than air (2.4). |
1984 |
|
|
1986 |
ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
CategoryE
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
1986 |
|
|
1986 |
ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-D
|
CategoryB
SW2
|
– |
See entry above. |
1986 |
|
|
1986 |
ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
1986 |
|
|
1987 |
ALCOHOLS, N.O.S. |
3
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-D
|
CategoryB
|
– |
– |
1987 |
|
|
1987 |
ALCOHOLS, N.O.S. |
3
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
CategoryA
|
– |
– |
1987 |
|
|
1988 |
ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
CategoryE
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
1988 |
|
|
1988 |
ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-D
|
CategoryB
SW2
|
– |
See entry above. |
1988 |
|
|
1988 |
ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
1988 |
|
|
1989 |
ALDEHYDES, N.O.S. |
3
|
– |
I |
274
|
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP27
|
F-E, S-D
|
CategoryE
|
– |
– |
1989 |
|
|
1989 |
ALDEHYDES, N.O.S. |
3
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-D
|
CategoryB
|
– |
– |
1989 |
|
|
1989 |
ALDEHYDES, N.O.S. |
3
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
CategoryA
|
– |
– |
1989 |
|
|
1990 |
BENZALDEHYDE |
9
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless or yellowish volatile oil with a bitter almond odour. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. |
1990 |
|
|
1991 |
CHLOROPRENE, STABILIZED |
3
|
6.1
|
I |
386
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP6 TP13
|
F-E, S-D
|
CategoryD
SW1
SW2
|
SGG10
|
Colourless liquid. Flashpoint: −20°C c.c. Explosive limits: 2.5% to 12%. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
1991 |
|
|
1992 |
FLAMMABLE LIQUID, TOXIC, N.O.S. |
3
|
6.1
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
CategoryE
SW2
|
– |
Flammable toxic liquid which is not specified by name in this class or, on account of its characteristics, in some other class. Toxic if swallowed, by skin contact or by inhalation. |
1992 |
|
|
1992 |
FLAMMABLE LIQUID, TOXIC, N.O.S. |
3
|
6.1
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-D
|
CategoryB
SW2
|
– |
See entry above. |
1992 |
|
|
1992 |
FLAMMABLE LIQUID, TOXIC, N.O.S. |
3
|
6.1
|
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
1992 |
|
|
1993 |
FLAMMABLE LIQUID, N.O.S. |
3
|
– |
I |
274
|
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP27
|
F-E, S-E
|
CategoryE
|
– |
– |
1993 |
|
|
1993 |
FLAMMABLE LIQUID, N.O.S. |
3
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-E
|
CategoryB
|
– |
– |
1993 |
|
|
1993 |
FLAMMABLE LIQUID, N.O.S. |
3
|
– |
III |
223
274
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-E
|
CategoryA
|
– |
– |
1993 |
|
|
1994 |
IRON PENTACARBONYL |
6.1
|
3
|
I |
354
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Yellow to dark red, volatile flammable liquid. Flashpoint: −15°C c.c. Explosive limits: 3.7% to 12.5%. May react with water or steam, evolving carbon monoxide, which is a toxic gas. Highly toxic if swallowed, by skin contact or by inhalation. |
1994 |
|
|
1999 |
TARS, LIQUID, including road oils, and cutback bitumens |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T3
|
TP3 TP29
|
F-E, S-E
|
CategoryB
|
– |
Mobile liquids prepared by mixing asphalt with petroleum distillate. Pungent odour. Immiscible with water. |
1999 |
|
|
1999 |
TARS, LIQUID, including road oils, and cutback bitumens |
3
|
– |
III |
955
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T1
|
TP3
|
F-E, S-E
|
CategoryA
|
– |
See entry above. |
1999 |
|
|
2000 |
CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap |
4.1
|
– |
III |
223
383
|
5 kg |
E1 |
P002
LP02
|
PP7 |
– |
– |
|
– |
– |
– |
F-A, S-I
|
CategoryA
|
– |
Ignites readily. When involved in a fire, evolves toxic fumes; in enclosed cargo spaces, these fumes may form an explosive mixture with air. |
2000 |
|
|
2001 |
COBALT NAPHTHENATES, POWDER |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-I
|
CategoryA
|
– |
Brown, amorphous powder. Insoluble in water. Readily combustible. |
2001 |
|
|
2002 |
CELLULOID, SCRAP |
4.2
|
– |
III |
223
|
0 |
E0 |
P002
LP02
|
PP8 |
IBC08
|
B3 |
|
– |
– |
– |
F-A, S-J
|
CategoryD
|
– |
Ignites readily. When involved in a fire, evolves toxic fumes; in enclosed cargo spaces, these fumes may form an explosive mixture with air. |
2002 |
|
|
2004 |
MAGNESIUM DIAMIDE |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
– |
|
– |
T3
|
TP33
|
F-G, S-M
|
CategoryC
H1
|
SG26
|
White powder. Ignites spontaneously in air. Reacts violently in contact with water. |
2004 |
|
|
2006 |
PLASTICS, NITROCELLULOSE-BASED, SELF-HEATING, N.O.S. |
4.2
|
– |
III |
274
|
0 |
E0 |
P002
|
– |
– |
– |
|
– |
– |
– |
F-A, S-G
|
CategoryC
|
– |
– |
2006 |
|
|
2008 |
ZIRCONIUM POWDER, DRY |
4.2
|
– |
I |
– |
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
T21
|
TP7 TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
Amorphous powder. Liable to ignite spontaneously in air. Forms explosive mixtures with oxidizing substances. |
2008 |
|
|
2008 |
ZIRCONIUM POWDER, DRY |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
See entry above. |
2008 |
|
|
2008 |
ZIRCONIUM POWDER, DRY |
4.2
|
– |
III |
223
|
0 |
E1 |
P002
LP02
|
PP31 L4 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
See entry above. |
2008 |
|
|
2009 |
ZIRCONIUM, DRY, finished sheets, strip or coiled wire |
4.2
|
– |
III |
223
|
0 |
E1 |
P002
LP02
|
PP31 L4 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
Hard, silvery metal, liable to ignite spontaneously in air. |
2009 |
|
|
2010 |
MAGNESIUM HYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
CategoryE
H1
|
SG26
SG35
|
White crystals. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
2010 |
|
|
2011 |
MAGNESIUM PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
CategoryE
SW2
SW5
H1
|
SG26
SG35
|
Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2011 |
|
|
2012 |
POTASSIUM PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
CategoryE
SW2
SW5
H1
|
SG26
SG35
|
Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2012 |
|
|
2013 |
STRONTIUM PHOSPHIDE |
4.3
|
6.1
|
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
CategoryE
SW2
SW5
H1
|
SG26
SG35
|
Solid. Reacts with acids or decomposes slowly in contact with water or damp air, evolving phosphine, a spontaneously flammable and highly toxic gas. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2013 |
|
|
2014 |
HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) |
5.1
|
8
|
II |
– |
1 L |
E2 |
P504
|
PP10 |
IBC02
|
B5 |
|
– |
T7
|
TP2 TP6 TP24
|
F-H, S-Q
|
CategoryD
SW1
|
SGG16
SG16
SG59
SG72
|
Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, except aluminium. In contact with combustible material, may cause fire or explosion. Causes burns to skin, eyes and mucous membranes. Even though stabilized, these solutions may evolve oxygen. |
2014 |
|
|
2015 |
HYDROGEN PEROXIDE, STABILIZED or HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide |
5.1
|
8
|
I |
– |
0 |
E0 |
P501
|
– |
– |
– |
|
– |
T9
|
TP2 TP6 TP24
|
F-H, S-Q
|
CategoryD
SW1
|
SGG16
SG16
SG59
|
Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, except aluminium. Decomposes vigorously in contact with permanganates. When involved in a fire, mixtures with combustible material may be explosive. Causes burns to skin, eyes and mucous membranes. Even though stabilized, these solutions may evolve oxygen. |
2015 |
|
|
2016 |
AMMUNITION, TOXIC, NON- EXPLOSIVE without burster or expelling charge, non-fuzed |
6.1
|
– |
– |
– |
0 |
E0 |
P600
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
CategoryE
SW2
H1
|
– |
Contents may evolve toxic fumes or vapour. Gases evolved are toxic by skin contact or by inhalation. |
2016 |
|
|
2017 |
AMMUNITION, TEAR-PRODUCING, NON-EXPLOSIVE without burster or expelling charge, non-fuzed |
6.1
|
8
|
– |
– |
0 |
E0 |
P600
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
CategoryE
SW2
H1
|
– |
Contents may evolve irritant gas or vapour with lachrymatory effects. |
2017 |
|
|
2018 |
CHLOROANILINES, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Crystalline solid. Melting point of pure para-chloroaniline: 70°C approximately. Toxic if swallowed, by skin contact or by dust inhalation. |
2018 |
|
|
2019 |
CHLOROANILINES, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
SG35
|
Colourless liquid. May be a mixture of two of the isomers (e.g. ortho- and meta-) of chloroaniline. Reacts with acids. Toxic if swallowed, by skin contact or by inhalation. |
2019 |
|
|
2020 |
CHLOROPHENOLS, SOLID |
6.1
|
– |
III |
205
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
A wide range of toxic solids. Toxic if swallowed, by skin contact or by dust inhalation. |
2020 |
|
|
2021 |
CHLOROPHENOLS, LIQUID |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. |
2021 |
|
|
2022 |
CRESYLIC ACID |
6.1
|
8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-B
|
CategoryB
|
– |
Colourless to brownish-yellow liquid mixture with a phenolic odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. “Cresylic acid” is a generic name for mixtures of cresols and higher alkylphenols, in varying proportions. It generally contains more than 95% phenolic compounds. |
2022 |
|
|
2023 |
EPICHLOROHYDRIN |
6.1
|
3
P
|
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-D
|
CategoryA
SW2
|
– |
Colourless flammable liquid with a chloroform-like odour. Flashpoint: approximately 32°C c.c. Toxic if swallowed, by skin contact or by inhalation. |
2023 |
|
|
2024 |
MERCURY COMPOUND, LIQUID, N.O.S. |
6.1
|
–
P
|
I |
43
66
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
CategoryB
SW2
|
SGG7
SGG11
|
Toxic if swallowed, by skin contact or by inhalation. |
2024 |
|
|
2024 |
MERCURY COMPOUND, LIQUID, N.O.S. |
6.1
|
–
P
|
II |
43
66
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
CategoryB
SW2
|
SGG7
SGG11
|
See entry above. |
2024 |
|
|
2024 |
MERCURY COMPOUND, LIQUID, N.O.S. |
6.1
|
–
P
|
III |
43
66
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
CategoryB
SW2
|
SGG7
SGG11
|
See entry above. |
2024 |
|
|
2025 |
MERCURY COMPOUND, SOLID, N.O.S. |
6.1
|
–
P
|
I |
43
66
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
Toxic if swallowed, by skin contact or by dust inhalation. |
2025 |
|
|
2025 |
MERCURY COMPOUND, SOLID, N.O.S. |
6.1
|
–
P
|
II |
43
66
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
See entry above. |
2025 |
|
|
2025 |
MERCURY COMPOUND, SOLID, N.O.S. |
6.1
|
–
P
|
III |
43
66
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
See entry above. |
2025 |
|
|
2026 |
PHENYLMERCURIC COMPOUND, N.O.S. |
6.1
|
–
P
|
I |
43
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
Usually white crystals or powder. Toxic if swallowed, by skin contact or by dust inhalation. |
2026 |
|
|
2026 |
PHENYLMERCURIC COMPOUND, N.O.S. |
6.1
|
–
P
|
II |
43
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
See entry above. |
2026 |
|
|
2026 |
PHENYLMERCURIC COMPOUND, N.O.S. |
6.1
|
–
P
|
III |
43
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG11
|
See entry above. |
2026 |
|
|
2027 |
SODIUM ARSENITE, SOLID |
6.1
|
– |
II |
43
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Greyish-white powder. Soluble in water. Reacts with oxidizing substances, evolving heat. Toxic if swallowed, by skin contact or by dust inhalation. |
2027 |
|
| △ |
2028 |
BOMBS, SMOKE, NON-EXPLOSIVE with corrosive liquid, without initiating device |
8
|
– |
– |
– |
0 |
E0 |
P803
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
CategoryE
SW2
|
– |
Corrosive content evolves dense smoke when in contact with air. Corrosive content may cause acid burns to skin. |
2028 |
△ |
|
2029 |
HYDRAZINE, ANHYDROUS |
8
|
3/6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-C
|
CategoryD
SW2
|
SGG18
SG5
SG8
SG35
|
Colourless, flammable liquid with an ammoniacal odour. Reacts violently with acids. Flashpoint: 52°C c.c. Miscible with water. Highly reactive reducing agent. Ignites spontaneously when in contact with porous materials such as earth, wood or cloth. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. |
2029 |
|
|
2030 |
HYDRAZINE, AQUEOUS SOLUTION with more than 37% hydrazine, by mass |
8
|
6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG18
SG35
|
Colourless liquid. Powerful reducing agent, burns readily. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
2030 |
|
|
2030 |
HYDRAZINE, AQUEOUS SOLUTION with more than 37% hydrazine, by mass |
8
|
6.1
|
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-B
|
CategoryD
SW2
|
SGG18
SG35
|
See entry above. |
2030 |
|
|
2030 |
HYDRAZINE, AQUEOUS SOLUTION with more than 37% hydrazine, by mass |
8
|
6.1
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryD
SW2
|
SGG18
SG35
|
See entry above. |
2030 |
|
|
2031 |
NITRIC ACID other than red fuming, with more than 70% nitric acid |
8
|
5.1
|
I |
– |
0 |
E0 |
P001
|
PP81 |
– |
– |
|
|
T10
|
TP2 TP13
|
F-A, S-Q
|
CategoryD
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Colourless liquid. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, evolving highly toxic gases (brown fumes). Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
2031 |
|
|
2031 |
NITRIC ACID other than red fuming, with at least 65% but with not more than 70% nitric acid |
8
|
5.1
|
II |
– |
1 L |
E2 |
P001
|
PP81 |
IBC02
|
B15 B20 |
|
– |
T8
|
TP2
|
F-A, S-Q
|
CategoryD
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Colourless liquid. Oxidant; may cause fire in contact with organic materials such as wood, cotton or straw, evolving highly toxic gases (brown fumes). Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
2031 |
|
|
2031 |
NITRIC ACID other than red fuming, with less than 65% nitric acid |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
PP81 |
IBC02
|
B15 B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryD
|
SGG1
SG36
SG49
|
See entry above. |
2031 |
|
|
2032 |
NITRIC ACID, RED FUMING |
8
|
5.1/6.1
|
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-Q
|
CategoryD
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Brown liquid. Powerful oxidant; may cause fire in contact with organic materials such as wood, cotton or straw. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by vapour inhalation. Causes severe burns to skin, eyes and mucous membranes. |
2032 |
|
|
2033 |
POTASSIUM MONOXIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
Deliquescent crystalline solid. Reacts violently with water, generating heat. Reacts with ammonium salts, evolving ammonia gas. Reacts violently with acids. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
2033 |
|
|
2034 |
HYDROGEN AND METHANE MIXTURE, COMPRESSED |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
SG46
|
Flammable, odourless gas mixtures. Much lighter than air. |
2034 |
|
|
2035 |
1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
CategoryB
SW2
|
– |
Flammable gas with a slight odour. Much heavier than air (2.9). |
2035 |
|
|
2036 |
XENON |
2.2
|
– |
– |
378
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, inert gas. Much heavier than air (4.5). |
2036 |
|
|
2037 |
RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable |
2 |
– |
– |
191
277
303
327
344
959
|
see SP277
|
E0 |
P003
LP200
|
PP17 PP96 L2 |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryB
SW2
SW22
|
– |
Normally contain mixtures of liquefied butane and propane in various proportions for use in camping stoves, etc. |
2037 |
|
|
2038 |
DINITROTOLUENES, LIQUID |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
B20 |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Immiscible with water. A commercial grade consisting of a mixture of the 2,4-, 3,4- and 3,5-isomers is an oily liquid. Toxic if swallowed, by skin contact or by inhalation. |
2038 |
|
|
2044 |
2,2-DIMETHYLPROPANE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable hydrocarbon gas. Explosive limits: 1.4% to 7.2%. Heavier than air (2.48). |
2044 |
|
|
2045 |
ISOBUTYL ALDEHYDE (ISOBUTYRALDEHYDE) |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid with a characteristic pungent odour. Flashpoint: −24°C c.c. Explosive limits: 1% to 12%. Immiscible with water. |
2045 |
|
|
2046 |
CYMENES |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids with an aromatic odour. Immiscible with water. Explosive limits: 0.7% to 5.6%. |
2046 |
|
|
2047 |
DICHLOROPROPENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless or yellow liquids with a sweet odour. Explosive limits: 5% to 14%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2047 |
|
|
2047 |
DICHLOROPROPENES |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
2047 |
|
|
2048 |
DICYCLOPENTADIENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
The pure substance is a solid with a melting point of 34°C. Flashpoint: 26°C to 38°C o.c. Commercial products are liquids. Immiscible with water. Harmful if swallowed. |
2048 |
|
|
2049 |
DIETHYLBENZENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids. Flashpoint: 49°C to 56°C c.c. Immiscible with water. The commercial product is a mixture of isomers. |
2049 |
|
|
2050 |
DIISOBUTYLENES, ISOMERIC COMPOUNDS |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquids. Flashpoint: −18°C to 21°C c.c. Explosive limits: 0.8% to 4.8%. Immiscible with water. |
2050 |
|
|
2051 |
2-DIMETHYLAMINOETHANOL |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
|
SG35
|
Colourless, flammable liquid with a fishy odour. Flashpoint: 31°C o.c. Miscible with water. Causes burns to skin, eyes and mucous membranes. |
2051 |
|
|
2052 |
DIPENTENE |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
CategoryA
|
– |
Colourless liquid with a lemon-like odour. Flashpoint: 43°C c.c. Explosive limits: 0.7% to 6.1%. Immiscible with water. |
2052 |
|
|
2053 |
METHYL ISOBUTYL CARBINOL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 41°C c.c. Explosive limits: 1% to 5.5%. Miscible with water. Harmful by inhalation. |
2053 |
|
|
2054 |
MORPHOLINE |
8
|
3
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2
|
F-E, S-C
|
CategoryA
|
– |
Colourless liquid with a fishy odour. Flashpoint: 38°C o.c. Explosive limits: 2% to 11.2%. Miscible with water. Harmful by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes. |
2054 |
|
|
2055 |
STYRENE MONOMER, STABILIZED |
3
|
– |
III |
386
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless, oily liquid. Flashpoint: 32°C c.c. Explosive limits: 1.1% to 6.1%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2055 |
|
|
2056 |
TETRAHYDROFURAN |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid with an ethereal odour. Flashpoint: below −18°C c.c. Explosive limits: 1.5% to 12%. Miscible with water. |
2056 |
|
|
2057 |
TRIPROPYLENE |
3
|
–
P
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Immiscible with water. |
2057 |
|
|
2057 |
TRIPROPYLENE |
3
|
–
P
|
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
2057 |
|
|
2058 |
VALERALDEHYDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 12°C c.c. Partially miscible with water. Irritating to skin, eyes and mucous membranes. |
2058 |
|
| △ |
2059 |
NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose |
3
|
– |
I |
28
198
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8 TP27
|
F-E, S-D
|
CategoryE
|
– |
When involved in a fire, evolves toxic nitrous fumes. |
2059 |
△ |
| △ |
2059 |
NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose |
3
|
– |
II |
28
198
|
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP8
|
F-E, S-D
|
CategoryB
|
– |
See entry above. |
2059 |
△ |
| △ |
2059 |
NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose |
3
|
– |
III |
28
198
223
|
5 L |
E0 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
2059 |
△ |
|
2067 |
AMMONIUM NITRATE BASED FERTILIZER |
5.1
|
– |
III |
306
307
900
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
BK3
|
TP33
|
F-H, S-Q
|
CategoryC
SW1
SW14
SW23
|
SGG2
SG16
SG42
SG45
SG47
SG48
SG51
SG56
SG58
SG59
SG61
|
Crystals, granules or prills. Wholly or partly soluble in water. Supporters of combustion. A major fire aboard a ship carrying these substances may involve a risk of explosion in the event of contamination (e.g. by fuel oil) or strong confinement. An adjacent detonation may also involve a risk of explosion. If heated strongly, decompose, giving off toxic gases and gases which support combustion. Transport of AMMONIUM NITRATE liable to self-heating sufficient to initiate decomposition is prohibited. |
2067 |
|
|
2071 |
AMMONIUM NITRATE BASED FERTILIZER |
9
|
– |
III |
193
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
BK2
|
– |
F-H, S-Q
|
CategoryA
SW26
|
SGG2
|
Usually granules. Wholly or partly soluble in water. These mixtures may be subject to self-sustaining decomposition if heated. The temperature in such a reaction can reach 500°C. Decomposition, once initiated, may spread throughout the remainder, producing gases which are toxic. None of these mixtures is subject to the explosion hazard. Transport of AMMONIUM NITRATE liable to self-heating sufficient to initiate decomposition is prohibited. |
2071 |
|
|
2073 |
AMMONIA SOLUTION, relative density less than 0.880 at 15°C in water, with more than 35% but not more than 50% ammonia |
2.2
|
–
P
|
– |
– |
120 mL |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryE
SW2
|
SGG2
SGG18
SG35
SG46
|
Solution in water of non-flammable gas with a pungent odour. Reacts violently with acids. Extremely dangerous to the eyes. |
2073 |
|
|
2074 |
ACRYLAMIDE, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
SW1
H2
|
– |
Crystals or powder. Soluble in water. May polymerise violently on melting. Toxic if swallowed, by skin contact or by inhalation. |
2074 |
|
|
2075 |
CHLORAL, ANHYDROUS, STABILIZED |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryD
SW2
|
– |
Colourless, mobile liquid, evolving toxic vapours which are considerably heavier than air. Toxic if swallowed, by skin contact or by inhalation. |
2075 |
|
|
2076 |
CRESOLS, LIQUID |
6.1
|
8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryB
|
– |
Colourless to light yellow liquids. Miscible with water. Melting point of meta-CRESOL: 12°C. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
2076 |
|
|
2077 |
alpha-NAPHTHYLAMINE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White crystals. Toxic if swallowed, by skin contact or by inhalation. |
2077 |
|
|
2078 |
TOLUENE DIISOCYANATE |
6.1
|
– |
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-A
|
CategoryC
SW1
SW2
|
– |
Colourless to pale yellow liquid with a pungent odour. Immiscible with water but reacts with it to form carbon dioxide. Melting point: 20°C (pure product). Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2078 |
|
|
2079 |
DIETHYLENETRIAMINE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
SW2
|
SGG18
SG35
|
Yellow hygroscopic liquid with ammoniacal odour. Soluble in water. Strongly alkaline, corrosive. Can form explosive mixtures with nitric acid. Reacts with oxidizing substances. Corrosive to copper and its alloys. Reacts violently with acids. Liquid and vapour can cause severe damage to skin and eyes. |
2079 |
|
|
2186 |
HYDROGEN CHLORIDE, REFRIGERATED LIQUID |
2.3
|
8
|
– |
900
|
– |
– |
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
– |
Transport is prohibited. |
2186 |
|
|
2187 |
CARBON DIOXIDE, REFRIGERATED LIQUID |
2.2
|
– |
– |
– |
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
CategoryD
|
– |
Non-flammable, liquefied gas, colourless and odourless. Heavier than air (1.5). Cannot remain in the liquid state above 31°C. |
2187 |
|
|
2188 |
ARSINE |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
Flammable, toxic, colourless gas with a garlic odour. Explosive limits: 3.9% to 77.8%. Much heavier than air (2.8). |
2188 |
|
|
2189 |
DICHLOROSILANE |
2.3
|
2.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
SG4
SG9
SG72
|
Flammable, toxic and corrosive gas. Reacts with water, evolving hydrogen chloride. Highly irritating to skin, eyes and mucous membranes. |
2189 |
|
|
2190 |
OXYGEN DIFLUORIDE, COMPRESSED |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
CategoryD
SW2
H1
|
SG6
SG19
|
Non-flammable, toxic and corrosive, colourless gas with a foul odour. Strong oxidizing agent. Reacts slowly with water or moist air to produce poisonous and corrosive fumes. Corrosive to glass and to most metals. Heavier than air (1.9). Highly irritating to skin, eyes and mucous membranes. |
2190 |
|
|
2191 |
SULPHURYL FLUORIDE |
2.3
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic, colourless, odourless gas. Reacts with water or moist air to produce toxic and corrosive fumes. Much heavier than air (3.5). Irritating to skin, eyes and mucous membranes. |
2191 |
|
|
2192 |
GERMANE |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
Flammable, toxic, colourless gas with a pungent odour. Much heavier than air (2.6). |
2192 |
|
|
2193 |
HEXAFLUOROETHANE (REFRIGERANT GAS R 116) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Non-flammable, colourless and odourless gas. Much heavier than air (4.8). Cannot remain in liquid state above 24.3°C. |
2193 |
|
|
2194 |
SELENIUM HEXAFLUORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Colourless, toxic and corrosive gas. Corrosive to glass and to most metals. Heavier than air. Highly irritating to skin, eyes and mucous membranes. |
2194 |
|
|
2195 |
TELLURIUM HEXAFLUORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic and corrosive colourless gas with an unpleasant odour. Decomposes in water, evolving highly toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (7.2). Highly irritating to skin, eyes and mucous membranes. |
2195 |
|
|
2196 |
TUNGSTEN HEXAFLUORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic and corrosive, colourless gas, or yellow liquid. Decomposes in water or moist air, evolving highly toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (10.3). Boiling point: 19.5°C. Highly irritating to skin, eyes and mucous membranes. |
2196 |
|
|
2197 |
HYDROGEN IODIDE, ANHYDROUS |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic and corrosive colourless gas with a pungent odour. Highly corrosive in the presence of water. Much heavier than air (4.4). Highly irritating to skin, eyes and mucous membranes. |
2197 |
|
|
2198 |
PHOSPHORUS PENTAFLUORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic and corrosive gas with an irritating odour. Reacts with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (4.3). Highly irritating to skin, eyes and mucous membranes. |
2198 |
|
|
2199 |
PHOSPHINE |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
Flammable, toxic, colourless gas with a garlic odour. Ignites spontaneously in air. Heavier than air (1.2). Irritating to skin, eyes and mucous membranes. |
2199 |
|
|
2200 |
PROPADIENE, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryB
SW1
SW2
|
– |
Liquefied, flammable, colourless gas. Explosive limits: 1.7% to 12%. Heavier than air (1.4). Boiling point: −34°C. Irritating to skin, eyes and mucous membranes. |
2200 |
|
|
2201 |
NITROUS OXIDE, REFRIGERATED LIQUID |
2.2
|
5.1
|
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5 TP22
|
F-C, S-W
|
CategoryD
SW2
|
– |
Liquefied, non-flammable, colourless gas with a slightly sweet odour. Strong oxidizing agent. Heavier than air (1.5). Cannot remain in liquid state above 36.5°C. |
2201 |
|
|
2202 |
HYDROGEN SELENIDE, ANHYDROUS |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
Flammable, toxic, colourless gas with a disagreeable odour. Much heavier than air (2.8). Highly irritating to skin, eyes and mucous membranes. |
2202 |
|
|
2203 |
SILANE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
SG43
SG46
|
Flammable, colourless gas with a foul odour. Explosive limits: 1% to 100%. Ignites spontaneously in air. Strong reducing agent which reacts violently with oxidizing substances. Heavier than air (1.1). |
2203 |
|
|
2204 |
CARBONYL SULPHIDE |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
Flammable, toxic, colourless gas with a foul odour. Much heavier than air (2.1). |
2204 |
|
|
2205 |
ADIPONITRILE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T3
|
TP1
|
F-A, S-A
|
CategoryA
|
SGG6
|
Colourless, odourless oil. Decomposes above 93°C, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. |
2205 |
|
|
2206 |
ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
CategoryE
SW1
SW2
|
– |
Liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. If under deck, with mechanical ventilation, six air changes per hour, except when carried in closed containers, when two air changes per hour are required. Irritating to skin, eyes and mucous membranes. |
2206 |
|
|
2206 |
ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP13 TP28
|
F-A, S-A
|
CategoryE
SW1
SW2
|
– |
Liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. If under deck, with mechanical ventilation, six air changes per hour, except when carried in closed containers, when two air changes per hour are required. Irritating to skin, eyes and mucous membranes. |
2206 |
|
|
2208 |
CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine |
5.1
|
–
P
|
III |
314
|
5 kg |
E1 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
CategoryD
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White or yellowish solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. |
2208 |
|
|
2209 |
FORMALDEHYDE SOLUTION with not less than 25% formaldehyde |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
– |
Colourless, clear liquid, with a suffocating pungent odour. Usually stabilized with methyl alcohol. Miscible with water. Causes burns to skin, eyes and mucous membranes. |
2209 |
|
|
2210 |
MANEB or MANEB PREPARATION with not less than 60% maneb |
4.2
|
4.3
P
|
III |
273
|
0 |
E1 |
P002
|
PP100 |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-G, S-L
|
CategoryA
H1
|
SG26
SG29
|
Yellow powder, liable to heat and to ignite spontaneously in air. May evolve toxic, irritating or flammable fumes when wet, when involved in a fire or in contact with acids. Used as fungicide. |
2210 |
|
|
2211 |
POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour |
9
|
– |
III |
382
965
|
5 kg |
E1 |
P002
|
PP14 |
IBC08
|
B3 B6 |
|
– |
T1
|
TP33
|
F-A, S-I
|
CategoryE
SW1
SW6
|
SG5
SG14
|
A moulding material in bead or granular form consisting predominantly of polystyrene, poly(methyl methacrylate) or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predominantly pentane. During storage, a small proportion of this pentane is released to the atmosphere; this proportion increases at elevated temperatures. |
2211 |
|
|
2212 |
ASBESTOS, AMPHIBOLE (amosite, tremolite, actinolite, anthophyllite, crocidolite) |
9
|
– |
II |
168
274
|
1 kg |
E0 |
P002
|
PP37 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
SW2
H4
|
SG29
|
Mineral fibres of varying length. Non-combustible. Inhalation of the dust of asbestos fibres is dangerous and therefore exposure should be avoided at all times. Always prevent the generation of asbestos dust. A safe level of airborne concentration of asbestos fibres may be obtained through effective packing. Cargo spaces or freight containers that have contained any type of raw asbestos should be carefully cleaned before discharging any remaining cargo, loading other cargo or carrying out repair or maintenance work. Whenever possible, cleaning of cargo spaces should be carried out whilst the ship is in a port where proper facilities and equipment, including proper respiratory apparatus and protective clothing, is available. Parts of the body that may have been exposed should be immediately and thoroughly washed. All waste material should be collected in impermeable and sealed bags for safe disposal ashore. If cleaning cannot be carried out at the discharge port, arrangements should be made in advance for cleaning to be carried out at the next port where necessary facilities are available. |
2212 |
|
|
2213 |
PARAFORMALDEHYDE |
4.1
|
– |
III |
223
967
|
5 kg |
E1 |
P002
LP02
|
PP12 |
IBC08
|
B3
|
|
– |
T1
BK2
BK3
|
TP33
|
F-A, S-G
|
CategoryA
SW23
|
– |
White powder with a pungent odour. Evolves formaldehyde, particularly when heated, which is irritating to eyes and mucous membranes. |
2213 |
|
|
2214 |
PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride |
8
|
– |
III |
169
939
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
White powder or flakes and lumps containing a high proportion of dust. Melting point: 131°C. The vapour of the molten substance has a flashpoint of 152°C c.c. and forms a flammable atmosphere with explosive limits of 1.7% to 10.4%. Causes burns to skin, eyes and mucous membranes. May be carried in the molten state. The molten substance can cause severe skin burns. |
2214 |
|
|
2215 |
MALEIC ANHYDRIDE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
SG50
SG57
|
White powder, needles, flakes, pellets, rods, briquettes, lumps or fused mass. Melting point: about 53°C. Fumes and dust are irritating to skin, eyes and mucous membranes. Inhalation can cause respiratory trouble. |
2215 |
|
|
2215 |
MALEIC ANHYDRIDE, MOLTEN |
8
|
– |
III |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T4
|
TP3
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
SG50
SG57
|
Melting point: about 53°C. The vapour of the molten substance has a flashpoint of 103°C c.c. and forms a flammable atmosphere with explosive limits of 1.4% to 7.1%. Fumes are irritating to skin, eyes and mucous membranes. |
2215 |
|
|
2216 |
FISH MEAL (FISH SCRAP), STABILIZED Anti-oxidant treated. Moisture content greater than 5% but not exceeding 12%, by mass. Fat content not more than 15% |
9
|
– |
III |
29
117
300
308
907
928
973
|
0 |
E1 |
P900
|
– |
IBC08
|
B3 |
|
– |
T1
BK2
|
TP33
|
F-A, S-J
|
CategoryB
SW24
|
SG18
SG65
|
Brown to greenish-brown product obtained through heating and drying of oily fish. Strong odour which may affect other cargo. Liable to heat spontaneously unless of low fat content or effectively anti-oxidant treated. |
2216 |
|
|
2217 |
SEED CAKE with not more than 1.5% oil and not more than 11% moisture |
4.2
|
– |
III |
29
142
973
|
0 |
E0 |
P002
LP02
|
PP20 |
IBC08
|
B3 B6 |
|
– |
BK2
|
– |
F-A, S-J
|
CategoryA
SW1
SW4
H1
|
– |
Residue remaining after oil has been extracted by a solvent process from oil-bearing seeds. Used mainly as an animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal, etc. May self-heat slowly if wet and ignite spontaneously. Before shipment, this cargo should be properly aged. The duration of ageing varies with the oil content. The seed cake should be substantially free from flammable solvent. Smoking and the use of naked lights should not be allowed during loading and unloading, and on entry to cargo spaces at any other time. |
2217 |
|
|
2218 |
ACRYLIC ACID, STABILIZED |
8
|
3
P
|
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryC
SW1
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquid with an acrid odour. Melting point: 13°C. Flashpoint: 54°C o.c. Miscible with water. May polymerize violently, which may cause fire and explosion, unless properly stabilized. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. |
2218 |
|
|
2219 |
ALLYL GLYCIDYL ETHER |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 48°C c.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2219 |
|
|
2222 |
ANISOLE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless to yellow liquid. Flashpoint: 41°C c.c. Explosive limits: 0.3% to 6.3%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2222 |
|
|
2224 |
BENZONITRILE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW2
|
SG35
|
Colourless liquid with an odour similar to oil of bitter almonds. Reacts with acids, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. |
2224 |
|
|
2225 |
BENZENESULPHONYL CHLORIDE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
|
Colourless to slightly yellow liquid with a pungent odour. Melting point: 12°C. Immiscible with water. Decomposes slowly in water. Harmful if swallowed or by skin contact. Highly irritating to skin, eyes and mucous membranes. |
2225 |
|
|
2226 |
BENZOTRICHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
Colourless to slightly yellow or brown fuming liquid. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Harmful if swallowed, by skin contact or by inhalation. Burns skin and eyes. Vapour irritates eyes and mucous membranes. |
2226 |
|
|
2227 |
n-BUTYL METHACRYLATE, STABILIZED |
3
|
– |
III |
386
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless liquid. Flashpoint: 41°C c.c. Explosive limits: 2% to 8%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2227 |
|
|
2232 |
2-CHLOROETHANAL |
6.1
|
– |
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW2
|
– |
Clear colourless liquid with a pungent odour. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
2232 |
|
|
2233 |
CHLOROANISIDINES |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Crystalline solid. Melting point: 52°C. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2233 |
|
|
2234 |
CHLOROBENZOTRIFLUORIDES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
SW2
|
SGG10
|
Colourless liquids with an aromatic odour. Flashpoint: 36°C to 59°C c.c. On contact with moisture, can evolve hydrogen fluoride, which is a toxic and corrosive gas. Harmful by inhalation. |
2234 |
|
|
2235 |
CHLOROBENZYL CHLORIDES, LIQUID |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2235 |
|
|
2236 |
3-CHLORO−4-METHYLPHENYL ISOCYANATE, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
CategoryB
SW2
|
– |
Colourless liquid with a pungent odour. Immiscible with water. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2236 |
|
|
2237 |
CHLORONITROANILINES |
6.1
|
–
P
|
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Yellow or orange crystalline powders or needles. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2237 |
|
|
2238 |
CHLOROTOLUENES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
SGG10
|
Colourless to brown liquids. Flashpoint: 43°C to 47°C c.c. Immiscible with water. When involved in a fire, evolve toxic gases. Harmful by skin contact or by inhalation. Irritating to eyes and mucous membranes. |
2238 |
|
|
2239 |
CHLOROTOLUIDINES, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Crystalline solids. Some isomers may melt at low temperature: melting range between 0°C and 24°C. Toxic if swallowed, by skin contact or by inhalation. |
2239 |
|
|
2240 |
CHROMOSULPHURIC ACID |
8
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
CategoryB
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
A liquid mixture of sulphuric acid and a chromium compound (e.g. chromium trioxide or sodium dichromate) and sometimes also water. Highly corrosive to most metals. Causes severe burns to skin, eyes and mucous membranes. |
2240 |
|
|
2241 |
CYCLOHEPTANE |
3
|
–
P
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-D
|
CategoryB
SW2
|
– |
Oily liquid. Immiscible with water. Narcotic. |
2241 |
|
|
2242 |
CYCLOHEPTENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Oily liquid. Immiscible with water. |
2242 |
|
|
2243 |
CYCLOHEXYL ACETATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 56°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2243 |
|
|
2244 |
CYCLOPENTANOL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless, oily liquid. Flashpoint: 51°C c.c. Immiscible with water. |
2244 |
|
|
2245 |
CYCLOPENTANONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 31°C c.c. Immiscible with water. |
2245 |
|
|
2246 |
CYCLOPENTENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP2
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquid. Flashpoint: −30°C c.c. Boiling point: 44°C. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic. |
2246 |
|
|
2247 |
n-DECANE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 47°C c.c. Explosive limits: 0.6% to 5.5%. Immiscible with water. |
2247 |
|
|
2248 |
DI-n-BUTYLAMINE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
|
SG35
|
Colourless, flammable liquid with an amine odour. Flashpoint: 39°C c.c. Partially miscible with water. Decomposes when heated, evolving flammable and toxic gases. Liquid is corrosive to skin, eyes and mucous membranes. Vapour irritates mucous membranes. |
2248 |
|
|
2249 |
DICHLORODIMETHYL ETHER, SYMMETRICAL |
6.1
|
3
|
I |
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
CategoryD
SW2
|
– |
Colourless, volatile, flammable liquid. Flashpoint: 42°C c.c. Immiscible with water. Decomposed by heat and water. Highly toxic if swallowed, by skin contact or by inhalation. The transport of this substance is prohibited except with special authorization granted by the competent authorities. |
2249 |
|
|
2250 |
DICHLOROPHENYL ISOCYANATES |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryB
SW1
SW2
|
– |
Colourless to yellowish crystalline solid with an irritating odour. Insoluble in water. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. May be carried in the molten state. Irritating to skin, eyes and mucous membranes. |
2250 |
|
|
2251 |
BICYCLO[2.2.1]-HEPTA−2,5-DIENE, STABILIZED (2,5-NORBORNADIENE, STABILIZED) |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
CategoryD
SW1
|
– |
Colourless, volatile liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 6.3%. Immiscible with water. |
2251 |
|
|
2252 |
1,2-DIMETHOXYETHANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid with an ethereal odour. Flashpoint: 1°C c.c. Miscible with water. |
2252 |
|
|
2253 |
N,N-DIMETHYLANILINE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Yellowish to brownish oily liquid. Combustible. Toxic if swallowed, by skin contact or by inhalation. |
2253 |
|
|
2254 |
MATCHES, FUSEE |
4.1
|
– |
III |
293
|
5 kg |
E0 |
P407
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
CategoryA
|
– |
Matches, the heads of which are prepared with a friction-sensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat, regardless of wind or other weather conditions. |
2254 |
|
|
2256 |
CYCLOHEXENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquid with an aromatic odour. Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. |
2256 |
|
|
2257 |
POTASSIUM |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
IBC04
|
B1 |
|
– |
T9
|
TP7 TP33
|
F-G, S-N
|
CategoryD
H1
|
SG26
SG35
|
Soft, silvery metal, solid or liquid. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
2257 |
|
|
2258 |
1,2-PROPYLENEDIAMINE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
SW2
|
SG35
|
Colourless, flammable liquid with an ammoniacal odour. Flashpoint range: 33°C to 48°C c.c. Miscible with water. When involved in a fire, evolves toxic gases. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2258 |
|
|
2259 |
TRIETHYLENETETRAMINE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryB
SW2
|
SGG18
SG35
|
Moderately viscous, yellow combustible liquid with an ammoniacal odour. Miscible with water. Strongly alkaline. Can form explosive mixtures with nitric acid. When involved in a fire, evolves toxic gases. Corrosive to copper and copper alloys. Reacts violently with acids. Liquid and vapours cause burns to skin, eyes and mucous membranes. Causes skin allergy. |
2259 |
|
|
2260 |
TRIPROPYLAMINE |
3
|
8
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
CategoryA
SW2
|
SG35
|
Colourless liquid. Flashpoint: 35°C c.c. Partially miscible with water. When involved in a fire, evolves toxic gases. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2260 |
|
|
2261 |
XYLENOLS, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Crystals or needles. Toxic if swallowed, by skin contact or by inhalation. |
2261 |
|
|
2262 |
DIMETHYLCARBAMOYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
Colourless to yellow liquid with a pungent odour. Immiscible with water. Reacts with water, evolving toxic and corrosive fumes. Causes tears. Causes burns to skin, eyes and mucous membranes. |
2262 |
|
|
2263 |
DIMETHYLCYCLOHEXANES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquids. Flashpoint: 5°C to 16°C c.c. Immiscible with water. |
2263 |
|
|
2264 |
N,N-DIMETHYL-CYCLOHEXYLAMINE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
SW2
|
SG35
|
Colourless, flammable liquid. Flashpoint: 43°C c.c. Partially miscible with water. Causes burns to skin, eyes and mucous membranes. |
2264 |
|
|
2265 |
N,N-DIMETHYLFORMAMIDE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 58°C c.c. Explosive limits: 2.2% to 16%. Miscible with water. May react violently with oxidizing materials. |
2265 |
|
|
2266 |
DIMETHYL-N-PROPYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-C
|
CategoryB
SW2
|
SG35
|
Colourless liquid with a fishy odour. Flashpoint: −11°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. |
2266 |
|
|
2267 |
DIMETHYL THIOPHOSPHORYL CHLORIDE |
6.1
|
8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryB
SW1
|
SGG1
SG36
SG49
|
Colourless, combustible liquid with a pungent odour. Reacts slowly with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. May decompose above 60°C, evolving flammable gases. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2267 |
|
|
2269 |
3,3’-IMINODIPROPYLAMINE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
- |
|
– |
T4
|
TP2
|
F-A, S-B
|
CategoryA
|
SG35
|
Colourless combustible liquid. Miscible with water. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. |
2269 |
|
|
2270 |
ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamine |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
SW2
|
SGG18
SG35
|
Aqueous solution of a flammable gas with an ammonia-like odour. Explosive limits: 3.5% to 14%. ETHYLAMINE SOLUTION, concentration 50%: flashpoint −11°C c.c.; boiling point 56°C. Pure ETHYLAMINE: boiling point 17°C. Miscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
2270 |
|
|
2271 |
ETHYL AMYL KETONES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids. Vapour is much heavier than air (4.4). ETHYL normal-AMYL KETONE: flashpoint 43°C c.c. ETHYL secondary-AMYL KETONE: flashpoint 57°C c.c. Immiscible with water. Dissolves some types of plastics. Irritating to skin, eyes and mucous membranes. |
2271 |
|
|
2272 |
N-ETHYLANILINE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SG17
SG35
|
Colourless to yellowish oily liquid. Reacts with acids, evolving highly toxic fumes of aniline and oxides of nitrogen. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2272 |
|
|
2273 |
2-ETHYLANILINE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SG17
SG35
|
Brown liquid. Immiscible with water. Reacts with acids, evolving highly toxic fumes of aniline and oxides of nitrogen. Reacts violently with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2273 |
|
|
2274 |
N-ETHYL-N-BENZYLANILINE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Light yellow, oily liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2274 |
|
|
2275 |
2-ETHYLBUTANOL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 57°C o.c. Immiscible with water. |
2275 |
|
|
2276 |
2-ETHYLHEXYLAMINE |
3
|
8
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
CategoryA
SW2
|
SG35
|
Colourless liquid. Flashpoint: 50°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. |
2276 |
|
|
2277 |
ETHYL METHACRYLATE, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless liquid with a pungent odour. Flashpoint: 20°C o.c. Lower explosive limit: 1.8%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2277 |
|
|
2278 |
n-HEPTENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: −3°C c.c. Immiscible with water. |
2278 |
|
|
2279 |
HEXACHLOROBUTADIENE |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SGG10
|
Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2279 |
|
|
2280 |
HEXAMETHYLENEDIAMINE, MOLTEN |
8
|
– |
III |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
SW1
H2
|
SG35
|
White crystals or shiny flakes with a specific odour. Melting point: 29°C. Soluble in water; solution in water is a strong alkali. Decomposes when heated, evolving flammable and toxic gases. Causes burns to skin, eyes and mucous membranes. |
2280 |
|
|
2280 |
HEXAMETHYLENEDIAMINE, SOLID |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
SW1
H2
|
SG35
|
See entry above. |
2280 |
|
|
2281 |
HEXAMETHYLENE DIISOCYANATE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-A
|
CategoryC
SW2
H1
|
– |
Colourless to light yellow liquid with a pungent odour. Immiscible with water but reacts with it, evolving heat and carbon dioxide gas. When heated, evolves toxic nitrous fumes. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2281 |
|
|
2282 |
HEXANOLS |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids. normal-HEXANOL: flashpoint 57°C c.c. Miscible with water. |
2282 |
|
|
2283 |
ISOBUTYL METHACRYLATE, STABILIZED |
3
|
– |
III |
386
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2283 |
|
|
2284 |
ISOBUTYRONITRILE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid. Flashpoint: 8°C c.c. Immiscible with water. Toxic by skin contact or by inhalation. |
2284 |
|
|
2285 |
ISOCYANATOBENZO-TRIFLUORIDES |
6.1
|
3
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
CategoryD
SW1
SW2
|
– |
Colourless or yellowish liquids with a pungent odour. Flashpoint of ortho- and meta-isomers: 56°C. Immiscible with water, but reacts with it to form carbon dioxide gas. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2285 |
|
|
2286 |
PENTAMETHYLHEPTANE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 43°C c.c. Immiscible with water. |
2286 |
|
|
2287 |
ISOHEPTENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquids. Immiscible with water. |
2287 |
|
|
2288 |
ISOHEXENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T11
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquids. Boiling range: 54°C to 69°C. Immiscible with water. |
2288 |
|
|
2289 |
ISOPHORONEDIAMINE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SG35
|
Colourless, slightly hygroscopic liquid with a slight amine odour. Combustible. Miscible with water. Harmful if swallowed. Irritating to skin, eyes and mucous membranes. |
2289 |
|
|
2290 |
ISOPHORONE DIISOCYANATE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2
|
F-A, S-A
|
CategoryB
SW2
|
– |
Colourless or yellowish liquid. Immiscible with water. When involved in a fire, evolves nitrous fumes. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2290 |
|
|
2291 |
LEAD COMPOUND, SOLUBLE, N.O.S. |
6.1
|
–
P
|
III |
199 274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG7
SGG9
|
Colourless crystals or powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2291 |
|
|
2293 |
4-METHOXY−4-METHYL-PENTAN−2-ONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. |
2293 |
|
|
2294 |
N-METHYLANILINE |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Colourless to brown combustible liquid. Toxic if swallowed, by skin contact or by inhalation. |
2294 |
|
|
2295 |
METHYL CHLOROACETATE |
6.1
|
3
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
CategoryD
|
– |
Colourless, flammable liquid with a pungent odour. Flashpoint: 47°C c.c. Vapour much heavier than air (vapour density relative to air: 3.8). Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
2295 |
|
|
2296 |
METHYLCYCLOHEXANE |
3
|
–
P
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP2
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: −4°C c.c. Explosive limits: 1.2% to 6.7%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2296 |
|
|
2297 |
METHYLCYCLOHEXANONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless to pale yellow liquids with a sweet odour. 2-METHYLCYCLOHEXANONE: flashpoint 46°C c.c. 3-METHYLCYCLOHEXANONE: flashpoint 51°C c.c. 4-METHYLCYCLOHEXANONE: flashpoint 40°C c.c. Immiscible with water. |
2297 |
|
|
2298 |
METHYLCYCLOPENTANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: below −10°C c.c. Explosive limits: 1% to 8.4%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2298 |
|
|
2299 |
METHYL DICHLOROACETATE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Liquid. Toxic if swallowed, by skin contact or by inhalation. |
2299 |
|
|
2300 |
2-METHYL−5-ETHYLPYRIDINE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless liquid with a pungent odour. Toxic if swallowed, by skin contact or by inhalation. |
2300 |
|
|
2301 |
2-METHYLFURAN |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquid with a sweetish odour. Flashpoint: −30°C c.c. Immiscible with water. When involved in a fire, evolves toxic gases. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. |
2301 |
|
|
2302 |
5-METHYLHEXAN−2-ONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 43°C c.c. Immiscible with water. |
2302 |
|
| △ |
2303 |
ISOPROPENYLBENZENE |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
SW1
|
– |
Colourless liquid. Flashpoint: 38°C to 54°C c.c. Explosive limits: 0.7% to 6.6%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2303 |
△ |
|
2304 |
NAPHTHALENE, MOLTEN |
4.1
|
–
P
|
III |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T1
|
TP3
|
F-A, S-H
|
CategoryC
|
– |
Molten liquid with a persistent odour. Melting point: 80°C. Evolves flammable vapours. As the melting point of naphthalene approximates very closely its flashpoint, care should be taken to avoid all possible causes of ignition. Contact between water and molten naphthalene above 110°C must be avoided, as the addition of water will cause violent foaming or even an explosion. |
2304 |
|
|
2305 |
NITROBENZENESULPHONIC ACID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Crystals. Soluble in water. Causes burns to skin, eyes and mucous membranes. |
2305 |
|
|
2306 |
NITROBENZOTRIFLUORIDES, LIQUID |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW2
|
– |
Pale straw-coloured, oily liquids with an aromatic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2306 |
|
|
2307 |
3-NITRO−4-CHLORO-BENZOTRIFLUORIDE |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW2
|
– |
Yellowish, oily liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2307 |
|
|
2308 |
NITROSYLSULPHURIC ACID, LIQUID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Clear, straw-coloured, oily liquid. Oxidant which may cause fire with organic materials (such as wood, straw, etc.). When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2308 |
|
|
2309 |
OCTADIENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 9°C to 15°C c.c. Immiscible with water. |
2309 |
|
|
2310 |
PENTANE−2,4-DIONE |
3
|
6.1
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 34°C c.c. Lower explosive limit: 1.7%. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2310 |
|
|
2311 |
PHENETIDINES |
6.1
|
– |
III |
279
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless to yellowish liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2311 |
|
|
2312 |
PHENOL, MOLTEN |
6.1
|
– |
II |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T7
|
TP3
|
F-A, S-A
|
CategoryB
SW2
|
– |
Molten liquid with a distinctive strong odour. Melting point: 10°C to 43°C (pure product). Toxic if swallowed, by skin contact or by inhalation. Rapidly absorbed through the skin. |
2312 |
|
|
2313 |
PICOLINES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryA
SW2
|
– |
Colourless to yellow liquids with a pungent or sweet odour. Explosive limits: 1.3% to 8.7%. Miscible with water. Harmful by inhalation. alpha-Picoline flashpoint: 28°C c.c. beta-Picoline flashpoint: 40°C c.c. gamma-Picoline flashpoint 40°C c.c. Irritating to skin, eyes and mucous membranes. |
2313 |
|
|
2315 |
POLYCHLORINATED BIPHENYLS, LIQUID |
9
|
–
P
|
II |
305
|
1 L |
E2 |
P906
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SG50
|
Colourless liquid (pure product) with perceptible odours. Immiscible with water. Harmful by ingestion or by skin contact. If spilled, can be a persistent hazard to the environment. This entry also covers articles, such as transformers and condensers, containing free liquid polychlorinated biphenyls. |
2315 |
|
|
2316 |
SODIUM CUPROCYANIDE, SOLID |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG6
SG35
|
White powder. Soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by dust inhalation. |
2316 |
|
|
2317 |
SODIUM CUPROCYANIDE SOLUTION |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
CategoryB
SW2
|
SGG6
SG35
|
Colourless liquid. Miscible with water. Decomposed by acids, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed, by skin contact or by inhalation. |
2317 |
|
|
2318 |
SODIUM HYDROSULPHIDE with less than 25% water of crystallization |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
CategoryA
|
SGG18
SG35
|
Colourless needles to lemon-coloured flakes. Soluble in water. Reacts violently with acids. |
2318 |
|
|
2319 |
TERPENE HYDROCARBONS, N.O.S. |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
CategoryA
|
– |
Colourless or yellowish liquids. Flashpoint: 32°C to 49°C c.c. Immiscible with water. |
2319 |
|
|
2320 |
TETRAETHYLENEPENTAMINE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Viscous liquid. Miscible with water. When involved in a fire, evolves toxic gases. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
2320 |
|
|
2321 |
TRICHLOROBENZENES, LIQUID |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SGG10
|
Colourless liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2321 |
|
|
2322 |
TRICHLOROBUTENE |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW1
SW2
|
SGG10
|
Colourless liquid. Immiscible with water. When heated, develops toxic and irritant gases such as phosgene and hydrogen chloride and may also explode. Toxic if swallowed, by skin contact or by inhalation. |
2322 |
|
|
2323 |
TRIETHYL PHOSPHITE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 44°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2323 |
|
|
2324 |
TRIISOBUTYLENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Immiscible with water. |
2324 |
|
|
2325 |
1,3,5-TRIMETHYLBENZENE |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 44°C c.c. Immiscible with water. Harmful by inhalation. |
2325 |
|
|
2326 |
TRIMETHYLCYCLOHEXYL- AMINE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SG35
|
Colourless, slightly hygroscopic, combustible liquid with a slight amine odour. Immiscible with water. Causes burns to skin, eyes and mucous membranes. |
2326 |
|
|
2327 |
TRIMETHYLHEXAMETHYLENE-DIAMINES |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SG35
|
Colourless, slightly hygroscopic, combustible liquids. Miscible with water. Irritating to skin, eyes and mucous membranes. |
2327 |
|
|
2328 |
TRIMETHYLHEXAMETHYLENE DIISOCYANATE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2 TP13
|
F-A, S-A
|
CategoryB
|
– |
Colourless or yellowish liquid. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2328 |
|
|
2329 |
TRIMETHYL PHOSPHITE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 23°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2329 |
|
|
2330 |
UNDECANE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 60°C c.c. Immiscible with water. |
2330 |
|
|
2331 |
ZINC CHLORIDE, ANHYDROUS |
8
|
–
P
|
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SGG7
SG36
SG49
|
White, deliquescent crystals. Soluble in water. Dust causes burns to skin, eyes and mucous membranes. |
2331 |
|
|
2332 |
ACETALDEHYDE OXIME |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 40°C c.c. Explosive limits: 4.2% to 52%. Freezing point 12°C. Miscible with water. Irritating to skin, eyes and mucous membranes. |
2332 |
|
|
2333 |
ALLYL ACETATE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid. Flashpoint: 7°C c.c. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Harmful if swallowed. |
2333 |
|
|
2334 |
ALLYLAMINE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
SG35
|
Colourless to light yellow volatile liquid with a pungent odour. Flashpoint: −29°C c.c. Explosive limits: 2.2% to 22%. Boiling range: 55°C to 58°C. Miscible with water. When involved in a fire, evolves highly toxic gases. Highly toxic if swallowed, by skin contact or by inhalation. |
2334 |
|
|
2335 |
ALLYL ETHYL ETHER |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid. Flashpoint: −11°C c.c. Vapour heavier than air. Immiscible with water. Narcotic. Toxic if swallowed, by skin contact or by inhalation. |
2335 |
|
|
2336 |
ALLYL FORMATE |
3
|
6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
2336 |
|
|
2337 |
PHENYL MERCAPTAN |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
SG35
|
Colourless flammable liquid with a foul odour. Flashpoint: 50°C c.c. Immiscible with water. In contact with acids or when involved in a fire, evolves highly toxic sulphurous fumes. Highly toxic if swallowed, by skin contact or by inhalation. |
2337 |
|
|
2338 |
BENZOTRIFLUORIDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
SW2
|
– |
Colourless liquid with an aromatic odour. Flashpoint: 12°C c.c. Lower explosive limit: 2.1%. Immiscible with water. On contact with moisture or air evolves hydrogen fluoride, which is a toxic and corrosive gas. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2338 |
|
|
2339 |
2-BROMOBUTANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
SW2
|
SGG10
|
Colourless liquid with a pleasant odour. Flashpoint: 21°C c.c. Immiscible with water. When involved in a fire, evolves toxic fumes. Narcotic. |
2339 |
|
|
2340 |
2-BROMOETHYL ETHYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
SW2
|
– |
Colourless liquid with an ethereal odour. Partially miscible with water. Harmful by inhalation. |
2340 |
|
|
2341 |
1-BROMO−3-METHYLBUTANE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
SGG10
|
Colourless liquid. Flashpoint: 23°C to 32°C c.c. Immiscible with water. |
2341 |
|
|
2342 |
BROMOMETHYLPROPANES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
SGG10
|
Colourless liquids. Immiscible with water. Harmful by inhalation. |
2342 |
|
|
2343 |
2-BROMOPENTANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
SGG10
|
Colourless or yellow liquid with a strong odour. Flashpoint: 21°C c.c. Immiscible with water. Harmful by inhalation. |
2343 |
|
|
2344 |
BROMOPROPANES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
SW2
|
SGG10
|
Colourless liquids. Immiscible with water. When involved in a fire, evolve toxic fumes. Harmful by inhalation. |
2344 |
|
|
2344 |
BROMOPROPANES |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
SGG10
|
See entry above. |
2344 |
|
|
2345 |
3-BROMOPROPYNE |
3
|
– |
II |
905 |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryD
SW2
|
– |
Colourless to light amber liquid with a sharp odour. Flashpoint: 10°C c.c. Lower explosive limit: 3%. Vapour much heavier than air (4.1). The pure product is shock-sensitive and decomposes with explosive violence, and the possibility of detonation, when heated under confinement. Can be ignited by impact. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Causes tears. |
2345 |
|
|
2346 |
BUTANEDIONE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Greenish-yellow liquid with a strong odour. Flashpoint: 6°C c.c. Miscible with water. |
2346 |
|
|
2347 |
BUTYL MERCAPTAN |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
SG35
SG50
SG57
|
Colourless liquids with a foul odour. tertiary-BUTYL MERCAPTAN: flashpoint −26°C c.c. secondary-BUTYL MERCAPTAN: flashpoint −23°C c.c. 1-BUTANETHIOL (normal-BUTYL MERCAPTAN): flashpoint 12°C c.c. ISOBUTYL MERCAPTAN: flashpoint −9°C c.c. Immiscible with water. On contact with acids, emit highly toxic fumes. |
2347 |
|
|
2348 |
BUTYL ACRYLATES, STABILIZED |
3
|
– |
III |
386
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless liquid with an unpleasant odour. Flashpoint: 36°C to 41°C c.c. Explosive limits: 1.2% to 9.9%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2348 |
|
|
2350 |
BUTYL METHYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Immiscible with water. |
2350 |
|
|
2351 |
BUTYL NITRITES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
SW2
|
– |
Yellowish, volatile, oily liquids. Partially miscible with water. Decompose on exposure to air, light, water or heat, evolving toxic nitrous fumes. Harmful by inhalation. |
2351 |
|
|
2351 |
BUTYL NITRITES |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
SW2
|
– |
See entry above. |
2351 |
|
|
2352 |
BUTYL VINYL ETHER, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryC
SW1
SW2
|
– |
Colourless, volatile liquid with a sharp ethereal odour. Flashpoint: −9°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2352 |
|
|
2353 |
BUTYRYL CHLORIDE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2 TP13
|
F-E, S-C
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2353 |
|
|
2354 |
CHLOROMETHYL ETHYL ETHER |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid with a pungent odour. Partially miscible with water. Fumes in air, evolving hydrogen chloride, which is an irritating and corrosive gas. Toxic by inhalation. Strong lachrymator. |
2354 |
|
|
2356 |
2-CHLOROPROPANE |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2 TP13
|
F-E, S-D
|
CategoryE
|
SGG10
|
Colourless liquid. Flashpoint: −32°C c.c. Explosive limits: 2.8% to 10.7%. Boiling point: 35°C. Immiscible with water. On contact with heat or flame, emits highly toxic phosgene gas. Can react vigorously with oxidizing materials. |
2356 |
|
|
2357 |
CYCLOHEXYLAMINE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
SW2
|
SG35
|
Colourless or yellowish flammable liquid with a fishy odour. Flashpoint: 27°C c.c. Explosive limits: 0.5% to 21.7%. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2357 |
|
|
2358 |
CYCLOOCTATETRAENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Freezing point: −4°C. Immiscible with water. |
2358 |
|
|
2359 |
DIALLYLAMINE |
3
|
6.1/8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC99
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
SW2
|
SG5
SG8
SG35
|
Colourless, volatile liquid with a disagreeable odour. Flashpoint: 7°C c.c. Partially miscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2359 |
|
|
2360 |
DIALLYL ETHER |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
|
– |
Colourless, volatile liquid with a perceptible odour. Flashpoint: −11°C c.c. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2360 |
|
|
2361 |
DIISOBUTYLAMINE |
3
|
8
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
CategoryA
|
SG35
|
Colourless liquid with a fishy odour. Flashpoint: 29°C c.c. Immiscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2361 |
|
|
2362 |
1,1-DICHLOROETHANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
SW2
|
SGG10
|
Colourless liquid with an aromatic, ethereal odour. Flashpoint: −10°C c.c. Lower explosive limit: 5.6%. Immiscible with water. When involved in a fire, emits toxic fumes of phosgene. Harmful by inhalation. |
2362 |
|
|
2363 |
ETHYL MERCAPTAN |
3
|
–
P
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2 TP13
|
F-E, S-D
|
CategoryE
|
SG50
SG57
|
Volatile liquid with a strong unpleasant odour. Flashpoint: −45°C c.c. Explosive limits: 2.8% to 18.2%. Boiling point: 35°C. Immiscible with water. |
2363 |
|
|
2364 |
n-PROPYLBENZENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 39°C c.c. Explosive limits: 0.8% to 6%. Immiscible with water. |
2364 |
|
|
2366 |
DIETHYL CARBONATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 25°C to 31°C c.c. Vapour much heavier than air (4.1). Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2366 |
|
|
2367 |
alpha-METHYL-VALERALDEHYDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 13°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2367 |
|
|
2368 |
alpha-PINENE |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-E
|
CategoryA
|
– |
Colourless liquid with an odour of turpentine. Flashpoint: 33°C c.c. Explosive limits: 0.8% to 6%. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2368 |
|
|
2370 |
1-HEXENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquid. Explosive limits: 1.2% to 6.9%. Immiscible with water. |
2370 |
|
|
2371 |
ISOPENTENES |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
CategoryE
|
– |
Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2371 |
|
|
2372 |
1,2-DI-(DIMETHYLAMINO)ETHANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 21°C c.c. Miscible with water. Irritability to skin, eyes and mucous membranes. |
2372 |
|
|
2373 |
DIETHOXYMETHANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: below −5°C c.c. Miscible with water. |
2373 |
|
|
2374 |
3,3-DIETHOXYPROPENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 15°C c.c. Partially miscible with water. Harmful by inhalation. |
2374 |
|
|
2375 |
DIETHYL SULPHIDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
|
– |
Colourless, volatile liquid with an odour of garlic. Flashpoint: −10°C c.c. Immiscible with water. |
2375 |
|
|
2376 |
2,3-DIHYDROPYRAN |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless, volatile liquid with an ethereal odour. Flashpoint: −16°C c.c. Miscible with water. |
2376 |
|
|
2377 |
1,1-DIMETHOXYETHANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid with a strong aromatic odour. Miscible with water. |
2377 |
|
|
2378 |
2-DIMETHYLAMINO-ACETONITRILE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
CategoryA
SW2
|
SG35
|
Colourless liquid. Flashpoint: 35°C c.c. Immiscible with water. On contact with water and acids, evolves toxic fumes. Toxic if swallowed, by skin contact or by inhalation. |
2378 |
|
|
2379 |
1,3-DIMETHYLBUTYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
|
SGG18
SG35
|
Colourless liquid with an ammonia-like odour. Flashpoint: 9°C to 13°C c.c. Immiscible with water. Reacts violently with acids. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2379 |
|
|
2380 |
DIMETHYLDIETHOXYSILANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 13°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. |
2380 |
|
|
2381 |
DIMETHYL DISULPHIDE |
3
|
6.1
P
|
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-D
|
CategoryB
SW2
|
– |
Yellow liquid with an unpleasant odour. Flashpoint: 15°C c.c. Immiscible with water. When involved in a fire, evolves toxic gases. Toxic if swallowed, by skin contact or by inhalation. |
2381 |
|
|
2382 |
DIMETHYLHYDRAZINE, SYMMETRICAL |
6.1
|
3
P
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
SGG18
SG17
SG35
|
Colourless, flammable, volatile liquid with an ammonia-like odour. Miscible with water. Reacts violently with acids. May react dangerously with oxidizing substances. Flashpoint: −17°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. |
2382 |
|
|
2383 |
DIPROPYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
SW1
|
SG35
|
Colourless liquid with a fishy odour. Flashpoint: 7°C c.c. Immiscible with water. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. |
2383 |
|
|
2384 |
DI-n-PROPYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint (pure product): −21°C c.c. Lower explosive limit: 1.7%. Immiscible with water. |
2384 |
|
|
2385 |
ETHYL ISOBUTYRATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless, volatile liquid with an aromatic odour. Flashpoint: 21°C c.c. Immiscible with water. |
2385 |
|
|
2386 |
1-ETHYLPIPERIDINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
|
SGG18
SG35
|
Colourless liquid. Flashpoint: 19°C c.c. Immiscible with water. Reacts violently with acids. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. May cause lung damage. |
2386 |
|
|
2387 |
FLUOROBENZENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
SGG10
|
Colourless liquid with a benzene odour. Flashpoint: −15°C c.c. Immiscible with water. Harmful by inhalation. |
2387 |
|
|
2388 |
FLUOROTOLUENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
SGG10
|
Colourless liquids. ortho-FLUOROTOLUENE: flashpoint 9°C c.c. meta-FLUOROTOLUENE: flashpoint 12°C c.c. para-FLUOROTOLUENE: flashpoint 10°C c.c. Immiscible with water. |
2388 |
|
|
2389 |
FURAN |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T12
|
TP2 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid with a strong odour. Flashpoint: below −18°C c.c. Explosive limits: 1.3% to 14.3%. Boiling point: 31°C. Immiscible with water. Harmful if swallowed, by skin contact or by inhalation. |
2389 |
|
|
2390 |
2-IODOBUTANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
SGG10
|
Colourless liquid. Flashpoint: 21°C c.c. Immiscible with water. |
2390 |
|
|
2391 |
IODOMETHYLPROPANES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
SGG10
|
Colourless liquids. Immiscible with water. |
2391 |
|
|
2392 |
IODOPROPANES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
SGG10
|
Colourless liquids. 1-IODOPROPANE: flashpoint 34°C c.c. 2-IODOPROPANE: flashpoint approx. 25°C c.c. Immiscible with water. |
2392 |
|
|
2393 |
ISOBUTYL FORMATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 5°C c.c. Explosive limits: 1.7% to 8%. Irritating to skin, eyes and mucous membranes. |
2393 |
|
|
2394 |
ISOBUTYL PROPIONATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 31°C c.c. Immiscible with water. |
2394 |
|
|
2395 |
ISOBUTYRYL CHLORIDE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2395 |
|
|
2396 |
METHACRYLALDEHYDE, STABILIZED |
3
|
6.1
|
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryD
SW1
SW2
|
– |
Colourless liquid. Flashpoint: 2°C c.c. Miscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. |
2396 |
|
|
2397 |
3-METHYLBUTAN−2-ONE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: −3°C c.c. Explosive limits: 1.5% to 8%. Immiscible with water. |
2397 |
|
|
2398 |
METHYL tert-BUTYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 8.4%. Boiling point: 55°C. Immiscible with water. |
2398 |
|
|
2399 |
1-METHYLPIPERIDINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
|
SGG18
SG35
|
Colourless liquid. Flashpoint: 3°C c.c. Miscible with water. Reacts violently with acids. Harmful by inhalation. Causes burns to skin, eyes and mucous membranes. |
2399 |
|
|
2400 |
METHYL ISOVALERATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Immiscible with water. |
2400 |
|
|
2401 |
PIPERIDINE |
8
|
3
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2
|
F-E, S-C
|
CategoryD
|
SGG18
SG35
|
Colourless liquid with a fish-like odour. Miscible with water. Reacts violently with acids. Solution in water is a strong alkali and is corrosive. When involved in fire, evolves toxic nitrous fumes. |
2401 |
|
|
2402 |
PROPANETHIOLS |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP13
|
F-E, S-D
|
CategoryE
|
SG50
SG57
|
Colourless or yellowish liquids with a strong unpleasant odour. Flashpoint: below −18°C c.c. Boiling range: 53°C to 67°C. Immiscible with water. |
2402 |
|
|
2403 |
ISOPROPENYL ACETATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 10°C c.c. Immiscible with water. |
2403 |
|
|
2404 |
PROPIONITRILE |
3
|
6.1
|
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless, volatile liquid with an ether-like odour. Flashpoint: 2°C c.c. Lower explosive limit: 3.1%. Miscible with water. When involved in a fire, evolves highly toxic cyanide fumes. Toxic if swallowed, by skin contact or by inhalation. |
2404 |
|
|
2405 |
ISOPROPYL BUTYRATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 25°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2405 |
|
|
2406 |
ISOPROPYL ISOBUTYRATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 20°C c.c. Immiscible with water. Narcotic. Irritating to skin, eyes and mucous membranes. |
2406 |
|
|
2407 |
ISOPROPYL CHLOROFORMATE |
6.1
|
3/8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
– |
– |
F-E, S-C
|
CategoryD
SW2
|
SGG1
SG5
SG8
SG36
SG49
|
Colourless flammable liquid. Flashpoint: 16°C c.c. Decomposed by water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2407 |
|
|
2409 |
ISOPROPYL PROPIONATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 21°C c.c. Immiscible with water. |
2409 |
|
|
2410 |
1,2,3,6-TETRAHYDROPYRIDINE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 16°C c.c. Miscible with water. Harmful by inhalation. |
2410 |
|
|
2411 |
BUTYRONITRILE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless liquid. Flashpoint: 21°C c.c. Lower explosive limit: 1.6%. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2411 |
|
|
2412 |
TETRAHYDROTHIOPHENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid with a pleasant odour. Flashpoint: 13°C c.c. Immiscible with water. |
2412 |
|
|
2413 |
TETRAPROPYL ORTHOTITANATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 38°C c.c. |
2413 |
|
|
2414 |
THIOPHENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
SW2
|
– |
Colourless liquid with an unpleasant odour. Flashpoint: −9°C c.c. Explosive limits: 1.5% to 12.5%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2414 |
|
|
2416 |
TRIMETHYL BORATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Reacts with water, evolving flammable vapours. |
2416 |
|
|
2417 |
CARBONYL FLUORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic and corrosive colourless gas with a pungent odour. Corrosive to glass and to most metals. Corrosive in the presence of water. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes. |
2417 |
|
|
2418 |
SULPHUR TETRAFLUORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
SG35
|
Non-flammable, toxic and corrosive, colourless gas with a pungent odour. Reacts with water, moist air or acids to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (3.7). Highly irritating to skin, eyes and mucous membranes. |
2418 |
|
|
2419 |
BROMOTRIFLUOROETHYLENE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryB
SW2
|
– |
Liquefied, flammable, colourless gas. Much heavier than air (5.6). Boiling point: −3°C. |
2419 |
|
|
2420 |
HEXAFLUOROACETONE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
CategoryD
SW2
|
– |
Non-flammable, toxic and corrosive, colourless, hygroscopic gas with an unpleasant odour. Reacts vigorously with water, evolving heat. Corrosive to glass and to most metals. Fumes in moist air. Much heavier than air (5.7). Highly irritating to skin, eyes and mucous membranes. |
2420 |
|
|
2421 |
NITROGEN TRIOXIDE |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
CategoryD
SW2
|
SG6
SG19
|
Liquefied, non-flammable, toxic and corrosive gas. At lower temperatures, present as a blue liquid. Strong oxidizing agent. Much heavier than air (2.6). Boiling point: 3.5°C. Highly irritating to skin, eyes and mucous membranes. |
2421 |
|
|
2422 |
OCTAFLUOROBUT−2-ENE (REFRIGERANT GAS R 1318) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable, colourless gas. Much heavier than air (6.9). Boiling point: 1.2°C. |
2422 |
|
|
2424 |
OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Liquefied, non-flammable, colourless gas. Much heavier than air (6.6). Boiling point: −36°C. |
2424 |
|
|
2426 |
AMMONIUM NITRATE, LIQUID (hot concentrated solution) |
5.1
|
– |
– |
252
942
|
0 |
E0 |
– |
– |
– |
– |
|
– |
T7
|
TP1 TP16 TP17
|
F-H, S-Q
|
CategoryD
|
SGG2
SG42
SG45
SG47
SG48
SG51
SG56
SG58
SG59
SG61
|
Hot aqueous solution of not more than 93% ammonium nitrate with not more than 0.2% combustible material (including organic material calculated as carbon) and free from any other added matter, containing at least 7% water, while the maximum content of chloride ions should not exceed 0.02%. May cause fire and explosion in contact with combustible material (e.g. wood, straw, cotton, oil, sugar, etc.), acids, and other class 5.1 substances and burn fiercely. Maximum allowable transport temperature of the solution 140°C. This temperature should be indicated on the transport unit. The acidity (pH) of the cargo when diluted with ten parts of water to one part of cargo, by mass, should be between 5.0 and 7.0. The concentration and temperature of the solution at the time of loading, its percentage of combustible materials and of chlorides, and the contents of free acid should be certified. |
2426 |
|
|
2427 |
POTASSIUM CHLORATE, AQUEOUS SOLUTION |
5.1
|
– |
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
CategoryB
|
SGG4
SG38
SG49
SG62
|
Colourless liquid. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
2427 |
|
|
2427 |
POTASSIUM CHLORATE, AQUEOUS SOLUTION |
5.1
|
– |
III |
223
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
CategoryB
|
SGG4
SG38
SG49
SG62
|
See entry above. |
2427 |
|
|
2428 |
SODIUM CHLORATE, AQUEOUS SOLUTION |
5.1
|
– |
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
CategoryB
|
SGG4
SG38
SG49
SG62
|
Colourless liquid. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
2428 |
|
|
2428 |
SODIUM CHLORATE, AQUEOUS SOLUTION |
5.1
|
– |
III |
223
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
CategoryB
|
SGG4
SG38
SG49
SG62
|
See entry above. |
2428 |
|
|
2429 |
CALCIUM CHLORATE, AQUEOUS SOLUTION |
5.1
|
– |
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
CategoryB
|
SGG4
SG38
SG49
SG62
|
Colourless liquid. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
2429 |
|
|
2429 |
CALCIUM CHLORATE, AQUEOUS SOLUTION |
5.1
|
– |
III |
223
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
CategoryB
|
SGG4
SG38
SG49
SG62
|
See entry above. |
2429 |
|
|
2430 |
ALKYLPHENOLS, SOLID, N.O.S. (including C2–C12 homologues) |
8
|
– |
I |
– |
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
CategoryB
|
– |
A wide range of colourless to pale straw-coloured solids with penetrating odours (sometimes camphor-like). Some have low melting points. Insoluble in water. Cause burns to skin, eyes and mucous membranes. |
2430 |
|
|
2430 |
ALKYLPHENOLS, SOLID, N.O.S. (including C2–C12 homologues) |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryB
|
– |
See entry above. |
2430 |
|
|
2430 |
ALKYLPHENOLS, SOLID, N.O.S. (including C2–C12 homologues) |
8
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
– |
See entry above. |
2430 |
|
|
2431 |
ANISIDINES |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Reddish or yellowish oily liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2431 |
|
|
2432 |
N,N-DIETHYLANILINE |
6.1
|
– |
III |
279
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless to yellow-brown oily liquid. Combustible. Toxic if swallowed, by skin contact or by inhalation. |
2432 |
|
|
2433 |
CHLORONITROTOLUENES, LIQUID |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SG6
SG8
SG10
SG12
|
Immiscible with water. Oxidizing substance which may explode or burn fiercely when in contact with organic materials. Toxic if swallowed, by skin contact or by inhalation. |
2433 |
|
|
2434 |
DIBENZYLDICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapour irritating to skin, eyes and mucous membranes. |
2434 |
|
|
2435 |
ETHYLPHENYL-DICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2435 |
|
|
2436 |
THIOACETIC ACID |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless or yellow liquid with a pungent odour. Miscible with water. Harmful by inhalation. |
2436 |
|
|
2437 |
METHYLPHENYL-DICHLOROSILANE |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2437 |
|
|
2438 |
TRIMETHYLACETYL CHLORIDE |
6.1
|
3/8
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-C
|
CategoryD
SW1
SW2
|
SGG1
SG5
SG8
SG36
SG49
|
Flammable liquid. Flashpoint: 19°C c.c. Boiling point: 108°C. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2438 |
|
|
2439 |
SODIUM HYDROGENDIFLUORIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW1
SW2
H2
|
SGG1
SG35
SG36
SG49
|
White, crystalline powder. Soluble in water. Decomposed by heat or acids, evolving hydrogen fluoride, a toxic extremely irritating and corrosive gas. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Causes burns to skin, eyes and mucous membranes. |
2439 |
|
|
2440 |
STANNIC CHLORIDE PENTAHYDRATE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
White, deliquescent solid. Melting point: about 60°C. Soluble in water. In the presence of water, corrosive to most metals. Irritating to skin, eyes and mucous membranes. |
2440 |
|
|
2441 |
TITANIUM TRICHLORIDE, PYROPHORIC or TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC |
4.2
|
8
|
I |
– |
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
CategoryD
SW2
H1
|
SGG7
SG26
|
Finely divided, violet, crystalline solid. May ignite on exposure to air or moisture. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2441 |
|
|
2442 |
TRICHLOROACETYL CHLORIDE |
8
|
– |
II |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Liquid with a pungent odour, which fumes in moist air. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture, corrosive to most metals. Liquid and vapours cause burns to skin, eyes and mucous membranes. |
2442 |
|
|
2443 |
VANADIUM OXYTRICHLORIDE |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Yellow liquid. Decomposition occurs on exposure to moist air, forming red fumes of vanadic acid and hydrogen chloride, a corrosive gas apparent as white fumes. Reacts with, or dissolves, many organic compounds. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2443 |
|
|
2444 |
VANADIUM TETRACHLORIDE |
8
|
– |
I |
– |
0 |
E0 |
P802
|
– |
– |
– |
|
– |
T10
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Reddish-brown liquid. Decomposes under the influence of light, evolving chlorine, a highly toxic and irritating gas. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Liquid and vapours cause burns to skin, eyes and mucous membranes. |
2444 |
|
|
2446 |
NITROCRESOLS, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Yellow crystals. Melting point: 32°C or above. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
2446 |
|
|
2447 |
PHOSPHORUS, WHITE, MOLTEN |
4.2
|
6.1
P
|
I |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T21
|
TP3 TP7 TP26
|
F-A, S-M
|
CategoryD
|
– |
Molten liquid. Melting point: 44°C. Ignites spontaneously in air. Toxic if swallowed, by skin contact or by inhalation. Shipped molten above its melting point. |
2447 |
|
|
2448 |
SULPHUR, MOLTEN |
4.1
|
– |
III |
– |
0 |
E0 |
– |
– |
IBC01
|
– |
|
– |
T1
|
TP3
|
F-A, S-H
|
CategoryC
|
SG17
|
Melting point: 119°C. Molten sulphur may contain hydrogen sulphide, which is highly poisonous in low concentrations. When involved in a fire, evolves toxic, very irritating and suffocating gas. Forms explosive and extremely sensitive mixtures with oxidizing substances. Shipped molten above its melting point. |
2448 |
|
|
2451 |
NITROGEN TRIFLUORIDE |
2.2
|
5.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
CategoryD
SW2
|
– |
Non-flammable, non-toxic, colourless, odourless gas. Strong oxidizing agent; reacts violently with many substances, e.g. grease, oil, etc. Much heavier than air (2.4). May cause slight eye irritation. |
2451 |
|
|
2452 |
ETHYLACETYLENE, STABILIZED |
2.1
|
– |
– |
386
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryB
SW1
SW2
|
– |
Liquefied, flammable, colourless gas with an odour similar to acetylene. Heavier than air (1.9). Boiling point: 8°C. Irritating to skin, eyes and mucous membranes. |
2452 |
|
|
2453 |
ETHYL FLUORIDE (REFRIGERANT GAS R 161) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Liquefied, flammable, colourless gas. Explosive limits: 5% to 10%. Heavier than air (1.7). Boiling point: −37°C. |
2453 |
|
|
2454 |
METHYL FLUORIDE (REFRIGERANT GAS R 41) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryE
SW2
|
– |
Flammable, colourless gas. Heavier than air (1.2). |
2454 |
|
|
2455 |
METHYL NITRITE |
2.2
|
– |
– |
900
|
– |
– |
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
– |
Transport is prohibited. |
2455 |
|
|
2456 |
2-CHLOROPROPENE |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
CategoryE
|
SGG10
|
Colourless liquid. Flashpoint: below −18°C c.c. Explosive limits: 2.5% to 12%. Boiling point: 23°C. Immiscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. |
2456 |
|
|
2457 |
2,3-DIMETHYLBUTANE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquid. Flashpoint: −29°C c.c. Explosive limits: 1.2% to 7%. Immiscible with water. Irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. |
2457 |
|
|
2458 |
HEXADIENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquids. 1,3-HEXADIENE: flashpoint −3°C c.c. 1,4-HEXADIENE: flashpoint −25°C c.c. 1,5-HEXADIENE: flashpoint −27°C c.c. 2,4-HEXADIENE: flashpoint −7°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2458 |
|
|
2459 |
2-METHYL−1-BUTENE |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
CategoryE
|
– |
Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2459 |
|
|
2460 |
2-METHYL−2-BUTENE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2460 |
|
|
2461 |
METHYLPENTADIENES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless liquids. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2461 |
|
|
2463 |
ALUMINIUM HYDRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-O
|
CategoryE
H1
|
SG26
|
White to grey powder. In contact with water, acids or moisture, evolves hydrogen, which may be ignited by the heat of the reaction. |
2463 |
|
|
2464 |
BERYLLIUM NITRATE |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
CategoryA
|
– |
White or light yellow deliquescent crystals, or fine dust. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. |
2464 |
|
|
2465 |
DICHLOROISOCYANURIC ACID, DRY or DICHLOROISOCYANURIC ACID SALTS |
5.1
|
– |
II |
135 |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
CategoryA
H1
|
– |
White crystalline powder or granules; slightly hygroscopic. Partially soluble in water. Mixtures with combustible material are sensitive to friction and are liable to ignite. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2465 |
|
|
2466 |
POTASSIUM SUPEROXIDE |
5.1
|
– |
I |
– |
0 |
E0 |
P503
|
– |
IBC06
|
B1 |
|
– |
– |
– |
F-G, S-Q
|
CategoryD
H1
|
SGG16
SG16
SG26
SG35
SG59
|
Yellow flakes. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. |
2466 |
|
|
2468 |
TRICHLOROISOCYANURIC ACID, DRY |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
CategoryA
H1
|
– |
Colourless powder or granules. Mixtures with combustible material are sensitive to friction and are liable to ignite. On contact with nitrogen compounds, fumes of nitrogen trichloride can be formed, which are very explosive. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2468 |
|
|
2469 |
ZINC BROMATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-H, S-Q
|
CategoryA
|
SGG3
SGG7
SG38
SG49
|
Colourless powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
2469 |
|
|
2470 |
PHENYLACETONITRILE, LIQUID |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SG35
|
Colourless to light brown liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2470 |
|
|
2471 |
OSMIUM TETROXIDE |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P002
|
PP30 PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryB
SW2
|
– |
Pale yellow, crystalline, volatile solid with an irritating odour. Highly toxic if swallowed, by skin contact or by inhalation. |
2471 |
|
|
2473 |
SODIUM ARSANILATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White, crystalline powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2473 |
|
|
2474 |
THIOPHOSGENE |
6.1
|
– |
I |
279
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW2
|
SG35
|
Red fuming liquid with a foul phosgene-like odour. Decomposes slowly in water. Reacts with acids, evolving toxic and corrosive fumes. Highly toxic if swallowed, by skin contact or by inhalation. |
2474 |
|
|
2475 |
VANADIUM TRICHLORIDE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SG36
SG49
|
Pink, deliquescent crystals. Decomposes in water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Irritating to skin, eyes and mucous membranes. |
2475 |
|
|
2477 |
METHYL ISOTHIOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
White crystals. Usually shipped as an oily liquid with a flashpoint below 60°C c.c. Melting point: 36°C (pure substance). Flashpoint: 32°C c.c. (pure substance). Insoluble in water. When involved in a fire, evolves toxic gases. Highly toxic if swallowed, by skin contact or by inhalation. |
2477 |
|
|
2478 |
ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
II |
274
|
1 L |
E2 |
P001
|
PP31 |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
CategoryD
SW2
|
– |
Flammable toxic liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2478 |
|
|
2478 |
ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
III |
223
274
|
5 L |
E1 |
P001
|
PP31 |
IBC03
|
– |
|
– |
T7
|
TP1 TP13 TP28
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
2478 |
|
|
2480 |
METHYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
SG35
|
Flammable liquid with a pungent odour. Flashpoint: −7°C c.c. (pure product). Boiling point: 38°C (pure product). Vapour heavier than air. Immiscible with water but reacts violently with it. In contact with water or acids, evolves highly toxic nitrous fumes. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2480 |
|
|
2481 |
ETHYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
SG35
|
Liquid with a pungent odour. Flashpoint: −18°C to 0°C c.c. Boiling point: 60°C. Immiscible with water but reacts violently with it. On contact with water or acids, or when heated above boiling point, evolves highly toxic nitrous fumes. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2481 |
|
|
2482 |
n-PROPYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Flammable liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Flashpoint: −18°C to 23°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2482 |
|
|
2483 |
ISOPROPYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Liquid with a pungent odour. Flashpoint: −10°C to 0°C c.c. Immiscible with water but reacts violently with it, evolving gases. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2483 |
|
|
2484 |
tert-BUTYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Colourless liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Flashpoint: 11°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2484 |
|
|
2485 |
n-BUTYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Colourless liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Flashpoint: 19°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2485 |
|
|
2486 |
ISOBUTYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Liquid with a pungent odour. Immiscible with water but reacts violently with it, evolving gases. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2486 |
|
|
2487 |
PHENYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Colourless to yellowish liquid with a pungent odour. Flashpoint: 51°C c.c. Immiscible with water. Reacts with water, evolving carbon dioxide. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2487 |
|
|
2488 |
CYCLOHEXYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Yellowish liquid with an irritating odour. Flashpoint: 53°C c.c. Immiscible with water. Reacts with water, evolving carbon dioxide. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2488 |
|
|
2490 |
DICHLOROISOPROPYL ETHER |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryB
|
– |
Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2490 |
|
|
2491 |
ETHANOLAMINE or ETHANOLAMINE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Colourless. Miscible with water. Corrosive to copper, copper compounds, copper alloys and rubber. Reacts violently with acids. Liquid and vapour cause burns to skin, eyes and mucous membranes. |
2491 |
|
|
2493 |
HEXAMETHYLENEIMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
SW2
|
– |
Yellowish liquid with an ammoniacal odour. Flashpoint: 18°C c.c. Miscible with water. Harmful by inhalation. Absorbed through the skin. Causes burns to skin, eyes and mucous membranes. |
2493 |
|
|
2495 |
IODINE PENTAFLUORIDE |
5.1
|
6.1/8
|
I |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
CategoryD
SW1
SW2
|
SGG1
SG6
SG16
SG19
SG35
SG36
SG49
|
Colourless, fuming liquid (density 3.75). Powerful oxidant; may cause fire in contact with organic material such as wood, cotton or straw. Reacts violently with water, evolving hydrogen fluoride, a toxic, extremely corrosive gas apparent as white fumes. In contact with acids or acid fumes, evolves highly toxic fumes of iodine, fluorine and their compounds. Highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2495 |
|
|
2496 |
PROPIONIC ANHYDRIDE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless, combustible liquid with a pungent odour. Reacts with water, forming propionic acid. Corrosive to skin, eyes and mucous membranes. |
2496 |
|
|
2498 |
1,2,3,6-TETRAHYDRO-BENZALDEHYDE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 57°C o.c. Immiscible with water. |
2498 |
|
|
2501 |
TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Aqueous solution. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2501 |
|
|
2501 |
TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
See entry above. |
2501 |
|
|
2502 |
VALERYL CHLORIDE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Liquid with a penetrating odour. Flashpoint: 23°C c.c. or above. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2502 |
|
|
2503 |
ZIRCONIUM TETRACHLORIDE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
White, lustrous crystals. Reacts with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Irritating to mucous membranes. |
2503 |
|
|
2504 |
TETRABROMOETHANE |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SGG10
|
Colourless to yellowish liquid with a camphor-like odour. Toxic if swallowed, by skin contact or by inhalation. |
2504 |
|
|
2505 |
AMMONIUM FLUORIDE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SGG2
SG35
|
Colourless crystals or powder with an ammonia-like odour. Readily soluble in water. Decomposes in contact with acids, evolving hydrogen fluoride, a corrosive gas. Toxic if swallowed, by skin contact or by dust inhalation. |
2505 |
|
|
2506 |
AMMONIUM HYDROGEN SULPHATE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW2
|
SGG1
SGG2
SG36
SG49
|
White, rhombic crystals. Soluble in water. When involved in a fire, evolves extremely irritating and corrosive fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2506 |
|
|
2507 |
CHLOROPLATINIC ACID, SOLID |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Red-brown crystals. Soluble in water. |
2507 |
|
|
2508 |
MOLYBDENUM PENTACHLORIDE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Black or green-black crystals. Hygroscopic. Reacts violently with water, evolving hydrogen chloride, a corrosive gas apparent as white fumes. Harmful if swallowed. Dust and vapour irritate skin, eyes and mucous membranes. |
2508 |
|
|
2509 |
POTASSIUM HYDROGEN SULPHATE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless crystals. Soluble in water. When involved in a fire, evolves extremely irritating and corrosive fumes. In the presence of moisture, corrosive to most metals. Irritating to skin, eyes and mucous membranes. |
2509 |
|
|
2511 |
2-CHLOROPROPIONIC ACID |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless, aqueous solution with a specific odour. Causes burns to skin, eyes and mucous membranes. |
2511 |
|
|
2512 |
AMINOPHENOLS (o-, m-, p-) |
6.1
|
– |
III |
279
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White or brownish (ortho- and para-) or reddish-yellow (meta-) crystals. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
2512 |
|
|
2513 |
BROMOACETYL BROMIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Clear liquid, colourless. Boiling point: 150°C. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Reacts violently with alkalis such as ammonia and hydrazine. Causes very severe burns to skin, eyes and mucous membranes. Vapour causes tears. |
2513 |
|
|
2514 |
BROMOBENZENE |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid with a characteristic odour. Flashpoint: 51°C c.c. Explosive limits: 0.5% to 2.8%. Immiscible with water. |
2514 |
|
|
2515 |
BROMOFORM |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
SW1
SW2
H2
|
SGG10
|
Colourless liquid or crystals (melting point 9°C) with a chloroform-like odour. Toxic if swallowed, by skin contact or by inhalation. Narcotic effect. |
2515 |
|
|
2516 |
CARBON TETRABROMIDE |
6.1
|
–
P
|
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
SW1
|
– |
Colourless crystals. Melting point: 48°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation of dust and vapour. |
2516 |
|
|
2517 |
1-CHLORO−1,1-DIFLUORO-ETHANE (REFRIGERANT GAS R 142b) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
CategoryB
SW2
|
– |
Flammable gas. Explosive limits: 8.5% to 14%. Much heavier than air (3.5). |
2517 |
|
|
2518 |
1,5,9-CYCLODODECATRIENE |
6.1
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
SW2
|
– |
Colourless liquid. Toxic if swallowed, by skin contact or by inhalation. |
2518 |
|
|
2520 |
CYCLOOCTADIENES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids. Immiscible with water. 1,5-CYCLOOCTADIENE: flashpoint 38°C c.c. Irritating to skin, eyes and mucous membranes. |
2520 |
|
|
2521 |
DIKETENE, STABILIZED |
6.1
|
3
|
I |
354
386
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW1
SW2
|
SG20
SG21
|
Colourless flammable liquid with a pungent odour. Flashpoint: 44°C c.c. Immiscible with water, but hydrolyses slowly in contact with it. The presence of acids, bases or amines can initiate explosive polymerization. Highly toxic if swallowed, by skin contact or by inhalation. |
2521 |
|
|
2522 |
2-DIMETHYLAMINOETHYL METHACRYLATE, STABILIZED |
6.1
|
– |
II |
386
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryD
SW2
|
– |
Combustible liquid. Causes tears. Toxic if swallowed, by skin contact or by inhalation. |
2522 |
|
|
2524 |
ETHYL ORTHOFORMATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Combustible liquid. Causes tears. Toxic if swallowed, by skin contact or by inhalation. |
2524 |
|
|
2524 |
ETHYL ORTHOFORMATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid with an ethereal odour. Flashpoint: 30°C c.c. Immiscible with water. |
2524 |
|
|
2525 |
ETHYL OXALATE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless, oily, aromatic liquid. Slowly decomposed by water. Toxic if swallowed, by skin contact or by dust inhalation. |
2525 |
|
|
2526 |
FURFURYLAMINE |
3
|
8
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
CategoryA
SW2
|
SG35
|
Pale yellow, oily liquid. Flashpoint: 37°C o.c. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2526 |
|
|
2527 |
ISOBUTYL ACRYLATE, STABILIZED |
3
|
– |
III |
386
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless liquid with a pungent odour. Flashpoint: 29°C o.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2527 |
|
|
2528 |
ISOBUTYL ISOBUTYRATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid with a fruity odour. Flashpoint: 37°C c.c. Explosive limits: 0.96% to 7.59%. Immiscible with water. |
2528 |
|
|
2529 |
ISOBUTYRIC ACID |
3
|
8
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
CategoryA
|
– |
Colourless liquid with a pungent odour. Flashpoint: 55°C c.c. Explosive limits: 2% to 9.2%. Miscible with water. Causes burns to skin and eyes. Irritating to skin, eyes and mucous membranes. |
2529 |
|
|
2531 |
METHACRYLIC ACID, STABILIZED |
8
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP18 TP30
|
F-A, S-B
|
CategoryC
SW1
SW2
|
SGG1
SG36
SG49
|
Colourless, combustible liquid with a specific odour. Miscible with water. Polymerizes readily above its melting point (15°C), thereby generating heat and possible risk of explosion; should therefore be properly stabilized. Cooling below melting point (15°C) followed by subsequent reheating can release uninhibited monomer that readily polymerizes. Decomposes when heated, evolving toxic gases. Causes burns to skin, eyes and mucous membranes. |
2531 |
|
|
2533 |
METHYL TRICHLOROACETATE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2533 |
|
|
2534 |
METHYLCHLOROSILANE |
2.3
|
2.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
SG4
SG9
|
Liquefied, flammable, toxic and corrosive colourless gas with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas. Heavier than air. Boiling point: 9°C. Highly irritating to skin, eyes and mucous membranes. |
2534 |
|
|
2535 |
4-METHYLMORPHOLINE (N-METHYLMORPHOLINE) |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
CategoryB
SW2
|
– |
Colourless liquid with an ammonia-like odour. Flashpoint: 13°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2535 |
|
|
2536 |
METHYLTETRAHYDROFURAN |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless, volatile liquid with an ether-like odour. Flashpoint: −11°C o.c. Immiscible with water. |
2536 |
|
|
2538 |
NITRONAPHTHALENE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
CategoryA
|
– |
Yellow crystals. Insoluble in water. Harmful if swallowed. |
2538 |
|
|
2541 |
TERPINOLENE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-E
|
CategoryA
|
– |
Colourless to pale amber liquid with a lemon odour. Flashpoint: 37°C c.c. Immiscible with water. |
2541 |
|
|
2542 |
TRIBUTYLAMINE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Colourless, combustible liquid with an amine odour. Immiscible with water. When involved in a fire, evolves toxic gases. Toxic if swallowed, by skin contact or by inhalation. |
2542 |
|
|
2545 |
HAFNIUM POWDER, DRY |
4.2
|
– |
I |
– |
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
Black amorphous powder. Insoluble in water. Liable to ignite spontaneously in air. Forms explosive mixtures with oxidizing substances. |
2545 |
|
|
2545 |
HAFNIUM POWDER, DRY |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
See entry above. |
2545 |
|
|
2545 |
HAFNIUM POWDER, DRY |
4.2
|
– |
III |
223
|
0 |
E1 |
P002
LP02
|
PP31 L4 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG15
SG26
|
See entry above. |
2545 |
|
|
2546 |
TITANIUM POWDER, DRY |
4.2
|
– |
I |
– |
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
CategoryD
H1
|
SGG7
SGG15
SG26
|
Grey powder. Liable to ignite spontaneously in air. Forms explosive mixtures with oxidizing substances. |
2546 |
|
|
2546 |
TITANIUM POWDER, DRY |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG7
SGG15
SG26
|
See entry above. |
2546 |
|
|
2546 |
TITANIUM POWDER, DRY |
4.2
|
– |
III |
223
|
0 |
E1 |
P002
LP02
|
PP31 L4 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-M
|
CategoryD
H1
|
SGG7
SGG15
SG26
|
See entry above. |
2546 |
|
|
2547 |
SODIUM SUPEROXIDE |
5.1
|
– |
I |
– |
0 |
E0 |
P503
|
– |
IBC06
|
B1 |
|
– |
– |
– |
F-G, S-Q
|
CategoryD
H1
|
SGG16
SG16
SG26
SG35
SG59
|
Pale yellow coarse powder or granules. Particularly if wetted with small quantities of water, a mixture with combustible material may ignite, following impact or friction. When involved in a fire, or in contact with water or acids, decomposes, evolving oxygen. Highly irritating to skin, eyes and mucous membranes. |
2547 |
|
|
2548 |
CHLORINE PENTAFLUORIDE |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
CategoryD
SW2
|
SG6
SG19
|
Non-flammable, toxic and corrosive gas. Forms dense, white, corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, a toxic, irritating and corrosive gas apparent as white fumes. Corrosive to glass and to most metals. Powerful oxidizing agent which may cause violent fires with combustible materials. Much heavier than air (4.5). Highly irritating to skin, eyes and mucous membranes. |
2548 |
|
|
2552 |
HEXAFLUOROACETONE HYDRATE, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryB
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
2552 |
|
|
2554 |
METHYLALLYL CHLORIDE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP13
|
F-E, S-D
|
CategoryE
|
SGG10
|
Colourless to yellowish, volatile liquid with a penetrating odour. Flashpoint: −12°C c.c. Explosive limits: 2.3% to 9.3%. Immiscible with water. When involved in a fire, may evolve highly toxic phosgene gas. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2554 |
|
| △ |
2555 |
NITROCELLULOSE WITH WATER (not less than 25% water, by mass) |
4.1
|
– |
II |
28
394
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
CategoryE
|
SG7
SG30
|
Desensitized explosive. Nitrocellulose may be granular or in flakes, blocks or fibrous form. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. |
2555 |
△ |
| △ |
2556 |
NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass) |
4.1
|
– |
II |
28
394
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
CategoryD
SW1
H2
|
SG7
SG30
|
Nitrocellulose may be granular or in flakes, blocks or fibrous form. In case of leakage, flammable vapours are evolved which, in closed compartments, may form explosive mixtures with air. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Highly explosive when dry. May form extremely sensitive compounds with heavy metals or their salts. |
2556 |
△ |
|
2557 |
NITROCELLULOSE with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WITH or WITHOUT PIGMENT |
4.1
|
– |
II |
241 394
|
0 |
E0 |
P406
|
PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
CategoryD
|
SG7
SG30
|
Nitrocellulose may be in granular form or in flakes. This product may also contain added pigments. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Burns extremely rapidly with intense heat radiation. The formulation should be prepared so that it remains homogeneous and does not separate during transport. May form extremely sensitive compounds with heavy metals or their salts. |
2557 |
|
|
2558 |
EPIBROMOHYDRIN |
6.1
|
3
P
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Flammable liquid. Flashpoint: 56°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. |
2558 |
|
|
2560 |
2-METHYLPENTAN−2-OL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 30°C c.c. Partially miscible with water. Irritating to skin, eyes and mucous membranes. |
2560 |
|
|
2561 |
3-METHYL−1-BUTENE |
3
|
– |
I |
– |
0 |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
CategoryE
|
– |
Colourless, volatile liquid with a disagreeable odour. Flashpoint: below −18°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2561 |
|
|
2564 |
TRICHLOROACETIC ACID SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryB
|
SGG1
SG36
SG49
|
Colourless, clear solution with a pungent odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2564 |
|
|
2564 |
TRICHLOROACETIC ACID SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryB
|
SGG1
SG36
SG49
|
See entry above. |
2564 |
|
|
2565 |
DICYCLOHEXYLAMINE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
- |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SG35
|
Clear, colourless, combustible liquid with a fishy odour which may taint other cargoes. Immiscible with water. Causes burns to skin, eyes and mucous membranes. |
2565 |
|
|
2567 |
SODIUM PENTACHLOROPHENATE |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White or light brown powder with a pungent odour. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2567 |
|
|
2570 |
CADMIUM COMPOUND |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Powder or crystals with various colours. May be soluble or insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2570 |
|
|
2570 |
CADMIUM COMPOUND |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
See entry above. |
2570 |
|
|
2570 |
CADMIUM COMPOUND |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
See entry above. |
2570 |
|
|
2571 |
ALKYLSULPHURIC ACIDS |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T8
|
TP2 TP13 TP28
|
F-A, S-B
|
CategoryC
SW15
|
SGG1
SG36
SG49
|
Colourless oily liquids. React with water, evolving heat. Cause burns to skin, eyes and mucous membranes. Highly corrosive to metal. |
2571 |
|
|
2572 |
PHENYLHYDRAZINE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW2
|
– |
Pale yellow oily liquid. Melting point: 20°C. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
2572 |
|
|
2573 |
THALLIUM CHLORATE |
5.1
|
6.1
P
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
CategoryA
|
SGG4
SG38
SG49
|
Colourless crystals. Slightly soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. |
2573 |
|
|
2574 |
TRICRESYL PHOSPHATE with more than 3% ortho-isomer |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Colourless liquid. A mixture of isomers. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2574 |
|
|
2576 |
PHOSPHORUS OXYBROMIDE, MOLTEN |
8
|
– |
II |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T7
|
TP3 TP13
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Melting point: 56°C. Reacts violently with water, evolving hydrogen bromide, a toxic and corrosive gas apparent as white fumes. Reacts violently with organic materials (such as wood, cotton, straw), causing fire. When involved in a fire, evolves highly toxic and corrosive gases. In the presence of moisture, highly corrosive to most metals. Vapours and liquid cause burns to skin, eyes and mucous membranes. Shipped molten above its melting point. |
2576 |
|
|
2577 |
PHENYLACETYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryC
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Reacts with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves highly toxic fumes. Corrosive to most metals. Vapour irritates eyes and mucous membranes. Liquid is corrosive to skin, eyes and mucous membranes. |
2577 |
|
|
2578 |
PHOSPHORUS TRIOXIDE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
SW1
H2
|
SGG1
SG36
SG49
|
Colourless crystals or white deliquescent powder. Melting point: 23°C. Reacts with water, evolving heat and at normal temperatures phosphoric acid, but at higher temperatures phosphine, a highly toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2578 |
|
|
2579 |
PIPERAZINE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
SW1
H2
|
SGG18
SG35
|
Colourless, deliquescent crystals, turning dark on exposure to light. Soluble in water. Decomposes when heated and when involved in a fire, evolving highly toxic nitrous fumes. The solution in water is a strong base and is highly corrosive. Reacts violently with acids. Irritating to skin, eyes and mucous membranes. |
2579 |
|
|
2580 |
ALUMINIUM BROMIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless to yellowish liquid. Highly corrosive to most metals. Vapour highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membranes. |
2580 |
|
|
2581 |
ALUMINIUM CHLORIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless to yellowish liquid. Highly corrosive to most metals. Vapour highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membranes. |
2581 |
|
|
2582 |
FERRIC CHLORIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Colourless to light brown liquid. Highly corrosive to most metals. |
2582 |
|
|
2583 |
ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
When involved in a fire, evolve highly toxic gases. Corrosive to most metals, especially in the presence of moisture. Cause burns to skin, eyes and mucous membranes. |
2583 |
|
|
2584 |
ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2 TP13
|
F-A, S-B
|
CategoryB
|
SGG1
SG36
SG49
|
Liquids usually with a pungent odour. When involved in a fire, evolve highly toxic gases. Highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. |
2584 |
|
|
2585 |
ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
Crystalline solids. When involved in a fire, evolve highly toxic gases. In the presence of moisture, corrosive to most metals. Cause burns to skin, eyes and mucous membranes. |
2585 |
|
|
2586 |
ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryB
|
SGG1
SG36
SG49
|
Liquids usually with a pungent odour. When involved in a fire, evolve highly toxic gases. Corrosive to most metals. Cause burns to skin, eyes and mucous membranes. |
2586 |
|
|
2587 |
BENZOQUINONE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Yellow crystals with an irritating and penetrating odour resembling that of chlorine. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2587 |
|
|
2588 |
PESTICIDE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryA
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2588 |
|
|
2588 |
PESTICIDE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
SW2
|
– |
See entry above. |
2588 |
|
|
2588 |
PESTICIDE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
SW2
|
– |
See entry above. |
2588 |
|
|
2589 |
VINYL CHLOROACETATE |
6.1
|
3
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
CategoryA
|
– |
Flammable liquid. Flashpoint: 50°C c.c. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2589 |
|
|
2590 |
ASBESTOS, CHRYSOTILE |
9
|
– |
III |
168
|
5 kg |
E1 |
P002
|
PP37 |
IBC08
|
B3 B21 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
SW2
H4
|
SG29
|
Mineral fibres of varying length. Non-combustible. Inhalation of the dust of asbestos fibres is dangerous and therefore exposure should be avoided at all times. Always prevent the generation of asbestos dust. A safe level of airborne concentration of asbestos fibres may be obtained through effective packing. Cargo spaces or freight containers that have contained any type of raw asbestos should be carefully cleaned before discharging any remaining cargo, loading other cargo or carrying out repair or maintenance work. Whenever possible, cleaning of cargo spaces should be carried out whilst the ship is in a port where proper facilities and equipment, including proper respiratory apparatus and protective clothing, are available. Parts of the body that may have been exposed should be immediately and thoroughly washed. All waste material should be collected in impermeable and sealed bags for safe disposal ashore. If cleaning cannot be carried out at the discharge port, arrangements should be made in advance for cleaning to be carried out at the next port where necessary facilities are available. |
2590 |
|
|
2591 |
XENON, REFRIGERATED LIQUID |
2.2
|
– |
– |
– |
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
CategoryD
|
– |
Liquefied, inert, colourless and odourless gas. Much heavier than air (4.5). |
2591 |
|
|
2599 |
CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane (REFRIGERANT GAS R 503) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
CategoryA
|
– |
Non-flammable, colourless gas with a mild ethereal odour. Much heavier than air (3.2). |
2599 |
|
|
2601 |
CYCLOBUTANE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryB
SW2
|
– |
Liquefied, flammable, colourless gas. Explosive limits: 1.8% to 10%. Heavier than air (1.9). Boiling point: 13°C. |
2601 |
|
|
2602 |
DICHLORODIFLUORO-METHANE AND DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
CategoryA
|
– |
Non-flammable, colourless and odourless gas. Much heavier than air (3.7). |
2602 |
|
|
2603 |
CYCLOHEPTATRIENE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP13
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless to dark yellow liquid with a characteristic odour. Flashpoint: 0°C to 4°C c.c. Immiscible with water. Reacts vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2603 |
|
|
2604 |
BORON TRIFLUORIDE DIETHYL ETHERATE |
8
|
3
|
I |
– |
0 |
E0 |
P001
|
PP31 |
– |
– |
|
– |
T10
|
TP2
|
F-E, S-C
|
CategoryD
SW2
|
SGG1
SG36
SG49
|
Colourless fuming flammable liquid. Flashpoint: 59°C c.c. The flashpoint will be lower when free ether is present. Reacts vigorously with oxidizing substances. Decomposes in contact with water, evolving toxic, corrosive and flammable vapours. Causes burns to skin, eyes and mucous membranes. Inhalation of small quantities of vapour can cause breathing difficulties. |
2604 |
|
|
2605 |
METHOXYMETHYL ISOCYANATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Colourless liquid with a pungent odour. Flashpoint: 13°C c.c. Immiscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
2605 |
|
|
2606 |
METHYL ORTHOSILICATE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
CategoryD
SW2
|
– |
Colourless, flammable liquid with an ethereal odour. Immiscible with water. Flashpoint: −18°C to 19°C c.c. Highly toxic if swallowed, by skin contact or by inhalation. May cause blindness. |
2606 |
|
|
2607 |
ACROLEIN DIMER, STABILIZED |
3
|
– |
III |
386
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryC
SW1
SW2
|
– |
Colourless liquid with a pungent odour. Flashpoint: 48°C o.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2607 |
|
|
2608 |
NITROPROPANES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids. Explosive limits: 2.2% to 11%. 1-NITROPROPANE: flashpoint approx. 33°C c.c. 2-NITROPROPANE: flashpoint approx. 28°C c.c. Partially miscible with water. Harmful by inhalation. |
2608 |
|
|
2609 |
TRIALLYL BORATE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
- |
|
– |
– |
– |
F-A, S-A
|
CategoryA
H1
|
– |
Liquid. Hydrolyses in contact with water, forming allyl alcohol. Toxic if swallowed, by skin contact or by inhalation. |
2609 |
|
|
2610 |
TRIALLYLAMINE |
3
|
8
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
CategoryA
SW2
|
SG35
|
Colourless liquid with a fishy odour. Flashpoint: 39°C o.c. Corrosive when in contact with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2610 |
|
|
2611 |
PROPYLENE CHLOROHYDRIN |
6.1
|
3
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-D
|
CategoryA
SW1
SW2
H2
|
– |
Colourless flammable liquid with a mild odour. Flashpoint: 51°C c.c. Miscible with water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by inhalation. |
2611 |
|
|
2612 |
METHYL PROPYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP2
|
F-E, S-D
|
CategoryE
SW2
|
– |
Colourless, volatile liquid with an ethereal odour. Flashpoint: below −18°C c.c. Lower explosive limit: 2%. Boiling point: 39°C. Partially miscible with water. Narcotic. Irritating to skin, eyes and mucous membranes. |
2612 |
|
|
2614 |
METHALLYL ALCOHOL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid with a pungent odour. Flashpoint: 34°C c.c. Miscible with water. Irritating to skin, eyes and mucous membranes. |
2614 |
|
|
2615 |
ETHYL PROPYL ETHER |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryE
|
– |
Colourless, volatile liquids. Flashpoint: below −18°C c.c. Explosive limits: 1.7% to 9.0%. Miscible with water. Irritating to skin, eyes and mucous membranes. |
2615 |
|
|
2616 |
TRIISOPROPYL BORATE |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquid. Flashpoint: 17°C to 60°C c.c. Reacts with water, evolving flammable vapours. |
2616 |
|
|
2616 |
TRIISOPROPYL BORATE |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
2616 |
|
|
2617 |
METHYLCYCLOHEXANOLS, flammable |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless, viscous liquid with a menthol-like odour. Flashpoint: 58°C c.c. Partially miscible with water. |
2617 |
|
|
2618 |
VINYLTOLUENES, STABILIZED |
3
|
– |
III |
386
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryC
SW1
|
– |
Colourless liquids. Flashpoint: 54°C to 60°C c.c. Explosive limits: 0.9% to 6.1%. Partially miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2618 |
|
|
2619 |
BENZYLDIMETHYLAMINE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
SW1
SW2
|
SG35
|
Colourless, flammable liquid with an aromatic odour. Flashpoint: 58°C c.c. Immiscible with water. Harmful if swallowed, by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes. |
2619 |
|
|
2620 |
AMYL BUTYRATES |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids. Flashpoint: 52°C to 58°C c.c. Partially miscible with water. |
2620 |
|
|
2621 |
ACETYL METHYL CARBINOL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Yellow liquid with a pleasant odour. Flashpoint: 44°C to 52°C c.c. Miscible with water. Reacts vigorously with oxidizing substances. Irritating to skin, eyes and mucous membranes. |
2621 |
|
|
2622 |
GLYCIDALDEHYDE |
3
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B8 |
|
– |
T7
|
TP1
|
F-E, S-D
|
CategoryA
SW2
|
– |
Colourless liquid with a pungent odour. Flashpoint: 31°C o.c. Miscible with water. Toxic by inhalation. Irritating to skin, eyes and mucous membranes. |
2622 |
|
|
2623 |
FIRELIGHTERS, SOLID with flammable liquid |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
PP15 |
– |
– |
|
– |
– |
– |
F-A, S-I
|
CategoryA
|
SG35
|
A porous solid, e.g. cellular urea–formaldehyde resin, compacted wood shavings, etc., impregnated with flammable liquid, usually white spirit or kerosene, and designed to burn in a controlled manner. When heated, evolves flammable vapours. |
2623 |
|
|
2624 |
MAGNESIUM SILICIDE |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
CategoryB
SW5
H1
|
SG26
|
White powder or crystals. Reacts with water or steam, evolving hydrogen, a flammable gas. In contact with acids, evolves silane, a spontaneously flammable gas. |
2624 |
|
|
2626 |
CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid |
5.1
|
– |
II |
900
|
1 L |
E0 |
P504
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-Q
|
CategoryD
|
SGG1
SG36
SG38
SG49
|
Colourless liquid. May decompose, evolving chlorine and oxygen with toxic, corrosive and oxidizing effects. May form explosive mixtures with ammonium compounds, combustible material or powdered metals. Corrosive to most metals. Transport of CHLORIC ACID, AQUEOUS SOLUTION with more than 10% chloric acid is prohibited. |
2626 |
|
|
2627 |
NITRITES, INORGANIC, N.O.S. |
5.1
|
– |
II |
274
900
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
CategoryA
|
SGG12
SG38
SG49
SG62
|
Solids. Solid mixtures with combustible material are readily ignited and may burn fiercely. Solid mixtures with ammonium compounds or cyanides may explode. If heated, may decompose, giving off toxic nitrous fumes. Harmful if swallowed. Transport of AMMONIUM NITRITES and mixtures of an inorganic nitrite with an ammonium salt is prohibited. |
2627 |
|
|
2628 |
POTASSIUM FLUOROACETATE |
6.1
|
– |
I |
– |
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryE
|
– |
Solid. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. |
2628 |
|
|
2629 |
SODIUM FLUOROACETATE |
6.1
|
– |
I |
– |
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryE
|
– |
White powder. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. |
2629 |
|
|
2630 |
SELENATES or SELENITES |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryE
|
– |
A wide range of toxic solids. Generally soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. |
2630 |
|
|
2642 |
FLUOROACETIC ACID |
6.1
|
– |
I |
– |
0 |
E5 |
P002
|
– |
IBC07 |
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
CategoryE
|
SGG1
SG36
SG49
|
Colourless crystals. Melting point: 33°C. Soluble in water. Highly toxic if swallowed, by skin contact or by dust inhalation. |
2642 |
|
|
2643 |
METHYL BROMOACETATE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryD
SW2
|
– |
Colourless to straw-coloured liquid. Slightly miscible with water. Causes tears. Toxic if swallowed, by skin contact or by inhalation. |
2643 |
|
|
2644 |
METHYL IODIDE |
6.1
|
– |
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW1
SW2
H2
|
SGG10
|
Colourless liquid. Boiling point: 42°C to 43°C. Slightly miscible with water. When heated, evolves toxic fumes. Highly toxic if swallowed, by skin contact or by inhalation. Has strong narcotic effects. |
2644 |
|
|
2645 |
PHENACYL BROMIDE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryB
SW2
|
– |
White crystals changing to a greenish colour under the influence of light. Melting point: 50°C. Insoluble in water. Causes tears. Toxic if swallowed, by skin contact or by inhalation. |
2645 |
|
|
2646 |
HEXACHLOROCYCLO-PENTADIENE |
6.1
|
– |
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW2
|
SGG10
|
Pale yellow liquid with a pungent odour. Immiscible with water. Causes tears. Highly toxic if swallowed, by skin contact or by inhalation. |
2646 |
|
|
2647 |
MALONONITRILE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
SW1
H2
|
– |
Colourless crystals. Melting point: 32°C. Soluble in water. When heated, evolves highly toxic cyanogen fumes. Toxic if swallowed, by skin contact or by dust inhalation. |
2647 |
|
|
2648 |
1,2-DIBROMOBUTAN−3-ONE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
CategoryB
SW2
|
– |
Liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. Causes tears. |
2648 |
|
|
2649 |
1,3-DICHLOROACETONE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryB
SW1
SW2
H2
|
– |
Crystals. Melting point: 45°C. Soluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. Causes tears. |
2649 |
|
|
2650 |
1,1-DICHLORO−1-NITRO-ETHANE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW1
SW2
H2
|
SG17
|
Liquid. Immiscible with water. May react vigorously with oxidizing substances. Decomposes when heated, evolving highly toxic fumes (oxides of nitrogen). Toxic if swallowed, by skin contact or by inhalation. |
2650 |
|
|
2651 |
4,4’-DIAMINODIPHENYL-METHANE |
6.1
|
–
P
|
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Tan-coloured flakes or lumps. Slightly soluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. May be carried in the molten state. |
2651 |
|
|
2653 |
BENZYL IODIDE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryB
SW1
SW2
H2
|
– |
Colourless crystals. Melting point: 24°C. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. Causes tears. |
2653 |
|
|
2655 |
POTASSIUM FLUOROSILICATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SG35
|
Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. |
2655 |
|
|
2656 |
QUINOLINE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
SW1
H2
|
– |
Colourless liquid with a pungent odour. Immiscible with water. When heated, evolves highly toxic fumes (of oxides of nitrogen). Toxic if swallowed, by skin contact or by inhalation. |
2656 |
|
|
2657 |
SELENIUM DISULPHIDE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Bright red-yellow crystals with a faint odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
2657 |
|
|
2659 |
SODIUM CHLOROACETATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2659 |
|
|
2660 |
NITROTOLUIDINES (MONO) |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Yellow to orange-red crystalline solids. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2660 |
|
|
2661 |
HEXACHLOROACETONE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryB
SW1
SW2
H2
|
– |
Colourless to yellowish liquid. Slightly miscible with water. When heated, evolves extremely toxic fumes (phosgene). Causes tears. Toxic if swallowed, by skin contact or by inhalation. |
2661 |
|
|
2664 |
DIBROMOMETHANE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SGG10
|
Clear, colourless liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2664 |
|
|
2667 |
BUTYLTOLUENES |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2667 |
|
|
2668 |
CHLOROACETONITRILE |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
CategoryD
SW1
SW2
H2
|
SG35
|
Colourless flammable liquid with a pungent odour. Flashpoint: 56°C c.c. Immiscible with water. Decomposes when heated, evolving highly toxic fumes of cyanides. Reacts with steam and acids, evolving toxic and flammable vapours. Highly toxic if swallowed, by skin contact or by inhalation. |
2668 |
|
|
2669 |
CHLOROCRESOLS SOLUTION |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW1
H2
|
– |
Solutions with a phenol-like odour. Slightly miscible with water. Decompose when heated, evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
2669 |
|
|
2669 |
CHLOROCRESOLS SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
SW1
H2
|
– |
See entry above. |
2669 |
|
|
2670 |
CYANURIC CHLORIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
SW1
SW2
H2
|
SGG1
SG36
SG49
|
Colourless crystals with a pungent odour. Reacts with water, forming toxic and corrosive acids. Decomposes when heated, evolving toxic and corrosive gases. Causes burns to skin, eyes and mucous membranes. |
2670 |
|
|
2671 |
AMINOPYRIDINES (o-, m-, p-) |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryB
SW1
SW2
H2
|
SGG18
SG35
|
White powder or crystals. Melting points: 58°C to 64°C. Soluble in water. Reacts violently with acids. Toxic if swallowed, by skin contact or by dust inhalation. |
2671 |
|
|
2672 |
AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15°C in water, with more than 10% but not more than 35% ammonia |
8
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
B11 |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
SW2
SW5
|
SGG18
SG35
|
Colourless liquid with a pungent odour. Corrosive to copper, nickel, zinc and tin and their alloys such as brass. Not significantly corrosive to iron and steel. Reacts violently with acids. Liquid and vapour cause burns to skin, eyes and mucous membranes. |
2672 |
|
|
2673 |
2-AMINO−4-CHLOROPHENOL |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Light brown crystals. Slightly soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2673 |
|
|
2674 |
SODIUM FLUOROSILICATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SG35
|
Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. |
2674 |
|
|
2676 |
STIBINE |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
CategoryD
SW2
|
– |
Flammable, toxic, colourless gas with a foul odour. Decomposes violently in the presence of water. Much heavier than air (4.3). |
2676 |
|
|
2677 |
RUBIDIUM HYDROXIDE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
Liquid. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
2677 |
|
|
2677 |
RUBIDIUM HYDROXIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
See entry above. |
2677 |
|
|
2678 |
RUBIDIUM HYDROXIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
Greyish-white solid, very hygroscopic. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
2678 |
|
|
2679 |
LITHIUM HYDROXIDE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
Colourless liquid. Corrosive to aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
2679 |
|
|
2679 |
LITHIUM HYDROXIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
See entry above. |
2679 |
|
|
2680 |
LITHIUM HYDROXIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG35
|
Colourless crystals. Soluble in water. Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. |
2680 |
|
|
2681 |
CAESIUM HYDROXIDE SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
Colourless liquid. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to glass, aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
2681 |
|
|
2681 |
CAESIUM HYDROXIDE SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
See entry above. |
2681 |
|
|
2682 |
CAESIUM HYDROXIDE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG18
SG22
SG35
|
Colourless or yellowish hygroscopic crystals. Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. In the presence of moisture, corrosive to glass, aluminium, zinc and tin. Causes burns to skin, eyes and mucous membranes. |
2682 |
|
|
2683 |
AMMONIUM SULPHIDE SOLUTION |
8
|
3/6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC01
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-C
|
CategoryB
SW1
H2
|
SGG2
SGG18
SG35
SG68
|
Yellow liquid with a foul odour (of rotten eggs). When heated, evolves toxic and flammable vapours. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. Corrosive to skin, eyes and mucous membranes. |
2683 |
|
|
2684 |
3-DIETHYLAMINO-PROPYLAMINE |
3
|
8
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-C
|
CategoryA
|
SG35
|
Colourless liquid with a fishy odour. Flashpoint: 59°C o.c. Miscible with water. Irritating to skin, eyes and mucous membranes. |
2684 |
|
|
2685 |
N,N-DIETHYLETHYLENE-DIAMINE |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
|
SG35
|
Colourless, flammable liquid with a fishy odour. Flashpoint: 46°C o.c. Miscible with water. Harmful by skin contact. Irritating to eyes and mucous membranes. |
2685 |
|
|
2686 |
2-DIETHYLAMINOETHANOL |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
CategoryA
|
SG35
|
Colourless liquid. Miscible with water. Reacts violently with oxidizing substances. Explosive limits: 1.8% to 28%. Flashpoint: 46°C to 60°C c.c. Causes burns to skin, eyes and mucous membranes. |
2686 |
|
|
2687 |
DICYCLOHEXYLAMMONIUM NITRITE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
CategoryA
|
SGG2
|
White powder. Insoluble in water. Harmful if swallowed. |
2687 |
|
|
2688 |
1-BROMO−3-CHLOROPROPANE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
SGG10
|
Colourless liquid. Immiscible with water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by inhalation. |
2688 |
|
|
2689 |
GLYCEROL alpha- MONOCHLOROHYDRIN |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2689 |
|
|
2690 |
N,n-BUTYLIMIDAZOLE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
CategoryA
|
– |
Colourless to amber mobile liquid. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2690 |
|
|
2691 |
PHOSPHORUS PENTABROMIDE |
8
|
– |
II |
– |
1 kg |
E0 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
CategoryB
SW1
SW2
H2
|
SGG1
SG36
SG37
SG49
|
Yellow hygroscopic crystals, evolving fumes in the air which are corrosive and heavier than air. Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. Reacts violently with ammonia, bases and many other substances and may cause fire and explosion. Decomposes when heated, evolving corrosive and toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2691 |
|
|
2692 |
BORON TRIBROMIDE |
8
|
– |
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
CategoryC
SW1
H2
|
SGG1
SG36
SG49
|
Colourless fuming liquid. Reacts violently with water, evolving toxic and corrosive fumes. Decomposes when heated, evolving toxic fumes. In the presence of moisture, highly corrosive to most metals. Liquid and vapour cause severe burns to skin, eyes and mucous membranes. |
2692 |
|
|
2693 |
BISULPHITES, AQUEOUS SOLUTION, N.O.S. |
8
|
– |
III |
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
- |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
CategoryA
SW2
|
SG35
|
Liquid with a pungent odour. Reacts with acids, evolving sulphur dioxide, a toxic gas. Causes burns to skin, eyes and mucous membranes. |
2693 |
|
|
2698 |
TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% maleic anhydride |
8
|
– |
III |
29
169
939
973
|
5 kg |
E1 |
P002
LP02
|
PP14 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
CategoryA
|
SGG1
SG36
SG49
|
White crystalline powders. React with water, evolving heat and forming tetrahydrophthalic acid. Cause burns to skin, eyes and mucous membranes. When heated, evolve acrid fumes which are irritating to skin, eyes and mucous membranes. |
2698 |
|
|
2699 |
TRIFLUOROACETIC ACID |
8
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2
|
F-A, S-B
|
CategoryB
SW1
SW2
H2
|
SGG1
SG36
SG49
|
Colourless, fuming, hygroscopic liquid with a pungent odour. Miscible with water. When heated to decomposition or in contact with acids, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapours are highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membranes. |
2699 |
|
|
2705 |
1-PENTOL |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
CategoryB
|
SG20
SG21
|
Colourless liquid with a perceptible odour. May react in contact with acids and alkalis. Causes burns to skin, eyes and mucous membranes. |
2705 |
|
|
2707 |
DIMETHYLDIOXANES |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
CategoryB
|
– |
Colourless liquids with a pungent odour. Partially miscible with water. React vigorously with oxidizing substances. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2707 |
|
|
2707 |
DIMETHYLDIOXANES |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
See entry above. |
2707 |
|
|
2709 |
BUTYLBENZENES |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquids with an unpleasant odour. Flashpoint: 34°C to 60°C c.c. Explosive limits: 0.7% to 6.9%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2709 |
|
|
2710 |
DIPROPYL KETONE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
CategoryA
|
– |
Colourless liquid. Flashpoint: 49°C c.c. Immiscible with water. |
2710 |
|
|
2713 |
ACRIDINE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
Small colourless to yellowish crystals or needles. Sublimes at 100°C. Practically insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
2713 |
|
|
2714 |
ZINC RESINATE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-I
|
CategoryA
|
SGG7
|
Powder or clear amber lumps. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. |
2714 |
|
|
2715 |
ALUMINIUM RESINATE |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-I
|
CategoryA
|
– |
Cream to brown coloured mass. Insoluble in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. |
2715 |
|
|
2716 |
1,4-BUTYNEDIOL |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
SG35
SG36
SG55
|
White crystals. Melting point: 58°C. Soluble in water. Forms explosive mixtures with mercury salts, acids, alkaline compounds and halides. Toxic if swallowed, by skin contact or by inhalation. |
2716 |
|
|
2717 |
CAMPHOR, synthetic |
4.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-I
|
CategoryA
|
– |
Colourless or white crystals, granules or easily broken masses with a penetrating, pungent and aromatic odour. Slightly soluble in water. When heated, evolves flammable and explosive vapours. Harmful if swallowed. |
2717 |
|
|
2719 |
BARIUM BROMATE |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
CategoryA
|
SGG3
SG38
SG49
|
White crystals or powder. Slightly soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. |
2719 |
|
|
2720 |
CHROMIUM NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
CategoryA
|
– |
Purple crystals. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. |
2720 |
|
|
2721 |
COPPER CHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
CategoryA
|
SGG4
SG38
SG49
|
Blue-green deliquescent crystals or powder. Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. |
2721 |
|
|
2722 |
LITHIUM NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
CategoryA
|
– |
Colourless deliquescent crystals. Soluble in water. Mixtures with combustible material are readily ignited and burn fiercely. Harmful if swallowed. |
2722 |
|
|
2723 |
MAGNESIUM CHLORATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
CategoryA
|
SGG4
SG38
SG49
|
White deliquescent crystals or powder. Soluble in water. Melting point: 35°C. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. The cargoes should be protected from moisture prior to and after loading. If weather is inclement, hatches should be closed. |
2723 |
|
|
2724 |
MANGANESE NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
CategoryA
|
– |
Pale pink deliquescent crystals. Soluble in water. Melting point between 26°C and 35°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. |
2724 |
|
|
2725 |
NICKEL NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
CategoryA
|
– |
Green deliquescent crystals. Soluble in water. Melting point: 55°C. Mixtures with combustible material are readily ignited and may burn fiercely. Solutions in water are slightly corrosive. Harmful if swallowed. |
2725 |
|
|
2726 |
NICKEL NITRITE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
CategoryA
|
SGG12
SG38
SG49
|
Reddish-yellow crystals. Decomposes if heated, giving off toxic nitrous fumes. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Harmful if swallowed. |
2726 |
|
|
2727 |
THALLIUM NITRATE |
6.1
|
5.1
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
CategoryA
|
– |
Colourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Toxic if swallowed, by skin contact or by dust inhalation. |
2727 |
|
|
2728 |
ZIRCONIUM NITRATE |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
CategoryA
|
– |
White crystals, flakes or powder. Soluble in water. Solutions in water are slightly corrosive. Harmful if swallowed. |
2728 |
|
|
2729 |
HEXACHLOROBENZENE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
CategoryA
|
– |
White needle-like crystals. Insoluble in water. Decomposes when heated, evolving highly toxic fumes. Toxic if swallowed, by skin contact or by dust inhalation. |
2729 |
|
|
2730 |
NITROANISOLES, LIQUID |
6.1
|
– |
III |
279
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Light reddish or amber liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2730 |
|
|
2732 |
NITROBROMOBENZENES, LIQUID |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
CategoryA
|
– |
Colourless to pale yellow liquids. Melting point of 1-BROMO−3-NITROBENZENE: 17°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2732 |
|
|
2733
|
AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. |
3
|
8
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP1 TP27
|
F-E, S-C
|
Category D
SW2
|
SGG18
SG35
|
Colourless to yellowish liquids with an unpleasant odour. Some are very volatile. Miscible with water. Corrosive to most metals, especially to copper and its alloys. When involved in a fire, evolve toxic gases. React violently with acids. Harmful by inhalation. Cause burns to skin, eyes and mucous membranes. |
2733 |
|
|
2733
|
AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. |
3
|
8
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP1 TP27
|
F-E, S-C
|
Category B
SW2
|
SGG18
SG35
|
See entry above. |
2733 |
|
|
2733
|
AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. |
3
|
8
|
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-E, S-C
|
Category A
SW2
|
SGG18
SG35
|
See entry above. |
2733 |
|
|
2734
|
AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
8
|
3
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-E, S-C
|
Category A
|
SGG18
SG35
|
Colourless to yellowish flammable liquids or solutions with a pungent odour. Miscible with water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. React violently with acids. Cause burns to skin, eyes and mucous membranes. |
2734 |
|
|
2734
|
AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
8
|
3
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-C
|
Category A
|
SGG18
SG35
|
See entry above. |
2734 |
|
|
2735
|
AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
Colourless to yellowish liquids or solutions with a pungent odour. Miscible with or soluble in water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. React violently with acids. Cause burns to skin, eyes and mucous membranes. |
2735 |
|
|
2735
|
AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP1 TP27
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
See entry above. |
2735 |
|
|
2735
|
AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
See entry above. |
2735 |
|
|
2738
|
N-BUTYLANILINE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SG17
|
Amber liquid with a perceptible odour. Immiscible with water. May react vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2738 |
|
|
2739
|
BUTYRIC ANHYDRIDE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
Colourless liquid. Decomposes in water to form butyric acid. |
2739 |
|
|
2740
|
n-PROPYL CHLOROFORMATE |
6.1
|
3/8
|
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-C
|
Category B
SW2
|
SGG1
SG5
SG8
SG36
SG49
|
Colourless flammable liquid. Flashpoint: 28°C c.c. Decomposed by water, generating propyl alcohol. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2740 |
|
|
2741
|
BARIUM HYPOCHLORITE with more than 22% available chlorine |
5.1
|
6.1
|
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category B
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White powder with pungent odour. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by dust inhalation. Dust irritates mucous membranes. Contact with eyes will cause serious injury to the cornea (blindness) if not treated immediately by using copious amounts of water followed by medical attention. |
2741 |
|
|
2742
|
CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. |
6.1
|
3/8
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC01
|
– |
|
– |
– |
– |
F-E, S-C
|
Category A
SW1
SW2
H1
H2
|
SGG1
SG5
SG8
SG36
SG49
|
A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: cyclohexyl chloroformate: 53°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
2742 |
|
|
2743
|
n-BUTYL CHLOROFORMATE |
6.1
|
3/8
|
II |
– |
100 mL |
E0 |
P001
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-C
|
Category A
SW1
SW2
H1
H2
|
SGG1
SG5
SG8
SG36
SG49
|
A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: 32°C c.c. to 39°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
2743 |
|
|
2744
|
CYCLOBUTYL CHLOROFORMATE |
6.1
|
3/8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC01
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-C
|
Category A
SW1
SW2
H1
H2
|
SGG1
SG5
SG8
SG36
SG49
|
A wide range of colourless to yellowish flammable liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Flashpoint: 38°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
2744 |
|
|
2745
|
CHLOROMETHYL CHLOROFORMATE |
6.1
|
8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-B
|
Category A
SW1
SW2
H1
H2
|
SGG1
SG36
SG49
|
A wide range of colourless to yellowish liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
2745 |
|
|
2746
|
PHENYL CHLOROFORMATE |
6.1
|
8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-B
|
Category A
SW1
SW2
H1
H2
|
SGG1
SG36
SG49
|
A wide range of colourless to yellowish liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
2746 |
|
|
2747
|
tert-BUTYLCYCLOHEXYL CHLOROFORMATE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
SW1
H1
H2
|
– |
Colourless to yellowish liquid. Reacts with water or decomposes if heated, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. |
2747 |
|
|
2748
|
2-ETHYLHEXYL CHLOROFORMATE |
6.1
|
8
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-B
|
Category A
SW1
SW2
H1
H2
|
SGG1
SG36
SG49
|
A wide range of colourless to yellowish liquids. React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
2748 |
|
|
2749
|
TETRAMETHYLSILANE |
3
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2
|
F-E, S-D
|
Category D
|
– |
Colourless, volatile liquid. Flashpoint: below −18°C c.c. Boiling point: 27°C. Immiscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. |
2749 |
|
|
2750
|
1,3-DICHLOROPROPANOL−2 |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW1
SW2
H2
|
– |
Colourless, slightly viscous liquid with a chloroform-like odour. Immiscible with water. Decomposes when heated, evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
2750 |
|
|
2751
|
DIETHYLTHIOPHOSPHORYL CHLORIDE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category D
SW1
SW2
H2
|
SGG1
SG36
SG49
|
Colourless liquid with a perceptible odour. Reacts slowly with water, forming hydrochloric acid. When involved in a fire, evolves toxic gases (hydrogen chloride and sulphur dioxide). Vapour highly irritating to eyes and mucous membranes. Liquid causes burns to skin, eyes and mucous membranes. |
2751 |
|
|
2752
|
1,2-EPOXY−3-ETHOXYPROPANE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Immiscible with water. Flashpoint: 47°C c.c. Irritating to skin, eyes and mucous membranes. |
2752 |
|
|
2753
|
N-ETHYLBENZYLTOLUIDINES, LIQUID |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1
|
F-A, S-A
|
Category A
|
– |
Liquids with a strong odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2753 |
|
|
2754
|
N-ETHYLTOLUIDINES |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Colourless to light amber liquids. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2754 |
|
|
2757
|
CARBAMATE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2757 |
|
|
2757
|
CARBAMATE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2757 |
|
|
2757
|
CARBAMATE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2757 |
|
|
2758
|
CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2758 |
|
|
2758
|
CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2758 |
|
|
2759
|
ARSENICAL PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2759 |
|
|
2759
|
ARSENICAL PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2759 |
|
|
2759
|
ARSENICAL PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2759 |
|
|
2760
|
ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2760 |
|
|
2760
|
ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2760 |
|
|
2761
|
ORGANOCHLORINE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2761 |
|
|
2761
|
ORGANOCHLORINE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2761 |
|
|
2761
|
ORGANOCHLORINE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2761 |
|
|
2762
|
ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2762 |
|
|
2762
|
ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2762 |
|
|
2763
|
TRIAZINE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2763 |
|
|
2763
|
TRIAZINE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2763 |
|
|
2763
|
TRIAZINE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2763 |
|
|
2764
|
TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2764 |
|
|
2764
|
TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2764 |
|
|
2771
|
THIOCARBAMATE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2771 |
|
|
2771
|
THIOCARBAMATE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2771 |
|
|
2771
|
THIOCARBAMATE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2771 |
|
|
2772
|
THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2772 |
|
|
2772
|
THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2772 |
|
|
2775
|
COPPER BASED PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2775 |
|
|
2775
|
COPPER BASED PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2775 |
|
|
2775
|
COPPER BASED PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2775 |
|
|
2776
|
COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2776 |
|
|
2776
|
COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2776 |
|
|
2777
|
MERCURY BASED PESTICIDE, SOLID, TOXIC |
6.1
|
–
P
|
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
SGG7
SGG11
|
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2777 |
|
|
2777
|
MERCURY BASED PESTICIDE, SOLID, TOXIC |
6.1
|
–
P
|
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
SGG7
SGG11
|
See entry above. |
2777 |
|
|
2777
|
MERCURY BASED PESTICIDE, SOLID, TOXIC |
6.1
|
–
P
|
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
SGG7
SGG11
|
See entry above. |
2777 |
|
|
2778
|
MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
P
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
SGG7
SGG11
|
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2778 |
|
|
2778
|
MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
P
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
SGG7
SGG11
|
See entry above. |
2778 |
|
|
2779
|
SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2779 |
|
|
2779
|
SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2779 |
|
|
2779
|
SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2779 |
|
|
2780
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2780 |
|
|
2780
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2780 |
|
|
2781
|
BIPYRIDILIUM PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2781 |
|
|
2781
|
BIPYRIDILIUM PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2781 |
|
|
2781
|
BIPYRIDILIUM PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2781 |
|
|
2782
|
BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2782 |
|
|
2782
|
BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2782 |
|
|
2783
|
ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2783 |
|
|
2783
|
ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2783 |
|
|
2783
|
ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2783 |
|
|
2784
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2784 |
|
|
2784
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2784 |
|
|
2785
|
4-THIAPENTANAL |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
PP31 |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category D
SW1
|
SG20
SG21
|
Colourless liquid with an extremely foul and persistent odour. Miscible with water. Decomposes rapidly in contact with acids and bases. Toxic if swallowed, by skin contact or by inhalation. |
2785 |
|
|
2786
|
ORGANOTIN PESTICIDE, SOLID, TOXIC |
6.1
|
–
P
|
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
2786 |
|
|
2786
|
ORGANOTIN PESTICIDE, SOLID, TOXIC |
6.1
|
–
P
|
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2786 |
|
|
2786
|
ORGANOTIN PESTICIDE, SOLID, TOXIC |
6.1
|
–
P
|
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2786 |
|
|
2787
|
ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
P
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2787 |
|
|
2787
|
ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
P
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2787 |
|
|
2788
|
ORGANOTIN COMPOUND, LIQUID, N.O.S. |
6.1
|
–
P
|
I |
43
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category A
SW2
|
– |
A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. |
2788 |
|
|
2788
|
ORGANOTIN COMPOUND, LIQUID, N.O.S. |
6.1
|
–
P
|
II |
43
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2788 |
|
|
2788
|
ORGANOTIN COMPOUND, LIQUID, N.O.S. |
6.1
|
–
P
|
III |
43
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2788 |
|
|
2789
|
ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
Category A
|
SGG1
SG36
SG49
|
Colourless flammable liquid with a pungent odour. When pure, crystallizes below 16°C. Flashpoint: 40°C c.c. (pure product), 60°C c.c. (80% solution). Explosive limits: 4% to 17%. Miscible with water. Corrosive to lead and most other metals. Corrosive to skin, eyes and mucous membranes. |
2789 |
|
|
2790
|
ACETIC ACID SOLUTION, not less than 50% but not more than 80% acid, by mass |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Corrosive to skin, eyes and mucous membranes. |
2790 |
|
|
2790
|
ACETIC ACID SOLUTION, more than 10% and less than 50% acid, by mass |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
See entry above. |
2790 |
|
|
2793
|
FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self-heating |
4.2
|
– |
III |
223
931
|
0 |
E1 |
P003
LP02
|
PP20 L3 |
IBC08
|
B4 B6 |
|
– |
BK2
|
– |
F-G, S-J
|
Category A
H1
|
SG26
|
These cargoes are liable to self-heating and to ignite spontaneously, particularly when in a finely divided form, wet or contaminated with such materials as unsaturated cutting oil, oily rags and other combustible matter. Self-heating or inadequate ventilation may cause dangerous depletion of oxygen in the stowage spaces. Excessive amounts of cast iron borings or organic materials may encourage heating. The swarf should be protected from moisture prior to and after loading. If, during loading, the weather is inclement, hatches should be closed or otherwise protected to keep the material dry. |
2793 |
|
|
2794
|
BATTERIES, WET, FILLED WITH ACID, electric storage |
8
|
– |
– |
295
|
1 L |
E0 |
P801
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
Category A
SW16
|
SGG1
SG36
SG49
|
Metal plates immersed in acid electrolyte in a glass, hard rubber or plastics receptacle. When electrically charged, may cause fire through short-circuiting of terminals. Acid electrolyte is corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Used batteries being transported for disposal or reclamation should be carefully checked prior to shipment to ensure the integrity of each battery and its suitability for transport. |
2794 |
|
| △ |
2795 |
BATTERIES, WET, FILLED WITH ALKALI, electric storage |
8
|
– |
– |
295
401
|
1 L |
E0 |
P801
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
Category A
SW16
|
SGG18
SG35
|
Metal plates immersed in alkaline electrolyte in a glass, hard rubber or plastics receptacle. When electrically charged, may cause fire through short-circuiting of terminals. Alkaline electrolyte is corrosive to aluminium, zinc and tin. Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. Used batteries being transported for disposal or reclamation should be carefully checked prior to shipment to ensure the integrity of each battery and its suitability for transport. |
2795 |
△ |
|
2796
|
SULPHURIC ACID with not more than 51% acid or BATTERY FLUID, ACID |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2
|
F-A, S-B
|
Category B
|
SGG1
SG36
SG49
|
Colourless liquid, mixture not exceeding 1.405 relative density. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2796 |
|
|
2797
|
BATTERY FLUID, ALKALI |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-B
|
Category A
|
SGG18
SG22
SG35
|
Reacts violently with acids. Reacts with ammonium salts, evolving ammonia gas. Corrosive to aluminium, zinc and tin. |
2797 |
|
|
2798
|
PHENYLPHOSPHORUS DICHLORIDE |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category B
SW2
|
SGG1
SG36
SG49
|
Colourless liquid. Causes burns to skin, eyes and mucous membranes. |
2798 |
|
|
2799
|
PHENYLPHOSPHORUS THIODICHLORIDE |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category B
SW2
|
SGG1
SG36
SG49
|
Colourless liquid which fumes slightly in air. Reacts with water or steam, evolving toxic and flammable vapours. Causes burns to skin, eyes and mucous membranes. |
2799 |
|
|
2800
|
BATTERIES, WET, NON-SPILLABLE, electric storage |
8
|
– |
– |
238
|
1 L |
E0 |
P003
|
PP16 |
– |
– |
|
– |
– |
– |
F-A, S-B
|
Category A
|
– |
Metal plates immersed in gelled alkaline or acid electrolyte in a glass, hard rubber or plastics receptacle of a non-spillable type. When electrically charged, may cause fire through short-circuiting of terminals. Cause burns to skin, eyes and mucous membranes. |
2800 |
|
|
2801
|
DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-B
|
Category A
|
– |
A wide range of corrosive liquids. Cause burns to skin, eyes and mucous membranes. |
2801 |
|
|
2801
|
DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category A
|
– |
See entry above. |
2801 |
|
|
2801
|
DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category A
|
– |
See entry above. |
2801 |
|
|
2802
|
COPPER CHLORIDE |
8
|
–
P
|
III |
– |
500 g |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
White to yellow-brown crystals or powder. Partially to fully soluble in water. Corrosive to steel. Causes burns to skin, eyes and mucous membranes. |
2802 |
|
| △ |
2803
|
GALLIUM |
8
|
– |
III |
365
|
5 kg |
E0 |
P800
|
PP41 |
– |
– |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category B
SW1
|
– |
Silvery-white metallic element that melts at 29°C, becoming a bright, shiny liquid. Insoluble in water. Highly corrosive to aluminium. Harmful if swallowed, by skin contact or by inhalation. Special care should be taken if a leakage occurs when carried in aluminium freight containers. Carriage should be prohibited in hovercraft and other ships constructed from aluminium. |
2803 |
△ |
|
2805
|
LITHIUM HYDRIDE, FUSED SOLID |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
H1
|
SG26
SG35
|
White, crystalline mass. Reacts with water, moisture or acids, evolving hydrogen which may be ignited by the heat of the reaction. |
2805 |
|
|
2806
|
LITHIUM NITRIDE |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
IBC04
|
B1 |
|
– |
– |
– |
F-A, S-O
|
Category E
|
– |
Brownish-red crystals or fine, free-flowing powder. Reacts slowly with water to form lithium hydroxide and ammonia. |
2806 |
|
|
2807
|
MAGNETIZED MATERIAL |
9
|
– |
– |
960
|
– |
– |
– |
– |
– |
– |
|
|
– |
– |
– |
– |
– |
Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. |
2807 |
|
|
2809
|
MERCURY |
8
|
6.1
|
III |
365
|
5 kg |
E0 |
P800
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
Category B
SW2
|
SGG7
SGG11
SG24
|
A silvery metallic element occurring in the liquid state at normal temperatures. Relative density: 13.546. Melting point: −39°C . Highly corrosive to aluminium. Toxic if swallowed, by skin contact or by inhalation. Special care should be taken if a leakage occurs during transport, especially when carried in breakable packages and in aluminium freight containers. Carriage should be prohibited in hovercraft and other ships constructed from aluminium. |
2809 |
|
|
2810
|
TOXIC LIQUID, ORGANIC, N.O.S. |
6.1
|
– |
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
2810 |
|
|
2810
|
TOXIC LIQUID, ORGANIC, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
2810 |
|
|
2810
|
TOXIC LIQUID, ORGANIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2810 |
|
|
2811
|
TOXIC SOLID, ORGANIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
2811 |
|
|
2811
|
TOXIC SOLID, ORGANIC, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
2811 |
|
|
2811
|
TOXIC SOLID, ORGANIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
2811 |
|
|
2812
|
SODIUM ALUMINATE, SOLID |
8
|
– |
– |
960
|
– |
– |
– |
– |
– |
– |
|
|
– |
– |
– |
– |
– |
Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. |
2812 |
|
|
2813
|
WATER-REACTIVE SOLID, N.O.S. |
4.3
|
– |
I |
274
|
0 |
E0 |
P403
|
PP31 |
IBC99
|
– |
|
– |
T9
|
TP7 TP33
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
2813 |
|
|
2813
|
WATER-REACTIVE SOLID, N.O.S. |
4.3
|
– |
II |
274
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
2813 |
|
|
2813
|
WATER-REACTIVE SOLID, N.O.S. |
4.3
|
– |
III |
223
274
|
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
2813 |
|
|
2814
|
INFECTIOUS SUBSTANCE, AFFECTING HUMANS |
6.2
|
– |
– |
318
341
|
0 |
E0 |
P620
|
– |
– |
– |
|
– |
BK2
|
– |
F-A, S-T
|
Category E
SW2
H1
H5
|
SG50
|
Substances which are dangerous to humans or to humans and animals. |
2814 |
|
|
2815
|
N-AMINOETHYLPIPERAZINE |
8
|
6.1
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category B
SW1
SW2
H2
|
SG35
SG50
|
Yellow liquid. Miscible with water. Corrosive to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. |
2815 |
|
|
2817
|
AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION |
8
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
B20 |
|
– |
T8
|
TP2 TP13
|
F-A, S-B
|
Category B
SW2
|
SGG1
SGG2
SG36
SG49
|
Colourless liquid. Miscible with water. Highly corrosive to most metals and glass. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2817 |
|
|
2817
|
AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION |
8
|
6.1
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP13
|
F-A, S-B
|
Category B
SW2
|
SGG1
SGG2
SG36
SG49
|
See entry above. |
2817 |
|
|
2818
|
AMMONIUM POLYSULPHIDE SOLUTION |
8
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-B
|
Category B
SW1
SW2
H2
|
SGG2
SGG18
SG35
|
Unstable yellowish liquid with a foul odour (of rotten eggs). Miscible with water. Reacts violently with acids. Decomposes in contact with acids, evolving hydrogen sulphide, a toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2818 |
|
|
2818
|
AMMONIUM POLYSULPHIDE SOLUTION |
8
|
6.1
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP13
|
F-A, S-B
|
Category B
SW1
SW2
H2
|
SGG2
SGG18
SG35
|
See entry above. |
2818 |
|
|
2819
|
AMYL ACID PHOSPHATE |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
Clear colourless liquid. A mixture of primary and amyl isomers. Immiscible with water. Corrosive to skin, eyes and mucous membranes. |
2819 |
|
|
2820
|
BUTYRIC ACID |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
SW1
H2
|
SGG1
SG36
SG49
|
Colourless liquid with a penetrating and unpleasant odour. Freezing point: −5°C to −8°C. Miscible with water. Corrosive to most metals. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. |
2820 |
|
|
2821
|
PHENOL SOLUTION |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Yellowish solutions with a perceptible odour. Toxic if swallowed, by skin contact or by inhalation. Rapidly absorbed through the skin. |
2821 |
|
|
2821
|
PHENOL SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
See entry above. |
2821 |
|
|
2822
|
2-CHLOROPYRIDINE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW2
|
– |
Colourless oily liquid. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2822 |
|
|
2823
|
CROTONIC ACID, SOLID |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 B21 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
SW1
H2
|
SGG1
SG36
SG49
|
White crystalline solid. Soluble in water. Decomposes when heated, evolving toxic fumes. Causes burns to skin, eyes and mucous membranes. |
2823 |
|
|
2826
|
ETHYL CHLOROTHIOFORMATE |
8
|
3
P
|
II |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
Category A
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquid. Flashpoint: 29°C c.c. Causes burns to skin, eyes and mucous membranes. |
2826 |
|
|
2829
|
CAPROIC ACID |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
Oily, colourless or yellowish liquid. Melting point: −4°C. Partially miscible with water. Corrosive to mild steel. Causes burns to skin, eyes and mucous membranes. |
2829 |
|
|
2830
|
LITHIUM FERROSILICON |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
SW2
SW5
H1
|
SG26
|
Dark, crystalline, metal-like powder or brittle lumps. In contact with moisture, evolves flammable and toxic gases. |
2830 |
|
|
2831
|
1,1,1-TRICHLOROETHANE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
SW2
|
SGG10
|
Colourless liquid. Immiscible with water. Decomposes when heated, evolving highly toxic fumes (phosgene and hydrogen chloride). Toxic if swallowed, by skin contact or by inhalation. Narcotic in high concentrations. |
2831 |
|
|
2834
|
PHOSPHOROUS ACID |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
SW1
|
SGG1
SG36
SG49
|
Colourless to yellow deliquescent crystals. Soluble in water. Mildly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2834 |
|
|
2835
|
SODIUM ALUMINIUM HYDRIDE |
4.3
|
– |
II |
– |
500 g |
E0 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category E
H1
|
SG26
SG35
|
White, crystalline solid. Reacts with water, moisture or acids, evolving hydrogen, which may be ignited by the heat of the reaction. |
2835 |
|
|
2837
|
BISULPHATES, AQUEOUS SOLUTION |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category A
|
– |
Colourless to white liquid. Miscible with water. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2837 |
|
|
2837
|
BISULPHATES, AQUEOUS SOLUTION |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
|
– |
See entry above. |
2837 |
|
|
2838
|
VINYL BUTYRATE, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category C
SW1
|
– |
Colourless liquid with a pungent odour. Flashpoint: 12°C c.c. Explosive limits: 1.4% to 8.8%. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2838 |
|
|
2839
|
ALDOL |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW1
H2
|
– |
Clear, colourless to yellow viscous liquid. Miscible with water. Decomposes at 85°C, evolving toxic fumes. May react vigorously with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2839 |
|
|
2840
|
BUTYRALDOXIME |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Immiscible with water. Flashpoint: 58°C c.c. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2840 |
|
|
2841
|
DI-n-AMYLAMINE |
3
|
6.1
|
III |
– |
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category A
|
SG35
|
Colourless liquid with an ammoniacal odour. Flashpoint: 52°C c.c. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2841 |
|
|
2842
|
NITROETHANE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless, oily liquid. Flashpoint: 28°C c.c. Lower explosive limit: 3.4%. When involved in a fire, evolves nitrous toxic fumes. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. |
2842 |
|
|
2844
|
CALCIUM MANGANESE SILICON |
4.3
|
– |
III |
– |
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category A
SW5
H1
|
SG26
SG35
|
In contact with water, evolves hydrogen, a flammable gas. In contact with acid, evolves silane, a spontaneously flammable gas. |
2844 |
|
|
2845
|
PYROPHORIC LIQUID, ORGANIC, N.O.S. |
4.2
|
– |
I |
274
|
0 |
E0 |
P400
|
– |
– |
– |
|
– |
T22
|
TP2 TP7
|
F-G, S-M
|
Category D
H1
|
SG26
SG63
|
Highly flammable liquids, may ignite spontaneously in moist air. In contact with air, evolve irritating and slightly toxic fumes. |
2845 |
|
|
2846
|
PYROPHORIC SOLID, ORGANIC, N.O.S. |
4.2
|
– |
I |
274
|
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
Category D
H1
|
SG26
|
Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. |
2846 |
|
|
2849
|
3-CHLOROPROPANOL−1 |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Colourless to light-yellow liquid. Miscible with water. Mildly corrosive to steel. Toxic if swallowed, by skin contact or by inhalation. |
2849 |
|
|
2850
|
PROPYLENE TETRAMER |
3
|
–
P
|
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP2
|
F-E, S-E
|
Category A
|
– |
Colourless liquid. Immiscible with water. Irritating to skin, eyes and mucous membranes. 1-dodecene is not marine pollutant. |
2850 |
|
|
2851
|
BORON TRIFLUORIDE DIHYDRATE |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category B
SW1
SW2
H2
|
SGG1
SG36
SG49
|
Colourless, non-fuming liquid. Boiling range: 58°C to 60°C. Reacts with water, evolving corrosive and toxic fumes. Corrosive to mild steel. Causes burns to skin, eyes and mucous membranes. |
2851 |
|
|
2852
|
DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP24 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SG7
SG30
|
Desensitized explosive. Golden-yellow, crystalline leaflets. Explosive and sensitive to shock and heat in the dry state. May form extremely sensitive compounds with heavy metals or their salts. |
2852 |
|
|
2853
|
MAGNESIUM FLUOROSILICATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SG35
|
Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. |
2853 |
|
|
2854
|
AMMONIUM FLUOROSILICATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SGG2
SG35
|
Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. |
2854 |
|
|
2855
|
ZINC FLUOROSILICATE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SGG7
SG35
|
Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. |
2855 |
|
|
2856
|
FLUOROSILICATES, N.O.S. |
6.1
|
– |
III |
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SG35
|
Solids which react with acids, evolving hydrogen fluoride and silicon tetrafluoride, irritating and corrosive gases. Toxic if swallowed, by skin contact or by dust inhalation. |
2856 |
|
|
2857
|
REFRIGERATING MACHINES containing non-flammable, non-toxic, gases or ammonia solutions (UN 2672) |
2.2
|
– |
– |
119
|
0 |
E0 |
P003
|
PP32 |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
– |
2857 |
|
|
2858
|
ZIRCONIUM, DRY, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) |
4.1
|
– |
III |
921
|
5 kg |
E1 |
P002
LP02
|
PP100 L3 |
– |
– |
|
– |
– |
– |
F-G, S-G
|
Category A
H1
|
SG25
SG26
|
Hard silvery metal. |
2858 |
|
|
2859
|
AMMONIUM METAVANADATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG2
SG6
SG8
SG10
SG12
|
White crystalline powder. Slightly soluble in water. May act as an oxidizing substance. Toxic if swallowed, by skin contact or by inhalation. |
2859 |
|
|
2861
|
AMMONIUM POLYVANADATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG2
SG6
SG8
SG10
SG12
|
Orange powder. Slightly soluble in water. May act as an oxidizing substance. Toxic if swallowed, by skin contact or by inhalation. |
2861 |
|
|
2862
|
VANADIUM PENTOXIDE, non-fused form |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Brownish powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
2862 |
|
|
2863
|
SODIUM AMMONIUM VANADATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SGG2
|
Orange wet cake (with 10% to 15% water). Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2863 |
|
|
2864
|
POTASSIUM METAVANADATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
White crystalline powder. Slightly soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
2864 |
|
|
2865
|
HYDROXYLAMINE SULPHATE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG35
SG36
SG49
|
Colourless to white crystalline powder. Soluble in water. May decompose explosively when heated. Causes burns to skin, eyes and mucous membranes. |
2865 |
|
|
2869
|
TITANIUM TRICHLORIDE MIXTURE |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category A
SW2
|
SGG1
SGG7
SG36
SG49
|
Violet crystalline solid. Reacts in moist air or in water, evolving heat and hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
2869 |
|
|
2869
|
TITANIUM TRICHLORIDE MIXTURE |
8
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
SW2
|
SGG1
SGG7
SG36
SG49
|
See entry above. |
2869 |
|
|
2870
|
ALUMINIUM BOROHYDRIDE |
4.2
|
4.3
|
I |
– |
0 |
E0 |
P400
|
– |
– |
– |
|
– |
T21
|
TP7 TP33
|
F-G, S-M
|
Category D
H1
|
SG26
|
Liquid. Ignites spontaneously in air. Reacts with water or steam to produce heat or hydrogen, which may form explosive mixtures with air. |
2870 |
|
| △ |
2870
|
ALUMINIUM BOROHYDRIDE IN DEVICES |
4.2
|
4.3
|
– |
– |
0 |
E0 |
P002
|
PP13 |
– |
– |
|
– |
– |
– |
F-G, S-M
|
Category D
H1
|
SG26
|
– |
2870 |
△ |
|
2871
|
ANTIMONY POWDER |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Metallic antimony in the form of a fine grey powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2871 |
|
|
2872
|
DIBROMOCHLOROPROPANES |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SGG10
|
Colourless liquid with a perceptible odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2872 |
|
|
2872
|
DIBROMOCHLOROPROPANES |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
SGG10
|
See entry above. |
2872 |
|
|
2873
|
DIBUTYLAMINOETHANOL |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Colourless liquid with a perceptible odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2873 |
|
|
2874
|
FURFURYL ALCOHOL |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
SG17
SG35
|
Clear, colourless, mobile liquid, becoming brown to dark-red upon exposure to light and air. Miscible with water. Reacts explosively with oxidizing substances. Toxic if swallowed, by skin contact or by inhalation. |
2874 |
|
|
2875
|
HEXACHLOROPHENE |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
White, odourless powder or crystals. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2875 |
|
|
2876
|
RESORCINOL |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
White to pink crystals. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2876 |
|
|
2878
|
TITANIUM SPONGE GRANULES or TITANIUM SPONGE POWDERS |
4.1
|
– |
III |
223
|
5 kg |
E1 |
P002
LP02
|
PP100 L3 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-G
|
Category D
H1
|
SGG7
SGG15
SG17
SG25
SG26
|
Silvery grey granules or dark grey, amorphous powder. May react with carbon dioxide, evolving oxygen. Forms explosive mixtures with oxidizing substances. |
2878 |
|
|
2879
|
SELENIUM OXYCHLORIDE |
8
|
6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-A, S-B
|
Category E
SW2
|
SGG1
SG36
SG49
|
Colourless, yellowish liquid. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes. |
2879 |
|
|
2880
|
CALCIUM HYPOCHLORITE, HYDRATED or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16% water |
5.1
|
–
P
|
II |
314
322
|
1 kg |
E2 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White or yellowish solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. |
2880 |
|
|
2880
|
CALCIUM HYPOCHLORITE, HYDRATED or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16% water |
5.1
|
–
P
|
III |
223
314
|
5 kg |
E1 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
See entry above |
2880 |
|
|
2881
|
METAL CATALYST, DRY |
4.2
|
– |
I |
274
|
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
T21
|
TP7 TP33
|
F-G, S-M
|
Category C
H1
|
SGG7
SGG15
SG25
SG26
|
Liable to ignite spontaneously in air. |
2881 |
|
|
2881
|
METAL CATALYST, DRY |
4.2
|
– |
II |
274
|
0 |
E0 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-M
|
Category C
H1
|
SGG7
SGG15
SG25
SG26
|
See entry above. |
2881 |
|
|
2881
|
METAL CATALYST, DRY |
4.2
|
– |
III |
223
274
|
0 |
E1 |
P002
LP02
|
PP31 L4 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-M
|
Category C
H1
|
SGG7
SGG15
SG25
SG26
|
See entry above. |
2881 |
|
|
2900
|
INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only |
6.2
|
– |
– |
318
341
|
0 |
E0 |
P620
|
– |
– |
– |
|
– |
BK2
|
– |
F-A, S-T
|
Category E
SW2
H1
H5
|
SG50
|
Substances which are dangerous to animals only. For action to be taken in the event of damage to, or leaking from, a package containing infectious substances, refer to 7.8.3. |
2900 |
|
|
2901
|
BROMINE CHLORIDE |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
Reddish-yellow non-flammable, toxic and corrosive gas. When heated to decomposition, emits highly toxic and corrosive fumes of bromine and chlorine. Reacts with water, evolving toxic and corrosive fumes. Powerful oxidizing agent which may cause violent fires with combustible materials. Much heavier than air. Highly irritating to skin, eyes and mucous membranes. |
2901 |
|
|
2902
|
PESTICIDE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2902 |
|
|
2902
|
PESTICIDE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
2902 |
|
|
2902
|
PESTICIDE, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2902 |
|
|
2903
|
PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2903 |
|
|
2903
|
PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2903 |
|
|
2903
|
PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
2903 |
|
|
2904
|
CHLOROPHENOLATES, LIQUID or PHENOLATES, LIQUID |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-B
|
Category A
|
– |
A wide range of corrosive liquids. Cause burns to skin, eyes and mucous membranes. |
2904 |
|
|
2905
|
CHLOROPHENOLATES, SOLID or PHENOLATES, SOLID |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
– |
A wide range of corrosive solids. Soluble in water. Cause burns to skin, eyes and mucous membranes. |
2905 |
|
| △ |
2907 |
ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose, mannose, starch, or calcium hydrogen phosphate |
4.1
|
– |
II |
28
127
|
0 |
E0 |
P406
|
PP26 PP80 |
IBC06
|
B12 B21 |
|
– |
– |
– |
F-A, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Pure isosorbide dinitrate is explosive. May form extremely sensitive compounds with heavy metals or their salts. |
2907 |
△ |
|
2908
|
RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – EMPTY PACKAGING |
7
|
See SP290
|
– |
290
368
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
|
– |
See 1.5.1 and 5.1.5.4.2. |
2908 |
|
|
2909
|
RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM |
7
|
See SP290
|
– |
290
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
|
– |
See 1.5.1 and 5.1.5.4.2. |
2909 |
|
|
2910
|
RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – LIMITED QUANTITY OF MATERIAL |
7
|
See SP290
|
– |
290
368
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
|
– |
See 1.5.1 and 5.1.5.4.2. |
2910 |
|
|
2911
|
RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – INSTRUMENTS or ARTICLES |
7
|
See SP290
|
– |
290
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
|
– |
See 1.5.1 and 5.1.5.4.2. |
2911 |
|
|
2912
|
RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
T5
|
TP4
|
F-I, S-S
|
Category A
SW20
SW21
|
– |
See 1.5.1. |
2912 |
|
|
2913
|
RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I, SCO-II or SCO-III), non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
T5
|
TP4
|
F-I, S-S
|
Category A
|
– |
See 1.5.1. |
2913 |
|
|
2915
|
RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW20
SW21
|
– |
See 1.5.1. |
2915 |
|
|
2916
|
RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
2916 |
|
|
2917 |
RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
2917 |
|
|
2919
|
RADIOACTIVE MATERIAL TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW13
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
2919 |
|
|
2920 |
CORROSIVE LIQUID, FLAMMABLE, N.O.S. |
8
|
3
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-E, S-C
|
Category C
SW1
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. |
2920 |
|
|
2920 |
CORROSIVE LIQUID, FLAMMABLE, N.O.S. |
8
|
3
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-C
|
Category C
SW1
SW2
|
– |
See entry above. |
2920 |
|
|
2921
|
CORROSIVE SOLID, FLAMMABLE, N.O.S. |
8
|
4.1
|
I |
274
|
0 |
E0 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-G
|
Category B
SW1
H2
|
– |
Causes burns to skin, eyes and mucous membranes. |
2921 |
|
|
2921
|
CORROSIVE SOLID, FLAMMABLE, N.O.S. |
8
|
4.1
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
SW1
H2
|
– |
See entry above. |
2921 |
|
|
2922
|
CORROSIVE LIQUID, TOXIC, N.O.S. |
8
|
6.1
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-B
|
Category B
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. |
2922 |
|
|
2922
|
CORROSIVE LIQUID, TOXIC, N.O.S. |
8
|
6.1
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
2922 |
|
|
2922
|
CORROSIVE LIQUID, TOXIC, N.O.S. |
8
|
6.1
|
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
2922 |
|
|
2923
|
CORROSIVE SOLID, TOXIC, N.O.S. |
8
|
6.1
|
I |
274
|
0 |
E0 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation. |
2923 |
|
|
2923
|
CORROSIVE SOLID, TOXIC, N.O.S. |
8
|
6.1
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
2923 |
|
|
2923
|
CORROSIVE SOLID, TOXIC, N.O.S. |
8
|
6.1
|
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
2923 |
|
|
2924
|
FLAMMABLE LIQUID, CORROSIVE, N.O.S. |
3
|
8
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2
|
F-E, S-C
|
Category E
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. |
2924 |
|
|
2924
|
FLAMMABLE LIQUID, CORROSIVE, N.O.S. |
3
|
8
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-C
|
Category B
SW2
|
– |
See entry above. |
2924 |
|
|
2924
|
FLAMMABLE LIQUID, CORROSIVE, N.O.S. |
3
|
8
|
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-E, S-C
|
Category A
SW2
|
– |
See entry above. |
2924 |
|
|
2925
|
FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. |
4.1
|
8
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category D
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. |
2925 |
|
|
2925
|
FLAMMA align="center">FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. |
4.1
|
8
|
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category D
SW2
|
– |
See entry above. |
2925 |
|
|
2926
|
FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. |
4.1
|
6.1
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. |
2926 |
|
|
2926
|
FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. |
4.1
|
6.1
|
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category B
SW2
|
– |
See entry above. |
2926 |
|
|
2927
|
TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. |
6.1
|
8
|
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-B
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2927 |
|
|
2927
|
TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. |
6.1
|
8
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
2927 |
|
|
2928
|
TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. |
6.1
|
8
|
I |
274
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
2928 |
|
|
2928
|
TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. |
6.1
|
8
|
II |
274
|
500 g |
E4 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
2928 |
|
|
2929
|
TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. |
6.1
|
3
|
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
2929 |
|
|
2929
|
TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. |
6.1
|
3
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2929 |
|
|
2930
|
TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. |
6.1
|
4.1
|
I |
274
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-G
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
2930 |
|
|
2930
|
TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. |
6.1
|
4.1
|
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
|
– |
See entry above. |
2930 |
|
|
2931
|
VANADYL SULPHATE |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Blue, crystalline powder. Soluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
2931 |
|
|
2933
|
METHYL 2-CHLORO- PROPIONATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with an ether-like odour. Flashpoint: 32°C c.c. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. |
2933 |
|
|
2934
|
ISOPROPYL 2-CHLORO- PROPIONATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with a sweetish odour. Flashpoint: 50°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2934 |
|
|
2935
|
ETHYL 2-CHLOROPROPIONATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with a pungent odour. Flashpoint: 38°C c.c. Immiscible with water. Irritating to skin, eyes and mucous membranes. |
2935 |
|
|
2936
|
THIOLACTIC ACID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Oily liquid with a foul odour. Melting point: 10°C. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2936 |
|
|
2937
|
alpha-METHYLBENZYL ALCOHOL, LIQUID |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Colourless liquid. Slightly miscible with water. Melting point: 21°C (pure substance). Toxic if swallowed, by skin contact or by inhalation. |
2937 |
|
|
2940
|
9-PHOSPHABICYCLONONANES (CYCLOOCTADIENE-PHOSPHINES) |
4.2
|
– |
II |
– |
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category A
|
– |
Colourless, waxy solids. Melting point: 40°C to 60°C. React in contact with materials such as sawdust or other cellulose-based materials, resulting in charring and evolution of toxic fumes. Irritating to skin, eyes and mucous membranes. |
2940 |
|
|
2941
|
FLUOROANILINES |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Liquids. Freezing points: −28°C to −2°C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2941 |
|
|
2942
|
2-TRIFLUOROMETHYLANILINE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
- |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
Liquid. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2942 |
|
|
2943
|
TETRAHYDRO-FURFURYLAMINE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless to yellowish liquid with an ammoniacal odour. Flashpoint: 45°C c.c. Miscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2943 |
|
|
2945
|
N-METHYLBUTYLAMINE |
3
|
8
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1
|
F-E, S-C
|
Category B
SW2
|
SG35
|
Colourless liquid. Flashpoint: 0°C c.c. Miscible with water. Harmful by inhalation. Causes burns to skin and eyes. Irritating to mucous membranes. |
2945 |
|
|
2946
|
2-AMINO−5-DIETHYLAMINO-PENTANE |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Liquid with an acrid odour. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2946 |
|
|
2947
|
ISOPROPYL CHLOROACETATE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid with a pungent odour. Flashpoint: 56°C c.c. Slightly soluble in water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
2947 |
|
|
2948
|
3-TRIFLUOROMETHYLANILINE |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
SW2
|
– |
Colourless to yellowish liquid. Melting point: 5°C. Slightly miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
2948 |
|
|
2949
|
SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
Colourless needles or yellow flakes. Soluble in water with a foul odour. Melting point: 52°C. Reacts violently with acids, evolving hydrogen sulphide, a toxic and flammable gas. Causes burns to skin, eyes and mucous membranes. |
2949 |
|
|
2950
|
MAGNESIUM GRANULES, COATED, particle size not less than 149 microns |
4.3
|
– |
III |
920
|
1 kg |
E1 |
P410
|
PP100 |
IBC08
|
B4 |
|
– |
T1
BK2
|
TP33
|
F-G, S-O
|
Category A
H1
|
SGG15
SG26
SG35
|
Coated granules with particle size ranging from 149 to 2,000 microns. In contact with water or acids, evolve hydrogen, a flammable gas. |
2950 |
|
|
2956 |
5-tert-BUTYL−2,4,6-TRINITRO- m-XYLENE (MUSK XYLENE) |
4.1
|
– |
III |
133 |
0 |
E0 |
P409
|
– |
– |
– |
|
– |
– |
– |
F-B, S-G
|
Category D
SW1
SW2
SW11
H2
H3
|
SG1
|
Insoluble in water. May explode if involved in a fire under confined conditions. Sensitive to strong detonation shock. Harmful if swallowed or by skin contact. |
2956 |
△ |
|
2965 |
BORON TRIFLUORIDE DIMETHYL ETHERATE |
4.3
|
3/8
|
I |
– |
0 |
E0 |
P401
|
PP31 |
– |
– |
|
– |
T10
|
TP2 TP7 TP13
|
F-G, S-O
|
Category D
SW2
H1
|
SG5
SG8
SG13
SG25
SG26
|
Colourless, flammable liquid. Flashpoint: 20°C c.c. but widely variable, depending upon free ether content. Freezing point: −14°C. Decomposes in contact with water, forming dimethyl ether, a flammable gas. Causes burns to skin, eyes and mucous membranes. |
2965 |
|
|
2966
|
THIOGLYCOL |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Colourless liquid with a foul odour. Miscible with water. Decomposes when heated, evolving sulphur dioxide. Toxic if swallowed, by skin contact or by inhalation. |
2966 |
|
|
2967
|
SULPHAMIC ACID |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
White crystalline powder. Soluble in water. Decomposes when heated, evolving toxic fumes. Causes burns to skin, eyes and mucous membranes. |
2967 |
|
|
2968
|
MANEB, STABILIZED or MANEB PREPARATION, STABILIZED against self-heating |
4.3
|
–
P
|
III |
223
946
|
1 kg |
E1 |
P002
|
PP100 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-L
|
Category B
H1
|
SG26
SG29
SG35
|
Yellow powder. May evolve toxic, irritating or flammable fumes when wet, when involved in a fire or in contact with acids. Requires certification from the shipper that the substance is not class 4.2. |
2968 |
|
|
2969
|
CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE |
9
|
– |
II |
141
|
5 kg |
E2 |
P002
|
PP34 |
IBC08
|
B4 B21 |
|
– |
T3
BK2
|
TP33
|
F-A, S-A
|
Category E
SW2
|
SG10
SG18
SG29
|
Whole beans or meal. The latter is the residue remaining after the oil has been extracted from the seeds. Castor beans contain a powerful allergen which, by inhalation of dust or by skin contact with crushed bean products, can give rise to severe irritation of the skin, eyes and mucous membranes in some persons. They are also toxic by ingestion. When handling these products, wear at least a dust mask and goggles. Avoid unnecessary skin contact. |
2969 |
|
|
2977
|
RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE |
7
|
6.1/8
|
– |
– |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category B
SW2
SW12
|
SG17
SG76
SG78
|
See 1.5.1. |
2977 |
|
|
2978
|
RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE non fissile or fissile-excepted |
7
|
6.1/8
|
– |
317
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category B
SW2
SW12
|
SG17
SG76
SG78
|
See 1.5.1. |
2978 |
|
|
2983
|
ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE with not more than 30% ethylene oxide |
3
|
6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7 TP13
|
F-E, S-D
|
Category E
SW1
SW2
|
– |
Colourless, volatile liquid with an ethereal odour. Flashpoint: below −18°C c.c. Explosive limits: 2.2% to 55%. Boiling point: 23°C to 28°C. Miscible with water. Corrosive to aluminium. Toxic if swallowed, by skin contact or by inhalation. Irritating to eyes and mucous membranes. |
2983 |
|
|
2984
|
HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) |
5.1
|
– |
III |
65
|
5 L |
E1 |
P504
|
– |
IBC02
|
B5 |
|
– |
T4
|
TP1 TP6 TP24
|
F-H, S-Q
|
Category B
SW1
|
SG16
SG59
SG72
|
Colourless liquid. Slowly decomposes, evolving oxygen; the rate of decomposition increases in contact with metals, except aluminium. |
2984 |
|
|
2985
|
CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. |
3
|
8
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T14
|
TP2 TP7 TP13 TP27
|
F-E, S-C
|
Category B
SW2
|
SGG1
SG36
SG49
|
Colourless liquids with a pungent odour. When involved in a fire, evolve toxic gases. React violently with water, evolving hydrogen chloride, an irritating and corrosive gas. In the presence of moisture, highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. |
2985 |
|
|
2986
|
CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. |
8
|
3
|
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T14
|
TP2 TP7 TP13 TP27
|
F-E, S-C
|
Category C
SW2
|
SGG1
SG36
SG49
|
Colourless, flammable liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. |
2986 |
|
|
2987
|
CHLOROSILANES, CORROSIVE, N.O.S. |
8
|
– |
II |
– |
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T14
|
TP2 TP7 TP13 TP27
|
F-A, S-B
|
Category C
SW2
|
SGG1
SG36
SG49
|
Colourless liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gases. In the presence of moisture, highly corrosive to most metals. Cause burns to skin, eyes and mucous membranes. |
2987 |
|
|
2988
|
CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S. |
4.3
|
3/8
|
I |
– |
0 |
E0 |
P401
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP7 TP13
|
F-G, S-N
|
Category D
SW2
H1
|
SGG1
SG5
SG8
SG13
SG25
SG26
SG36
SG49
|
Colourless, very volatile liquids, flammable and corrosive, with a pungent odour. Immiscible with water. React violently with water or steam to produce heat which may lead to self-ignition; toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Cause burns to skin, eyes and mucous membranes. |
2988 |
|
|
2989
|
LEAD PHOSPHITE, DIBASIC |
4.1
|
– |
II |
922
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
|
SGG7
SGG9
SG29
|
Fine white crystals or powder. Insoluble in water. Combustion can be sustained, even in the absence of air. Harmful if swallowed. |
2989 |
|
|
2989
|
LEAD PHOSPHITE, DIBASIC |
4.1
|
– |
III |
922
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category B
|
SGG7
SGG9
SG29
|
See entry above. |
2989 |
|
|
2990
|
LIFE-SAVING APPLIANCES, SELF-INFLATING |
9
|
– |
– |
296
|
0 |
E0 |
P905
|
– |
– |
– |
|
– |
– |
– |
F-A, S-V
|
Category A
|
SG18
SG71
|
These articles may contain: .1 class 2.2 compressed gases; .2 signal devices (class 1) which may include smoke and illumination signal flares; signal devices must be packed in plastic or fibreboard inner packagings; .3 electric storage batteries; .4 first aid kit; or .5 “strike anywhere” matches. |
2990 |
|
|
2991
|
CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2991 |
|
|
2991
|
CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2991 |
|
|
2991
|
CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
2991 |
|
|
2992
|
CARBAMATE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2992 |
|
|
2992
|
CARBAMATE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
2992 |
|
|
2992
|
CARBAMATE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2992 |
|
|
2993
|
ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2993 |
|
|
2993
|
ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2993 |
|
|
2993
|
ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
2993 |
|
|
2994
|
ARSENICAL PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2994 |
|
|
2994
|
ARSENICAL PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
2994 |
|
|
2994
|
ARSENICAL PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2994 |
|
|
2995
|
ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
It frequently contains petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2995 |
|
|
2995
|
ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2995 |
|
|
2995
|
ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
2995 |
|
|
2996
|
ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2996 |
|
|
2996
|
ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
2996 |
|
|
2996
|
ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2996 |
|
|
2997
|
TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
It frequently contains petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2997 |
|
|
2997
|
TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
2997 |
|
|
2997
|
TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
2997 |
|
|
2998
|
TRIAZINE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See alphabetical index to identify those pesticides which are marine pollutants. Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
2998 |
|
|
2998
|
TRIAZINE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
2998 |
|
|
2998
|
TRIAZINE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
2998 |
|
|
3005
|
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3005 |
|
|
3005
|
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3005 |
|
|
3005
|
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3005 |
|
|
3006
|
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3006 |
|
|
3006
|
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3006 |
|
|
3006
|
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3006 |
|
|
3009
|
COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3009 |
|
|
3009
|
COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3009 |
|
|
3009
|
COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3009 |
|
|
3010
|
COPPER BASED PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3010 |
|
|
3010
|
COPPER BASED PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3010 |
|
|
3010
|
COPPER BASED PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3010 |
|
|
3011
|
MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
P
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
SGG7
SGG11
|
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3011 |
|
|
3011
|
MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
P
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
SGG7
SGG11
|
See entry above. |
3011 |
|
|
3011
|
MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
P
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
SGG7
SGG11
|
See entry above. |
3011 |
|
|
3012
|
MERCURY BASED PESTICIDE, LIQUID, TOXIC |
6.1
|
–
P
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
SGG7
SGG11
|
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3012 |
|
|
3012
|
MERCURY BASED PESTICIDE, LIQUID, TOXIC |
6.1
|
–
P
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
SGG7
SGG11
|
See entry above. |
3012 |
|
|
3012
|
MERCURY BASED PESTICIDE, LIQUID, TOXIC |
6.1
|
–
P
|
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
SGG7
SGG11
|
See entry above. |
3012 |
|
|
3013
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3013 |
|
|
3013
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3013 |
|
|
3013
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3013 |
|
|
3014
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3014 |
|
|
3014
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3014 |
|
|
3014
|
SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3014 |
|
|
3015
|
BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3015 |
|
|
3015
|
BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3015 |
|
|
3015
|
BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3015 |
|
|
3016
|
BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3016 |
|
|
3016
|
BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3016 |
|
|
3016
|
BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3016 |
|
|
3017
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3017 |
|
|
3017
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3017 |
|
|
3017
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3017 |
|
|
3018
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3018 |
|
|
3018
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3018 |
|
|
3018
|
ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3018 |
|
|
3019
|
ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
P
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3019 |
|
|
3019
|
ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
P
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3019 |
|
|
3019
|
ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
P
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3019 |
|
|
3020
|
ORGANOTIN PESTICIDE, LIQUID, TOXIC |
6.1
|
–
P
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3020 |
|
|
3020
|
ORGANOTIN PESTICIDE, LIQUID, TOXIC |
6.1
|
–
P
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3020 |
|
|
3020
|
ORGANOTIN PESTICIDE, LIQUID, TOXIC |
6.1
|
–
P
|
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3020 |
|
|
3021
|
PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3021 |
|
|
3021
|
PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3021 |
|
|
3022
|
1,2-BUTYLENE OXIDE, STABILIZED |
3
|
– |
II |
386
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category C
SW1
|
SG20
SG21
|
Colourless liquid. Flashpoint: −15°C c.c. Explosive limits: 1.5% to 18.3%. Reacts violently with acids, alkalis and oxidizers. Miscible with water. Harmful if swallowed or by inhalation. Irritating to skin, eyes and mucous membranes. |
3022 |
|
|
3023
|
2-METHYL−2-HEPTANETHIOL |
6.1
|
3
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
SG57
|
Colourless flammable liquid with a foul odour. Flashpoint: 31°C c.c. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. |
3023 |
|
|
3024
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3024 |
|
|
3024
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3024 |
|
|
3025
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Liquid flammable pesticides having a flashpoint between 23°C and 60°C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3025 |
|
|
3025
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3025 |
|
|
3025
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3025 |
|
|
3026
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3026 |
|
|
3026
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3026 |
|
|
3026
|
COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3026 |
|
|
3027
|
COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
3027 |
|
|
3027
|
COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3027 |
|
|
3027
|
COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3027 |
|
|
3028
|
BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE, SOLID electric storage |
8
|
– |
III |
295
304
|
5 kg |
E0 |
P801
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
Category A
|
SGG18
SG35
|
Series of metal plates immersed in dry potassium hydroxide in a closed receptacle. When electrically charged, may cause fire through short-circuiting of terminals. Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label. Used batteries being transported for disposal or reclamation should be carefully checked prior to shipment to ensure the integrity of each battery and its suitability for transport. React violently with acids. |
3028 |
|
|
3048
|
ALUMINIUM PHOSPHIDE PESTICIDE |
6.1
|
– |
I |
153
930
|
0 |
E0 |
P002
|
PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category E
SW2
SW5
|
– |
Waxed pellets, adequately stabilized powder, tablets or crystals. Highly toxic if swallowed, by skin contact or by inhalation. |
3048 |
|
|
3054
|
CYCLOHEXYL MERCAPTAN |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
SW2
|
SG50
SG57
|
Colourless liquid with a garlic-like odour. Flashpoint: 49°C c.c. Immiscible with water. Harmful by inhalation. Irritating to skin, eyes and mucous membranes. |
3054 |
|
|
3055
|
2-(2-AMINOETHOXY)ETHANOL |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
|
SG35
|
Colourless, slightly viscous liquid with a mild odour. Miscible with water. Harmful if swallowed or by inhalation. Corrosive to skin, eyes and mucous membranes. |
3055 |
|
|
3056
|
n-HEPTALDEHYDE |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless or pale yellow, oily liquid with a pungent odour. Flashpoint: 35°C to 45°C c.c. Explosive limits: 1.1% to 5.2%. Slightly soluble in water. Irritating to skin, eyes and mucous membranes. |
3056 |
|
|
3057
|
TRIFLUOROACETYL CHLORIDE |
2.3
|
8
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
TP21
|
F-C, S-U
|
Category D
SW2
|
– |
Liquefied, non-flammable, toxic and corrosive gas. Reacts with water. Corrosive to glass and to most metals, including steel. Heavier than air (1.4 at 20°C). Highly irritating to skin, eyes and mucous membranes. |
3057 |
|
|
3064 |
NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin |
3
|
– |
II |
28
359
|
0 |
E0 |
P300
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category E
|
– |
Immiscible with water. Ignites readily. When involved in a fire, evolves toxic nitrous fumes. Not explosive in this state but damage to, or leakage from, a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. |
3064 |
△ |
|
3065
|
ALCOHOLIC BEVERAGES, with more than 70% alcohol by volume |
3
|
– |
II |
– |
5 L |
E2 |
P001
|
PP2 |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category A
|
– |
Aqueous solutions of ethanol produced and supplied as alcoholic beverages. Miscible with water. Flashpoint: −13°C c.c. or greater. |
3065 |
|
|
3065
|
ALCOHOLIC BEVERAGES, with more than 24% but not more than 70% alcohol by volume |
3
|
– |
III |
144
145
247
|
5 L |
E1 |
P001
|
PP2 |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Alcoholic beverages containing more than 24% alcohol but not more than 70% by volume, when transported as part of the manufacturing process, may be transported in wooden barrels with a capacity of more than 250 L and not more than 500 L meeting the general requirements of 4.1.1, as appropriate, on the following conditions: .1 the wooden barrels should be checked and tightened before filling; .2 sufficient ullage (not less than 3%) should be left to allow for the expansion of the liquid; .3 the wooden barrels should be transported with the bungholes pointing upwards; .4 the wooden barrels should be transported in containers meeting the requirements of the International Convention for Safe Containers, 1972 (CSC Convention), as amended. Each wooden barrel should be secured in custom-made cradles and should be wedged by appropriate means to prevent them from being displaced in any way during transport; and .5 when carried on board ships, the containers should be stowed in open cargo spaces or in enclosed cargo spaces complying with the requirements for class 3 flammable liquids with a flashpoint of 23°C c.c. or less in regulation II−2/19 of SOLAS, 74, as amended. |
3065 |
|
|
3066
|
PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) |
8
|
– |
II |
163
367
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-B
|
Category B
SW2
|
– |
Corrosive content. Causes burns to skin, eyes and mucous membranes. |
3066 |
|
|
3066
|
PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound) |
8
|
– |
III |
163
223
367
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-A, S-B
|
Category A
SW2
|
– |
Corrosive content. Causes burns to skin, eyes and mucous membranes. |
3066 |
|
|
3070
|
ETHYLENE OXIDE AND DICHLORODIFLUORO-METHANE MIXTURE with not more than 12.5% ethylene oxide |
2.2
|
– |
– |
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas. Much heavier than air. |
3070 |
|
|
3071
|
MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. |
6.1
|
3
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category C
SW2
|
SG57
|
Colourless to yellow flammable liquids with a garlic odour. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
3071 |
|
|
3072
|
LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment |
9
|
– |
– |
296 |
0 |
E0 |
P905
|
– |
– |
– |
|
– |
– |
– |
F-A, S-V
|
Category A
|
SG18
SG71
|
These articles may contain: .1 class 2.2 compressed gases; .2 signal devices (class 1) which may include smoke and illumination signal flares; signal devices must be packed in plastic or fibreboard inner packagings; .3 electric storage batteries; .4 first aid kit; or .5 “strike anywhere” matches. |
3072 |
|
|
3073
|
VINYLPYRIDINES, STABILIZED |
6.1
|
3/8
|
II |
386
|
100 mL |
E4 |
P001
|
– |
IBC01
|
– |
|
– |
T7
|
TP2 TP13
|
F-E, S-C
|
Category C
SW1
SW2
|
SGG18
SG5
SG8
SG35
|
Colourless to straw-coloured flammable liquids. Flashpoint: 42°C to 51°C c.c. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. React violently with acids. |
3073 |
|
| △ |
3077 |
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. |
9
|
– |
III |
274
335
375
966
967
969
|
5 kg |
E1 |
P002
LP02
|
PP12 |
IBC08
|
B3 |
|
– |
T1
BK1
BK2
BK3
|
TP33
|
F-A, S-F
|
Category A
SW23
|
– |
– |
3077 |
△ |
|
3078
|
CERIUM, turnings or gritty powder |
4.3
|
– |
II |
– |
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-O
|
Category E
H1
|
SGG15
SG26
SG35
|
Grey, ductile metal or powder. Decomposes in water and reacts violently with acids, evolving hydrogen, which may be ignited by the heat of the reaction. |
3078 |
|
|
3079
|
METHACRYLONITRILE, STABILIZED |
6.1
|
3
|
I |
354
386
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW1
SW2
|
– |
Colourless, mobile liquid with a pungent odour. Flashpoint: 4°C c.c. Explosive limits: 3% to 17%. Partially miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Practice has shown that this substance may leak from packagings that ordinarily are leakproof to other chemicals. |
3079 |
|
|
3080
|
ISOCYANATES, TOXIC, FLAMMABLE, N.O.S or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. |
6.1
|
3
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category D
SW1
SW2
|
– |
Flammable liquids or solutions with a pungent odour. Immiscible with or insoluble in water, but react with it to form carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
3080 |
|
| △ |
3082 |
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
9
|
– |
III |
274
335
375
966
967
969
|
5 L |
E1 |
P001
LP01
|
PP1 |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-A, S-F
|
Category A
|
– |
– |
3082 |
△ |
|
3083
|
PERCHLORYL FLUORIDE |
2.3
|
5.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
– |
Non-flammable, toxic, colourless gas with a characteristic sweet odour. Strong oxidizing agent; may cause fire in contact with organic materials. Reacts with water or moist air to produce toxic and corrosive fumes. Mixtures with oils or combustible materials may explode. Much heavier than air (3.6). Irritating to skin, eyes and mucous membranes. |
3083 |
|
|
3084
|
CORROSIVE SOLID, OXIDIZING, N.O.S. |
8
|
5.1
|
I |
274
|
0 |
E0 |
P002
|
– |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-Q
|
Category C
|
– |
Causes burns to skin, eyes and mucous membranes. |
3084 |
|
|
3084
|
CORROSIVE SOLID, OXIDIZING, N.O.S. |
8
|
5.1
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category C
|
– |
See entry above. |
3084 |
|
|
3085
|
OXIDIZING SOLID, CORROSIVE, N.O.S. |
5.1
|
8
|
I |
274
|
0 |
E0 |
P503
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
Category D
H1
|
SG38
SG49
SG60
|
Causes burns to skin, eyes and mucous membranes. Particular care in handling should be exercised if packages have become wetted. |
3085 |
|
|
3085
|
OXIDIZING SOLID, CORROSIVE, N.O.S. |
5.1
|
8
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category B
H1
|
SG38
SG49
SG60
|
See entry above. |
3085 |
|
|
3085
|
OXIDIZING SOLID, CORROSIVE, N.O.S. |
5.1
|
8
|
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category B
H1
|
SG38
SG49
SG60
|
See entry above. |
3085 |
|
|
3086
|
TOXIC SOLID, OXIDIZING, N.O.S. |
6.1
|
5.1
|
I |
274
|
0 |
E5 |
P002
|
– |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-Q
|
Category C
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3086 |
|
|
3086
|
TOXIC SOLID, OXIDIZING, N.O.S. |
6.1
|
5.1
|
II |
274
|
500 g |
E4 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category C
|
– |
See entry above. |
3086 |
|
|
3087
|
OXIDIZING SOLID, TOXIC, N.O.S. |
5.1
|
6.1
|
I |
274
900
|
0 |
E0 |
P503
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
Category D
|
SG38
SG49
SG60
|
Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. |
3087 |
|
|
3087
|
OXIDIZING SOLID, TOXIC, N.O.S. |
5.1
|
6.1
|
II |
274
900
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
|
See entry above. |
3087 |
|
|
3087
|
OXIDIZING SOLID, TOXIC, N.O.S. |
5.1
|
6.1
|
III |
223
274
900
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
|
See entry above. |
3087 |
|
|
3088
|
SELF-HEATING SOLID, ORGANIC, N.O.S. |
4.2
|
– |
II |
274
|
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category C
|
– |
Liable to self-heating or spontaneous combustion. |
3088 |
|
|
3088
|
SELF-HEATING SOLID, ORGANIC, N.O.S. |
4.2
|
– |
III |
223
274
|
0 |
E1 |
P002
LP02
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category C
|
– |
See entry above. |
3088 |
|
|
3089
|
METAL POWDER, FLAMMABLE, N.O.S. |
4.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
PP100 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-G
|
Category B
H1
|
SGG7
SGG15
SG17
SG25
SG26
|
– |
3089 |
|
|
3089
|
METAL POWDER, FLAMMABLE, N.O.S. |
4.1
|
– |
III |
223
|
5 kg |
E1 |
P002
|
PP100 |
IBC08
|
B4 B21 |
|
– |
T1
|
TP33
|
F-G, S-G
|
Category A
H1
|
SGG7
SGG15
SG17
SG25
SG26
|
– |
3089 |
|
| △ |
3090 |
LITHIUM METAL BATTERIES (including lithium alloy batteries) |
9
|
– |
– |
188
230
310
377
384
387
|
0 |
E0 |
P903
P908
P909
P910
P911
LP903
LP904
LP905
LP906
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
SW19
|
– |
Electrical batteries containing lithium metal may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. |
3090 |
△ |
| △ |
3091 |
LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) |
9
|
– |
– |
188
230
310
360
376
377
384
387
390
|
0 |
E0 |
P903
P908
P909
P910
P911
LP903
LP904
LP905
LP906
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
SW19
|
– |
Electrical batteries containing lithium metal may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. |
3091 |
△ |
|
3092
|
1-METHOXY−2-PROPANOL |
3
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T2
|
TP1
|
F-E, S-D
|
Category A
|
– |
Colourless liquid. Flashpoint: 29°C to 35°C c.c. Explosive limits: 1.7% to 11.5%. Miscible with water. Reacts with strong oxidizing substances. Irritating to skin, eyes and mucous membranes. |
3092 |
|
|
3093
|
CORROSIVE LIQUID, OXIDIZING, N.O.S. |
8
|
5.1
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
Category C
|
– |
Causes burns to skin, eyes and mucous membranes. |
3093 |
|
|
3093
|
CORROSIVE LIQUID, OXIDIZING, N.O.S. |
8
|
5.1
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category C
|
– |
See entry above. |
3093 |
|
|
3094
|
CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. |
8
|
4.3
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
Category D
H1
|
SG26
|
Causes burns to skin, eyes and mucous membranes. |
3094 |
|
|
3094
|
CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. |
8
|
4.3
|
II |
274
|
500 mL |
E2 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
Category D
H1
|
SG26
|
See entry above. |
3094 |
|
|
3095
|
CORROSIVE SOLID, SELF-HEATING, N.O.S. |
8
|
4.2
|
I |
274
|
0 |
E0 |
P002
|
– |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-N
|
Category D
|
– |
Causes burns to skin, eyes and mucous membranes. |
3095 |
|
|
3095
|
CORROSIVE SOLID, SELF-HEATING, N.O.S. |
8
|
4.2
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-N
|
Category D
|
– |
See entry above. |
3095 |
|
|
3096
|
CORROSIVE SOLID, WATER-REACTIVE, N.O.S. |
8
|
4.3
|
I |
274
|
0 |
E0 |
P002
|
– |
– |
– |
|
– |
T6
|
TP33
|
F-G, S-L
|
Category D
H1
|
SG26
|
Causes burns to skin, eyes and mucous membranes. |
3096 |
|
|
3096
|
CORROSIVE SOLID, WATER-REACTIVE, N.O.S. |
8
|
4.3
|
II |
274
|
1 kg |
E2 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-L
|
Category D
H1
|
SG26
|
See entry above. |
3096 |
|
|
3097
|
FLAMMABLE SOLID, OXIDIZING, N.O.S. |
4.1
|
5.1
|
II |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
– |
– |
– |
3097 |
|
|
3097
|
FLAMMABLE SOLID, OXIDIZING, N.O.S. |
4.1
|
5.1
|
III |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
T1
|
TP33
|
F-A, S-Q
|
– |
– |
– |
3097 |
|
|
3098
|
OXIDIZING LIQUID, CORROSIVE, N.O.S. |
5.1
|
8
|
I |
274
|
0 |
E0 |
P502
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
Category D
H1
|
SG38
SG49
SG60
|
Causes burns to skin, eyes and mucous membranes. Particular care in handling should be exercised if packages have become wetted. |
3098 |
|
|
3098
|
OXIDIZING LIQUID, CORROSIVE, N.O.S. |
5.1
|
8
|
II |
274
|
1 L |
E2 |
P504
|
– |
IBC01
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category B
H1
|
SG38
SG49
SG60
|
See entry above. |
3098 |
|
|
3098
|
OXIDIZING LIQUID, CORROSIVE, N.O.S. |
5.1
|
8
|
III |
223
274
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category B
H1
|
SG38
SG49
SG60
|
See entry above. |
3098 |
|
|
3099
|
OXIDIZING LIQUID, TOXIC, N.O.S. |
5.1
|
6.1
|
I |
274
|
0 |
E0 |
P502
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
Category D
|
SG38
SG49
SG60
|
Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. |
3099 |
|
|
3099
|
OXIDIZING LIQUID, TOXIC, N.O.S. |
5.1
|
6.1
|
II |
274
|
1 L |
E2 |
P504
|
– |
IBC01
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
|
See entry above. |
3099 |
|
|
3099
|
OXIDIZING LIQUID, TOXIC, N.O.S. |
5.1
|
6.1
|
III |
223
274
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
|
See entry above. |
3099 |
|
|
3100
|
OXIDIZING SOLID, SELF-HEATING, N.O.S. |
5.1
|
4.2
|
I |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
– |
– |
– |
3100 |
|
|
3100
|
OXIDIZING SOLID, SELF-HEATING, N.O.S. |
5.1
|
4.2
|
II |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
– |
– |
– |
3100 |
|
|
3101
|
ORGANIC PEROXIDE TYPE B, LIQUID |
5.2
|
See SP181
|
– |
122
181
195
274
|
25 mL |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG1
SG35
SG36
SG72
|
May explode at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3101 |
|
|
3102
|
ORGANIC PEROXIDE TYPE B, SOLID |
5.2
|
See SP181
|
– |
122
181
195
274
|
100 g |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG1
SG35
SG36
SG72
|
May explode at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Addition of water to disuccinic acid peroxide will decrease its thermal stability. May evolve irritant or toxic fumes. |
3102 |
|
|
3103
|
ORGANIC PEROXIDE TYPE C, LIQUID |
5.2
|
– |
– |
122
195
274
|
25 mL |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
May decompose violently at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for tert-butyl hydroperoxide. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3103 |
|
|
3104
|
ORGANIC PEROXIDE TYPE C, SOLID |
5.2
|
– |
– |
122
195
274
|
100 g |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
May decompose violently at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3104 |
|
|
3105
|
ORGANIC PEROXIDE TYPE D, LIQUID |
5.2
|
– |
– |
122
274
|
125 mL |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for acetylacetone peroxide, tert-butyl hydroperoxide and peroxyacetic acid, Type D, stabilized. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3105 |
|
|
3106
|
ORGANIC PEROXIDE TYPE D, SOLID |
5.2
|
– |
– |
122
274
|
500 g |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water except for 3-chloroperoxybenzoic acid. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3106 |
|
|
3107
|
ORGANIC PEROXIDE TYPE E, LIQUID |
5.2
|
– |
– |
122
274
|
125 mL |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for tert-amyl hydroperoxide, and tert-butyl hydroperoxide and peroxyacetic acid, Type E, stabilized. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3107 |
|
|
3108
|
ORGANIC PEROXIDE TYPE E, SOLID |
5.2
|
– |
– |
122
274
|
500 g |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3108 |
|
|
3109
|
ORGANIC PEROXIDE TYPE F, LIQUID |
5.2
|
– |
– |
122
274
|
125 mL |
E0 |
P520
|
– |
IBC520
|
– |
|
– |
T23
|
– |
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water except for tert-butyl hydroperoxide; dibenzoyl peroxide; dilauroyl peroxide and peroxyacetic acid, Type F, stabilized. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3109 |
|
|
3110
|
ORGANIC PEROXIDE TYPE F, SOLID |
5.2
|
– |
– |
122
274
|
500 g |
E0 |
P520
|
– |
IBC520
|
– |
|
– |
T23
|
TP33
|
F-J, S-R
|
Category D
SW1
|
SG35
SG36
SG72
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. May evolve irritant or toxic fumes. |
3110 |
|
|
3111
|
ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED |
5.2
|
See SP181
|
– |
122
181
195
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG1
SG35
SG36
SG72
|
May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3111 |
|
|
3112
|
ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED |
5.2
|
See SP181
|
– |
122
181
195
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG1
SG35
SG36
SG72
|
May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3112 |
|
|
3113
|
ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
195
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
May decompose violently at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3113 |
|
|
3114
|
ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
195
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
May decompose violently at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3114 |
|
|
3115
|
ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3115 |
|
|
3116
|
ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water except for diperoxyazelaic acid. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3116 |
|
|
3117
|
ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3117 |
|
|
3118
|
ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water except for di-(2-ethylhexyl) peroxydicarbonate. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3118 |
|
|
3119
|
ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
274
923
|
0 |
E0 |
P520
|
– |
IBC520
|
– |
|
– |
T23
|
– |
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water except for di-(4-tert-butylcyclohexyl) peroxydicarbonate, dicetyl peroxydicarbonate and dimyristyl peroxydicarbonate. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3119 |
|
|
3120
|
ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED |
5.2
|
– |
– |
122
274
923
|
0 |
E0 |
P520
|
– |
IBC520
|
– |
|
– |
T23
|
TP33
|
F-F, S-R
|
Category D
SW1
SW3
|
SG35
SG36
SG72
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in the table 2.5.3.2.4. The temperature should be checked regularly. May evolve irritant or toxic fumes. |
3120 |
|
|
3121
|
OXIDIZING SOLID, WATER-REACTIVE, N.O.S. |
5.1
|
4.3
|
I |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
H1
|
SG26
|
– |
3121 |
|
|
3121
|
OXIDIZING SOLID, WATER-REACTIVE, N.O.S. |
5.1
|
4.3
|
II |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
H1
|
SG26
|
– |
3121 |
|
|
3122
|
TOXIC LIQUID, OXIDIZING, N.O.S. |
6.1
|
5.1
|
I |
274
315
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
Category C
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3122 |
|
|
3122
|
TOXIC LIQUID, OXIDIZING, N.O.S. |
6.1
|
5.1
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category C
|
– |
See entry above. |
3122 |
|
|
3123
|
TOXIC LIQUID, WATER-REACTIVE, N.O.S. |
6.1
|
4.3
|
I |
274
315
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category D
SW2
H1
|
SG26
|
Toxic if swallowed, by skin contact or by inhalation. |
3123 |
|
|
3123
|
TOXIC LIQUID, WATER-REACTIVE, N.O.S. |
6.1
|
4.3
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-G, S-N
|
Category D
SW2
H1
|
SG26
|
See entry above. |
3123 |
|
|
3124
|
TOXIC SOLID, SELF-HEATING, N.O.S. |
6.1
|
4.2
|
I |
274
|
0 |
E5 |
P002
|
– |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-J
|
Category D
SW2
|
– |
Highly toxic if swallowed, by skin contact or by inhalation. |
3124 |
|
|
3124
|
TOXIC SOLID, SELF-HEATING, N.O.S. |
6.1
|
4.2
|
II |
274
|
0 |
E4 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category D
SW2
|
– |
See entry above. |
3124 |
|
|
3125
|
TOXIC SOLID, WATER-REACTIVE, N.O.S. |
6.1
|
4.3
|
I |
274
|
0 |
E5 |
P099
|
– |
– |
– |
|
– |
T6
|
TP33
|
F-G, S-N
|
Category D
SW2
H1
|
SG26
|
Toxic if swallowed, by skin contact or by inhalation. |
3125 |
|
|
3125
|
TOXIC SOLID, WATER-REACTIVE, N.O.S. |
6.1
|
4.3
|
II |
274
|
500 g |
E4 |
P002
|
PP100 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category D
SW2
H1
|
SG26
|
See entry above. |
3125 |
|
|
3126
|
SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. |
4.2
|
8
|
II |
274
|
0 |
E2 |
P410
|
– |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3126 |
|
|
3126
|
SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. |
4.2
|
8
|
III |
223
274
|
0 |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3126 |
|
|
3127
|
SELF-HEATING SOLID, OXIDIZING, N.O.S. |
4.2
|
5.1
|
II |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
T3
|
TP33
|
F-A, S-J
|
– |
– |
– |
3127 |
|
|
3127
|
SELF-HEATING SOLID, OXIDIZING, N.O.S. |
4.2
|
5.1
|
III |
223
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
T1
|
TP33
|
F-A, S-J
|
– |
– |
– |
3127 |
|
|
3128
|
SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. |
4.2
|
6.1
|
II |
274
|
0 |
E2 |
P410
|
– |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3128 |
|
|
3128
|
SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. |
4.2
|
6.1
|
III |
223
274
|
0 |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3128 |
|
|
3129
|
WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. |
4.3
|
8
|
I |
274
|
0 |
E0 |
P402
|
– |
– |
|
– |
– |
T14
|
TP2 TP7 TP13
|
F-G, S-N
|
Category D
H1
|
SG26
|
– |
3129 |
|
| △ |
3129
|
WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. |
4.3
|
8
|
II |
274
|
0 |
E0 |
P402
|
– |
IBC01
|
– |
|
– |
T11
|
TP2 TP7
|
F-G, S-N
|
Category D
SW31
H1
|
SG26
|
– |
3129 |
△ |
| △ |
3129
|
WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. |
4.3
|
8
|
III |
223
274
|
0 |
E1 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP7
|
F-G, S-N
|
Category D
SW31
H1
|
SG26
|
– |
3129 |
△ |
|
3130
|
WATER-REACTIVE LIQUID, TOXIC, N.O.S. |
4.3
|
6.1
|
I |
274
|
0 |
E0 |
P402
|
– |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SG26
|
– |
3130 |
|
| △ |
3130
|
WATER-REACTIVE LIQUID, TOXIC, N.O.S. |
4.3
|
6.1
|
II |
274
|
0 |
E0 |
P402
|
– |
IBC01
|
– |
– |
|
– |
– |
F-G, S-N
|
Category D
SW31
H1
|
SG26
|
– |
3130 |
△ |
| △ |
3130
|
WATER-REACTIVE LIQUID, TOXIC, N.O.S. |
4.3
|
6.1
|
III |
223
274
|
0 |
E1 |
P001 |
– |
IBC02
|
– |
– |
|
– |
– |
F-G, S-N
|
Category D
SW31
H1
|
SG26
|
– |
3130 |
△ |
|
3131
|
WATER-REACTIVE SOLID, CORROSIVE, N.O.S. |
4.3
|
8
|
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33
|
F-G, S-L
|
Category D
H1
|
SG26
|
– |
3131 |
|
|
3131
|
WATER-REACTIVE SOLID, CORROSIVE, N.O.S. |
4.3
|
8
|
II |
274
|
0 |
E2 |
P410
|
PP31 PP40 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-L
|
Category E
SW5
H1
|
SG26
|
– |
3131 |
|
|
3131
|
WATER-REACTIVE SOLID, CORROSIVE, N.O.S. |
4.3
|
8
|
III |
223
274
|
0 |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-L
|
Category E
SW5
H1
|
SG26
|
– |
3131 |
|
|
3132
|
WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. |
4.3
|
4.1
|
I |
274
|
0 |
E0 |
P403
|
PP31 |
IBC99
|
– |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SG26
|
– |
3132 |
|
|
3132
|
WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. |
4.3
|
4.1
|
II |
274
|
0 |
E2 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
SW5
H1
|
SG26
|
– |
3132 |
|
|
3132
|
WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. |
4.3
|
4.1
|
III |
223
274
|
0 |
E1 |
P410
|
PP31 |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category E
SW5
H1
|
SG26
|
– |
3132 |
|
|
3133
|
WATER-REACTIVE SOLID, OXIDIZING, N.O.S. |
4.3
|
5.1
|
II |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
H1
|
SG26
|
– |
3133 |
|
|
3133
|
WATER-REACTIVE SOLID, OXIDIZING, N.O.S. |
4.3
|
5.1
|
III |
223
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-G, S-L
|
H1
|
SG26
|
– |
3133 |
|
|
3134
|
WATER-REACTIVE SOLID, TOXIC, N.O.S. |
4.3
|
6.1
|
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SG26
|
– |
3134 |
|
|
3134
|
WATER-REACTIVE SOLID, TOXIC, N.O.S. |
4.3
|
6.1
|
II |
274
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
SW5
H1
|
SG26
|
– |
3134 |
|
|
3134
|
WATER-REACTIVE SOLID, TOXIC, N.O.S. |
4.3
|
6.1
|
III |
223
274
|
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category E
SW5
H1
|
SG26
|
– |
3134 |
|
|
3135
|
WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. |
4.3
|
4.2
|
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category D
H1
|
SG26
|
– |
3135 |
|
|
3135
|
WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. |
4.3
|
4.2
|
II |
274
|
0 |
E2 |
P410
|
PP31 |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
SW5
H1
|
SG26
|
– |
3135 |
|
|
3135
|
WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. |
4.3
|
4.2
|
III |
223
274
|
0 |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category E
SW5
H1
|
SG26
|
– |
3135 |
|
|
3136
|
TRIFLUOROMETHANE, REFRIGERATED LIQUID |
2.2
|
– |
– |
– |
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
Category D
|
– |
Liquefied, non-flammable gas. Much heavier than air (2.4). |
3136 |
|
|
3137
|
OXIDIZING SOLID, FLAMMABLE, N.O.S. |
5.1
|
4.1
|
I |
274
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-G, S-Q
|
H1
|
SG25
SG26
|
– |
3137 |
|
|
3138
|
ETHYLENE, ACETYLENE AND PROPYLENE MIXTURE, REFRIGERATED LIQUID containing at least 71.5% ethylene, with not more than 22.5% acetylene and not more than 6% propylene |
2.1
|
– |
– |
– |
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-D, S-U
|
Category D
SW2
|
SG46
|
Liquefied, flammable, colourless mixture of gases with a garlic odour. Explosive limits: 2.7% to 36%. Lighter than air (0.96). |
3138 |
|
|
3139
|
OXIDIZING LIQUID, N.O.S. |
5.1
|
– |
I |
274
|
0 |
E0 |
P502
|
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
Category D
|
SG38
SG49
SG60
|
– |
3139 |
|
|
3139
|
OXIDIZING LIQUID, N.O.S. |
5.1
|
– |
II |
274
|
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
|
– |
3139 |
|
|
3139
|
OXIDIZING LIQUID, N.O.S. |
5.1
|
– |
III |
223
274
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-Q
|
Category B
|
SG38
SG49
SG60
|
– |
3139 |
|
|
3140
|
ALKALOIDS, LIQUID, N.O.S. or ALKALOIDS SALTS, LIQUID, N.O.S. |
6.1
|
– |
I |
43
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
A wide range of toxic liquids, generally of vegetable origin. Toxic if swallowed, by skin contact or by inhalation. |
3140 |
|
|
3140
|
ALKALOIDS, LIQUID, N.O.S. or ALKALOIDS SALTS, LIQUID, N.O.S. |
6.1
|
– |
II |
43
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
See entry above. |
3140 |
|
|
3140
|
ALKALOIDS, LIQUID, N.O.S. or ALKALOIDS SALTS, LIQUID, N.O.S. |
6.1
|
– |
III |
43
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
See entry above. |
3140 |
|
|
3141
|
ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. |
6.1
|
– |
III |
45
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. |
3141 |
|
|
3142
|
DISINFECTANT, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category A
SW2
|
– |
A wide range of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. |
3142 |
|
|
3142
|
DISINFECTANT, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3142 |
|
|
3142
|
DISINFECTANT, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3142 |
|
|
3143
|
DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
|
– |
A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. |
3143 |
|
|
3143
|
DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3143 |
|
|
3143
|
DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
A wide range of toxic solids. Toxic if swallowed, by skin contact or by inhalation. |
3143 |
|
|
3144
|
NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. |
6.1
|
– |
I |
43
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category B
SW2
|
– |
A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. |
3144 |
|
|
3144
|
NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. |
6.1
|
– |
II |
43
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3144 |
|
|
3144
|
NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. |
6.1
|
– |
III |
43
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3144 |
|
|
3145
|
ALKYLPHENOLS, LIQUID, N.O.S. (including C2–C12 homologues) |
8
|
– |
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2
|
F-A, S-B
|
Category B
|
– |
A wide range of colourless to pale straw-coloured liquids with penetrating odours (sometimes camphor-like). Liquids slightly miscible with water. Cause burns to skin, eyes and mucous membranes. |
3145 |
|
|
3145
|
ALKYLPHENOLS, LIQUID, N.O.S. (including C2–C12 homologues) |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category B
|
– |
See entry above. |
3145 |
|
|
3145
|
ALKYLPHENOLS, LIQUID, N.O.S. (including C2–C12 homologues) |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category A
|
– |
See entry above. |
3145 |
|
|
3146
|
ORGANOTIN COMPOUND, SOLID, N.O.S. |
6.1
|
–
P
|
I |
43
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
SW2
|
– |
A wide variety of toxic solids. Toxic if swallowed, by skin contact or by inhalation. |
3146 |
|
|
3146
|
ORGANOTIN COMPOUND, SOLID, N.O.S. |
6.1
|
–
P
|
II |
43
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3146 |
|
|
3146
|
ORGANOTIN COMPOUND, SOLID, N.O.S. |
6.1
|
–
P
|
III |
43
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3146 |
|
|
3147
|
DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category A
|
– |
A wide range of corrosive solids or pastes. Cause burns to skin, eyes and mucous membranes. |
3147 |
|
|
3147
|
DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. |
8
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category A
|
– |
See entry above. |
3147 |
|
|
3147
|
DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. |
8
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
– |
See entry above. |
3147 |
|
| △ |
3148
|
WATER-REACTIVE LIQUID, N.O.S. |
4.3
|
– |
I |
274
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
T13
|
TP2 TP7
|
F-G, S-N
|
Category D
SW2
SW31
H1
|
SG26
|
– |
3148 |
△ |
| △ |
3148
|
WATER-REACTIVE LIQUID, N.O.S. |
4.3
|
– |
II |
274
|
500 mL |
E2 |
P402
|
PP31 |
IBC01
|
– |
|
– |
T7
|
TP2 TP7
|
F-G, S-N
|
Category D
SW2
SW31
H1
|
SG26
|
– |
3148 |
△ |
| △ |
3148
|
WATER-REACTIVE LIQUID, N.O.S. |
4.3
|
– |
III |
223
274
|
1 L |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
T7
|
TP2 TP7
|
F-G, S-N
|
Category D
SW2
SW31
H1
|
SG26
|
– |
3148 |
△ |
|
3149
|
HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED |
5.1
|
8
|
II |
196
|
1 L |
E2 |
P504
|
PP10 |
IBC02
|
B5 |
|
– |
T7
|
TP2 TP6 TP24
|
F-H, S-Q
|
Category D
SW1
|
SGG16
SG16
SG59
SG72
|
Colourless liquid. Carried as an aqueous solution. Slowly decomposes, evolving oxygen; the rate of decomposition increases on contact with most metals. In contact with combustible material, may cause fire. Causes burns to skin, eyes and mucous membranes. Even though stabilized, these solutions may evolve oxygen. |
3149 |
|
|
3150
|
DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device |
2.1
|
– |
– |
– |
0 |
E0 |
P003
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category B
SW2
|
– |
Various small devices used for cosmetic and other purposes, and their refills. |
3150 |
|
|
3151
|
POLYHALOGENATED BIPHENYLS, LIQUID or HALOGENATED MONOMETHYL-DIPHENYLMETHANES, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID |
9
|
–
P
|
II |
203
305
|
1 L |
E2 |
P906
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
SG50
|
Viscous liquids with a perceptible odour. Harmful by ingestion or by skin contact. This entry also covers articles, such as transformers and condensers, containing free liquid polyhalogenated biphenyls or polyhalogenated terphenyls. |
3151 |
|
|
3152
|
POLYHALOGENATED BIPHENYLS, SOLID or HALOGENATED MONOMETHYL-DIPHENYLMETHANES, SOLID or POLYHALOGENATED TERPHENYLS, SOLID |
9
|
–
P
|
II |
203
305
958
|
1 kg |
E2 |
P906
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SG50
|
Solid with a perceptible odour. Melting point of solids varies from 2°C to 164°C. Harmful by ingestion or by skin contact. This entry also covers articles, such as rags, cotton waste, clothing or sawdust, containing polyhalogenated biphenyls or polyhalogenated terphenyls where no free visible liquid is present. |
3152 |
|
|
3153
|
PERFLUORO(METHYL VINYL ETHER) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category E
SW2
|
– |
Explosive limits: 7% to 73%. Much heavier than air (4.8). Boiling point: −27°C. |
3153 |
|
|
3154
|
PERFLUORO(ETHYL VINYL ETHER) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category E
SW2
|
– |
Explosive limits: 7% to 73%. Much heavier than air (6.4). Boiling point: 12°C. |
3154 |
|
|
3155
|
PENTACHLOROPHENOL |
6.1
|
–
P
|
II |
43
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Toxic if swallowed, by skin contact or by dust inhalation. |
3155 |
|
|
3156
|
COMPRESSED GAS, OXIDIZING, N.O.S. |
2.2
|
5.1
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
|
– |
– |
3156 |
|
|
3157
|
LIQUEFIED GAS, OXIDIZING, N.O.S. |
2.2
|
5.1
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
|
– |
– |
3157 |
|
|
3158
|
GAS, REFRIGERATED LIQUID, N.O.S. |
2.2
|
– |
– |
274
|
120 mL |
E1 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-C, S-V
|
Category D
|
– |
– |
3158 |
|
|
3159
|
1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134a) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Non-flammable gas with a mild ether-like odour. Much heavier than air (3.5). |
3159 |
|
|
3160
|
LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. |
2.3
|
2.1
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
– |
3160 |
|
|
3161
|
LIQUEFIED GAS, FLAMMABLE, N.O.S. |
2.1
|
– |
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category D
SW2
|
– |
– |
3161 |
|
|
3162
|
LIQUEFIED GAS, TOXIC, N.O.S. |
2.3
|
– |
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
– |
3162 |
|
|
3163
|
LIQUEFIED GAS, N.O.S. |
2.2
|
– |
– |
274
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
– |
3163 |
|
|
3164
|
ARTICLES, PRESSURIZED, PNEUMATIC or HYDRAULIC (containing non-flammable gas) |
2.2
|
– |
– |
283
371
|
120 mL |
E0 |
P003
|
PP32 |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
Articles containing non-flammable, non-toxic gas necessary for their operation. |
3164 |
|
| △ |
3165
|
AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) (M86 fuel) |
3
|
6.1/8
|
– |
– |
0 |
E0 |
P301
|
– |
– |
– |
|
– |
– |
– |
F-E, S-C
|
Category D
SW2
|
SG5
SG8
SG13
|
The mixture is miscible with water and may react dangerously with oxidizing substances. The mixture is highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3165 |
△ |
|
3166
|
VEHICLE, FLAMMABLE GAS POWERED or VEHICLE, FLAMMABLE LIQUID POWERED or VEHICLE, FUEL CELL, FLAMMABLE GAS POWERED or VEHICLE, FUEL CELL, FLAMMABLE LIQUID POWERED |
9
|
– |
– |
356
388
961
962
|
– |
– |
– |
– |
– |
– |
|
– |
– |
– |
*
|
Category A
|
– |
Types of articles transported under this entry include, but are not limited to motor vehicles, hybrid vehicles, fuel cell powered vehicles, motorcycles and boats. *
F-D, S-U for gases or F-E, S-E for liquids. |
3166 |
|
|
3167
|
GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid |
2.1
|
– |
– |
209
|
0 |
E0 |
P201
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
|
– |
– |
3167 |
|
|
3168
|
GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid |
2.3
|
2.1
|
– |
209
|
0 |
E0 |
P201
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
|
– |
– |
3168 |
|
|
3169
|
GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid |
2.3
|
– |
– |
209
|
0 |
E0 |
P201
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
|
– |
– |
3169 |
|
|
3170
|
ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS |
4.3
|
– |
II |
244
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
BK2
|
TP33
|
F-G, S-P
|
Category B
SW5
H1
|
SGG15
SG26
|
Grey powder or lumps with some metallic inclusions. Contact with water may cause heating with possible evolution of flammable and toxic gases such as hydrogen and ammonia. This entry includes e.g. aluminium dross, aluminium skimmings, spent cathodes, spent potliner and aluminium salt slags. |
3170 |
|
|
3170
|
ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS |
4.3
|
– |
III |
223
244
|
1 kg |
E1 |
P002
|
PP31 |
IBC08
|
B4 |
|
– |
T1
BK2
|
TP33
|
F-G, S-P
|
Category B
SW5
H1
|
SGG15
SG26
|
See entry above. |
3170 |
|
| △ |
3171
|
BATTERY-POWERED VEHICLE or BATTERY-POWERED EQUIPMENT |
9
|
– |
– |
388
961
962
971
|
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
F-A, S-I
|
Category A
|
– |
This entry applies to vehicles and equipment powered by wet batteries, metallic sodium batteries or sodium alloy batteries with the batteries installed. |
3171 |
△ |
|
3172
|
TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. |
6.1
|
– |
I |
210
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category B
|
– |
Toxins from plant, animal or bacterial sources which contain infectious substances or toxins that are contained in infectious substances should be classified in class 6.2. Toxic if swallowed, by skin contact or by inhalation. |
3172 |
|
|
3172
|
TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. |
6.1
|
– |
II |
210
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-A, S-A
|
Category B
|
– |
See entry above. |
3172 |
|
|
3172
|
TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. |
6.1
|
– |
III |
210
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
– |
– |
F-A, S-A
|
Category A
|
– |
See entry above. |
3172 |
|
|
3174
|
TITANIUM DISULPHIDE |
4.2
|
– |
III |
– |
0 |
E1 |
P002
LP02
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category A
|
SGG7
|
Yellow or grey powder with an unpleasant odour. In contact with water slowly evolves hydrogen sulphide gas. |
3174 |
|
|
3175
|
SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. |
4.1
|
– |
II |
216
274
|
1 kg |
E2 |
P002
|
PP9 |
IBC06
|
B21 |
|
– |
T3
BK2
|
TP33
|
F-A, S-I
|
Category B
|
– |
Mixtures of non-dangerous solids (such as soil, sand, production materials, etc.) and flammable liquids. |
3175 |
|
|
3176
|
FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. |
4.1
|
– |
II |
274
|
0 |
E0 |
– |
– |
- |
– |
|
– |
T3
|
TP3 TP26
|
F-A, S-H
|
Category C
|
– |
Shipped molten above its melting point. |
3176 |
|
|
3176
|
FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. |
4.1
|
– |
III |
223
274
|
0 |
E0 |
– |
– |
– |
– |
|
– |
T1
|
TP3 TP26
|
F-A, S-H
|
Category C
|
– |
See entry above. |
3176 |
|
|
3178
|
FLAMMABLE SOLID, INORGANIC, N.O.S. |
4.1
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
|
– |
– |
3178 |
|
|
3178
|
FLAMMABLE SOLID, INORGANIC, N.O.S. |
4.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category B
|
– |
– |
3178 |
|
|
3179
|
FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. |
4.1
|
6.1
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. |
3179 |
|
|
3179
|
FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. |
4.1
|
6.1
|
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category B
SW2
|
– |
See entry above. |
3179 |
|
|
3180
|
FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. |
4.1
|
8
|
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category D
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. |
3180 |
|
|
3180
|
FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. |
4.1
|
8
|
III |
223
274
|
5 kg |
E1 |
P002
|
– |
IBC06
|
– |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category D
SW2
|
– |
See entry above. |
3180 |
|
|
3181
|
METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. |
4.1
|
– |
II |
274
|
1 kg |
E2 |
P002
|
PP31 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-I
|
Category B
SW2
|
SGG7
|
Decomposes in water. Liable to spontaneous heating. Irritating to skin and mucous membranes. |
3181 |
|
|
3181
|
METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. |
4.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-I
|
Category B
SW2
|
SGG7
|
See entry above. |
3181 |
|
|
3182
|
METAL HYDRIDES, FLAMMABLE, N.O.S. |
4.1
|
– |
II |
274
|
1 kg |
E2 |
P410
|
PP31 PP40 |
IBC04
|
– |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category E
|
– |
– |
3182 |
|
|
3182
|
METAL HYDRIDES, FLAMMABLE, N.O.S. |
4.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
|
PP31 |
IBC04
|
– |
|
– |
T1
|
TP33
|
F-A, S-G
|
Category E
|
– |
– |
3182 |
|
|
3183
|
SELF-HEATING LIQUID, ORGANIC, N.O.S. |
4.2
|
– |
II |
274
|
0 |
E2 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3183 |
|
|
3183
|
SELF-HEATING LIQUID, ORGANIC, N.O.S. |
4.2
|
– |
III |
223
274
|
0 |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3183 |
|
|
3184
|
SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. |
4.2
|
6.1
|
II |
274
|
0 |
E2 |
P402
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3184 |
|
|
3184
|
SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. |
4.2
|
6.1
|
III |
223
274
|
0 |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3184 |
|
|
3185
|
SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. |
4.2
|
8
|
II |
274
|
0 |
E2 |
P402
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3185 |
|
|
3185
|
SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. |
4.2
|
8
|
III |
223
274
|
0 |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3185 |
|
|
3186
|
SELF-HEATING LIQUID, INORGANIC, N.O.S. |
4.2
|
– |
II |
274
|
0 |
E2 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3186 |
|
|
3186
|
SELF-HEATING LIQUID, INORGANIC, N.O.S. |
4.2
|
– |
III |
223
274
|
0 |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3186 |
|
|
3187
|
SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. |
4.2
|
6.1
|
II |
274
|
0 |
E2 |
P402
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3187 |
|
|
3187
|
SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. |
4.2
|
6.1
|
III |
223
274
|
0 |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3187 |
|
|
3188
|
SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. |
4.2
|
8
|
II |
274
|
0 |
E2 |
P402
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3188 |
|
|
3188
|
SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. |
4.2
|
8
|
III |
223
274
|
0 |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
– |
– |
F-A, S-J
|
Category C
|
– |
– |
3188 |
|
|
3189
|
METAL POWDER, SELF-HEATING, N.O.S. |
4.2
|
– |
II |
274
|
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-J
|
Category C
H1
|
SGG7
SGG15
SG26
|
Forms explosive mixtures with oxidizing substances. |
3189 |
|
|
3189
|
METAL POWDER, SELF-HEATING, N.O.S. |
4.2
|
– |
III |
223
274
|
0 |
E1 |
P002
LP02
|
PP31 L4 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-J
|
Category C
H1
|
SGG7
SGG15
SG26
|
See entry above. |
3189 |
|
|
3190
|
SELF-HEATING SOLID, INORGANIC, N.O.S. |
4.2
|
– |
II |
274
|
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category C
|
– |
Liable to self-heating or spontaneous combustion. |
3190 |
|
|
3190
|
SELF-HEATING SOLID, INORGANIC, N.O.S. |
4.2
|
– |
III |
223
274
|
0 |
E1 |
P002
LP02
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category C
|
– |
See entry above. |
3190 |
|
|
3191
|
SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. |
4.2
|
6.1
|
II |
274
|
0 |
E2 |
P410
|
– |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3191 |
|
|
3191
|
SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. |
4.2
|
6.1
|
III |
223
274
|
0 |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3191 |
|
|
3192
|
SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. |
4.2
|
8
|
II |
274
|
0 |
E2 |
P410
|
– |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3192 |
|
|
3192
|
SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. |
4.2
|
8
|
III |
274
|
0 |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category C
|
– |
– |
3192 |
|
|
3194
|
PYROPHORIC LIQUID, INORGANIC, N.O.S. |
4.2
|
– |
I |
274
|
0 |
E0 |
P400
|
– |
– |
– |
|
– |
– |
– |
F-G, S-M
|
Category D
H1
|
SG26
SG63
|
Highly flammable liquids, may ignite spontaneously in moist air. In contact with air, evolve irritating and slightly toxic fumes. |
3194 |
|
|
3200
|
PYROPHORIC SOLID, INORGANIC, N.O.S. |
4.2
|
– |
I |
274
|
0 |
E0 |
P404
|
PP31 |
– |
– |
|
– |
T21
|
TP7 TP33
|
F-G, S-M
|
Category D
H1
|
SG26
|
Liable to ignite spontaneously in air. If shaken, may produce sparks. In contact with water, evolve hydrogen, a flammable gas. |
3200 |
|
|
3205
|
ALKALINE EARTH METAL ALCOHOLATES, N.O.S. |
4.2
|
– |
II |
183 274
|
0 |
E2 |
P410
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category B
|
– |
Free-flowing hygroscopic powders. Irritating to skin, eyes and mucous membranes. |
3205 |
|
|
3205
|
ALKALINE EARTH METAL ALCOHOLATES, N.O.S. |
4.2
|
– |
III |
183 223
274
|
0 |
E1 |
P002
LP02
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category B
|
– |
Free-flowing hygroscopic powders. Irritating to skin, eyes and mucous membranes. |
3205 |
|
|
3206
|
ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. |
4.2
|
8
|
II |
182
274
|
0 |
E2 |
P410
|
PP31 |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category B
|
SGG18
SG35
|
Free-flowing hygroscopic powder. Cause burns to skin, eyes and mucous membranes. |
3206 |
|
|
3206
|
ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. |
4.2
|
8
|
III |
182
223
274
|
0 |
E1 |
P002
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category B
|
SGG18
SG35
|
See entry above. |
3206 |
|
|
3208
|
METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. |
4.3
|
– |
I |
274
|
0 |
E0 |
P403
|
PP31 |
IBC99
|
– |
|
– |
– |
– |
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
3208 |
|
|
3208
|
METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. |
4.3
|
– |
II |
274
|
500 g |
E2 |
P410
|
PP31 PP40 |
IBC07
|
B4 B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
3208 |
|
|
3208
|
METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. |
4.3
|
– |
III |
223
274
|
1 kg |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
3208 |
|
|
3209
|
METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. |
4.3
|
4.2
|
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
– |
– |
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
3209 |
|
|
3209
|
METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. |
4.3
|
4.2
|
II |
274
|
0 |
E0 |
P410
|
PP31 PP40 |
IBC05
|
B21 |
|
– |
T3
|
TP33
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
3209 |
|
|
3209
|
METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. |
4.3
|
4.2
|
III |
223
274
|
0 |
E1 |
P410
|
PP31 |
IBC08
|
B4 |
|
– |
T1
|
TP33
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
|
– |
3209 |
|
|
3210
|
CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
II |
274
351
|
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category B
|
SG38
SG49
SG62
|
When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium chlorate, aqueous solution is prohibited. |
3210 |
|
|
3210
|
CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
III |
223
274
351
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category B
|
SG38
SG49
SG62
|
See entry above. |
3210 |
|
|
3211
|
PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category B
|
SGG13
SG38
SG49
SG62
|
When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
3211 |
|
|
3211
|
PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
III |
223
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category B
|
SGG13
SG38
SG49
SG62
|
See entry above. |
3211 |
|
|
3212
|
HYPOCHLORITES, INORGANIC, N.O.S. |
5.1
|
– |
II |
274
349
900
903
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-H, S-Q
|
Category D
SW1
SW17
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
Solids. Critical ambient temperature of decomposition may be as low as 60°C. May cause fire in contact with organic material or ammonium compounds. React with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Dust irritates mucous membranes. Transport of ammonium hypochlorite and mixtures of a hypochlorite with an ammonium salt is prohibited. |
3212 |
|
|
3213
|
BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
II |
274
350
|
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category B
|
SGG3
SG38
SG49
SG62
|
When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium bromate, aqueous solution is prohibited. |
3213 |
|
|
3213
|
BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
III |
223
274
350
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category B
|
SGG3
SG38
SG49
SG62
|
See entry above. |
3213 |
|
|
3214
|
PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
II |
274
353
|
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category D
|
SGG14
SG38
SG49
SG60
SG62
|
When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium permanganate, aqueous solution is prohibited. |
3214 |
|
|
3215
|
PERSULPHATES, INORGANIC, N.O.S. |
5.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-Q
|
Category A
|
SG40
SG49
|
Solids. Solid mixtures with combustible material are sensitive to friction and are liable to ignite. React fiercely with cyanides when heated or by friction. May form explosive mixture with powdered metals or ammonium compounds. |
3215 |
|
|
3216
|
PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
III |
– |
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1 TP29
|
F-A, S-Q
|
Category A
|
SG38
SG49
SG62
|
When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
3216 |
|
|
3218
|
NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
II |
270 |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-A, S-Q
|
Category B
|
SG38
SG49
SG62
|
When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
3218 |
|
|
3218
|
NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
III |
223
270
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-A, S-Q
|
Category B
|
SG38
SG49
SG62
|
See entry above. |
3218 |
|
|
3219
|
NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
II |
274
900
|
1 L |
E2 |
P504
|
– |
IBC01
|
– |
|
– |
T4
|
TP1
|
F-A, S-Q
|
Category B
|
SGG12
SG38
SG49
SG62
|
When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water of the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly with fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion; .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. Transport of ammonium nitrites, aqueous solution is prohibited. |
3219 |
|
|
3219
|
NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. |
5.1
|
– |
III |
223
274
900
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-A, S-Q
|
Category B
|
SGG12
SG38
SG49
SG62
|
See entry above. |
3219 |
|
|
3220
|
PENTAFLUOROETHANE (REFRIGERANT GAS R 125) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable gas with a mild ether-like odour. Much heavier than air (4.2). |
3220 |
|
|
3221
|
SELF-REACTIVE LIQUID TYPE B |
4.1
|
See SP181
|
– |
181 274
|
25 mL |
E0 |
P520
|
PP21 |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG1
SG35
SG36
|
May explode at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3221 |
|
|
3222
|
SELF-REACTIVE SOLID TYPE B |
4.1
|
See SP181
|
– |
181 274
|
100 g |
E0 |
P520
|
PP21 |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG1
SG35
SG36
|
May explode at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3222 |
|
|
3223
|
SELF-REACTIVE LIQUID TYPE C |
4.1
|
– |
– |
274
|
25 mL |
E0 |
P520
|
PP21 PP94 PP95 |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
May decompose violently at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3223 |
|
|
3224
|
SELF-REACTIVE SOLID TYPE C |
4.1
|
– |
– |
274
|
100 g |
E0 |
P520
|
PP21 PP94 PP95 |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
May decompose violently at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3224 |
|
|
3225
|
SELF-REACTIVE LIQUID TYPE D |
4.1
|
– |
– |
274
|
125 mL |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3225 |
|
|
3226
|
SELF-REACTIVE SOLID TYPE D |
4.1
|
– |
– |
274
|
500 g |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Insoluble in water except: 4-(BENZYL(ETHYL)AMINO)−3-ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE 3-CHLORO−4-DIETHYLAMINOBENZENEDIAZONIUM ZINC CHLORIDE 4-DIPROPYLAMINOBENZENEDIAZONIUM ZINC CHLORIDE SODIUM 2-DIAZO−1-NAPHTHOL−4-SULPHONATE SODIUM 2-DIAZO−1-NAPHTHOL−5-SULPHONATE |
3226 |
|
|
3227
|
SELF-REACTIVE LIQUID TYPE E |
4.1
|
– |
– |
274
|
125 mL |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3227 |
|
|
3228
|
SELF-REACTIVE SOLID TYPE E |
4.1
|
– |
– |
274
|
500 g |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3228 |
|
|
3229
|
SELF-REACTIVE LIQUID TYPE F |
4.1
|
– |
– |
274
|
125 mL |
E0 |
P520
|
– |
IBC99
|
– |
|
– |
T23
|
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3229 |
|
|
3230
|
SELF-REACTIVE SOLID TYPE F |
4.1
|
– |
– |
274
|
500 g |
E0 |
P520
|
– |
IBC99
|
– |
|
– |
T23
|
– |
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3230 |
|
|
3231
|
SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED |
4.1
|
See SP181
|
– |
181
194
274
923
|
0 |
E0 |
P520
|
PP21 |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG1
SG35
SG36
|
May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. |
3231 |
|
|
3232
|
SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED |
4.1
|
See SP181
|
– |
181
194
274
923
|
0 |
E0 |
P520
|
PP21 |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG1
SG35
SG36
|
May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. |
3232 |
|
|
3233
|
SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
PP21 |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. |
3233 |
|
|
3234
|
SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
PP21 |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
May explode at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water except: 3-METHYL−4-(PYRROLIDIN−1-YL)BENZENEDIAZONIUM TETRAFLUOROBORATE TETRAMINEPALLADIUM(II) NITRATE Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. |
3234 |
|
|
3235
|
SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3235 |
|
|
3236
|
SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Soluble in water except: AZODICARBONAMIDE FORMULATION TYPE D 2,2’-AZODI(2,4-DIMETHYL−4-METHOXYVALERONITRILE) 2,2’-AZODI(2,4-DIMETHYLVALERONITRILE) 2,2’-AZODI(2-METHYLBUTYRONITRILE) N-FORMYL−2-(NITROMETHYLENE)−1,3-PERHYDROTHIAZINE 4-NITROSOPHENOL Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. |
3236 |
|
|
3237
|
SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. |
3237 |
|
|
3238
|
SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
– |
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature should be checked regularly. |
3238 |
|
|
3239
|
SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
T23
|
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature must be checked regularly. |
3239 |
|
|
3240
|
SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED |
4.1
|
– |
– |
194
274
923
|
0 |
E0 |
P520
|
– |
– |
– |
|
– |
T23
|
– |
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Control and emergency temperatures for each formulation can be found in 2.4.2.3.2.3. The temperature must be checked regularly. |
3240 |
|
|
3241
|
2-BROMO−2-NITROPROPANE−1,3-DIOL |
4.1
|
– |
III |
– |
5 kg |
E1 |
P520
|
PP22 |
IBC08
|
B3 |
|
– |
– |
– |
F-J, S-G
|
Category C
SW1
SW2
H2
H3
|
– |
White crystals. Soluble in water. Decomposes when heated, evolving toxic gases. Sensitive to strong detonation shock. This substance shall be packed in accordance with packing method OP6 (see applicable packing instruction). |
3241 |
|
|
3242
|
AZODICARBONAMIDE |
4.1
|
– |
II |
215
|
500 g |
E0 |
P409
|
– |
– |
– |
|
– |
T3
|
TP33
|
F-J, S-G
|
Category D
|
SG17
SG35
SG36
|
Yellow or orange powder. Insoluble in water. Heat may cause exothermic decomposition, producing carbon monoxide (a toxic and flammable gas) and nitrogen. May explode if involved in a fire under confined conditions. Addition of activators (e.g. zinc compounds) may result in a decrease of thermal stability and/or a change in explosive properties. |
3242 |
|
|
3243
|
SOLIDS CONTAINING TOXIC LIQUID, N.O.S. |
6.1
|
– |
II |
217
274
|
500 g |
E4 |
P002
|
PP9 |
IBC02
|
– |
|
– |
T3
BK2
|
TP33
|
F-A, S-A
|
Category B
SW2
|
– |
Mixtures of non-dangerous solids (such as soil, sand, production materials, etc.) and toxic liquids. Toxic if swallowed, by skin contact or by inhalation. |
3243 |
|
|
3244
|
SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. |
8
|
– |
II |
218
274
|
1 kg |
E2 |
P002
|
PP9 |
IBC05
|
– |
|
– |
T3
BK2
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
Mixtures of non-dangerous solids (such as soil, sand, production materials, etc.) and corrosive liquids. Cause burns to skin, eyes and mucous membranes. |
3244 |
|
|
3245
|
GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED ORGANISMS |
9
|
– |
– |
219 |
0 |
E0 |
P904
|
– |
IBC99
|
– |
|
– |
– |
– |
F-A, S-T
|
SW7 |
SG50
|
– |
3245 |
|
|
3246
|
METHANESULPHONYL CHLORIDE |
6.1
|
8
|
I |
354
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
Category D
SW2
|
SGG1
SG36
SG49
|
Pale yellow liquid. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3246 |
|
|
3247
|
SODIUM PEROXOBORATE, ANHYDROUS |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-Q
|
Category A
SW1
H1
|
– |
Yellowish, odourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Harmful if swallowed. |
3247 |
|
|
3248
|
MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
II |
220
221
|
1 L |
E2 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3248 |
|
|
3248
|
MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
III |
220
221
223
|
5 L |
E1 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category A
|
– |
See entry above. |
3248 |
|
|
3249
|
MEDICINE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
II |
221
|
500 g |
E4 |
P002
|
– |
– |
– |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category C
SW2
|
– |
Toxic if swallowed, by skin contact or by dust inhalation. |
3249 |
|
|
3249
|
MEDICINE, SOLID, TOXIC, N.O.S. |
6.1
|
– |
III |
221
223
|
5 kg |
E1 |
P002
LP02
|
– |
– |
– |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category C
SW2
|
– |
See entry above. |
3249 |
|
|
3250
|
CHLOROACETIC ACID, MOLTEN |
6.1
|
8
|
II |
– |
0 |
E0 |
– |
– |
– |
– |
|
– |
T7
|
TP3 TP28
|
F-A, S-B
|
Category C
SW2
|
SGG1
SG36
SG49
|
Molten liquid. Melting point may be as low as 50°C. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3250 |
|
|
3251
|
ISOSORBIDE−5-MONONITRATE |
4.1
|
– |
III |
226
|
5 kg |
E0 |
P409
|
– |
– |
– |
|
– |
– |
– |
F-F, S-G
|
Category D
SW1
SW2
H2
H3
|
– |
May explode if involved in a fire under confined conditions. Sensitive to strong detonation shock. |
3251 |
|
|
3252
|
DIFLUOROMETHANE (REFRIGERANT GAS R 32) |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable colourless gas. Heavier than air (1.8). |
3252 |
|
|
3253
|
DISODIUM TRIOXOSILICATE |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
Colourless hygroscopic solid. Dangerous reaction with oxidizers. In the presence of moisture, reacts with aluminium, zinc, tin and their compounds, evolving hydrogen, a flammable gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
3253 |
|
|
3254
|
TRIBUTYLPHOSPHANE |
4.2
|
– |
I |
– |
0 |
E0 |
P400
|
– |
– |
– |
|
– |
T21
|
TP2 TP7
|
F-A, S-M
|
Category D
|
SG44
|
Colourless yellowish liquid. Insoluble in water. Strong garlic odour (phosphine). Liable to heat and ignite spontaneously in air. If involved in a fire, evolves phosphine, a flammable and highly toxic gas. Reacts violently with oxidizing substances (peroxides, halogens, nitric oxides and carbon tetrachloride). Irritating to mucous membranes. |
3254 |
|
|
3255
|
tert-BUTYL HYPOCHLORITE |
4.2
|
8
|
I |
976
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-A, S-M
|
Category D
|
SGG8
|
Volatile flammable slightly yellow liquid with a pungent odour. Immiscible with water. Boiling point: 77°C to 79°C. Flashpoint between −15°C and −10°C. Exposure to light causes immediate dangerous decomposition. Causes burns to skin, eyes and mucous membranes. |
3255 |
|
|
3256
|
ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60°C, at or above its flashpoint |
3
|
– |
III |
274
|
0 |
E0 |
P099
|
– |
IBC01
|
– |
|
– |
T3
|
TP3 TP29
|
F-E, S-D
|
Category A
|
– |
– |
3256 |
|
|
3257
|
ELEVATED TEMPERATURE LIQUID, N.O.S. at or above 100°C and below its flashpoint (including molten metals, molten salts, etc.) |
9
|
– |
III |
232
274
|
0 |
E0 |
P099
|
– |
IBC01
|
– |
|
– |
T3
|
TP3 TP29
|
F-A, S-P
|
Category A
SW5
|
– |
Any liquid which is transported at or above 100°C but below its flashpoint. May cause fire if in contact with combustible material due to extreme temperature. |
3257 |
|
|
3258
|
ELEVATED TEMPERATURE SOLID, N.O.S. at or above 240°C |
9
|
– |
III |
232
274
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-A, S-P
|
Category A
SW5
|
– |
Any solid which is transported at or above 240°C. May cause fire if in contact with combustible material due to extreme temperature. |
3258 |
|
|
3259
|
AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
Colourless to yellowish solids with a pungent odour. Miscible with or soluble in water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. Cause burns to skin, eyes and mucous membranes. React violently with acids. |
3259 |
|
|
3259
|
AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. |
8
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
See entry above. |
3259 |
|
|
3259
|
AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. |
8
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
See entry above. |
3259 |
|
|
3260
|
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category B
|
SGG1
SG36
SG49
|
Causes burns to skin, eyes and mucous membranes. |
3260 |
|
|
3260
|
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
|
SGG1
SG36
SG49
|
See entry above. |
3260 |
|
|
3260
|
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
See entry above. |
3260 |
|
|
3261
|
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category B
|
SGG1
SG36
SG49
|
Causes burns to skin, eyes and mucous membranes. |
3261 |
|
|
3261
|
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
|
SGG1
SG36
SG49
|
See entry above. |
3261 |
|
|
3261
|
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
See entry above. |
3261 |
|
|
3262
|
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category B
|
SGG18
SG35
|
Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. |
3262 |
|
|
3262
|
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
|
SGG18
SG35
|
See entry above. |
3262 |
|
|
3262
|
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
See entry above. |
3262 |
|
|
3263
|
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category B
|
SGG18
SG35
|
Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. |
3263 |
|
|
3263
|
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
|
SGG18
SG35
|
See entry above. |
3263 |
|
|
3263
|
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
See entry above. |
3263 |
|
|
3264
|
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG1
SG36
SG49
|
Causes burns to skin, eyes and mucous membranes. |
3264 |
|
|
3264
|
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG1
SG36
SG49
|
See entry above. |
3264 |
|
|
3264
|
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category A
SW2
|
SGG1
SG36
SG49
|
See entry above. |
3264 |
|
|
3265
|
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG1
SG36
SG49
|
Causes burns to skin, eyes and mucous membranes. |
3265 |
|
|
3265
|
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG1
SG36
SG49
|
See entry above. |
3265 |
|
|
3265
|
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category A
SW2
|
SGG1
SG36
SG49
|
See entry above. |
3265 |
|
|
3266
|
CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG18
SG35
|
Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. |
3266 |
|
|
3266
|
CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG18
SG35
|
See entry above. |
3266 |
|
|
3266
|
CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category A
SW2
|
SGG18
SG35
|
See entry above. |
3266 |
|
|
3267
|
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. |
8
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG18
SG35
|
Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. |
3267 |
|
|
3267
|
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. |
8
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
SGG18
SG35
|
See entry above. |
3267 |
|
|
3267
|
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. |
8
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-B
|
Category A
SW2
|
SGG18
SG35
|
See entry above. |
3267 |
|
|
3268
|
SAFETY DEVICES, electrically initiated |
9
|
– |
– |
280
289
|
0 |
E0 |
P902
LP902
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category A
|
– |
– |
3268 |
|
|
3269
|
POLYESTER RESIN KIT, liquid base material |
3
|
– |
II |
236
340
|
5 L |
See SP340
|
P302
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category B
|
– |
Polyester resin kits consist of two components: a base material (flammable liquid) and an activator (organic peroxide), each separately packed in an inner packaging. |
3269 |
|
|
3269
|
POLYESTER RESIN KIT, liquid base material |
3
|
– |
III |
236
340
|
5 L |
See SP340
|
P302
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category A
|
– |
See entry above. |
3269 |
|
| △ |
3270
|
NITROCELLULOSE MEMBRANE FILTERS with not more than 12.6% nitrogen, by dry mass |
4.1
|
– |
II |
237
286
403
|
1 kg |
E2 |
P411
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category D
|
– |
Filters may be small round pieces or large sheets. When involved in a fire, evolve toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Burn rapidly with intense heat radiation. |
3270 |
△ |
|
3271
|
ETHERS, N.O.S. |
3
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-D
|
Category B
|
– |
– |
3271 |
|
|
3271
|
ETHERS, N.O.S. |
3
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
Category A
|
– |
– |
3271 |
|
|
3272
|
ESTERS, N.O.S. |
3
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-D
|
Category B
|
– |
– |
3272 |
|
|
3272
|
ESTERS, N.O.S. |
3
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
Category A
|
– |
– |
3272 |
|
|
3273
|
NITRILES, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category E
SW2
|
SG35
|
Liquids evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Toxic if swallowed, by skin contact or by inhalation. |
3273 |
|
|
3273
|
NITRILES, FLAMMABLE, TOXIC, N.O.S. |
3
|
6.1
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
SG35
|
See entry above. |
3273 |
|
|
3274
|
ALCOHOLATES SOLUTION, N.O.S. in alcohol |
3
|
8
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
– |
– |
F-E, S-C
|
Category B
|
SGG18
SG35
|
Colourless solution. Reacts violently with water. Causes burns to skin, eyes and mucous membranes. |
3274 |
|
|
3275
|
NITRILES, TOXIC, FLAMMABLE, N.O.S. |
6.1
|
3
|
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
SG35
|
Flammable liquids, evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
3275 |
|
|
3275
|
NITRILES, TOXIC, FLAMMABLE, N.O.S. |
6.1
|
3
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
SG35
|
See entry above. |
3275 |
|
|
3276
|
NITRILES, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
|
SG35
|
Liquids, evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Miscible with water. Toxic if swallowed, by skin contact or by inhalation. |
3276 |
|
|
3276
|
NITRILES, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
|
SG35
|
See entry above. |
3276 |
|
|
3276
|
NITRILES, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
|
SG35
|
See entry above. |
3276 |
|
|
3277
|
CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. |
6.1
|
8
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T8
|
TP2 TP13 TP28
|
F-A, S-B
|
Category A
SW1
SW2
H1
H2
|
SGG1
SG36
SG49
|
React and decompose with water or heat, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
3277 |
|
|
3278
|
ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
I |
43
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3278 |
|
|
3278
|
ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
II |
43
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3278 |
|
|
3278
|
ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
III |
43
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3278 |
|
|
3279
|
ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. |
6.1
|
3
|
I |
43
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
A wide variety of toxic flammable liquids. Toxic if swallowed, by skin contact or by inhalation. |
3279 |
|
|
3279
|
ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. |
6.1
|
3
|
II |
43
274
|
100 mL |
E4 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3279 |
|
|
3280
|
ORGANOARSENIC COMPOUND, LIQUID, N.O.S. |
6.1
|
– |
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3280 |
|
|
3280
|
ORGANOARSENIC COMPOUND, LIQUID, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3280 |
|
|
3280
|
ORGANOARSENIC COMPOUND, LIQUID, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3280 |
|
|
3281
|
METAL CARBONYLS, LIQUID, N.O.S. |
6.1
|
– |
I |
274
315
|
0 |
E5 |
P601
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category D
SW2
|
– |
A range of metal carbonyls which, when heated, can give off carbon monoxide, a toxic gas. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
3281 |
|
|
3281
|
METAL CARBONYLS, LIQUID, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
SW2
|
– |
A range of metal carbonyls which, when heated, can give off carbon monoxide, a toxic gas. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation. |
3281 |
|
|
3281
|
METAL CARBONYLS, LIQUID, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3281 |
|
|
3282
|
ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3282 |
|
|
3282
|
ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3282 |
|
|
3282
|
ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3282 |
|
|
3283
|
SELENIUM COMPOUND, SOLID, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3283 |
|
|
3283
|
SELENIUM COMPOUND, SOLID, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3283 |
|
|
3283
|
SELENIUM COMPOUND, SOLID, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3283 |
|
|
3284
|
TELLURIUM COMPOUND, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3284 |
|
|
3284
|
TELLURIUM COMPOUND, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3284 |
|
|
3284
|
TELLURIUM COMPOUND, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3284 |
|
|
3285
|
VANADIUM COMPOUND, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3285 |
|
|
3285
|
VANADIUM COMPOUND, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3285 |
|
|
3285
|
VANADIUM COMPOUND, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3285 |
|
|
3286
|
FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. |
3
|
6.1/8
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-C
|
Category E
SW2
|
SG5
SG8
|
Flammable, toxic, corrosive liquid. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3286 |
|
|
3286
|
FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. |
3
|
6.1/8
|
II |
274
|
1 L |
E2 |
P001
|
– |
IBC99
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-C
|
Category B
SW2
|
SG5
SG8
|
See entry above. |
3286 |
|
|
3287
|
TOXIC LIQUID, INORGANIC, N.O.S. |
6.1
|
– |
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3287 |
|
|
3287
|
TOXIC LIQUID, INORGANIC, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3287 |
|
|
3287
|
TOXIC LIQUID, INORGANIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3287 |
|
|
3288
|
TOXIC SOLID, INORGANIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3288 |
|
|
3288
|
TOXIC SOLID, INORGANIC, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3288 |
|
|
3288
|
TOXIC SOLID, INORGANIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3288 |
|
|
3289
|
TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. |
6.1
|
8
|
I |
274
315
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-B
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3289 |
|
|
3289
|
TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. |
6.1
|
8
|
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
3289 |
|
|
3290
|
TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. |
6.1
|
8
|
I |
274
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3290 |
|
|
3290
|
TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. |
6.1
|
8
|
II |
274
|
500 g |
E4 |
P002
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
SW2
|
– |
See entry above. |
3290 |
|
|
3291
|
CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. |
6.2
|
– |
– |
– |
0 |
E0 |
P621
LP621
|
– |
IBC620
|
– |
|
– |
BK2
|
– |
F-A, S-T
|
SW28 |
– |
Derived from the medical treatment of animals, humans or from bio-research. |
3291 |
|
| △ |
3292
|
BATTERIES, CONTAINING METALLIC SODIUM OR SODIUM ALLOY or CELLS, CONTAINING METALLIC SODIUM OR SODIUM ALLOY |
4.3
|
– |
– |
239
401
|
0 |
E0 |
P408
|
– |
– |
– |
|
– |
– |
– |
F-G, S-P
|
Category A
H1
|
SG26
|
Series of hermetically sealed metal cells containing sodium, electrically connected and secured within a metal casing. “Cold” batteries (batteries containing elemental sodium only in the solid state) are electrically inert. Batteries are activated by heating to between 300°C and 350°C before operating to produce electricity. Activated batteries (i.e. “hot” batteries containing liquid elemental sodium) may cause fire through short-circuit of the terminals. Batteries or cells should not be offered for transport at a temperature such that liquid elemental sodium is present in the battery or cell unless approved, and under conditions of transport established by the competent authority. |
3292 |
△ |
|
3293
|
HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
SGG18
SG35
|
Colourless liquid. Reacts violently with acids. Toxic if swallowed, by skin contact or by inhalation. |
3293 |
|
|
3294
|
HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide |
6.1
|
3
P
|
I |
900
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
– |
Flammable solution, evolving extremely toxic flammable vapours. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Transport of HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with more than 45% hydrogen cyanide is prohibited. |
3294 |
|
|
3295
|
HYDROCARBONS, LIQUID, N.O.S. |
3
|
– |
I |
– |
500 mL |
E3 |
P001
|
– |
– |
– |
|
– |
T11
|
TP1 TP8 TP28
|
F-E, S-D
|
Category E
|
– |
Immiscible with water. |
3295 |
|
|
3295
|
HYDROCARBONS, LIQUID, N.O.S. |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-D
|
Category B
|
– |
See entry above. |
3295 |
|
|
3295
|
HYDROCARBONS, LIQUID, N.O.S. |
3
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
Category A
|
– |
See entry above. |
3295 |
|
|
3296
|
HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Non-flammable compressed gas. Heavier than air (1.4). |
3296 |
|
|
3297
|
ETHYLENE OXIDE AND CHLOROTETRAFLUORO-ETHANE MIXTURE with not more than 8.8% ethylene oxide |
2.2
|
– |
– |
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, colourless gas with an ether-like odour. Much heavier than air. |
3297 |
|
|
3298
|
ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide |
2.2
|
– |
– |
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, colourless gas with an ether-like odour. Much heavier than air. |
3298 |
|
|
3299
|
ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide |
2.2
|
– |
– |
392
|
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, colourless gas with an ether-like odour. Much heavier than air. |
3299 |
|
|
3300
|
ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Liquefied, flammable, toxic colourless gas with an ether-like odour. Heavier than air (1.5). |
3300 |
|
|
3301
|
CORROSIVE LIQUID, SELF-HEATING, N.O.S. |
8
|
4.2
|
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-J
|
Category D
|
– |
Causes burns to skin, eyes and mucous membranes. |
3301 |
|
|
3301
|
CORROSIVE LIQUID, SELF-HEATING, N.O.S. |
8
|
4.2
|
II |
274
|
0 |
E2 |
P001
|
– |
– |
– |
|
– |
– |
– |
F-A, S-J
|
Category D
|
– |
See entry above. |
3301 |
|
|
3302
|
2-DIMETHYLAMINOETHYL ACRYLATE, STABILIZED |
6.1
|
– |
II |
386
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category D
SW1
|
– |
Colourless to light yellow liquid. Acrid odour. Miscible with water. Causes tears. Stabilized with hydroquinone derivatives. Hydrolyses in water to give off acrylic acid and dimethylaminoethanol. Toxic if swallowed, by skin contact or by inhalation. |
3302 |
|
|
3303
|
COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. |
2.3
|
5.1
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
– |
– |
3303 |
|
|
3304
|
COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. |
2.3
|
8
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
– |
3304 |
|
|
3305
|
COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. |
2.3
|
2.1/8
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
SG4
SG9
|
– |
3305 |
|
|
3306
|
COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. |
2.3
|
5.1/8
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
– |
3306 |
|
|
3307
|
LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. |
2.3
|
5.1
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
– |
– |
3307 |
|
|
3308
|
LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. |
2.3
|
8
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
– |
3308 |
|
|
3309
|
LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. |
2.3
|
2.1/8
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
SG4
SG9
|
– |
3309 |
|
|
3310
|
LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. |
2.3
|
5.1/8
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
– |
3310 |
|
|
3311
|
GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. |
2.2
|
5.1
|
– |
274
|
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5 TP22
|
F-C, S-W
|
Category D
|
– |
– |
3311 |
|
|
3312
|
GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. |
2.1
|
– |
– |
274
|
0 |
E0 |
P203
|
– |
– |
– |
|
– |
T75
|
TP5
|
F-D, S-U
|
Category D
SW2
|
– |
– |
3312 |
|
|
3313
|
ORGANIC PIGMENTS, SELF-HEATING |
4.2
|
– |
II |
– |
0 |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category C
|
– |
Self-heating coloured powder or granules. Odourless. Liable to self-heating or spontaneous combustion. |
3313 |
|
|
3313
|
ORGANIC PIGMENTS, SELF-HEATING |
4.2
|
– |
III |
223
|
0 |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category C
|
– |
See entry above. |
3313 |
|
|
3314
|
PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form, evolving flammable vapour |
9
|
– |
III |
207
965
|
5 kg |
E1 |
P002
|
PP14 |
IBC08
|
B3 B6 |
|
– |
– |
– |
F-A, S-I
|
Category E
SW1
SW6
|
SG5
SG14
|
A moulding material consisting predominantly of polystyrene, poly(methyl methacrylate) or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predominantly pentane. During storage, a small proportion of this pentane is released to the atmosphere; this proportion increases at elevated temperatures. |
3314 |
|
|
3315
|
CHEMICAL SAMPLE, TOXIC |
6.1
|
– |
I |
250 |
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category D
SW2
|
– |
This entry may only be used for samples of chemicals taken for analysis in connection with the implementation of the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction. The transport of substances under this entry shall be in accordance with the chain of custody and security procedures specified by the Organization for the Prohibition of Chemical Weapons. The chemical sample may only be transported providing prior approval has been granted by the competent authority or the Director General of the Organization for the Prohibition of Chemical Weapons. During transport, the packaging shall be accompanied by a copy of the document of approval for transport, showing the quantity limitations and the packing requirements. |
3315 |
|
|
3316
|
CHEMICAL KIT or FIRST AID KIT |
9
|
– |
– |
251
340
|
See SP251
|
See SP340
|
P901
|
– |
– |
– |
|
– |
– |
– |
F-A, S-P
|
Category A
|
– |
– |
3316 |
|
|
3317
|
2-AMINO−4,6-DINITROPHENOL, WETTED with not less than 20% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SG7
SG30
|
Desensitized explosive. Red crystals. Insoluble in water. Explosive in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Harmful if swallowed or by skin contact. |
3317 |
|
|
3318
|
AMMONIA SOLUTION, relative density less than 0.880 at 15°C in water, with more than 50% ammonia |
2.3
|
8
P
|
– |
23 |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-U
|
Category D
SW2
|
SGG18
SG35
SG46
|
Highly concentrated solution in water of a non-flammable, toxic and corrosive gas with a pungent odour. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. Reacts violently with acids. Highly irritating to skin, eyes and mucous membranes. Suffocating in low concentrations. |
3318 |
|
| △ |
3319
|
NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass |
4.1
|
– |
II |
28
272
274
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
– |
Desensitized explosive with lactose, glucose or cellulose. White solid. Soluble in water. When involved in a fire, the nitroglycerin may accumulate and may produce an explosion. Contact with water may dissolve the desensitizer (lactose or glucose), causing migration and accumulation of the nitroglycerin, which may explode. Nitroglycerin is more dense than water. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. Inhalation of vapours may cause headaches, dizziness and fainting. |
3319 |
△ |
|
3320
|
SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION with not more than 12% sodium borohydride and not more than 40% sodium hydroxide, by mass |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
Off-white clear liquid with a slight hydrocarbon odour. Reacts violently with acids. In contact with acids or if diluted with large amount of water, evolves hydrogen gas and heat. Causes burns to skin, eyes and mucous membranes. |
3320 |
|
|
3320
|
SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION with not more than 12% sodium borohydride and not more than 40% sodium hydroxide, by mass |
8
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP2
|
F-A, S-B
|
Category A
|
SGG18
SG35
|
See entry above. |
3320 |
|
|
3321
|
RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
T5
|
TP4
|
F-I, S-S
|
Category A
SW20
SW21
|
– |
See 1.5.1. |
3321 |
|
|
3322
|
RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
T5
|
TP4
|
F-I, S-S
|
Category A
SW21
|
– |
See 1.5.1. |
3322 |
|
|
3323
|
RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted |
7
|
See SP172
|
– |
172
317
325
|
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
3323 |
|
|
3324
|
RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
SW20
SW21
|
– |
See 1.5.1. |
3324 |
|
|
3325
|
RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
SW21
|
– |
See 1.5.1. |
3325 |
|
|
3326
|
RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. |
3326 |
|
|
3327
|
RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
SW20
SW21
|
– |
See 1.5.1. |
3327 |
|
|
3328
|
RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
3328 |
|
|
3329
|
RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
3329 |
|
|
3330
|
RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
3330 |
|
|
3331
|
RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE |
7
|
See SP172
|
– |
172 326 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW13
|
– |
See 1.5.1. For ships transporting an INF cargo as defined in regulation VII/14 of the SOLAS Convention, 1974, as amended, refer also to the INF Code. |
3331 |
|
|
3332
|
RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissile-excepted |
7
|
See SP172
|
– |
172 317 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
|
– |
See 1.5.1. |
3332 |
|
|
3333
|
RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE |
7
|
See SP172
|
– |
172 |
0 |
E0 |
See 4.1.9
|
See 4.1.9 |
See 4.1.9
|
See 4.1.9
|
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
– |
See 1.5.1. |
3333 |
|
|
3334
|
AVIATION REGULATED LIQUID, N.O.S. |
9
|
– |
– |
960
|
– |
– |
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
– |
Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. |
3334 |
|
|
3335
|
AVIATION REGULATED SOLID, N.O.S. |
9
|
– |
– |
960
|
– |
– |
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
– |
Not subject to the provisions of this Code but may be subject to provisions governing the transport of dangerous goods by other modes. |
3335 |
|
|
3336
|
MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. |
3
|
– |
I |
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2
|
F-E, S-D
|
Category E
|
SG50
SG57
|
Colourless to yellow liquids with a garlic odour. Immiscible with water. |
3336 |
|
|
3336
|
MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. |
3
|
– |
II |
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP1 TP8 TP28
|
F-E, S-D
|
Category B
|
SG50
SG57
|
See entry above. |
3336 |
|
|
3336
|
MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. |
3
|
– |
III |
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-D
|
Category B
|
SG50
SG57
|
See entry above. |
3336 |
|
|
3337
|
REFRIGERANT GAS R 404A |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.06). Very high exposures may cause anaesthetic effects and asphyxiation. |
3337 |
|
|
3338
|
REFRIGERANT GAS R 407A |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.17). Very high exposures may cause anaesthetic effects and asphyxiation. |
3338 |
|
|
3339
|
REFRIGERANT GAS R 407B |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.19). Very high exposures may cause anaesthetic effects and asphyxiation. |
3339 |
|
|
3340
|
REFRIGERANT GAS R 407 C |
2.2
|
– |
– |
– |
120 mL |
E1 |
P200
|
– |
– |
– |
|
– |
T50
|
– |
F-C, S-V
|
Category A
|
– |
Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.16). Very high exposures may cause anaesthetic effects and asphyxiation. |
3340 |
|
|
3341
|
THIOUREA DIOXIDE |
4.2
|
– |
II |
– |
0 |
E2 |
P002
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category D
|
– |
White to yellow-white crystalline powder. Virtually odourless. Strong reducing agent. Violent exothermic decomposition above 100°C with emission of large amounts of sulphur oxides, ammonia, carbon monoxide, carbon dioxide, nitrogen oxides and hydrogen sulphide. Extended exposure to temperatures above 50°C and moisture may cause visible decomposition. Dust irritating to skin, eyes and mucous membranes. |
3341 |
|
|
3341
|
THIOUREA DIOXIDE |
4.2
|
– |
III |
223
|
0 |
E1 |
P002
LP02
|
PP31 |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category D
|
– |
See entry above. |
3341 |
|
|
3342
|
XANTHATES |
4.2
|
– |
II |
– |
0 |
E2 |
P002
|
PP31 |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category D
SW2
|
– |
Hygroscopic yellow powder with an unpleasant odour. On contact with moisture, evolves highly flammable vapours such as carbon disulphide (UN 1131, which has a flashpoint of −30°C c.c. and a very low ignition temperature of 100°C). When confined, can cause an explosion due to the wide explosive limits of the vapours. Finely divided dust forms explosive mixtures in air. Care should be taken when opening cargo transport units in case carbon disulphide vapours are present. |
3342 |
|
|
3342
|
XANTHATES |
4.2
|
– |
III |
223
|
0 |
E1 |
P002
LP02
|
PP31 |
IBC08
|
B3 |
|
|
T1
|
TP33
|
F-A, S-J
|
Category D
SW2
|
– |
See entry above. |
3342 |
|
| △ |
3343
|
NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass |
3
|
– |
– |
28
274
278
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-E, S-Y
|
Category D
|
– |
– |
3343 |
△ |
| △ |
3344
|
PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass |
4.1
|
– |
II |
28
272
274
|
0 |
E0 |
P406
|
PP26 PP80 |
– |
– |
– |
|
– |
– |
F-B, S-J
|
Category E
|
– |
– |
3344 |
△ |
|
3345
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
3345 |
|
|
3345
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3345 |
|
|
3345
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B21 |
|
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3345 |
|
|
3346
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Pesticides frequently containing petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3346 |
|
|
3346
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3346 |
|
|
3347
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3347 |
|
|
3347
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3347 |
|
|
3347
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3347 |
|
|
3348
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3348 |
|
|
3348
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3348 |
|
|
3348
|
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3348 |
|
|
3349
|
PYRETHROID PESTICIDE, SOLID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
– |
|
T6
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid pesticides present a very wide range of toxic hazard. Toxic if swallowed, by skin contact or by inhalation. |
3349 |
|
|
3349
|
PYRETHROID PESTICIDE, SOLID, TOXIC |
6.1
|
– |
II |
61
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3349 |
|
|
3349
|
PYRETHROID PESTICIDE, SOLID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
|
T1
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3349 |
|
|
3350
|
PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
I |
61
274
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3350 |
|
|
3350
|
PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C |
3
|
6.1
|
II |
61
274
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3350 |
|
|
3351
|
PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3351 |
|
|
3351
|
PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-E, S-D
|
Category B
SW2
|
– |
See entry above. |
3351 |
|
|
3351
|
PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23°C |
6.1
|
3
|
III |
61
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-E, S-D
|
Category A
SW2
|
– |
See entry above. |
3351 |
|
|
3352
|
PYRETHROID PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
I |
61
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
SW2
|
– |
Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition. Toxic if swallowed, by skin contact or by inhalation. |
3352 |
|
|
3352
|
PYRETHROID PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
II |
61
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
SW2
|
– |
See entry above. |
3352 |
|
|
3352
|
PYRETHROID PESTICIDE, LIQUID, TOXIC |
6.1
|
– |
III |
61
223
274
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T7
|
TP2 TP28
|
F-A, S-A
|
Category A
SW2
|
– |
See entry above. |
3352 |
|
|
3354
|
INSECTICIDE GAS, FLAMMABLE, N.O.S. |
2.1
|
– |
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
|
– |
Flammable mixtures of insecticides with liquefied gases. |
3354 |
|
|
3355
|
INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. |
2.3
|
2.1
|
– |
274
|
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Toxic, flammable mixtures of insecticides with liquefied gases. |
3355 |
|
|
3356
|
OXYGEN GENERATOR, CHEMICAL |
5.1
|
– |
– |
284 |
0 |
E0 |
P500
|
– |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
|
– |
Oxygen generators, chemical are devices containing chemicals which, upon activation, release oxygen as a product of chemical reaction. Chemical oxygen generators are used for the generation of oxygen for respiratory support, e.g. in aircraft, submarines, spacecraft, bomb shelters and breathing apparatus. Oxidizing salts such as chlorates and perchlorates of lithium, sodium and potassium, which are used in chemical oxygen generators, evolve oxygen when heated. These salts are mixed (compounded) with a fuel, usually iron powder, to form a chlorate candle, which produces oxygen by continuous reaction. The fuel is used to generate heat by oxidation. Once the reaction begins, oxygen is released from the hot salt by thermal decomposition (a thermal shield is used around the generator). A portion of the oxygen reacts with the fuel to produce more heat, which produces more oxygen, and so on. Initiation of the reaction can be achieved by a percussion device, friction device or electric wire. |
3356 |
|
| △ |
3357
|
NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass |
3
|
– |
II |
28
274
288
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-E, S-Y
|
Category D
|
– |
– |
3357 |
△ |
|
3358
|
REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas |
2.1
|
– |
– |
291
|
0 |
E0 |
P003
|
PP32 |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
|
– |
– |
3358 |
|
|
3359
|
FUMIGATED CARGO TRANSPORT UNIT |
9
|
– |
– |
302
|
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
F-A, S-D
|
Category B
SW2
|
– |
A ‘FUMIGATED CARGO TRANSPORT UNIT’ is a closed cargo transport unit containing goods or materials that either are or have been fumigated within the unit. The fumigant gases used are either poisonous or asphyxiant. The gases are usually evolved from solid or liquid preparations distributed within the unit. See also 5.5.2. |
3359 |
|
|
3360
|
FIBRES, VEGETABLE, DRY |
4.1
|
– |
– |
29
123
299
973
|
0 |
E0 |
P003
|
PP19 |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
|
– |
Ignite readily. Consignments of cotton, dry having a density not less than 360 kg/m3, flax, dry having a density not less than 400 kg/m3, sisal, dry having a density not less than 360 kg/m3 (ISO Standard 8115 (1986)) and tampico fibre, dry having a density not less than 360 kg/m³ are not subject to the provisions of this Code when carried in closed cargo transport units. |
3360 |
|
|
3361
|
CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. |
6.1
|
8
|
II |
274
|
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T14
|
TP2 TP7 TP13 TP27
|
F-A, S-B
|
Category C
SW2
|
SGG1
SG36
SG49
|
Colourless to yellow liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
3361 |
|
|
3362
|
CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. |
6.1
|
3/8
|
II |
274
|
0 |
E0 |
P010
|
– |
– |
– |
|
– |
T14
|
TP2 TP7 TP13 TP27
|
F-E, S-C
|
Category C
SW2
|
SGG1
SG5
SG8
SG36
SG49
|
Colourless to yellow flammable liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
3362 |
|
|
3363
|
DANGEROUS GOODS IN ARTICLES or DANGEROUS GOODS IN MACHINERY or DANGEROUS GOODS IN APPARATUS |
9
|
– |
– |
301
|
See SP301
|
E0 |
P907
|
– |
– |
– |
|
– |
– |
– |
F-A, S-P
|
Category A
|
– |
Types of articles transported under this entry contain only limited quantities of dangerous goods. |
3363 |
|
|
3364
|
TRINITROPHENOL (PICRIC ACID), WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP24 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. |
3364 |
|
|
3365
|
TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP24 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Explosive and sensitive to shock and heat in the dry state. Reacts violently with heavy metals and their salts. |
3365 |
|
|
3366
|
TRINITROTOLUENE (TNT), WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP24 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Reacts violently with heavy metals and their salts. |
3366 |
|
|
3367
|
TRINITROBENZENE, WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP24 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of odourless yellow crystals. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Harmful if swallowed or by skin contact. Reacts violently with heavy metals and their salts. |
3367 |
|
|
3368
|
TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP24 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow crystals. Soluble in water. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to shock and heat in the dry state. Harmful if swallowed or by skin contact. Reacts violently with heavy metals and their salts. |
3368 |
|
|
3369
|
SODIUM DINITRO-o-CRESOLATE, WETTED with not less than 10% water, by mass |
4.1
|
6.1
P
|
I |
28
|
0 |
E0 |
P406
|
PP24 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Substance in pure form consists of yellow powder. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes; in closed compartments, these fumes may form an explosive mixture with air. Explosive and sensitive to friction in the dry state. Toxic if swallowed, by skin contact or by inhalation. |
3369 |
|
|
3370
|
UREA NITRATE, WETTED with not less than 10% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP31 PP78 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. May form extremely sensitive compounds with heavy metals or their salts. Explosive and sensitive to friction in the dry state. Harmful if swallowed or by skin contact. |
3370 |
|
|
3371
|
2-METHYLBUTANAL |
3
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-D
|
Category B
|
– |
Colourless liquid. Flashpoint: −3.5°C. Explosive limits: 1.3 to 13.9%. Slightly miscible with water. |
3371 |
|
|
3373
|
BIOLOGICAL SUBSTANCE, CATEGORY B
|
6.2
|
– |
– |
319
341
|
0 |
E0 |
P650
|
– |
– |
– |
|
– |
T1
BK2
|
TP1
|
F-A, S-T
|
Category C
SW2
SW18
|
– |
Substances which are known or are reasonably expected to contain pathogens, transported in a form that, when exposure to it occurs, are not capable of causing permanent disability, life-threatening or fatal disease to humans or animals. Human or animal specimens for which there is minimal likelihood that pathogens are present are not subject to the provisions of this Code (see 2.6.3.2.3.6). Other exemptions are stated in 2.6.3.2.3. |
3373 |
|
|
3374
|
ACETYLENE, SOLVENT FREE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW1
SW2
|
SG46
|
Flammable gas with slight odour. Explosive limits: 2.1 to 80%. Lighter than air (0.907). Acetylene without solvent. Rough handling and exposure to local heating should be avoided, since these conditions may result in delayed explosion. Empty cylinders should be carried with the same precautions as filled cylinders. |
3374 |
|
|
3375
|
AMMONIUM NITRATE EMULSION or SUSPENSION or GEL, intermediate for blasting explosives |
5.1
|
– |
II |
309
|
0 |
E2 |
P505
|
– |
IBC02
|
B16 |
|
– |
T1
|
TP1 TP9 TP17 TP32
|
F-H, S-Q
|
Category D
SW1
|
SGG2
SG16
SG42
SG45
SG47
SG48
SG51
SG56
SG58
SG59
SG61
|
Non-sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. Substances shall satisfactorily pass test series 8 of the Manual of Tests and Criteria, part I, section 18 and be approved by the competent authority. |
3375 |
|
|
3376
|
4-NITROPHENYLHYDRAZINE, with not less than 30% water, by mass |
4.1
|
– |
I |
28
|
0 |
E0 |
P406
|
PP26 PP31 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category E
|
SG7
SG30
|
Desensitized explosive. Dark orange solid. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Harmful if swallowed or by skin contact. |
3376 |
|
|
3377
|
SODIUM PERBORATE MONOHYDRATE |
5.1
|
– |
III |
967
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
|
T1
BK2
BK3
|
TP33
|
F-A, S-Q
|
Category A
SW1
SW23
H1
|
SGG16
SG59
|
White crystals or powder. Partially soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Risk of decomposition when exposed to continuous heat (exothermic decomposition ≥ 60°C). When involved in a fire or exposed to high temperatures, it may decompose, yielding oxygen and steam. Harmful if swallowed. |
3377 |
|
|
3378
|
SODIUM CARBONATE PEROXYHYDRATE |
5.1
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
– |
|
T3
BK2
|
TP33
|
F-A, S-Q
|
Category A
SW1
H1
|
SGG16
SG59
|
White crystals or powder. Soluble in water. Mixtures with combustible material are readily ignited. Decomposes in contact with water and acids, forming hydrogen peroxide. Risk of decomposition when exposed to continuous heat (exothermic decomposition ≥ 60°C). When involved in a fire or exposed to high temperatures, it may decompose, yielding oxygen and steam. Irritating to eyes, skin and mucous membranes. Harmful if swallowed. |
3378 |
|
|
3378
|
SODIUM CARBONATE PEROXYHYDRATE |
5.1
|
– |
III |
967 |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B21 |
|
|
T1
BK2
BK3
|
TP33
|
F-A, S-Q
|
Category A
SW1
SW23
H1
|
SGG16
SG59
|
See entry above. |
3378 |
|
|
3379
|
DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. |
3
|
– |
I |
274
311
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-E, S-Y
|
Category D
|
SG30
|
Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. |
3379 |
|
|
3380
|
DESENSITIZED EXPLOSIVE, SOLID, N.O.S. |
4.1
|
– |
I |
274
311
394
|
0 |
E0 |
P099
|
– |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SG7
SG30
|
Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. |
3380 |
|
|
3381
|
TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or equal to 200 mL/m3 and saturated vapour concentration greater than or equal to 500 LC50
|
6.1
|
– |
I |
274
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. |
3381 |
|
|
3382
|
TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or equal to 1000 m L/m3 and saturated vapour concentration greater than or equal to 10 LC50
|
6.1
|
– |
I |
274
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-A
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard. Highly toxic if swallowed, by skin contact or by inhalation. |
3382 |
|
|
3383
|
TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 mL/m3 and saturated vapour concentration greater than or equal to 500 LC50
|
6.1
|
3
|
I |
274
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable. Highly toxic if swallowed, by skin contact or by inhalation. |
3383 |
|
|
3384
|
TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 mL/m3 and saturated vapour concentration greater than or equal to 10 LC50
|
6.1
|
3
|
I |
274
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable. Highly toxic if swallowed, by skin contact or by inhalation. |
3384 |
|
|
3385
|
TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 200 mL/m3 and saturated vapour concentration greater than or equal to 500 LC50
|
6.1
|
4.3
|
I |
274
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-G, S-N
|
Category D
SW2
H1
|
SG26
|
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive. Highly toxic if swallowed, by skin contact or by inhalation. |
3385 |
|
|
3 386
|
TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 1000 mL/m3 and saturated vapour concentration greater than or equal to 10 LC50
|
6.1
|
4.3
|
I |
274
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-G, S-N
|
Category D
SW2
H1
|
SG26
|
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive. Highly toxic if swallowed, by skin contact or by inhalation. |
3 386
|
|
|
3387
|
TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC50 lower than or equal to 200 mL/m3 and saturated vapour concentration greater than or equal to 500 LC50
|
6.1
|
5.1
|
I |
274
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-A, S-Q
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being an oxidizer. Highly toxic if swallowed, by skin contact or by inhalation. |
3387 |
|
|
3388
|
TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC50 lower than or equal to 1000 mL/m3 and saturated vapour concentration greater than or equal to 10 LC50
|
6.1
|
5.1
|
I |
274
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-Q
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being an oxidizer. Highly toxic if swallowed, by skin contact or by inhalation. |
3388 |
|
|
3389
|
TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 mL/m3 and saturated vapour concentration greater than or equal to 500 LC50
|
6.1
|
8
|
I |
274
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-A, S-B
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being corrosive. Highly toxic if swallowed, by skin contact or by inhalation. |
3389 |
|
|
3390
|
TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 mL/m3 and saturated vapour concentration greater than or equal to 10 LC50
|
6.1
|
8
|
I |
274
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-A, S-B
|
Category D
SW2
|
– |
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being corrosive. Highly toxic if swallowed, by skin contact or by inhalation. |
3390 |
|
|
3391
|
ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC |
4.2
|
– |
I |
274
|
0 |
E0 |
P404
|
PP86 |
– |
– |
|
– |
T21
|
TP7 TP33 TP36
|
F-G, S-M
|
Category D
H1
|
SG26
SG72
|
Liable to ignite spontaneously in air. If shaken, may produce sparks. |
3391 |
|
|
3392
|
ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC |
4.2
|
– |
I |
274
|
0 |
E0 |
P400
|
PP86 |
– |
– |
|
– |
T21
|
TP2 TP7 TP36
|
F-G, S-M
|
Category D
H1
|
SG26
SG63
SG72
|
Highly flammable liquid. Liable to ignite spontaneously in air. In contact with air, evolve irritating and slightly toxic fumes. |
3392 |
|
|
3393
|
ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER-REACTIVE |
4.2
|
4.3
|
I |
274
|
0 |
E0 |
P404
|
PP86 |
– |
– |
|
– |
T21
|
TP7 TP33 TP36 TP41
|
F-G, S-M
|
Category D
H1
|
SG26
SG35
SG72
|
Liable to ignite spontaneously in air. If shaken, may produce sparks. React violently with moisture, water and acids, evolving flammable gas. |
3393 |
|
|
3394
|
ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE |
4.2
|
4.3
|
I |
274
|
0 |
E0 |
P400
|
PP86 |
– |
– |
|
– |
T21
|
TP2 TP7 TP36 TP41
|
F-G, S-M
|
Category D
H1
|
SG26
SG35
SG63
SG72
|
Highly flammable liquid. Liable to ignite spontaneously in air. In contact with air, evolve irritating and slightly toxic fumes. React violently with moisture, water and acids, evolving flammable gas. |
3394 |
|
|
3395
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE |
4.3
|
– |
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
Reacts violently with moisture, water and acids, evolving flammable gas. |
3395 |
|
|
3395
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE |
4.3
|
– |
II |
274
|
500 g |
E2 |
P410
|
PP31 |
IBC04
|
– |
|
– |
T3
|
TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3395 |
|
|
3395
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE |
4.3
|
– |
III |
223
274
|
1 kg |
E1 |
P410
|
PP31 |
IBC06
|
– |
|
– |
T1
|
TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3395 |
|
|
3396
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE |
4.3
|
4.1
|
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
Flammable solid. Reacts violently with moisture, water and acids, evolving flammable gas. |
3396 |
|
|
3396
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE |
4.3
|
4.1
|
II |
274
|
500 g |
E2 |
P410
|
PP31 |
IBC04
|
– |
|
– |
T3
|
TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3396 |
|
|
3396
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE |
4.3
|
4.1
|
III |
223
274
|
1 kg |
E1 |
P410
|
PP31 |
IBC06
|
– |
|
– |
T1
|
TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3396 |
|
|
3397
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING |
4.3
|
4.2
|
I |
274
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
Liable to self-heating or spontaneous combustion. Reacts violently with moisture, water and acids, evolving flammable gas. |
3397 |
|
|
3397
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING |
4.3
|
4.2
|
II |
274
|
500 g |
E2 |
P410
|
PP31 |
IBC04
|
– |
|
– |
T3
|
TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3397 |
|
|
3397
|
ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING |
4.3
|
4.2
|
III |
223
274
|
1 kg |
E1 |
P410
|
PP31 |
IBC06
|
– |
|
– |
T1
|
TP33 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3397 |
|
|
3398
|
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE |
4.3
|
– |
I |
274
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
T13
|
TP2 TP7 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
Reacts violently with moisture, water and acids, evolving flammable gas. |
3398 |
|
|
3398
|
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE |
4.3
|
– |
II |
274
|
500 mL |
E2 |
P001
|
PP31 |
IBC01
|
– |
|
– |
T7
|
TP2 TP7 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
Reacts violently with moisture, water and acids, evolving flammable gas. |
3398 |
|
|
3398
|
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE |
4.3
|
– |
III |
223
274
|
1 L |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
T7
|
TP2 TP7 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3398 |
|
|
3399
|
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE |
4.3
|
3
|
I |
274
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
T13
|
TP2 TP7 TP36 TP41
|
F-G, S-N
|
Category D
SW2
H1
|
SG26
SG35
SG72
|
Flammable liquid. Reacts violently with moisture, water and acids, evolving flammable gas. |
3399 |
|
|
3399
|
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE |
4.3
|
3
|
II |
274
|
500 mL |
E2 |
P001
|
PP31 |
IBC01
|
– |
|
– |
T7
|
TP2 TP7 TP36 TP41
|
F-G, S-N
|
Category D
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3399 |
|
|
3399
|
ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE |
4.3
|
3
|
III |
223
274
|
1 L |
E1 |
P001
|
PP31 |
IBC02
|
– |
|
– |
T7
|
TP2 TP7 TP36 TP41
|
F-G, S-N
|
Category E
SW2
H1
|
SG26
SG35
SG72
|
See entry above. |
3399 |
|
|
3400
|
ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING |
4.2
|
– |
II |
274
|
500 g |
E2 |
P410
|
– |
IBC06
|
– |
|
– |
T3
|
TP33 TP36
|
F-A, S-J
|
Category C
|
SG72
|
Liable to self-heating or spontaneous combustion. |
3400 |
|
|
3400
|
ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING |
4.2
|
– |
III |
223
274
|
1 kg |
E1 |
P002
|
– |
IBC08
|
– |
|
– |
T1
|
TP33 TP36
|
F-A, S-J
|
Category C
|
SG72
|
See entry above. |
3400 |
|
|
3401
|
ALKALI METAL AMALGAM, SOLID |
4.3
|
– |
I |
182
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33
|
F-G, S-N
|
Category D
H1
|
SGG7
SGG11
SG26
SG35
|
Silvery solid, consisting of metal alloyed with mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. |
3401 |
|
|
3402
|
ALKALINE EARTH METAL AMALGAM, SOLID |
4.3
|
– |
I |
183
|
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33
|
F-G, S-N
|
Category D
H1
|
SGG7
SGG11
SG26
SG35
|
Consists of metal alloyed with mercury. Contains 2% to 10% alkaline earth metals and may contain up to 98% mercury. Reacts with moisture, water or acids, evolving hydrogen, a flammable gas. When heated, evolves toxic vapours. |
3402 |
|
|
3403
|
POTASSIUM METAL ALLOYS, SOLID |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33
|
F-G, S-L
|
Category D
H1
|
SG26
SG35
|
Soft, silvery metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
3403 |
|
|
3404
|
POTASSIUM SODIUM ALLOYS, SOLID |
4.3
|
– |
I |
– |
0 |
E0 |
P403
|
PP31 |
– |
– |
|
– |
T9
|
TP7 TP33
|
F-G, S-L
|
Category D
H1
|
SG26
SG35
|
Soft, silvery metal. Floats on water. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. Highly reactive, sometimes with explosive effect. |
3404 |
|
|
3405
|
BARIUM CHLORATE SOLUTION |
5.1
|
6.1
|
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
SG62
|
Colourless aqueous solution. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by inhalation. Leakage and subsequent evaporation of the water from the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion, .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
3405 |
|
|
3405
|
BARIUM CHLORATE SOLUTION |
5.1
|
6.1
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
SG62
|
See entry above. |
3405 |
|
|
3406
|
BARIUM PERCHLORATE SOLUTION |
5.1
|
6.1
|
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
SG62
|
Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. Toxic if swallowed, by skin contact or by inhalation. Leakage and subsequent evaporation of the water from the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion, .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
3406 |
|
|
3406
|
BARIUM PERCHLORATE SOLUTION |
5.1
|
6.1
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG13
SG38
SG49
SG62
|
See entry above. |
3406 |
|
|
3407
|
CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION |
5.1
|
– |
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
SG62
|
Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. Leakage and subsequent evaporation of the water from the solutions may present increased dangers as follows: .1 in contact with combustible material (particularly fibrous material such as jute, cotton or sisal) or sulphur, danger of spontaneous combustion, .2 in contact with ammonium compounds, powdered metals or oils, danger of explosion. |
3407 |
|
|
3407
|
CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION |
5.1
|
– |
III |
223
|
5 L |
E1 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG4
SG38
SG49
SG62
|
See entry above. |
3407 |
|
|
3408
|
LEAD PERCHLORATE SOLUTION |
5.1
|
6.1
P
|
II |
– |
1 L |
E2 |
P504
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG7
SGG9
SGG13
SG38
SG49
|
Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated. May form explosive mixtures with combustible material, powdered metals or ammonium compounds. These mixtures are liable to ignite. When involved in a fire, may cause an explosion. |
3408 |
|
|
3408
|
LEAD PERCHLORATE SOLUTION |
5.1
|
6.1
P
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-H, S-Q
|
Category A
|
SGG7
SGG9
SGG13
SG38
SG49
|
See entry above. |
3408 |
|
|
3409
|
CHLORONITROBENZENES, LIQUID |
6.1
|
– |
II |
279
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Yellow liquid. Toxic if swallowed, by skin contact or by inhalation. |
3409 |
|
|
3410
|
4-CHLORO-o-TOLUIDINE HYDROCHLORIDE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3410 |
|
|
3411
|
beta-NAPHTHYLAMINE SOLUTION |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3411 |
|
|
3411
|
beta-NAPHTHYLAMINE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3411 |
|
|
3412
|
FORMIC ACID with not less than 10% but not more than 85% acid by mass |
8
|
– |
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category A
SW2
|
SGG1
SG36
SG49
|
Colourless liquid with a pungent odour. Corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
3412 |
|
|
3412
|
FORMIC ACID with not less than 5% but less than 10% acid by mass |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
SW2
|
SGG1
SG36
SG49
|
See entry above. |
3412 |
|
|
3413
|
POTASSIUM CYANIDE SOLUTION |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P001
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
Category B
|
SGG6
SG35
|
Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. |
3413 |
|
|
3413
|
POTASSIUM CYANIDE SOLUTION |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
PP31 |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
|
SGG6
SG35
|
Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. |
3413 |
|
|
3413
|
POTASSIUM CYANIDE SOLUTION |
6.1
|
–
P
|
III |
223
|
5 L |
E1 |
P001
LP01
|
PP31 |
IBC03
|
– |
|
– |
T7
|
TP2 TP13 TP28
|
F-A, S-A
|
Category A
|
SGG6
SG35
|
See entry above. |
3413 |
|
|
3414
|
SODIUM CYANIDE SOLUTION |
6.1
|
–
P
|
I |
– |
0 |
E5 |
P001
|
PP31 |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-A, S-A
|
Category B
|
SGG6
SG35
|
Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Highly toxic if swallowed or by skin contact. |
3414 |
|
|
3414
|
SODIUM CYANIDE SOLUTION |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
PP31 |
IBC02
|
– |
|
– |
T11
|
TP2 TP13 TP27
|
F-A, S-A
|
Category B
|
SGG6
SG35
|
See entry above. |
3414 |
|
|
3414
|
SODIUM CYANIDE SOLUTION |
6.1
|
–
P
|
III |
223
|
5 L |
E1 |
P001
LP01
|
PP31 |
IBC03
|
– |
|
– |
T7
|
TP2 TP13 TP28
|
F-A, S-A
|
Category A
|
SGG6
SG35
|
See entry above. |
3414 |
|
|
3415
|
SODIUM FLUORIDE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
SG35
|
Colourless liquid. Reacts with acids, evolving hydrogen fluoride, a toxic, irritating and corrosive gas, apparent as white fumes. Toxic if swallowed, by skin contact or by inhalation. |
3415 |
|
|
3416
|
CHLOROACETOPHENONE, LIQUID |
6.1
|
– |
II |
– |
0 |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP13
|
F-A, S-A
|
Category D
SW1
SW2
H2
|
– |
Liquid evolving irritating vapour (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. |
3416 |
|
|
3417
|
XYLYL BROMIDE, SOLID |
6.1
|
– |
II |
– |
0 |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category D
SW2
|
– |
Crystals or powder, evolving irritating vapour (“Tear Gas”). Toxic if swallowed, by skin contact or by inhalation. |
3417 |
|
|
3418
|
2,4-TOLUYLENEDIAMINE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3418 |
|
|
3419
|
BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
White crystalline solid. Melting point: 23°C. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
3419 |
|
|
3420
|
BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
White crystalline solid. Melting point: 28°C. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
3420 |
|
|
3421
|
POTASSIUM HYDROGEN DIFLUORIDE SOLUTION |
8
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category A
SW1
SW2
|
SGG1
SG35
SG36
SG49
|
Decomposed by heat or acids, evolving hydrogen fluoride, a toxic, extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3421 |
|
|
3421
|
POTASSIUM HYDROGEN DIFLUORIDE SOLUTION |
8
|
6.1
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
SW1
SW2
|
SGG1
SG35
SG36
SG49
|
See entry above. |
3421 |
|
|
3422
|
POTASSIUM FLUORIDE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
SG35
|
Decomposed by acids, evolving hydrogen fluoride, an irritating and corrosive gas. Toxic if swallowed, by skin contact or by inhalation. |
3422 |
|
| △ |
3423
|
TETRAMETHYLAMMONIUM HYDROXIDE, SOLID |
6.1
|
8
|
I |
279
409
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-B
|
Category A
|
SGG2
SGG18
SG35
|
Very soluble in water with a strong ammonia-like odour. Highly toxic if swallowed, by skin contact or by dust inhalation. When heated emits toxic fumes of nitrogen and ammonia. Corrosive to metals and tissue. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
3423 |
△ |
|
3424
|
AMMONIUM DINITRO-o-CRESOLATE SOLUTION |
6.1
|
–
P
|
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category B
|
SGG2
SG15
SG16
SG30
SG63
|
The commercial product is a 50% suspension in water. May support combustion and burn without oxygen. When involved in a fire, evolves toxic fumes. Forms extremely sensitive explosive compounds with lead, silver or other heavy metals and their compounds. Toxic if swallowed, by skin contact or by inhalation. |
3424 |
|
|
3424
|
AMMONIUM DINITRO-o-CRESOLATE SOLUTION |
6.1
|
–
P
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
SGG2
SG15
SG16
SG30
SG63
|
See entry above. |
3424 |
|
|
3425
|
BROMOACETIC ACID, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
Colourless, deliquescent crystals. Melting point: 51°C. Corrosive to most metals. Harmful if swallowed. Causes burns to eyes and skin. |
3425 |
|
|
3426
|
ACRYLAMIDE SOLUTION |
6.1
|
– |
III |
223
|
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
SW1
H2
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3426 |
|
|
3427
|
CHLOROBENZYL CHLORIDES, SOLID |
6.1
|
–
P
|
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
|
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Colourless crystalline solid. Melting point: 29°C. Immiscible with or insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3427 |
|
|
3428
|
3-CHLORO−4-METHYLPHENYL ISOCYANATE, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
SW2
|
– |
Colourless solid with a pungent odour. Melting point: 23°C. Insoluble in water. Reacts with water, evolving carbon dioxide. Toxic if swallowed, by skin contact or by inhalation. Irritating to skin, eyes and mucous membranes. |
3428 |
|
|
3429
|
CHLOROTOLUIDINES, LIQUID |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Brown liquid. Toxic if swallowed, by skin contact or by inhalation. |
3429 |
|
|
3430
|
XYLENOLS, LIQUID |
6.1
|
– |
II |
– |
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-A
|
Category A
|
– |
The commercial products are liquids with a pungent tar odour. Toxic if swallowed, by skin contact or by inhalation. |
3430 |
|
|
3431
|
NITROBENZOTRIFLUORIDES, SOLID |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Low melting point (31°C to 32°C) solids with an aromatic odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3431 |
|
|
3432
|
POLYCHLORINATED BIPHENYLS, SOLID |
9
|
–
P
|
II |
305
958
|
1 kg |
E2 |
P906
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SG50
|
Solids with perceptible odour. Insoluble in water. Harmful by ingestion or by skin contact. If spilled, can be a persistent hazard to the environment. This entry also covers articles, such as rags, cotton waste, clothing or sawdust, containing polychlorinated biphenyls where no free visible liquid is present. |
3432 |
|
|
3434
|
NITROCRESOLS, LIQUID |
6.1
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-A
|
Category A
|
– |
Slightly miscible in water. Toxic if swallowed, by skin contact or by inhalation. |
3434 |
|
|
3436
|
HEXAFLUOROACETONE HYDRATE, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
SW2
|
– |
This entry covers solid hydrate and hexafluoroacetone. Melting point of the pure substance: 23°C. Toxic if swallowed, by skin contact or by inhalation. |
3436 |
|
|
3437
|
CHLOROCRESOLS, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW1
H2
|
– |
White or pink crystals with a phenol-like odour. Melting point: 45°C to 68°C. Slightly soluble in water. Decomposes when heated, evolving extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. |
3437 |
|
|
3438
|
alpha-METHYLBENZYL ALCOHOL, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Slightly soluble in water. Melting point: 21°C (pure substance). Toxic if swallowed, by skin contact or by inhalation. |
3438 |
|
|
3439
|
NITRILES, SOLID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
SG35
|
Solid, evolving toxic vapours. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3439 |
|
|
3439
|
NITRILES, SOLID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
SG35
|
See entry above. |
3439 |
|
|
3439
|
NITRILES, SOLID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SG35
|
See entry above. |
3439 |
|
|
3440
|
SELENIUM COMPOUND, LIQUID, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP7
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3440 |
|
|
3440
|
SELENIUM COMPOUND, LIQUID, N.O.S. |
6.1
|
– |
II |
274
|
100 mL |
E4 |
P001
|
– |
IBC02
|
– |
|
– |
T11
|
TP2 TP7
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3440 |
|
|
3440
|
SELENIUM COMPOUND, LIQUID, N.O.S. |
6.1
|
– |
III |
223
274
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T7
|
TP1 TP28
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3440 |
|
|
3441
|
CHLORODINITROBENZENES, SOLID |
6.1
|
–
P
|
II |
279
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SG15
|
Crystals. Melting point: 27°C to 53°C. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. |
3441 |
|
|
3442
|
DICHLOROANILINES, SOLID |
6.1
|
–
P
|
II |
279
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
SW2
|
– |
Solid with a penetrating odour. Liquid mixtures of various isomers of dichloroanilines, some of which in the pure state may be solid, with a melting point varying from 24°C to 72°C. Toxic if swallowed, by skin contact or by inhalation. |
3442 |
|
|
3443
|
DINITROBENZENES, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
SG15
|
May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. |
3443 |
|
|
3444
|
NICOTINE HYDROCHLORIDE, SOLID |
6.1
|
– |
II |
43
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Deliquescent crystals or solids or pastes. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3444 |
|
|
3445
|
NICOTINE SULPHATE, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Solid or paste. Soluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3445 |
|
|
3446
|
NITROTOLUENES, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellow solid. Melting point: para-NITROTOLUENE: 52°C to 54°C. Toxic if swallowed, by skin contact or by inhalation. |
3446 |
|
|
3447
|
NITROXYLENES, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellow solid. Melting points: 4-NITRO−2-XYLENE: 29°C to 31°C, 5-NITRO−3-XYLENE: 72°C to 74°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3447 |
|
|
3448
|
TEAR GAS SUBSTANCE, SOLID, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E0 |
P002
|
PP31 |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category D
SW2
|
– |
“Tear gas substance” is a generic term for substances which, in minute quantities dispersed in air, cause extreme eye irritation and profuse tears. Toxic if swallowed, by skin contact or by inhalation. |
3448 |
|
|
3448
|
TEAR GAS SUBSTANCE, SOLID, N.O.S. |
6.1
|
– |
II |
274
|
0 |
E0 |
P002
|
PP31 |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category D
SW2
|
– |
See entry above. |
3448 |
|
|
3449
|
BROMOBENZYL CYANIDES, SOLID |
6.1
|
– |
I |
138
|
0 |
E5 |
P002
|
PP31 |
– |
– |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category D
SW1
SW2
H2
|
SGG6
SG35
|
Volatile, yellow crystals evolving irritating vapours (“Tear Gas”). Melting point: meta-BROMOBENZYL CYANIDE 25°C. Highly toxic if swallowed, by skin contact or by inhalation. |
3449 |
|
|
3450
|
DIPHENYLCHLOROARSINE, SOLID |
6.1
|
–
P
|
I |
– |
0 |
E0 |
P002
|
PP31 |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category D
SW2
|
– |
When pure, volatile, colourless crystals evolving an irritating vapour (“Tear Gas”). Melting point: 41°C. Highly toxic if swallowed, by skin contact or by inhalation. |
3450 |
|
|
3451
|
TOLUIDINES, SOLID |
6.1
|
–
P
|
II |
279
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
para-TOLUIDINE is solid in pure form, with a melting point of approximately 45°C. Toxic if swallowed, by skin contact or by inhalation. |
3451 |
|
|
3452
|
XYLIDINES, SOLID |
6.1
|
– |
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
3,4-Dimethylaniline is a solid, which has a melting point of 47°C. Toxic if swallowed, by skin contact or by dust inhalation. |
3452 |
|
|
3453
|
PHOSPHORIC ACID, SOLID |
8
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category A
|
SGG1
SG36
SG49
|
Very deliquescent, crystalline solid. Melting point: 42°C. Soluble in water. Mildly corrosive to most metals. |
3453 |
|
|
3454
|
DINITROTOLUENES, SOLID |
6.1
|
–
P
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category A
|
– |
Yellow crystals or flakes, insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3454 |
|
|
3455
|
CRESOLS, SOLID |
6.1
|
8
|
II |
– |
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category B
|
– |
Light yellow solid. Soluble in water. Melting points of CRESOLS: ortho-CRESOL: 30°C, para-CRESOL: 35°C. Toxic if swallowed, by skin contact or by inhalation. Cause burns to skin, eyes and mucous membranes. |
3455 |
|
|
3456
|
NITROSYLSULPHURIC ACID, SOLID |
8
|
– |
II |
– |
1 kg |
E2 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-B
|
Category D
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Crystalline solid. Oxidant which may cause fire with organic materials (such as wood, straw, etc.). When involved in a fire, evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
3456 |
|
|
3457
|
CHLORONITROTOLUENES, SOLID |
6.1
|
–
P
|
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
SG6
SG8
SG10
SG12
|
Melting range 20°C to 40°C. Insoluble in water. Oxidizing substance which may explode or burn fiercely when in contact with organic materials. Toxic if swallowed, by skin contact or by inhalation. |
3457 |
|
|
3458
|
NITROANISOLES, SOLID |
6.1
|
– |
III |
279
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Light reddish or amber crystals. Melting points: 38°C to 54°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3458 |
|
|
3459
|
NITROBROMOBENZENES, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Colourless to pale yellow crystals which may liquefy under transport conditions. Melting points: 1-BROMO−2-NITROBENZENE: 43°C. 1-BROMO−4-NITROBENZENE: 127°C. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3459 |
|
|
3460
|
N-ETHYLBENZYLTOLUIDINES, SOLID |
6.1
|
– |
III |
– |
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
Solid which may liquefy under transport conditions. Strong odour. Insoluble in water. Toxic if swallowed, by skin contact or by inhalation. |
3460 |
|
|
3462
|
TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. |
6.1
|
– |
I |
210
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxins from plant, animal or bacterial sources which contain infectious substances or toxins that are contained in infectious substances should be classified in class 6.2. Toxic if swallowed, by skin contact or by inhalation. |
3462 |
|
|
3462
|
TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. |
6.1
|
– |
II |
210
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3462 |
|
|
3462
|
TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. |
6.1
|
– |
III |
210
223
274
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3462 |
|
|
3463
|
PROPIONIC ACID, with not less than 90% acid by mass |
8
|
3
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-C
|
Category A
|
SGG1
SG36
SG49
|
Colourless flammable liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Burns skin. Vapours irritate mucous membranes. Pure PROPIONIC ACID: flashpoint 50°C c.c. |
3463 |
|
|
3464
|
ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. |
6.1
|
– |
I |
43
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3464 |
|
|
3464
|
ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. |
6.1
|
– |
II |
43
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3464 |
|
|
3464
|
ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. |
6.1
|
– |
III |
43
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3464 |
|
|
3465
|
ORGANOARSENIC COMPOUND, SOLID, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3465 |
|
|
3465
|
ORGANOARSENIC COMPOUND, SOLID, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3465 |
|
|
3465
|
ORGANOARSENIC COMPOUND, SOLID, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3465 |
|
|
3466
|
METAL CARBONYLS, SOLID, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category D
SW2
|
– |
Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. |
3466 |
|
|
3466
|
METAL CARBONYLS, SOLID, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category D
SW2
|
– |
See entry above. |
3466 |
|
|
3466
|
METAL CARBONYLS, SOLID, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category D
SW2
|
– |
See entry above. |
3466 |
|
|
3467
|
ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. |
6.1
|
– |
I |
274
|
0 |
E5 |
P002
|
– |
IBC07
|
B1 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category B
|
– |
Toxic if swallowed, by skin contact or by inhalation. |
3467 |
|
|
3467
|
ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. |
6.1
|
– |
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-A
|
Category B
|
– |
See entry above. |
3467 |
|
|
3467
|
ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. |
6.1
|
– |
III |
223
274
|
5 kg |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-A
|
Category A
|
– |
See entry above. |
3467 |
|
|
3468
|
HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT |
2.1
|
– |
– |
321
356
|
0 |
E0 |
P205
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
|
– |
Article containing flammable odourless gas, which is much lighter than air. |
3468 |
|
|
3469
|
PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) |
3
|
8
|
I |
163
367
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T11
|
TP2 TP7
|
F-E, S-C
|
Category E
SW2
|
– |
Miscibility with water depends upon the composition. Corrosive contents cause burns to skin, eyes and mucous membranes. |
3469 |
|
|
3469
|
PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) |
3
|
8
|
II |
163
367
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP8 TP28
|
F-E, S-C
|
Category B
SW2
|
– |
See entry above. |
3469 |
|
|
3469
|
PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) |
3
|
8
|
III |
163
223
367
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1 TP29
|
F-E, S-C
|
Category A
SW2
|
– |
See entry above. |
3469 |
|
|
3470
|
PAINT, CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including paint thinning or reducing compound) |
8
|
3
|
II |
163
367
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2 TP8 TP28
|
F-E, S-C
|
Category B
SW2
|
– |
Miscibility with water depends upon the composition. Corrosive contents cause burns to skin, eyes and mucous membranes. |
3470 |
|
|
3471
|
HYDROGENDIFLUORIDES SOLUTION, N.O.S. |
8
|
6.1
|
II |
– |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category A
SW1
SW2
|
SG35
|
When involved in a fire or in contact with acids, evolves hydrogen fluoride, an extremely irritating and corrosive gas. Corrosive to glass, other siliceous materials and most metals. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3471 |
|
|
3471
|
HYDROGENDIFLUORIDES SOLUTION, N.O.S. |
8
|
6.1
|
III |
223
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
SW1
SW2
|
SG35
|
See entry above. |
3471 |
|
|
3472
|
CROTONIC ACID, LIQUID |
8
|
– |
III |
– |
5 L |
E1 |
P001
LP01
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-A, S-B
|
Category A
SW1
H2
|
SGG1
SG36
SG49
|
Causes burns to skin, eyes and mucous membranes. |
3472 |
|
|
3473
|
FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT containing flammable liquids |
3
|
– |
– |
328
|
1 L |
E0 |
P004
|
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category A
|
– |
Fuel cell cartridges containing flammable liquids including methanol or methanol/water solutions. Fuel cell cartridges may also be shipped in, or packed with, equipment. |
3473 |
|
|
3474
|
1-HYDROXYBENZOTRIAZOLE MONOHYDRATE |
4.1
|
– |
I |
– |
0 |
E0 |
P406
|
PP48 |
– |
– |
|
– |
– |
– |
F-B, S-J
|
Category D
|
SG7
SG30
|
Desensitized explosive. White to light beige powder. Explosive and sensitive to friction in the dry state. When involved in a fire, evolves toxic fumes; in closed compartments these fumes may form an explosive mixture with air. May form extremely sensitive compounds with heavy metals or their salts. |
3474 |
|
|
3475
|
ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10% ethanol |
3
|
– |
II |
333 |
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T4
|
TP1
|
F-E, S-E
|
Category E
|
– |
Colourless, volatile liquids. Miscibility with water depends on the composition. |
3475 |
|
|
3476
|
FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing water-reactive substances |
4.3
|
– |
– |
328
334
|
500 mL or 500 g |
E0 |
P004
|
– |
– |
– |
|
– |
– |
– |
F-G, S-P
|
Category A
H1
|
SG26
|
Fuel cell cartridges containing water-reactive substances may also be shipped in, or packed with, equipment. |
3476 |
|
|
3477
|
FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing corrosive substances |
8
|
– |
– |
328
334
|
1 L or 1 kg |
E0 |
P004
|
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
Category A
|
– |
Fuel cell cartridges containing corrosive substances may also be shipped in, or packed with, equipment. |
3477 |
|
|
3478
|
FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas |
2.1
|
– |
– |
328
338
|
120 mL |
E0 |
P004
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category B
|
– |
Fuel cell cartridges containing butane or other flammable liquefied gas may also be shipped in, or packed with, equipment. |
3478 |
|
|
3479
|
FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride |
2.1
|
– |
– |
328
339
|
120 mL |
E0 |
P004
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category B
|
– |
Fuel cell cartridges containing hydrogen, butane or other flammable odourless gas, which is much lighter than air, may also be shipped in or packed with equipment. |
3479 |
|
| △ |
3480
|
LITHIUM ION BATTERIES (including lithium ion polymer batteries) |
9
|
– |
– |
188
230
310
348
376
377
384
387
|
0 |
E0 |
P903
P908
P909
P910
P911
LP903
LP904
LP905
LP906
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
SW19
|
– |
Electrical batteries containing lithium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. |
3480 |
△ |
| △ |
3481
|
LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) |
9
|
– |
– |
188
230
310
348
360
376
377
384
387
390
|
0 |
E0 |
P903
P908
P909
P910
P911
LP903
LP904
LP905
LP906
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
SW19
|
– |
Electrical batteries containing lithium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. |
3481 |
△ |
| △ |
3482
|
ALKALI METAL DISPERSION, FLAMMABLE or ALKALINE EARTH METAL DISPERSION, FLAMMABLE |
4.3
|
3
|
I |
182
183
|
0 |
E0 |
P402
|
PP31 |
– |
– |
|
– |
T13
|
TP2 TP7 TP42
|
F-G, S-N
|
Category D
H1
|
SG26
SG35
|
Finely divided alkali or alkaline earth metal suspended in a flammable liquid. Reacts violently with moisture, water or acids, evolving hydrogen, which may be ignited by the heat of the reaction. |
3482 |
△ |
|
3483
|
MOTOR FUEL ANTI-KNOCK MIXTURE, FLAMMABLE |
6.1
|
3
P
|
I |
– |
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-D
|
Category D
SW1
SW2
|
SGG7
SGG9
|
Volatile flammable liquids evolving toxic vapour. Mixture of tetraethyllead or tetramethyllead with ethylene dibromide and ethylene dichloride. Insoluble in water. Highly toxic if swallowed, by skin contact or by inhalation. |
3483 |
|
|
3484
|
HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE with more than 37% hydrazine, by mass |
8
|
3
6.1
|
I |
– |
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T10
|
TP2 TP13
|
F-E, S-C
|
Category D
SW2
|
SGG18
SG5
SG8
SG35
|
Colourless flammable liquid. Powerful reducing agent, burns readily. Toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. |
3484 |
|
|
3485
|
CALCIUM HYPOCHLORITE, DRY, CORROSIVE or CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) |
5.1
|
8
P
|
II |
314
|
1 kg |
E2 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White or yellowish corrosive solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
3485 |
|
|
3486
|
CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 10% but not more than 39% available chlorine |
5.1
|
8
P
|
III |
314
|
5 kg |
E1 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White or yellowish corrosive solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
3486 |
|
|
3487
|
CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water |
5.1
|
8
P
|
II |
314
322
|
1 kg |
E2 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
White or yellowish corrosive solid (powder, granules or tablets) with chlorine-like odour. Soluble in water. May cause fire in contact with organic material or ammonium compounds. Substances are liable to exothermic decomposition at elevated temperatures. This condition may lead to fire or explosion. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds). Liable to heat slowly. Reacts with acids, evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous membranes. |
3487 |
|
|
3487
|
CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water |
5.1
|
8
P
|
III |
223
314
|
5 kg |
E1 |
P002
|
PP85 |
– |
– |
|
– |
– |
– |
F-H, S-Q
|
Category D
SW1
SW11
|
SGG8
SG35
SG38
SG49
SG53
SG60
|
See entry above. |
3487 |
|
|
3488
|
TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 mL/m3 and saturated vapour concentration greater than or equal to 500 LC50
|
6.1
|
3
8
|
I |
274
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
SG5
SG8
|
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable and corrosive. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3488 |
|
|
3489
|
TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 mL/m3 and saturated vapour concentration greater than or equal to 10 LC50
|
6.1
|
3
8
|
I |
274
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-E, S-D
|
Category D
SW2
|
SG5
SG8
|
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being flammable and corrosive. Highly toxic if swallowed, by skin contact or by inhalation. Causes burns to skin, eyes and mucous membranes. |
3489 |
|
|
3490
|
TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 mL/m3 and saturated vapour concentration greater than or equal to 500 LC50
|
6.1
|
4.3
3
|
I |
274
|
0 |
E0 |
P601
|
– |
– |
– |
|
– |
T22
|
TP2 TP13
|
F-G, S-N
|
Category D
SW2
H1
|
SG5
SG13
SG25
SG26
|
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. |
3490 |
|
|
3491
|
TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 mL/m3 and saturated vapour concentration greater than or equal to 10 LC50
|
6.1
|
4.3
3
|
I |
274
|
0 |
E0 |
P602
|
– |
– |
– |
|
– |
T20
|
TP2 TP13
|
F-G, S-N
|
Category D
SW2
H1
|
SG5
SG13
SG25
SG26
|
A variety of toxic liquids which present a highly toxic inhalation hazard as well as being water-reactive and flammable. Highly toxic if swallowed, by skin contact or by inhalation. |
3491 |
|
|
3494
|
PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC |
3
|
6.1
|
I |
343
|
0 |
E0 |
P001
|
– |
– |
– |
|
– |
T14
|
TP2 TP13
|
F-E, S-E
|
Category D
SW2
|
– |
Immiscible with water. Evolves hydrogen sulphide, which is a flammable, toxic gas with a foul odour, heavier than air (1.2). Toxic if swallowed, by skin contact or by inhalation. |
3494 |
|
|
3494
|
PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC |
3
|
6.1
|
II |
343
|
1 L |
E2 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-E, S-E
|
Category D
SW2
|
– |
See entry above. |
3494 |
|
|
3494
|
PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC |
3
|
6.1
|
III |
343
|
5 L |
E1 |
P001
|
– |
IBC03
|
– |
|
– |
T4
|
TP1
|
F-E, S-E
|
Category C
SW2
|
– |
See entry above. |
3494 |
|
|
3495
|
IODINE |
8
|
6.1
|
III |
279
|
5 kg |
E1 |
P002
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-B
|
Category B
SW2
|
SG37
|
Bluish-black solid with a metallic lustre and a pungent odour. Melting point: 114°C. Below its melting point, may evolve vapours which are irritating to skin, eyes and mucous membranes. Slightly soluble in water but soluble in most organic solvents. Corrosive to most metals. |
3495 |
|
|
3496
|
BATTERIES, NICKEL-METAL HYDRIDE |
9
|
– |
– |
117
963
|
0 |
E0 |
See SP963
|
– |
IBC08
|
– |
|
– |
– |
– |
F-A, S-I
|
Category A
SW1
|
– |
Nickel-metal hydride cells or batteries packed with or contained in equipment and nickel-metal hydride button cells are not subject to the provisions of this Code. |
3496 |
|
|
3497
|
KRILL MEAL |
4.2
|
– |
II |
300 |
0 |
E2 |
P410
|
– |
IBC06
|
B21 |
|
– |
T3
|
TP33
|
F-A, S-J
|
Category B
SW27
|
SG65
|
Pink to red meal derived from Krill which is a shrimp-like marine organism. Medium odour, which may affect other sensitive cargo. Liable to self-heating. Naturally rich in anti-oxidants, which lessen the risk of spontaneous heating. |
3497 |
|
|
3497
|
KRILL MEAL |
4.2
|
– |
III |
223
300
|
0 |
E1 |
P002
LP02
|
– |
IBC08
|
B3 |
|
– |
T1
|
TP33
|
F-A, S-J
|
Category A
|
– |
See entry above. |
3497 |
|
|
3498
|
IODINE MONOCHLORIDE, LIQUID |
8
|
– |
II |
– |
1 L |
E0 |
P001
|
– |
IBC02
|
– |
|
– |
T7
|
TP2
|
F-A, S-B
|
Category D
SW2
|
SGG1
SG6
SG16
SG17
SG19
SG36
SG49
|
Red Liquid. Reacts violently with water, evolving irritating and corrosive gases apparent as white fumes. Powerful oxidant: may cause fire in contact with organic materials such as wood, cotton or straw. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes. |
3498 |
|
|
3499
|
CAPACITOR, ELECTRIC DOUBLE LAYER (with an energy storage capacity greater than 0.3 Wh) |
9
|
– |
– |
361
|
0 |
E0 |
P003
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
|
– |
Articles intended to store energy containing a non-dangerous activated carbon and an electrolyte. Electric double layer capacitors installed in equipment may be transported in a charged state. |
3499 |
|
|
3500
|
CHEMICAL UNDER PRESSURE, N.O.S. |
2.2
|
– |
– |
274
362
|
0 |
E0 |
P206
|
PP97 |
– |
– |
|
– |
T50
|
TP4 TP40
|
F-C, S-V
|
Category B
|
– |
Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. |
3500 |
|
|
3501
|
CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. |
2.1
|
– |
– |
274
362
|
0 |
E0 |
P206
|
PP89 |
– |
– |
|
– |
T50
|
TP4 TP40
|
F-D, S-U
|
Category D
SW2
|
– |
Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. |
3501 |
|
|
3502
|
CHEMICAL UNDER PRESSURE, TOXIC, N.O.S. |
2.2
|
6.1
|
– |
274
362
|
0 |
E0 |
P206
|
PP89 |
– |
– |
|
– |
T50
|
TP4 TP40
|
F-C, S-V
|
Category D
SW2
|
– |
Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. |
3502 |
|
|
3503
|
CHEMICAL UNDER PRESSURE, CORROSIVE, N.O.S. |
2.2
|
8
|
– |
274
362
|
0 |
E0 |
P206
|
PP89 |
– |
– |
|
– |
T50
|
TP4 TP40
|
F-C, S-V
|
Category D
SW2
|
– |
Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. |
3503 |
|
|
3504
|
CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. |
2.1
|
6.1
|
– |
274
362
|
0 |
E0 |
P206
|
PP89 |
– |
– |
|
– |
T50
|
TP4 TP40
|
F-D, S-U
|
Category D
SW2
|
– |
Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. |
3504 |
|
|
3505
|
CHEMICAL UNDER PRESSURE, FLAMMABLE, CORROSIVE, N.O.S. |
2.1
|
8
|
– |
274
362
|
0 |
E0 |
P206
|
PP89 |
– |
|
|
– |
T50
|
TP4 TP40
|
F-D, S-U
|
Category D
SW2
|
– |
Liquids, pastes or powders, pressurized with a propellant which meets the definition of a gas. |
3505 |
|
| △ |
3506
|
MERCURY CONTAINED IN MANUFACTURED ARTICLES |
8
|
6.1
|
– |
366
|
5 kg |
E0 |
P003
|
PP90 |
|
|
|
– |
– |
– |
F-A, S-B
|
Category B
SW2
|
SG24
|
Mercury (UN 2809) is highly corrosive to aluminium. Carriage should be prohibited in hovercraft and other ships constructed with aluminium. |
3506 |
△ |
|
3507
|
URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, less than 0.1 kg per package, non-fissile or fissile-excepted |
6.1
|
7/8
|
I |
317
369
|
0 |
E0 |
P603
|
– |
– |
– |
|
– |
– |
– |
F-I, S-S
|
Category A
SW12
|
SG77
|
See 1.5.1. |
3507 |
|
|
3508
|
CAPACITOR, ASYMMETRIC (with an energy storage capacity greater than 0.3Wh) |
9
|
– |
– |
372
|
0 |
E0 |
P003
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
|
– |
Articles intended to store energy containing positive and negative electrodes comprised of different materials and an electrolyte. Asymetric capacitors may be transported in a charged state. |
3508 |
|
|
3509
|
PACKAGINGS, DISCARDED, EMPTY, UNCLEANED |
9
|
– |
– |
968
|
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
– |
– |
– |
This entry shall not be used for sea transport. Discarded packaging shall meet the requirements of 4.1.1.11. Discarded packaging means packagings, large packagings or intermediate bulk containers (IBC), or parts thereof, which have contained dangerous goods, other than radioactive material, which are transported for disposal, recycling or recovery of their material, other than reconditioning, repair, routine maintenance, remanufacturing or reuse, and which have been emptied to the extent that only residues of dangerous goods adhering to the packaging parts are present. |
3509 |
|
|
3510
|
ADSORBED GAS, FLAMMABLE, N.O.S. |
2.1
|
– |
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
– |
3510 |
|
|
3511
|
ADSORBED GAS, N.O.S. |
2.2
|
– |
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
– |
3511 |
|
|
3512
|
ADSORBED GAS, TOXIC, N.O.S. |
2.3
|
– |
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
– |
3512 |
|
|
3513
|
ADSORBED GAS, OXIDIZING, N.O.S. |
2.2
|
5.1
|
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
|
– |
– |
3513 |
|
|
3514
|
ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S. |
2.3
|
2.1
|
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
– |
3514 |
|
|
3515
|
ADSORBED GAS, TOXIC, OXIDIZING, N.O.S. |
2.3
|
5.1
|
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
– |
– |
3515 |
|
|
3516
|
ADSORBED GAS, TOXIC, CORROSIVE, N.O.S. |
2.3
|
8
|
– |
274
379
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
– |
3516 |
|
|
3517
|
ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. |
2.3
|
2.1
8
|
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
SG4
SG9
|
– |
3517 |
|
|
3518
|
ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. |
2.3
|
5.1
8
|
– |
274
|
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
– |
3518 |
|
|
3519
|
BORON TRIFLUORIDE, ADSORBED |
2.3
|
8
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass and most metals. Much heavier than air (2.35). Highly irritating to skin, eyes and mucous membranes. |
3519 |
|
|
3520
|
CHLORINE, ADSORBED |
2.3
|
5.1/8
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-W
|
Category D
SW2
|
SG6
SG19
|
Non-flammable, toxic and corrosive yellow gas with a pungent odour. Corrosive to glass and to most metals. Much heavier than air (2.4). Highly irritating to skin, eyes and mucous membranes. Powerful oxidant which may cause fire. |
3520 |
|
|
3521
|
SILICON TETRAFLUORIDE, ADSORBED |
2.3
|
8
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic and corrosive gas with a pungent odour. Corrosive to metals. In moist air, produces hydrogen fluoride. Much heavier than air (3.6). Highly irritating to skin, eyes and mucous membranes. |
3521 |
|
|
3522
|
ARSINE, ADSORBED |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable, toxic, colourless gas with a garlic odour. Explosive limits: 3.9% to 77.8%. Much heavier than air (2.8). |
3522 |
|
|
3523
|
GERMANE, ADSORBED |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable, toxic, colourless gas with a pungent odour. Much heavier than air (2.6). |
3523 |
|
|
3524
|
PHOSPHORUS PENTAFLUORIDE, ADSORBED |
2.3
|
8
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
Category D
SW2
|
– |
Non-flammable, toxic and corrosive gas with an irritating odour. Reacts with water or moist air to produce toxic and corrosive fumes. Corrosive to glass and to most metals. Much heavier than air (4.3). Highly irritating to skin, eyes and mucous membranes. |
3524 |
|
|
3525
|
PHOSPHINE, ADSORBED |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable, toxic, colourless gas with a garlic odour. Ignites spontaneously in air. Heavier than air (1.2). Irritating to skin, eyes and mucous membranes. |
3525 |
|
|
3526
|
HYDROGEN SELENIDE, ADSORBED |
2.3
|
2.1
|
– |
– |
0 |
E0 |
P208
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
Flammable, toxic, colourless gas with a disagreeable odour. Much heavier than air (2.8). Highly irritating to skin, eyes and mucous membranes. |
3526 |
|
|
3527
|
POLYESTER RESIN KIT, solid base material |
4.1
|
– |
II |
236
340
|
5 kg |
See SP340
|
P412
|
– |
– |
– |
|
– |
– |
– |
F-A, S-G
|
Category B
|
– |
Polyester resin kits consist of two components: a base material (flammable solid) and an activator (organic peroxide), each separately packed in an inner packaging. |
3527 |
|
|
3527
|
POLYESTER RESIN KIT, solid base material |
4.1
|
– |
III |
236
340
|
5 kg |
See SP340
|
P412
|
– |
– |
– |
|
– |
– |
– |
F-A, S-G
|
Category B
|
– |
See entry above. |
3527 |
|
|
3528
|
ENGINE, INTERNAL COMBUSTION, FLAMMABLE LIQUID POWERED or ENGINE, FUEL CELL, FLAMMABLE LIQUID POWERED or MACHINERY, INTERNAL COMBUSTION, FLAMMABLE LIQUID POWERED or MACHINERY, FUEL CELL, FLAMMABLE LIQUID POWERED |
3
|
– |
– |
363
972
|
0 |
E0 |
P005
|
– |
– |
– |
|
– |
– |
– |
F-E, S-E
|
Category E
SW29
|
– |
Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems or fuel cells (e.g. combustion engines, generators, compressors, turbines, heating units, etc.). |
3528 |
|
|
3529
|
ENGINE, INTERNAL COMBUSTION, FLAMMABLE GAS POWERED or ENGINE, FUEL CELL, FLAMMABLE GAS POWERED or MACHINERY, INTERNAL COMBUSTION, FLAMMABLE GAS POWERED or MACHINERY, FUEL CELL, FLAMMABLE GAS POWERED |
2.1
|
– |
– |
356
363
972
|
0 |
E0 |
P005
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category E
|
– |
Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems or fuel cells (e.g. combustion engines, generators, compressors, turbines, heating units, etc.). |
3529 |
|
|
3530
|
ENGINE, INTERNAL COMBUSTION or MACHINERY, INTERNAL COMBUSTION |
9
|
–
P
|
– |
363
972
|
0 |
E0 |
P005
|
– |
– |
– |
|
– |
– |
– |
F-A, S-F
|
Category A
|
– |
Types of articles transported under this entry include engines or machinery, powered by fuels classified as dangerous goods via internal combustion systems (e.g. combustion engines, generators, compressors, turbines, heating units, etc.). |
3530 |
|
|
3531
|
POLYMERIZING SUBSTANCE, SOLID, STABILIZED, N.O.S. |
4.1
|
– |
III |
274
386
|
0 |
E0 |
P002
|
PP92 |
IBC07
|
B18 |
|
– |
T7
|
TP4 TP6 TP33
|
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Polymerizes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. |
3531 |
|
|
3532
|
POLYMERIZING SUBSTANCE, LIQUID, STABILIZED, N.O.S. |
4.1
|
– |
III |
274
386
|
0 |
E0 |
P001
|
PP93 |
IBC03
|
B19 |
|
– |
T7
|
TP4 TP6
|
F-J, S-G
|
Category D
SW1
|
SG35
SG36
|
Polymerizes at elevated temperatures or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. |
3532 |
|
|
3533
|
POLYMERIZING SUBSTANCE, SOLID, TEMPERATURE CONTROLLED, N.O.S. |
4.1
|
– |
III |
274
386
|
0 |
E0 |
P002
|
PP92 |
IBC07
|
B18 |
|
– |
T7
|
TP4 TP6 TP33
|
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Polymerizes at temperatures higher than the self-accelerating polymerization temperature or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. Control and emergency temperatures can be found in the transport document as required in 5.4.1.5.5. The temperature must be checked regularly. |
3533 |
|
|
3534
|
POLYMERIZING SUBSTANCE, LIQUID, TEMPERATURE CONTROLLED, N.O.S. |
4.1
|
– |
III |
274
386
|
0 |
E0 |
P001
|
PP93 |
IBC03
|
B19 |
|
– |
T7
|
TP4 TP6
|
F-F, S-K
|
Category D
SW1
SW3
|
SG35
SG36
|
Polymerizes at temperatures higher than the self-accelerating polymerization temperature or in a fire. Burns vigorously. Immiscible with water. Contact with alkalis or acids may cause dangerous polymerization. The products of combustion or self-accelerating polymerization may be toxic by inhalation. Control and emergency temperatures can be found in the transport document as required in 5.4.1.5.5. The temperature must be checked regularly. |
3534 |
|
|
3535
|
TOXIC SOLID, FLAMMABLE, INORGANIC, N.O.S. |
6.1
|
4.1
|
I |
274
|
0 |
E5 |
P002
|
– |
IBC99
|
– |
|
– |
T6
|
TP33
|
F-A, S-G
|
Category B
|
– |
Toxic if swallowed, by skin contact or by dust inhalation. |
3535 |
|
|
3535
|
TOXIC SOLID, FLAMMABLE, INORGANIC, N.O.S. |
6.1
|
4.1
|
II |
274
|
500 g |
E4 |
P002
|
– |
IBC08
|
B4 B21 |
|
– |
T3
|
TP33
|
F-A, S-G
|
Category B
|
– |
See entry above. |
3535 |
|
| △ |
3536
|
LITHIUM BATTERIES INSTALLED IN CARGO TRANSPORT UNIT lithium ion batteries or lithium metal batteries |
9
|
– |
– |
389 |
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category D
SW1
SW2
|
– |
Cargo transport unit containing lithium metal or lithium ion batteries which is designed to serve as mobile power supply unit. |
3536 |
△ |
| △ |
3537
|
ARTICLES CONTAINING FLAMMABLE GAS, N.O.S. |
2.1
|
See 2.0.6.6
|
– |
274
310
391
|
0 |
E0 |
P006
LP03
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
– |
– |
3537 |
△ |
| △ |
3538
|
ARTICLES CONTAINING NON-FLAMMABLE, NON-TOXIC GAS, N.O.S. |
2.2
|
See 2.0.6.6
|
– |
274
310
391
396
|
0 |
E0 |
P006
LP03
|
– |
– |
– |
|
– |
– |
– |
F-C, S-V
|
Category A
|
– |
– |
3538 |
△ |
|
3539
|
ARTICLES CONTAINING TOXIC GAS, N.O.S. |
2.3
|
See 2.0.6.6
|
– |
274
391
|
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
F-C, S-U
|
– |
– |
– |
3539 |
|
| △ |
3540
|
ARTICLES CONTAINING FLAMMABLE LIQUID, N.O.S. |
3
|
See 2.0.6.6 |
– |
274
310
391
|
0 |
E0 |
P006 LP03 |
– |
– |
– |
|
– |
– |
– |
F-E, S-D
|
Category B
|
– |
– |
3540 |
△ |
| △ |
3541
|
ARTICLES CONTAINING FLAMMABLE SOLID, N.O.S. |
4.1
|
See 2.0.6.6 |
– |
274
310
391
|
0 |
E0 |
P006 LP03 |
– |
– |
– |
|
– |
– |
– |
F-A, S-G
|
Category B
|
– |
– |
3541 |
△ |
|
3542
|
ARTICLES CONTAINING A SUBSTANCE LIABLE TO SPONTANEOUS COMBUSTION, N.O.S. |
4.2
|
See 2.0.6.6
|
– |
274
391
|
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
* |
– |
– |
* F-G, S-M for pyrophoric substances, F-A, S-J for self-heating substances |
3542 |
|
|
3543
|
ARTICLES CONTAINING A SUBSTANCE WHICH IN CONTACT WITH WATER EMITS FLAMMABLE GASES, N.O.S. |
4.3
|
See 2.0.6.6
|
– |
274
391
|
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
F-G, S-N
|
– |
– |
– |
3543 |
|
|
3544
|
ARTICLES CONTAINING OXIDIZING SUBSTANCE, N.O.S. |
5.1
|
See 2.0.6.6
|
– |
274
391
|
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
F-A, S-Q
|
– |
– |
– |
3544 |
|
|
3545
|
ARTICLES CONTAINING ORGANIC PEROXIDE, N.O.S. |
5.2
|
See 2.0.6.6
|
– |
274
391
|
0 |
E0 |
– |
– |
– |
– |
|
– |
– |
– |
F-J, S-R
|
– |
– |
– |
3545 |
|
| △ |
3546
|
ARTICLES CONTAINING TOXIC SUBSTANCE, N.O.S. |
6.1
|
See 2.0.6.6
|
– |
274
310
391
|
0 |
E0 |
P006
LP03
|
– |
– |
– |
|
– |
– |
– |
F-A, S-A
|
Category B
SW2 * |
– |
Toxic if swallowed, by skin contact or by dust inhalation. * When competent authority approval is required by SP391, the stowage and handling will be specified by the competent authority. |
3546 |
△ |
| △ |
3547
|
ARTICLES CONTAINING CORROSIVE SUBSTANCE, N.O.S. |
8
|
See 2.0.6.6 |
– |
274
310
391
|
0 |
E0 |
P006 LP03 |
– |
– |
– |
|
– |
– |
– |
F-A, S-B
|
Category B
SW2
|
– |
Causes burns to skin, eyes and mucous membranes. |
3547 |
△ |
| △ |
3548
|
ARTICLES CONTAINING MISCELLANEOUS DANGEROUS GOODS, N.O.S. |
9
|
See 2.0.6.6
|
– |
274
310
391
|
0 |
E0 |
P006
LP03
|
– |
– |
– |
|
– |
– |
– |
F-A, S-P
|
Category A
|
– |
– |
3548 |
△ |
|
3549
|
MEDICAL WASTE, CATEGORY A, AFFECTING HUMANS, solid or MEDICAL WASTE, CATEGORY A, AFFECTING ANIMALS only, solid |
6.2
|
– |
– |
395
975
|
0 |
E0 |
P622
LP622
|
– |
– |
– |
|
– |
– |
– |
F-A, S-T
|
Category E
SW2
H1
H5
|
SG50
|
Waste containing substances which are dangerous to humans and/or animals. |
3549 |
|
|
3550
|
COBALT DIHYDROXIDE POWDER, containing not less than 10% respirable particles |
6.1
|
P
|
I |
– |
0 |
E5 |
P002
|
– |
IBC07
|
B1 B40 |
|
– |
T6
|
TP33
|
F-A, S-A
|
Category D
SW2
|
– |
Pink odourless powder. Toxic by dust inhalation. |
3550 |
|
| ■ |
3551
|
SODIUM ION BATTERIES with organic electrolyte |
9
|
– |
– |
188
230
310
348
376
377
384
400
401
|
0 |
E0 |
P903
P908
P909
P910
P911
LP903
LP904
LP905
LP906
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
SW19
|
– |
Electrical batteries containing sodium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. |
3551 |
■ |
| ■ |
3552
|
SODIUM ION BATTERIES CONTAINED IN EQUIPMENT or SODIUM ION BATTERIES PACKED WITH EQUIPMENT, with organic electrolyte |
9
|
– |
– |
188
230
310
348
376
377
384
400
401
|
0 |
E0 |
P903
P908
P909
P910
P911
LP903
LP904
LP905
LP906
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
SW19
|
– |
Electrical batteries containing sodium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit. |
3552 |
■ |
| ■ |
3553
|
DISILANE |
2.1
|
– |
– |
– |
0 |
E0 |
P200
|
– |
– |
– |
|
– |
– |
– |
F-D, S-U
|
Category D
SW2
|
SG43
SG46
|
Gas that is extremely flammable and spontaneously ignites in air (pyrophoric). Repulsive odour. Slowly decomposes with water. Irritant to mucous membranes and is an asphyxiant. Boiling point −14.3°C. Lighter than air (0.675). |
3553 |
■ |
| ■ |
3554
|
GALLIUM CONTAINED IN MANUFACTURED ARTICLES |
8
|
– |
– |
366
|
5 kg |
E0 |
P003
|
PP90 |
– |
– |
– |
|
– |
– |
F-A, S-B
|
Category B
SW1
|
– |
Gallium (UN 2803) is highly corrosive to aluminium. Carriage should be prohibited in hovercraft and other ships constructed from aluminium. |
3554 |
■ |
| ■ |
3555
|
TRIFLUOROMETHYL-TETRAZOLE-SODIUM SALT IN ACETONE, with not less than 68% acetone, by mass |
3
|
–
|
II |
28
|
0 |
E0 |
P303
|
PP26 |
– |
– |
– |
|
– |
– |
F-E, S-Y
|
Category D
SW1
SW11
H2
H3
|
SG30
|
Desensitized explosive. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals and their salts. |
3555 |
■ |
| ■ |
3556
|
VEHICLE, LITHIUM ION BATTERY POWERED |
9
|
–
|
– |
384
388
405
961
962
|
0 |
E0 |
P912
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
|
– |
This entry applies to vehicles powered by lithium ion batteries with the batteries installed, such as electrically-powered cars, lawn tractors, wheelchairs and other mobility aids. |
3556 |
■ |
| ■ |
3557
|
VEHICLE, LITHIUM METAL BATTERY POWERED |
9
|
–
|
– |
384
388
405
961
962
|
0 |
E0 |
P912
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
|
– |
This entry applies to vehicles powered by lithium metal batteries with the batteries installed, such as electrically-powered cars, lawn tractors, wheelchairs and other mobility aids. |
3557 |
■ |
| ■ |
3558
|
VEHICLE, SODIUM ION BATTERY POWERED |
9
|
–
|
– |
384
388
404
405
961
962
977
|
0 |
E0 |
P912
|
– |
– |
– |
|
– |
– |
– |
F-A, S-I
|
Category A
|
– |
This entry applies to vehicles powered by sodium ion batteries with the batteries installed, such as electrically-powered cars, lawn tractors, wheelchairs and other mobility aids. |
3558 |
■ |
| ■ |
3559
|
FIRE SUPPRESSANT DISPERSING DEVICES |
9
|
–
|
– |
407
|
0 |
E0 |
P902
|
– |
– |
– |
|
– |
– |
– |
F-B, S-X
|
Category A
|
– |
Articles which contain a pyrotechnic substance, which are intended to disperse a fire extinguishing agent (or aerosol) when activated, and which do not contain any other dangerous goods. |
3559 |
■ |
| ■ |
3560
|
TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with not less than 25% tetramethylammonium hydroxide |
6.1
|
8
|
I |
279
408
409
|
0 |
E5 |
P001
|
– |
– |
|
– |
– |
T14
|
TP2
|
F-A, S-B
|
Category D
SW2
|
SGG2
SGG18
SG35
|
Colourless liquid with a strong ammonia-like odour that is miscible with water. Highly toxic if swallowed, by skin contact or by inhalation. Corrosive to metal. When heated emits toxic fumes of nitrogen oxides and ammonia. Causes burns to skin, eyes, and mucous membranes. Reacts violently with acids. |
3560 |
■ |